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Chiheng Dong

Publications and source records attributed to Chiheng Dong.

At least 19 recordsLinked to original sources

Bending-like stress induced by solder joint under uniaxial tensile testing in 2G-HTS tapes: Impact and optimization approach

The reversible stress limit (\mathit{R}_{rev}) of second-generation high-temperature superconducting (2G-HTS) tapes is a critical performance indicator, typically characterized through uniaxial tensile testing. In practice, the accuracy of the measured Rrev value is often compromised by stress concentration induced by the voltage tap solder joint. The present study investigates the underlying interference mechanism using integrated experimental and numerical methods. Mechanistic analysis reveals that under uniaxial tensile loading, the local geometric inhomogeneity introduced by the solder joint induces an external, bending-like stress in the vicinity of the solder joint, transitioning from additional tensile stress in the zone adjacent to the joint to additional compressive stress in the zone remote from it. When the solder joint is attached to the front surface of the tape (the side closer to the superconducting layer), the superconducting layer experiences localized additional tensile stress, triggering premature damage and early \mathit{I}_{c} degradation. Consequently, an optimized back-surface soldering approach is proposed, which positions the superconducting layer in a localized compressive zone. Experimental validation demonstrates that the proposed approach effectively mitigates testing errors for various tape configurations. Notably, for the tape with a copper layer thickness of 5 μm, the measured \mathit{R}_{rev} increased from 546 MPa to 734 MPa, corresponding to a 42% increase, and moved closer to the actual value. The findings provide essential insights for the precision characterization of the electromechanical performances (EMPs) of 2G-HTS tapes.

cond-mat.supr-con

Asymmetric stress engineering of dense dislocations in brittle superconductors for strong vortex pinning

Large lossless currents in high-temperature superconductors (HTS) critically rely on dense defects with suitable size and dimensionality to pin vortices, with dislocations being particularly effective due to their one-dimensional geometry to interact extensively with vortex lines. However, in non-metallic compounds such as HTS with rigid lattices, conventional deformation methods typically lead to catastrophic fracture rather than dislocation-mediated plasticity, making it a persistent challenge to introduce dislocations at high density. Here, we propose an asymmetric stress field strategy using extrusion to directly nucleate a high-density of dislocations in HTS by activating shear-driven lattice slip and twisting under superimposed hydrostatic compression. As demonstrated in iron-based superconductors (IBS), atomic displacements of nearly one angstrom trigger the formation of tilted dislocation lines with a density approaching that of metals. With further structural refinement, these dislocations serve as strong pinning centers that lead to a fivefold enhancement in the current-carrying capacity of IBS at 33 T, along with low anisotropy and a large irreversibility field. This work not only establishes a scalable route to engineer pinning landscapes in HTS, but also offers a generalizable framework for manipulating dislocation structures in rigid crystalline systems.

cond-mat.supr-con

Strengthened proximity effect at grain boundaries to enhance inter-grain supercurrent in Ba1-xKxFe2As2 superconductors

Iron-based superconductors have great potential for high-power applications due to their prominent high-field properties. One of the central issues in enhancing the critical current density of iron-based superconducting wires is to reveal the roles and limitations of grain boundaries in supercurrent transport. Here, we finely tuned the electronic properties of grain boundaries by doping Ba1-xKxFe2As2 superconductors in a wide range (0.25<x<0.598). It is found that the intra-grain Jcintra peaks near x~0.287, while the inter-grain Jcinter has a maximum at about x~0.458. Remarkably, the grain boundary transparency parameter defined as Jcinter/Jcintra rises monotonically with doping. Through detailed microscopic analysis, we suggest that the FeAs segregation phase commonly existing at grain boundaries and the adjacent grains constitute superconductor-normal metal-superconductor (SNS) Josephson junctions which play a key role in transporting supercurrent. A sandwich model based on the proximity effect and the SNS junction is proposed to well interpret our data. It is found that overdoping in superconducting grains largely strengthens the proximity effect and consequently enhances the intergrain supercurrent. Our results will shed new insights and inspirations for improving the application parameters of iron-based superconductors by grain boundary engineering.

cond-mat.supr-con

High-performance Ba1-xKxFe2As2 superconducting tapes with grain texture engineered via a scalable and cost-effective fabrication

Nowadays the development of high-field magnets strongly relies on the performance of superconducting materials. Iron-based superconductors exhibit high upper critical fields and low electromagnetic anisotropy, making them particularly attractive for high-field applications, especially in particle accelerator magnets, nuclear magnetic resonance spectrometers, medical magnetic resonance imaging systems and nuclear fusion reactors. Herein, through an industrially scalable and cost-effective manufacturing strategy, a practical level critical current density up to 1.1x10^5 A/cm2 at 4.2 K in an external magnetic field of 10 T was achieved in Cu/Ag composite sheathed Ba0.6K0.4Fe2As2 superconducting tapes. The preparation strategy combines flat rolling to induce grain texture and a subsequent hot-isostatic-pressing densification. By varying the parameters of rolling, the degree of grain texture was engineered. It is found that the transport properties of the Ba1-xKxFe2As2 tapes can be enhanced by applying a large amount of deformation during rolling, which can be attributed to the improved degree of c-axis texture. Microstructure characterizations on the highest-performance tape demonstrate that the Ba1-xKxFe2As2 phase has a uniform element distribution and small grains with good connectivity. Grain boundary pinning is consequently enhanced as proved by large currents circulating through the sample even at 25 K. Our work proves that Cu/Ag composite sheathed Ba1-xKxFe2As2 superconducting tapes can be a promising competitor for practical high-field applications in terms of the viable, scalable and cost-effective fabrication strategy applied and the high transport properties achieved in this work.

cond-mat.supr-con

Slow Vortex Creep Induced by Strong Grain Boundary Pinning in Advanced Ba122 Superconducting Tapes

We report the temperature, magnetic field and time dependences of magnetization in advanced Ba122 superconducting tapes. The sample exhibits a peculiar vortex creep behavior. Below 10 K, the normalized magnetization relaxation rate S=dln(-M)/dln(t) shows a temperature insensitive plateau with a value comparable to that of the low temperature superconductors, which can be explained within the framework of the collective creep theory. It then enters into a second collective creep regime when the temperature increases. Interestingly, the relaxation rate below 20 K tends to saturate with the increasing field. However, it changes to a power law dependence on field at a higher temperature. A vortex phase diagram composed of the collective and the plastic creep regions is concluded. Benefit from the strong grain boundary pinning, the advanced Ba122 superconducting tape has promising potential to be applied not only in liquid helium but also in liquid hydrogen or at the temperature accessible with cryocoolers.

cond-mat.supr-con

First performance test of 30 mm iron-based superconductor single pancake coil under 24 T background field

The iron-based superconductor (IBS) single pancake coil (SPC) with 30 mm inner diameter was firstly fabricated and tested under 24 T background field. This SPC was successfully made using the 7-filamentary Ba1-xKxFe2As2 (Ba122) tape by wind-and-react method. This IBS coil show the highest Ic value at magnetic field reported so far. For example, the transport critical current of this Ba122 SPC achieved 35 A at 4.2 K and 10 T, which is about half of that of short sample. This indicates that the non-insulation winding process together with the stainless-steel tape is suitable to the iron-based superconductor. Even more encouraging is the fact that the Ic of this SPC is still as high as 26 A under 24 T background field, which is still about 40% of that at zero external magnetic field. These results clearly demonstrate that the iron-based superconductors are very promising for high-field magnet applications.

cond-mat.supr-con

Chemical stability and superconductivity in Ag-sheathed CaKFe4As4 superconducting tapes

Ag-sheathed CaKFe4As4 superconducting tapes have been fabricated via the ex-situ powder-in-tube method. Thermal and X-ray diffraction analyses suggest that the CaKFe4As4 phase is unstable at high temperatures. It decomposes into the CaAgAs phase which reacts strongly with the silver sheath. We therefore sintered the tape at 500C and obtain a transport critical current density Jc(4.2 K, 0 T)~ 2.7x10^4 A/cm2. The pinning potential derived from magnetoresistance measurements is one order of magnitude lower than that of the (Ba/Sr)1-xKxFe2As2 tapes. Combining with the scanning electron microscopy and magneto-optical imaging results, we suggest that bad connectivity between superconducting grains caused by the low sintering temperature is the main factor responsible for the low Jc. However, this system is still a promising candidate for superconducting wires and tapes if we further optimize the post-annealing process to achieve better grain connectivity.

cond-mat.supr-con

Calorimetric evidence for enhancement of homogeneity in high performance Sr1-xKxFe2As2 superconductors

We comparatively studied the critical current density, magnetization and specific heat of the rolled and the hot-pressed Sr1-xKxFe2As2 tapes. The Schottky anomaly that is obvious in the specific heat of the rolled tape disappears in the hot-pressed tape. Moreover, the hot-pressed tape has a higher fraction of superconductivity and a narrower distribution of superconducting transition temperature than the rolled tape. Combined with the magnetization data, we conclude that sintering under high pressure provides a better environment for complete chemical reaction and more homogenous dopant distribution, which is beneficial to the global current of a superconductor.

cond-mat.supr-con

High transport current superconductivity in powder-in-tube Ba0.6K0.4Fe2As2 tapes at 27 tesla

The high upper critical field and low anisotropy of iron-based superconductors make them being particularly attractive for high-field applications. However, the current carrying capability needs to be enhanced by overcoming the weak-link effect between misaligned grains inside wire and tape conductors. Here we demonstrate a high transport critical current density (Jc) reaching 1.5x10^5 A/cm^2 (Ic = 437 A) at 4.2 K and 10 T in Ba0.6K0.4Fe2As2 (Ba-122) tapes prepared by a combination of conventional powder-in-tube method and optimized hot-press technique. The transport Jc measured at 4.2 K under high magnetic fields of 27 T is still on the level of 5.5x10^4 A/cm^2, which is much higher than those of low-temperature superconductors. This is the first report of hot-pressed Ba-122 superconducting tapes and these Jc values are by far the highest ever reported for iron-based superconducting wires and tapes. These high-performance tapes exhibit high degree of c-axis texture of Ba-122 grains and low anisotropy of transport Jc, showing great potential for construction of high-field superconducting magnets.

cond-mat.supr-con

Fabrication and Transport Properties of 100 m Class Sr0.6K0.4Fe2As2 Wires and Pancake Coils

Iron-pnictides are hotly studied since 2008 in the superconducting materials research area, due to their special properties and unclear mechanism. Big achievement has been made in the pnictide research during the past years. For practical uses, pnictide superconductor should be fabricated in a long wire form which can be used for different devices. In this work, 100 m class 7-core Sr0.6K0.4Fe2As2 (Sr122) tapes have been made using the powder-in-tube technique, which is reported for the first time. Clearly, an average Jc of 1.3x10^4 A/cm^2 at 10 T was reached over the 115 meter length, showing a high property and good uniformity of 100 meter level Sr122 tapes. Using the 10 m long Sr122 tapes, two double-pancake coils were fabricated by a wind and reaction technique. No transport current could be measured for the coil made from the mono-filamentary tape. However, transport Ic was obtained in the coil made from the 7-filamentary tape. The factors which affect the superconducting property of the coil were discussed in this work.

cond-mat.supr-con

Vortex pinning and dynamics in high performance Sr0.6K0.4Fe2As2 superconductor

We have studied vortex pinning and dynamics in a Sr0.6K0.4Fe2As2 superconducting tape with critical current density Jc~0.1 MA/cm2 at 4.2 K and 10 T. It is found that grain boundary pinning is dominant in the vortex pinning mechanism. Furthermore, we observe large density of dislocations which can also serve as effective pinning centers. We find that the temperature dependence of critical current density is in agreement with the model of vortices pinned via spatial fluctuation of charge carrier mean free path. Magnetic relaxation measurement indicates that the magnetization depends on time in a logarithmic way. The relaxation rate in the low and intermediate temperature region is small, and it exhibits a weak temperature and field dependence. A crossover from elastic creep to plastic creep regime is observed. Finally, we conclude a vortex phase diagram for the high performance Sr0.6K0.4Fe2As2 superconducting tape.

cond-mat.supr-con

Critical current density and microstructure of iron sheathed multifilamentary Sr1-xKxFe2As2/Ag composite conductors

Iron-based superconductors have been considered to be very promising in high-field applications, for which multifilamentary wire and tape conductors with high mechanical strength are essential. In this work, 7-,19- and 114-filament Sr0.6K0.4Fe2As2 (Sr-122) superconducting wires and tapes with silver as matrix and iron as outer reinforcing sheath were produced by the ex situ powder-in-tube method. The mass densities of Sr-122 phase in 7- and 19-filament conductors were investigated by microhardness characterization, which revealed a positive correlation between hardness and transport critical current density (Jc) in round wires and flat tapes with various thicknesses. For Sr-122/Ag/Fe 114-filament conductors, in which an average cross-sectional filament size smaller than 50 microns was achieved by drawing into round wires of 2.0 mm in diameter, the transport Jc can be significantly enhanced by flat rolling, as for the 7- and 19-filament conductors. The highest transport Jc of the 7-,19- and 114-filament Sr-122/Ag/Fe tapes reached 1.4x10^4, 8.4x10^3 and 6.3x10^3 A cm-2 (4.2 K, 10 T), respectively, showing a Jc degradation with the increase of filament number. This Jc degradation can be ascribed to the sausage effect for filaments in longitudinal direction and the grain refinement in these very fine filaments.

cond-mat.supr-con

Superconductivity and Disorder Effect in TlNi$_2$Se$_{2-x}$S$_x$ crystals

After our first discovery of superconductivity (SC) with $T_C$=3.7 K in TlNi$_2$Se$_2$, we grew successfully a series of TlNi$_2$Se$_{2-x}$S$_x$ (0.0 $\leq$ x $\leq$2.0) single crystals. The measurements of resistivity, susceptibility and specific heat were carried out. We found that SC with $T_C$=2.3 K also emerges in TlNi$_2$S$_2$ crystal, which appears to involve heavy electrons with an effective mass $m^*$=13$\sim$25 $m_b$, as inferred from the normal state electronic specific heat and the upper critical field, $H_{C2}(T)$. It was found that the $T_C$ and superconducting volume fraction in TlNi$_2$Se$_{2-x}$S$_x$ crystals changes with the disorder degree induced by the partial substitution of S for Se, which is characterized by the residual resistivity ratio (\textit{RRR}). The effect of the disorder on SC may provide some information for understanding the mechanism of SC in this new Ni-chalcogenide system.

cond-mat.supr-con

Large transport Jc in Cu-sheathed Sr0.6K0.4Fe2As2 superconducting tape conductors

Copper sheath is the first choice for manufacturing high-Tc superconducting wires and tapes because of its high electrical and thermal conductivities, low cost and good mechanical properties. However, Cu can easily react with superconducting cores, such as BSCCO, MgB2 and pnictides, during high-temperature sintering process and therefore drastically decrease the transport Jc. Here, we report the fabrication of Cu-sheathed Sr1-xKxFe2As2 tapes with superior Jc performance using a simple hot pressing method that is capable of eliminating the lengthy high-temperature sintering required by conventional process. We obtained high-quality Sr1-xKxFe2As2 tapes with processing at 800oC for 30 minutes and measured high Tc and sharp transition. This rapid fabrication method can effectively thwart the diffusion of Cu into polycrystalline Sr-122 core. As a consequence, we achieved high transport Jc of 3.1x10^4 A/cm^2 in 10 T and 2.7x10^4 A/cm^2 in 14 T at 4.2 K. The in-field Jc performance is by far the highest reported for Cu-sheathed high-Tc conductors. Our results demonstrate the potential of Cu sheath for practical application of pnictide wires and tapes.

cond-mat.supr-con

Hot pressing to enhance the transport Jc of Sr0.6K0.4Fe2As2 superconducting tapes

High-performance Sr0.6K0.4Fe2As2 (Sr-122) tapes have been successfully fabricated using hot pressing (HP) process. The effect of HP temperatures (850-925 C) on the c-axis texture, resistivity, Vickers micro-hardness, microstructure and critical current properties has been systematically studied. Taking advantage of high degree of c-axis texture, well grain connectivity and and large concentration of strong-pinning defects, we are able to obtain an excellent Jc of 1.2x10^5 A/cm^2 at 4.2 K and 10 T for Sr-122 tapes. More importantly, the field dependence of Jc turns out to be very weak, such that in 14 T the Jc remains ~1.0x10^5 A/cm^2. These Jc values are the highest ever reported so far for iron-pnictide wires and tapes, achieving the level desired for practical applications. Our results clearly strengthen the position of iron-pnictide conductors as a competitor to the conventional and MgB2 superconductors for high field applications.

cond-mat.supr-con

High critical current density in textured Ba-122/Ag tapes fabricated by scalable rolling process

The industrial manufacturing of the long-length iron-pnictide wires and tapes requires simple and low-cost technology. Although the transport critical current density of the FeAs-122 tapes has already achieved the practical application level, their fabrication procedures are relatively complicated or required specialized instruments. Ag-sheathed Ba0.6K0.4Fe2As2 superconducting tapes were fabricated by the scalable rolling process. At 4.2 K and 10 T, the critical current density Jc has achieved 5.4x10^4 A/cm2. We ascribe the excellent performance to the high purity and homogeneity of the superconducting phase, high density and high c-axis texture of the superconducting core. Our method provides a simple way to scale up the production of the long-length iron-based superconducting tapes with high Jc.

cond-mat.supr-con

Enhancement of transport critical current density of SmFeAsO1-xFx tapes fabricated by an ex-situ powder-in-tube method with a Sn-presintering process

SmFeAsO1-xFx (Sm1111) tapes were prepared by an ex-situ powder-in-tube method with a Sn-presintering process. Scanning electron microscopy revealed apparent difference in microstructure between Sn-presintered tapes and the previously reported polycrystalline Sm1111 bulk, since Sn has reduced FeAs wetting phase and filled the voids between Sm1111 grains. The Sn-presintered tapes showed significant enhanced field dependences of transport Jc compared with Sn-added tapes. A highest transport critical current density (Jc) of 3.45x10^4 A cm-2 at 4.2 K and self-field is achieved. Magneto-optical (MO) imaging further confirmed large and well-distributed global and intergranular Jc in Sn-presintered Sm1111 tapes.

cond-mat.supr-con

Realization of practical level current densities in Sr0.6K0.4Fe2As2 tape conductors for high-field applications

122 type pnictide superconductors are of particular interest for high-field applications because of their large upper critical fields Hc2 (> 100 T), low Hc2 anisotropy r (< 2), and high thin-film critical current densities Jc (> 1 MA/cm2 at 4.2 K). Successful magnet applications require fabrication of polycrystalline superconducting wires that exhibit large in-field Jc, which is limited by poor grain coupling and weak-link behavior at grain boundaries. Here we report our recent achievement in the developing Sr0.6K0.4Fe2As2 tapes with transport Jc up to 0.1 MA/cm2 at 10 T and 4.2 K. This value is by far the highest ever recorded for iron based superconducting wires and has surpassed the threshold for practical application for the first time. The synergy effects of enhanced grain connectivity, alleviation of the weak-link behavior at grain boundaries, and the strong intrinsic pinning characteristics led to the superior Jc performance exhibited in our samples. This advanced Jc result opens up the possibility for iron-pnictide superconducting wires to win the race in high-field magnet applications.

cond-mat.supr-con