arXiv subjects

Chulan Kwon

Publications and source records attributed to Chulan Kwon.

At least 19 recordsLinked to original sources

arXiv2024

Dynamics of a small quantum system open to a bath with thermostat

We investigate dynamics of a small quantum system open to a bath with thermostat. We introduce another bath, called super bath, weakly coupled with the bath to provide it with thermostat, which has either the Lindblad or Redfield type. We treat the interaction between the system and bath via a rigorous perturbation theory. Due to the thermostat, the bath behaves dissipative and stochastic, for which the usual Born-Markov assumption is not needed. We consider a specific example of a harmonic oscillator system, and a photonic bath in a large container, and a super bath of the Caldeira-Legget oscillators distributed on the inner surface of the container. We use the $P$-representation for the total harmonic system. We derive the reduced time-evolution equation for the system by explicitly finding the correlation between the system and bath beyond the product state, that was not obtainable in the previous theory for the system and bath isolated from environment, and marginalizing bath degrees of freedom. Remarkably, the associated dynamic equation for the system density matrix is of the same form as the Redfield master equation with different coefficients depending on thermostat used. We find steady state does not depend on thermostat, but time-dependent state does, that agrees with common expectation. We expect to apply our theory to general systems. Unlike the usual quantum master equations, our reduced dynamics allows investigation for time-dependent protocols and non-equilibrium quantum stochastic dynamics will be investigated in future.

quant-ph↗

arXiv2022

Statistical inference as Green's functions

Statistical inference from data is a foundational task in science. Recently, it has received growing attention for its central role in inference systems of primary interest in data sciences and machine learning. However, the understanding of statistical inference is not that solid while remains as a matter of subjective belief or as the routine procedures once claimed objective. We here show that there is an objective description of statistical inference for long sequence of exchangeable binary random variables, the prototypal stochasticity in theories and applications. A linear differential equation is derived from the identity known as de Finetti's representation theorem, and it turns out that statistical inference is given by the Green's functions. Our finding is an answer to the normative issue of science that pursues the objectivity based on data, and its significance will be far-reaching in most pure and applied fields.

cond-mat.stat-mech↗

arXiv2021

Thermodynamic uncertainty relation for underdamped dynamics driven by time-dependent protocols

The thermodynamic uncertainty relation (TUR) for underdamped dynamics has intriguing problems while its counterpart for overdamped dynamics has recently been derived. Even for the case of steady states, a proper way to match underdamped and overdamped TURs has not been found. We derive the TUR for underdamped systems subject to general time-dependent protocols, that covers steady states, by using the Cram\'{e}r-Rao inequality. We show the resultant TUR to give rise to the inequality of the product of the variance and entropy production. We prove it to approach to the known overdamped result for large viscosity limit. We present three examples to confirm our rigorous result.

cond-mat.stat-mech↗

arXiv2021

Rapid-Prototyping a Brownian Particle in an Active Bath

Particles kicked by external forces to produce mobility distinct from thermal diffusion are an iconic feature of the active matter problem. Here, we map this onto a minimal model for experiment and theory covering the wide time and length scales of usual active matter systems. A particle diffusing in a harmonic potential generated by an optical trap is kicked by programmed forces with time correlation at random intervals following the Poisson process. The model's generic simplicity allows us to find conditions for which displacements are Gaussian (or not), how diffusion is perturbed (or not) by kicks, and quantifying heat dissipation to maintain the non-equilibrium steady state in an active bath. The model reproduces experimental results of tracer mobility in an active bath of swimming algal cells. It can be used as a stochastic dynamic simulator for Brownian objects in various active baths without mechanistic understanding, owing to the generic framework of the protocol.

cond-mat.soft↗

arXiv2019

Non-equilibrium driven by an external torque in the presence of a magnetic field

We investigate a motion of a colloid in a harmonic trap driven out of equilibrium by an external non-conservative force producing a torque in the presence of a uniform magnetic field. We find that steady state exists only for a proper range of parameters such as mass, viscosity coefficient, and stiffness of the harmonic potential, and the magnetic field, which is not observed in the overdamped limit. We derive the existence condition for the steady state. We examine the combined influence of the non-conservative force and the magnetic field on non-equilibrium characteristics such as non-Boltzmann steady-state probability distribution function, probability currents, entropy production, position-velocity correlation, and violation of fluctuation-dissipation relation.

cond-mat.stat-mech↗

arXiv2018

Three heats in strongly coupled system and bath

We investigate three kinds of heat produced in a system and a bath strongly coupled via an interaction Hamiltonian. By studying the energy flows between the system, the bath, and their interaction, we provide rigorous definitions of two types of heat, $Q_{\rm S}$ and $Q_{\rm B}$ from the energy loss of the system and the energy gain of the bath, respectively. This is in contrast to the equivalence of $Q_{\rm S}$ and $Q_{\rm B}$, which is commonly assumed to hold in the weak coupling regime. The bath we consider is equipped with a thermostat which enables it to reach an equilibrium. We identify another kind of heat $Q_{\rm SB}$ from the energy dissipation of the bath into the super bath that provides the thermostat. We derive the fluctuation theorems (FT's) with the system variables and various heats, which are discussed in comparison with the FT for the total entropy production. We take an example of a sliding harmonic potential of a single Brownian particle in a fluid and calculate the three heats in a simplified model. These heats are found to equal on average in the steady state of energy, but show different fluctuations at all times.

cond-mat.stat-mech↗

arXiv2016

Mutual information change in feedback processes driven by measurement

We investigate thermodynamics of feedback processes driven by measurement. Regarding system and memory device as a composite system, mutual information as a measure of correlation between the two constituents contributes to the entropy of the composite system, which makes the generalized total entropy of the joint system and reservoir satisfy the second law of thermodynamics. We investigate the thermodynamics of the Szilard engine for an intermediate period before the completion of cycle. We show the second law to hold resolving the paradox of Maxwell's demon independent of the period taken into account. We also investigate a feedback process to confine a particle excessively within a trap, which is operated by repetitions of feedback in a finite time interval. We derive the stability condition for multi-step feedback and find the condition for confinement below thermal fluctuation in the absence of feedback. The results are found to depend on interval between feedback steps and intensity of feedback protocol, which are expected to be important parameters in real experiments.

cond-mat.stat-mech↗

arXiv2016

Molecular dynamics study on a nonequilibrium motion of a colloidal particle driven by an external torque

We investigate the motion of a colloidal particle driven out of equilibrium by an external torque. We use the molecular dynamics simulation that is alternative to the numerical integration approach based on the Langevin equation and is expected to mimic an experiment more realistically. We choose a heat bath composed of thousands of particles interacting to each other through the Lennard-Jones potential and impose the Langevin thermostat to maintain it in equilibrium. We prepare a single colloidal particle to interact with the particles of the heat bath also by the Lennard-Jones potential while any dissipative force and noise are not employed. We prepare the simulation protocol fit to the overdamped limit in real experiments by increasing the size and mass of the colloidal particle. We study the stochastic properties of the nonequilibrium fluctuations for work and heat produced incessantly in time. We accurately confirm the fluctuation theorem for the work production. We show our results to agree accurately with those from the numerical integration of the Langevin equation.

cond-mat.stat-mech↗

arXiv2016

Information thermodynamics for a multi-feedback process with time delay

We investigate a measurement-feedback process of repeated operations with time delay. During a finite-time interval, measurement on the system is performed and the feedback protocol derived from the measurement outcome is applied with time delay. This protocol is maintained into the next interval until a new protocol from the next measurement is applied. Unlike a feedback process without delay, both memories associated with previous and present measurement outcomes are involved in the system dynamics, which naturally brings forth a joint system described by a system state and two memory states. The thermodynamic second law provides a lower bound for heat flow into a thermal reservoir by the (3-state) Shannon entropy change of the joint system. However, as the feedback protocol depends on memory states sequentially, we can deduce a tighter bound for heat flow by integrating out irrelevant memory states during dynamics. As a simple example, we consider the so-called cold damping feedback process where the velocity of a particle is measured and a dissipative feedback protocol is applied to decelerate the particle. We confirm that the heat flow is well above the tightest bound. We also examine the long-time limit of this feedback process, which turns out to exhibit an interesting instability transition as well as heating by controlling parameters such as measurement errors, time interval, protocol strength, and time delay length. We discuss the underlying mechanism for instability and heating, which might be unavoidable in reality.

cond-mat.stat-mech↗

arXiv2016

Comment on "Exact fluctuation theorem without ensemble quantities"

In a recent work by Cuetara et al. (Phys. Rev. E 89, 052119 (2014)), the authors claimed that if a system is prepared under suitable initial conditions, then the total entropy production (EP) for the system and reservoirs can be expressed in terms of physically measurable quantities. However, the backward protocol used in their work is not time-reversed of the forward protocol so that the quantity obtained from the ratio of the forward and backward path probabilities is neither the total EP nor any measurable quantity. We propose a suitable setup which satisfies their pursuit. We also provide a theoretical background as to what quantity satisfies the fluctuation theorem depending on the intial conditions chosen for the forward and backward processes.

cond-mat.stat-mech↗

arXiv2015

Housekeeping Entropy in Continuous Stochastic Dynamics with Odd-Parity Variables

We investigate the decomposition of the total entropy production in continuous stochastic dynamics when there are odd-parity variables that change their signs under time reversal. The first component of the entropy production, which satisfies the fluctuation theorem, is associated with the usual excess heat that appears during transitions between stationary states. The remaining housekeeping part of the entropy production can be further split into two parts. We show that this decomposition can be achieved in infinitely many ways characterized by a single parameter {\sigma}. For an arbitrary value of {\sigma}, one of the two parts contributing to the housekeeping entropy production satisfies the fluctuation theorem. We show that for a range of {\sigma} values this part can be associated with the breakage of the detailed balance in the steady state, and can be regarded as a continuous version of the corresponding entropy production that has been obtained previously for discrete state variables. The other part of the housekeeping entropy does not satisfy the fluctuation theorem and is related to the parity asymmetry of the stationary state distribution. We discuss our results in connection with the difference between continuous and discrete variable cases especially in the conditions for the detailed balance and the parity symmetry of the stationary state distribution.

cond-mat.stat-mech↗

arXiv2015

Path-dependent Entropy Production

A rigorous derivation of nonequilibrium entropy production via the path-integral formalism is presented. Entropy production is defined as the entropy change piled in a heat reservoir as a result of a nonequilibrium thermodynamic process. It is a central quantity by which various forms of the fluctuation theorem are obtained. The two kinds of the stochastic dynamics are investigated: the Langevin dynamics for an even-parity state and the Brownian motion of a single particle. Mathematical ambiguities in deriving the functional form of the entropy production, which depends on path in state space, are clarified by using a rigorous quantum mechanical approach.

cond-mat.stat-mech↗

arXiv2015

Unconventional entropy production in the presence of momentum-dependent forces

We investigate an unconventional nature of the entropy production (EP) in nonequilibrium systems with odd-parity variables that change signs under time reversal. We consider the Brownian motion of a particle in contact with a heat reservoir, where particle momentum is an odd-parity variable. In the presence of an {\it external} momentum-dependent force, the EP transferred to environment is found {\em not} equivalent to usual reservoir entropy change due to heat transfer. There appears an additional unconventional contribution to the EP, which is crucial for maintaining the non-negativity of the (average) total EP enforced by the thermodynamic second law. A few examples are considered to elucidate the novel nature of the EP. We also discuss detailed balance conditions with a momentum-dependent force.

cond-mat.stat-mech↗

arXiv2015

Overdamped limit and inverse friction expansion for the Brownian motion in an inhomogeneous medium

We revisit the problem of the overdamped (large friction) limit of the Brownian dynamics in an inhomogeneous medium characterized by a position-dependent friction coefficient and a multiplicative noise (local temperature) in one space dimension. Starting from the Kramers equation and analyzing it through the expansion in terms of eigenfunctions of a quantum harmonic oscillator, we derive analytically the corresponding Fokker-Planck equation in the overdamped limit. The result is fully consistent with the previous finding by Sancho, San Miguel, and Dürr \cite{Sanc82}. Our method allows us to generalize the Brinkman's hierarchy, and thus it would be straightforward to obtain higher-order corrections in a systematic inverse friction expansion without any assumption. Our results are confirmed by numerical simulations for simple examples.

cond-mat.stat-mech↗

arXiv2015

Total cost of operating an information engine

We study a two-level system controlled in a discrete feedback loop, modeling both the system and the controller in terms of stochastic Markov processes. We find that the extracted work, which is known to be bounded from above by the mutual information acquired during measurement, has to be compensated by an additional energy supply during the measurement process itself, which is bounded by the same mutual information from below. Our results confirm that the total cost of operating an information engine is in full agreement with the conventional second law of thermodynamics. We also consider the efficiency of the information engine as function of the cycle time and discuss the operating condition for maximal power generation. Moreover, we find that the entropy production of our information engine is maximal for maximal efficiency, in sharp contrast to conventional reversible heat engines.

cond-mat.stat-mech↗

arXiv2014

Heat fluctuations and initial ensembles

Time-integrated quantities such as work and heat increase incessantly in time during nonequilibrium processes near steady states. In the long-time limit, the average values of work and heat become asymptotically equivalent to each other, since they only differ by a finite energy change in average. However, the fluctuation theorem (FT) for the heat is found not to hold with the equilibrium initial ensemble, while the FT for the work holds. This reveals an intriguing effect of everlasting initial memory stored in rare events. We revisit the problem of a Brownian particle in a harmonic potential dragged with a constant velocity, which is in contact with a thermal reservoir. The heat and work fluctuations are investigated with initial Boltzmann ensembles at temperatures generally different from the reservoir temperature. We find that, in the infinite-time limit, the FT for the work is fully recovered for arbitrary initial temperatures, while the heat fluctuations significantly deviate from the FT characteristics except for the infinite initial-temperature limit (a uniform initial ensemble). Furthermore, we succeed in calculating finite-time corrections to the heat and work distributions analytically, using the modified saddle point integral method recently developed by us. Interestingly, we find non-commutativity between the infinite-time limit and the infinite-initial-temperature limit for the probability distribution function (PDF) of the heat.

cond-mat.stat-mech↗

arXiv2013

Modified saddle-point integral near singularity for the large deviation function

Long-time-integrated quantities in stochastic processes, in or out of equilibrium, usually exhibit rare but huge fluctuations. Work or heat production is such a quantity, of which the probability distribution function displays an exponential decay characterized by the large deviation function (LDF). The LDF is often deduced from the cumulant generating function through the inverse Fourier transformation. The saddle-point integration method is a powerful technique to obtain the asymptotic results in the Fourier integral, but a special care should be taken when the saddle point is located near a singularity of the integrand. In this paper, we present a modified saddle-point method to handle such a difficulty efficiently. We investigate the dissipated and injected heat production in equilibration processes with various initial conditions, as an example, where the generating functions contain branch-cut singularities as well as power-law ones. Exploiting the new modified saddle-point integrations, we obtain the leading finite-time corrections for the LDF's, which are confirmed by numerical results.

cond-mat.stat-mech↗

arXiv2013

Multiple dynamic transitions in nonequilibrium work fluctuations

The time-dependent work probability distribution function $P(W)$ is investigated analytically for a diffusing particle trapped by an anisotropic harmonic potential and driven by a nonconservative drift force in two dimensions. We find that the exponential tail shape of $P(W)$ characterizing rare-event probabilities undergoes a sequence of dynamic transitions in time. These remarkable locking-unlocking type transitions result from an intricate interplay between a rotational mode induced by the nonconservative force and an anisotropic decaying mode due to the conservative attractive force. We expect that most of high-dimensional dynamical systems should exhibit similar multiple dynamic transitions.

cond-mat.stat-mech↗