Searcharxiv⌕ Search

arXiv subjects

Christian Van den Broeck

Publications and source records attributed to Christian Van den Broeck.

36 records · Page 2Linked to original sources
arXiv2014

Work statistics in stochastically driven systems

We identify the conditions under which a stochastic driving inducing energy changes on a system coupled to a thermal bath can be treated as a work source. When these conditions are met, the work statistics satisfies the Crooks fluctuation theorem traditionally derived for deterministic drivings. We illustrate this fact by calculating and comparing the work statistics for a two-level system driven respectively by a stochastic and a deterministic piecewise constant protocol.

cond-mat.stat-mech↗
arXiv2013

Efficiency at maximum power of a chemical engine

A cyclically operating chemical engine is considered that converts chemical energy into mechanical work. The working fluid is a gas of finite-sized spherical particles interacting through elastic hard collisions. For a generic transport law for particle uptake and release, the efficiency at maximum power $η$ takes the form 1/2+cΔμ+ O(Δμ^2), with 1/2 a universal constant and $Δμ$ the chemical potential difference between the particle reservoirs. The linear coefficient c is zero for engines featuring a so-called left/right symmetry or particle fluxes that are antisymmetric in the applied chemical potential difference. Remarkably, the leading constant in $η$ is non-universal with respect to an exceptional modification of the transport law. For a nonlinear transport model we obtain η= 1/(θ+1), with θ>0 the power of $Δμ$ in the transport equation

physics.chem-ph↗
arXiv2013

Large deviation function and fluctuation theorem for classical particle transport

We analytically evaluate the large deviation function in a simple model of classical particle transfer between two reservoirs. We illustrate how the asymptotic large time regime is reached starting from a special propagating initial condition. We show that the steady state fluctuation theorem holds provided that the distribution of the particle number decays faster than an exponential, implying analyticity of the generating function and a discrete spectrum for its evolution operator.

cond-mat.stat-mech↗
arXiv2012

Stochastically driven single level quantum dot: a nano-scale finite-time thermodynamic machine and its various operational modes

We describe a single-level quantum dot in contact with two leads as a nanoscale finite-time thermodynamic machine. The dot is driven by an external stochastic force that switches its energy between two values. In the isothermal regime, it can operate as a rechargeable battery by generating an electric current against the applied bias in response to the stochastic driving, and re-delivering work in the reverse cycle. This behavior is reminiscent of the Parrondo paradox. If there is a thermal gradient the device can function as a work-generating thermal engine, or as a refrigerator that extracts heat from the cold reservoir via the work input of the stochastic driving. The efficiency of the machine at maximum power output is investigated for each mode of operation, and universal features are identified.

cond-mat.stat-mech↗
arXiv2012

Efficiency of isothermal molecular machines at maximum power

We derive upper and lower bounds for the efficiency of an isothermal molecular machine operating at maximum power. The upper bound is reached when the activated state is close to the fueling or reactant state (Eyring-like), while the lower bound is reached when the activated state is close to the product state (Kramers-like).

cond-mat.stat-mech↗
arXiv2011

Thermodynamics of a stochastic twin elevator

We study the non-equilibrium thermodynamics of a single particle with two available energy levels, in contact with a classical (Maxwell-Boltzmann) or quantum (Bose-Einstein) heat bath. The particle can undergo transitions between the levels via thermal activation or deactivation. The energy levels are alternately raised at a given rate regardless of occupation by the particle, maintaining a fixed energy gap equal to epsilon between them. We explicitly calculate the work, heat and entropy production rates. The efficiency in both the classical and the quantum case goes to a limit between 100% and 50% that depends on the relative rates of particle transitions and level elevation. In the classical problem we explicitly find the large deviation functions for heat, work, and internal energy.

cond-mat.stat-mech↗
arXiv2011

Second law and Landauer principle far from equilibrium

The amount of work that is needed to change the state of a system in contact with a heat bath between specified initial and final nonequilibrium states is at least equal to the corresponding equilibrium free energy difference plus (resp. minus) temperature times the information of the final (resp. the initial) state relative to the corresponding equilibrium distributions.

cond-mat.stat-mech↗
arXiv2010

Efficiency at maximum power of low dissipation Carnot engines

We study the efficiency at maximum power, $η^*$, of engines performing finite-time Carnot cycles between a hot and a cold reservoir at temperatures $T_h$ and $T_c$, respectively. For engines reaching Carnot efficiency $η_C=1-T_c/T_h$ in the reversible limit (long cycle time, zero dissipation), we find in the limit of low dissipation that $η^*$ is bounded from above by $η_C/(2-η_C)$ and from below by $η_C/2$. These bounds are reached when the ratio of the dissipation during the cold and hot isothermal phases tend respectively to zero or infinity. For symmetric dissipation (ratio one) the Curzon-Ahlborn efficiency $η_{CA}=1-\sqrt{T_c/T_h}$ is recovered.

cond-mat.stat-mech↗
arXiv2010

The Three Faces of the Second Law: I. Master Equation Formulation

We propose a new formulation of stochastic thermodynamics for systems subjected to nonequilibrium constraints (i.e. broken detailed balance at steady state) and furthermore driven by external time-dependent forces. A splitting of the second law occurs in this description leading to three second law like relations. The general results are illustrated on specific solvable models. The present paper uses a master equation based approach.

cond-mat.stat-mech↗
arXiv2010

The Three Faces of the Second Law: II. Fokker-Planck Formulation

The total entropy production is the sum of two contributions, the so-called adiabatic and nonadiabatic entropy production, each of which is non-negative. We derive their explicit expressions for continuous Markov processes, discuss their properties and illustrate their behavior on two exactly solvable models.

cond-mat.stat-mech↗
arXiv2010

Three detailed fluctuation theorems

The total entropy production of a trajectory can be split into an adiabatic and a non-adiabatic contribution, deriving respectively from the breaking of detailed balance via nonequilibrium boundary conditions or by external driving. We show that each of them, the total, the adiabatic and the non-adiabatic trajectory entropy, separately satisfies a detailed fluctuation theorem.

cond-mat.stat-mech↗
arXiv2010

Quantum-dot Carnot engine at maximum power

We evaluate the efficiency at maximum power of a quantum-dot Carnot heat engine. The universal value of the coefficients at the linear and quadratic order in the temperature gradient are reproduced. Curzon-Ahlborn efficiency is recovered in the limit of weak dissipation.

cond-mat.stat-mech↗
arXiv2009

Finite time thermodynamics for a single level quantum dot

We investigate the finite time thermodynamics of a single-level fermion system interacting with a thermal reservoir through a tunneling junction. The optimal protocol to extract the maximum work from the system when moving the single energy level between an initial higher value and a final lower value in a finite time is calculated from a quantum master equation. The calculation also yields the optimal protocol to raise the energy level with the expenditure of the least amount of work on the system. The optimal protocol displays discontinuous jumps at the initial and final times.

cond-mat.stat-mech↗
arXiv2009

Entropy production as correlation between system and reservoir

We derive an exact (classical and quantum) expression for the entropy production of a finite system placed in contact with one or several finite reservoirs each of which is initially described by a canonical equilibrium distribution. Whereas the total entropy of system plus reservoirs is conserved, we show that the system entropy production is always positive and is a direct measure of the system-reservoir correlations and/or entanglements. Using an exactly solvable quantum model, we illustrate our novel interpretation of the Second Law in a microscopically reversible finite-size setting, with strong coupling between system and reservoirs. With this model, we also explicitly show the approach of our exact formulation to the standard description of irreversibility in the limit of a large reservoir.

cond-mat.stat-mech↗
arXiv2009

Extracting chemical energy by growing disorder: Efficiency at maximum power

We consider the efficiency of chemical energy extraction from the environment by the growth of a copolymer made of two constituent units in the entropy-driven regime. We show that the thermodynamic nonlinearity associated with the information processing aspect is responsible for a branching of the system properties such as power, speed of growth, entropy production, and efficiency, with varying affinity. The standard linear thermodynamics argument which predicts an efficiency of 1/2 at maximum power is inappropriate because the regime of maximum power is located either outside of the linear regime or on a separate bifurcated branch, and because the usual thermodynamic force is not the natural variable for this optimization.

cond-mat.stat-mech↗
arXiv2009

Universality of efficiency at maximum power

We investigate the efficiency of power generation by thermo-chemical engines. For strong coupling between the particle and heat flows and in the presence of a left-right symmetry in the system, we demonstrate that the efficiency at maximum power displays universality up to quadratic order in the deviation from equilibrium. A maser model is presented to illustrate our argument.

cond-mat.stat-mech↗
arXiv2008

Thermoelectric efficiency at maximum power in a quantum dot

We identify the operational conditions for maximum power of a nanothermoelectric engine consisting of a single quantum level embedded between two leads at different temperatures and chemical potentials. The corresponding thermodynamic efficiency agrees with the Curzon-Ahlborn expression up to quadratic terms in the gradients, supporting the thesis of universality beyond linear response.

cond-mat.stat-mech↗