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Christian Van den Broeck

Publications and source records attributed to Christian Van den Broeck.

At least 19 recordsLinked to original sources

Phase transitions in persistent and run-and-tumble walks

We calculate the large deviation function of the end-to-end distance and the corresponding extension-versus-force relation for (isotropic) random walks, on and off-lattice, with and without persistence, and in any spatial dimension. For off-lattice random walks with persistence, the large deviation function undergoes a first order phase transition in dimension $d> 5$. In the corresponding force-versus-extension relation, the extension becomes independent of the force beyond a critical value. The transition is anticipated in dimensions $d=4$ and $d=5$, where full extension is reached at a finite value of the applied stretching force. Full analytic details are revealed in the run-and-tumble limit. Finally, on-lattice random walks with persistence display a softening phase in dimension $d=3$ and above, preceding the usual stiffening appearing beyond a critical value of the force.

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A continuous-time persistent random walk model for flocking

Random walkers characterized by random positions and random velocities lead to normal diffusion. A random walk was originally proposed by Einstein to model Brownian motion and to demonstrate the existence of atoms and molecules. Such a walker represents an inanimate particle driven by environmental fluctuations. On the other hand, there are many examples of so-called "persistent random walkers", including self-propelled particles that are able to move with almost constant speed while randomly changing their direction of motion. Examples include living entities (ranging from flagellated unicellular organisms to complex animals such as birds and fish), as well as synthetic materials. Here we discuss such persistent non-interacting random walkers as a model for active particles. We also present a model that includes interactions among particles, leading to a transition to flocking, that is, to a net flux where the majority of the particles move in the same direction. Moreover, the model exhibits secondary transitions that lead to clustering and more complex spatially structured states of flocking. We analyze all these transitions in terms of bifurcations using a number of mean field strategies (all to all interaction and advection-reaction equations for the spatially structured states), and compare these results with direct numerical simulations of ensembles of these interacting active particles.

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Stochastic thermodynamics for a periodically driven single-particle pump

We present the stochastic thermodynamic analysis of a time-periodic single particle pump, including explicit results for flux, thermodynamic force, entropy production, work, heat and efficiency. These results are valid far from equilibrium. The deviations from the linear (Onsager) regime are discussed.

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General criterion for harmonicity

Inspired by Kubo-Anderson Markov processes, we introduce a new class of transfer matrices whose largest eigenvalue is determined by a simple explicit algebraic equation. Applications include the free energy calculation for various equilibrium systems and a general criterion for perfect harmonicity, i.e., a free energy that is exactly quadratic in the external field. As an illustration, we construct a "perfect spring", namely a polymer with non-Gaussian, exponentially distributed sub-units which nevertheless remains harmonic until it is fully stretched. This surprising discovery is confirmed by Monte Carlo and Langevin simulations.

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Discrete-time thermodynamic uncertainty relation

We generalize the thermodynamic uncertainty relation, providing an entropic upper bound for average fluxes in time-continuous steady-state systems (Gingrich et al., Phys. Rev. Lett. 116, 120601 (2016)), to time-discrete Markov chains and to systems under time-symmetric, periodic driving.

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Large deviations in Taylor dispersion

We establish a link between the phenomenon of Taylor dispersion and the theory of empirical distributions. Using this connection, we derive, upon applying the theory of large deviations, an alternative and much more precise description of the long-time regime for Taylor dispersion.

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Brownian duet: A novel tale of thermodynamic efficiency

We calculate analytically the stochastic thermodynamic properties of an isothermal Brownian engine driven by a duo of time-periodic forces, including its Onsager coefficients, the stochastic work of each force, and the corresponding stochastic entropy production. We verify the relations between different operational regimes, maximum power, maximum efficiency and minimum dissipation, and reproduce the signature features of the stochastic efficiency. All these results are experimentally tested without adjustable parameters on a colloidal system.

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Power-efficiency-dissipation relations in linear thermodynamics

We derive general relations between maximum power, maximum efficiency, and minimum dissipation regimes from linear irreversible thermodynamics. The relations simplify further in the presence of a particular symmetry of the Onsager matrix, which can be derived from detailed balance. The results are illustrated on a periodically driven system and a three terminal device subject to an external magnetic field.

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Linear stochastic thermodynamics for periodically driven systems

The theory of linear stochastic thermodynamics is developed for periodically driven systems in contact with a single reservoir. Appropriate thermodynamic forces and fluxes are identified, starting from the entropy production for a Markov process. Onsager coefficients are evaluated, the Onsager-Casimir relations are verified, and explicit expressions are given for an expansion in terms of Fourier components. The results are illustrated on a periodically modulated two level system including the optimization of the power output.

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Efficiency of Single Particle Engines

We study the efficiency of a single particle Szilard and Carnot engine. Within a first order correction to the quasi-static limit, the work distribution is found to be Gaussian and the correction factor to average work and efficiency only depends on the piston speed. The stochastic efficiency is studied for both models and the recent findings on efficiency fluctuations are confirmed numerically. Special features are revealed in the zero temperature limit.

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Onsager coefficients in periodically driven systems

We evaluate the Onsager matrix for a system under time-periodic driving by considering all its Fourier components. By application of the second law, we prove that all the fluxes converge to zero in the limit of zero dissipation. Reversible efficiency can never be reached at finite power. The implication for an Onsager matrix, describing reduced fluxes, is that its determinant has to vanish. In the particular case of only two fluxes, the corresponding Onsager matrix becomes symmetric.

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Stochastic Efficiency: Five Case Studies

Stochastic efficiency is evaluated in five case studies: driven Brownian motion, effusion with a thermo-chemical and thermo-velocity gradient, a quantum dot and a model for information to work conversion. The salient features of stochastic efficiency, including the maximum of the large deviation function at the reversible efficiency, are reproduced. The approach to and extrapolation into the asymptotic time regime are documented.

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Universal theory of efficiency fluctuations

Using the fluctuation theorem supplemented with geometric arguments, we derive universal features of the (long-time) efficiency fluctuations for thermal and isothermal machines operating under steady or periodic driving, close or far from equilibrium. In particular, the long-time probability for observing a reversible efficiency in a given engine is identical to that for the same engine working under the time-reversed driving. When the driving is symmetric, this reversible efficiency becomes the least probable.

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The unlikely Carnot efficiency

The efficiency of an heat engine is traditionally defined as the ratio of its average output work over its average input heat. Its highest possible value was discovered by Carnot in 1824 and is a cornerstone concept in thermodynamics. It led to the discovery of the second law and to the definition of the Kelvin temperature scale. Small-scale engines operate in the presence of highly fluctuating input and output energy fluxes. They are therefore much better characterized by fluctuating efficiencies. In this study, using the fluctuation theorem, we identify universal features of efficiency fluctuations. While the standard thermodynamic efficiency is, as expected, the most likely value, we find that the Carnot efficiency is, surprisingly, the least likely in the long time limit. Furthermore the probability distribution for the efficiency assumes a universal scaling form when operating close-to-equilibrium. We illustrate our results analytically and numerically on two model systems.

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Descending from infinity: Convergence of tailed distributions

We investigate the relaxation of long-tailed distributions under stochastic dynamics that do not support such tails. Linear relaxation is found to be a borderline case in which long tails are exponentially suppressed in time but not eliminated. Relaxation stronger than linear suppresses long tails immediately, but may lead to strong transient peaks in the probability distribution. A delta function initial distribution under stronger than linear decay displays not one but two different regimes of diffusive spreading.

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Fluctuation symmetry in a two-state Markov model

We show that the scaled cumulant generating and large deviation function, associated to a two-state Markov process involving two processes, obey a symmetry relation reminiscent of the fluctuation theorem, independent from any conditions on the transition rates. The Legendre transform leading from the scaled cumulant generating function to the large deviation function is performed in an ingenious way, avoiding the sign problem associated to taking a square root. Applications to the theory of random walks and to the stochastic thermodynamics for a quantum dot are presented.

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