Searcharxiv⌕ Search

arXiv subjects

Chunlei Wang

Publications and source records attributed to Chunlei Wang.

At least 37 records · Page 2Linked to original sources

A unified theory to describe the transition of stable nanobubbles to unstable microbubbles on homogeneous surface

Experiments have not only revealed the remarkably long lifetime of nanobubbles, but also demonstrated the diffusive instability of bubbles above micrometers, thus a full-scale physical understanding on the stability of bubbles is in urgent need. Herein, we develop a model that captures the state transition from the stable nanobubbles to the unstable microbubbles on homogeneous surfaces. The transition explains the typical long lifetime, limited height and small contact angle of surface nanobubbles observed in experiments. The consequent phase diagram shows that the bubble size and gas dissolving saturation determine the dynamic behaviors of surface bubbles, namely growth, stability, shrinkage or dissolution.

cond-mat.soft↗

Ultrathin ferrimagnetic GdFeCo films with very low damping

Ferromagnetic materials dominate as the magnetically active element in spintronic devices, but come with drawbacks such as large stray fields, and low operational frequencies. Compensated ferrimagnets provide an alternative as they combine the ultrafast magnetization dynamics of antiferromagnets with a ferromagnet-like spin-orbit-torque (SOT) behavior. However to use ferrimagnets in spintronic devices their advantageous properties must be retained also in ultrathin films (t < 10 nm). In this study, ferrimagnetic Gdx(Fe87.5Co12.5)1-x thin films in the thickness range t = 2-20 nm were grown on high resistance Si(100) substrates and studied using broadband ferromagnetic resonance measurements at room temperature. By tuning their stoichiometry, a nearly compensated behavior is observed in 2 nm Gdx(Fe87.5Co12.5)1-x ultrathin films for the first time, with an effective magnetization of Meff = 0.02 T and a low effective Gilbert damping constant of α = 0.0078, comparable to the lowest values reported so far in 30 nm films. These results show great promise for the development of ultrafast and energy efficient ferrimagnetic spintronic devices.

cond-mat.mtrl-sci↗

Asymptotic Normality of the Posterior Distributions in a Class of Hidden Markov Models

We show that the posterior distribution of parameters in a hidden Markov model with parametric emission distributions and discrete and known state space is asymptotically normal. The main novelty of our proof is that it is based on a testing condition and the sequence of test functions is obtained using an optimal transportation inequality.

math.ST↗

Divide-and-Conquer Bayesian Inference in Hidden Markov Models

Divide-and-conquer Bayesian methods consist of three steps: dividing the data into smaller computationally manageable subsets, running a sampling algorithm in parallel on all the subsets, and combining parameter draws from all the subsets. The combined parameter draws are used for efficient posterior inference in massive data settings. A major restriction of existing divide-and-conquer methods is that their first two steps assume that the observations are independent. We address this problem by developing a divide-and-conquer method for Bayesian inference in parametric hidden Markov models, where the state space is known and finite. Our main contributions are two-fold. First, after partitioning the data into smaller blocks of consecutive observations, we modify the likelihood for performing posterior computations on the subsets such that the posterior variances of the subset and true posterior distributions have the same asymptotic order. Second, if the number of subsets is chosen appropriately depending on the mixing properties of the hidden Markov chain, then we show that the subset posterior distributions defined using the modified likelihood are asymptotically normal as the subset sample size tends to infinity. The latter result also implies that we can use any existing combination algorithm in the third step. We show that the combined posterior distribution obtained using one such algorithm is close to the true posterior distribution in 1-Wasserstein distance under widely used regularity assumptions. Our numerical results show that the proposed method provides an accurate approximation of the true posterior distribution than its competitors in diverse simulation studies and a real data analysis.

stat.ME↗

Unexpected Hydrophobicity on Self-Assembled Monolayers Terminated with Two Hydrophilic Hydroxyl Groups

Current major approaches to access surface hydrophobicity include directly introducing hydrophobic nonpolar groups/molecules into surface or elaborately fabricating surface roughness. Here, for the first time, molecular dynamics simulations show an unexpected hydrophobicity with a contact angle of $82^o$ on a flexible self-assembled monolayer terminated only with two hydrophilic OH groups ($(OH)_2\!-\!SAM$). This hydrophobicity is attributed to the formation of a hexagonal-ice-like H-bonding structure in the OH matrix of $(OH)_2\!-\!SAM$, which sharply reduces the hydrogen bonds between surface and water molecules above. The unique simple interface presented here offers a significant molecular-level platform for examining the bio-interfacial interactions ranging from biomolecules binding to cell adhesion.

physics.app-ph↗

Automated Model Selection for Time-Series Anomaly Detection

Time-series anomaly detection is a popular topic in both academia and industrial fields. Many companies need to monitor thousands of temporal signals for their applications and services and require instant feedback and alerts for potential incidents in time. The task is challenging because of the complex characteristics of time-series, which are messy, stochastic, and often without proper labels. This prohibits training supervised models because of lack of labels and a single model hardly fits different time series. In this paper, we propose a solution to address these issues. We present an automated model selection framework to automatically find the most suitable detection model with proper parameters for the incoming data. The model selection layer is extensible as it can be updated without too much effort when a new detector is available to the service. Finally, we incorporate a customized tuning algorithm to flexibly filter anomalies to meet customers' criteria. Experiments on real-world datasets show the effectiveness of our solution.

cs.LG↗

Hydrogen Polarity of Interfacial Water Regulates Heterogeneous Ice Nucleation

Using all-atomic molecular dynamics(MD) simulations, we show that various substrates could induce interfacial water (IW) to form the same ice-like oxygen lattice but different hydrogen polarity order, and regulate the heterogeneous ice nucleation on the IW. We develop an efficient MD method to probe the shape, structure of ice nuclei and the corresponding supercooling temperatures. We find that the polarization of hydrogens in IW increases the surface tension between the ice nucleus and the IW, thus lifts the free energy barrier of heterogeneous ice nucleation. The results show that not only the oxygen lattice order but the hydrogen disorder of IW on substrates are required to effectively facilitate the freezing of atop water.

physics.comp-ph↗

Contact Angle Measurement in Lattice Boltzmann Method

Contact angle is an essential characteristic in wetting, capillarity and moving contact line; however, although contact angle phenomena are effectively simulated, an accurate and real-time measurement for contact angle has not been well studied in computational fluid dynamics, especially in dynamic environments. Here, we design a geometry-based mesoscopic scheme to onthesport measure the contact angle in the lattice Boltzmann method. The computational results without gravity effect are in excellent agreement with the benchmarks from the spherical cap method. The qualities of the scheme are further verified in gravitational environments by simulating sessile and pendent droplets on smooth solid surfaces and contact angle hysteresis on chemically heterogeneous surfaces. This scheme is simple, efficient and requires only the local data. It is independent of multiphase models and can be easily extended to 3D dynamic contact angle measurements.

physics.comp-ph↗

Molecular-Scale Hydrophilicity Induced by Solute: Molecular-thick Charged Pancakes of Aqueous Salt Solution on Hydrophobic Carbon-based Surfaces

We directly observed molecular-thick aqueous salt-solution pancakes on a hydrophobic graphite surface under ambient conditions employing atomic force microscopy. This observation indicates the unexpected molecular-scale hydrophilicity of the salt solution on graphite surfaces, which is different from the macroscopic wetting property of a droplet standing on the graphite surface. Interestingly, the pancakes spontaneously displayed strong positively charged behavior. Theoretical studies showed that the formation of such positively charged pancakes is attributed to cation-π interactions between Na+ ions in the aqueous solution and aromatic rings on the graphite surface, promoting the adsorption of water molecules together with cations onto the graphite surface; i.e., Na+ ions as a medium adsorbed to the graphite surface through cation-π interactions on one side while at the same time bonding to water molecules through hydration interaction on the other side at a molecular scale. These findings suggest that actual interactions regarding carbon-based graphitic surfaces including those of graphene, carbon nanotubes, and biochar may be significantly different from existing theory and they provide new insight into the control of surface wettability, interactions and related physical, chemical and biological processes.

cond-mat.soft↗

Mass transportation of thermally driven nanotube nanomotors with defects

Thermally driven nanotube nanomotors provide linear mass transportation controlled by a temperature gradient. However, the underlying mechanism is still unclear where the mass transportation velocity in experiment is much lower than that resulting from simulations. Considering that defects are common in fabricated nanotubes, we use molecular dynamics simulations to show that the mass transportation would be considerably impeded by the potential barriers or wells induced by the defects, which provides a possible picture to understand the relative low value at microscopic level. The optimal structure and the factors which would affect the performance are discussed. The result indicates considering defects is helpful in designing nanotube nanomotor and other new nanomotor-based devices.

cond-mat.mes-hall↗

Galilean Invariant Fluid-Solid Interfacial Dynamics in Lattice Boltzmann Simulations

Galilean invariance is a fundamental property; however, although the lattice Boltzmann equation itself is Galilean invariant, this property is usually not taken into account in the treatment of the fluid-solid interface. Here, we show that consideration of Galilean invariance in fluid-solid interfacial dynamics can greatly enhance the computational accuracy and robustness in a numerical simulation. Surprisingly, simulations are so vastly improved that the force fluctuation is very small and a time average becomes unnecessary.

physics.flu-dyn↗

High critical current density and low anisotropy in textured Sr1-xKxFe2As2 tapes for high field applications

From the application point of view, large critical current densities Jc (H) for superconducting wires are required, preferably for magnetic fields higher than 5 T. Here we show that strong c-axis textured Sr1-xKxFe2As2 tapes with nearly isotropic transport Jc were fabricated by an ex-situ powder-in-tube (PIT) process. At 4.2 K, the Jc values show extremely weak magnetic field dependence and reach high values of 1.7x10^4 A/cm^2 at 10 T and 1.4x10^4 A/cm^2 at 14 T, respectively, these values are by far the highest ever reported for iron based wires and approach the Jc level desired for practical applications. Transmission electron microscopy investigations revealed that amorphous oxide layers at grain boundaries were significantly reduced by Sn addition which resulted in greatly improved intergranular connectivity. Our results demonstrated the strong potential of using iron based superconductors for high field applications.

cond-mat.supr-con↗

Fabrication and transport properties of Sr0.6K0.4Fe2As2 multifilamentary superconducting wires

Seven-core Ag/Fe sheathed Sr0.6K0.4Fe2As2 (Sr-122) superconducting wires were produced by the ex situ powder-in-tube (PIT) method. The relationship between the cold-work deformation process and the superconducting properties of wires were systematically studied. It was found that flat rolling can efficiently increase the density of the superconducting core and largely improve the transport critical current density (Jc) of as-drawn wires. The Jc of the best sample achieved 21.1 kA/cm^2 at 4.2 K in self field, and showed very weak magnetic field dependence in high fields. Our result suggested a promising future of multifilamentary iron-based superconductors in practical application.

cond-mat.supr-con↗

Improved transport critical currents in Ag and Pb co-doped BaxK1-xFe2As2 superconducting tapes

Fe-clad BaxK1-xFe2As2 superconducting tapes were fabricated by the ex situ powder-in-tube method combined with a short high-temperature annealing technique. The effect of annealing time and different dopants on the transport properties of the BaxK1-xFe2As2 tapes were systematically studied. By co-doping with Ag and Pb, the transport critical current density Jc of BaxK1-xFe2As2 tapes was significantly improved in whole field region and the highest transport Jc was up to 1.4x10^4 A/cm^2 (Ic=100 A) at 4.2K in self field. It is proposed that the superior Jc in the co-doped samples are due to the combine effect of Pb doping at low fields and Ag doping at high fields.

cond-mat.supr-con↗

Effect of starting materials on the superconducting properties of SmFeAsO1-xFx tapes

SmFeAsO1-xFx tapes were prepared using three kinds of starting materials. It shows that the starting materials have an obvious effect on the impurity phases in final superconducting tapes. Compared with the other samples, the samples fabricated by SmAs, FeO, Fe2As, and SmF3 have the smallest arsenide impurity phase and voids. As a result, these samples possess much denser structure and better grain connectivity. Moreover, among the three kinds of samples fabricated in this work, this kind of sample has the highest zero-resistivity temperature ~40 K and largest critical current density ~4600 A/cm^2 in self-field at 4.2 K. This is the highest Jc values reported so far for SmFeAsO1-xFx wires and tapes.

cond-mat.supr-con↗

High transport critical current densities in textured Fe-sheathed Sr1-xKxFe2As2+Sn superconducting tapes

We report the realization of grain alignment in Sn-added Sr1-xKxFe2As2 superconducting tapes prepared by ex-situ powder-in-tube method. At 4.2 K, high transport critical current densities Jc of 2.5x10^4 A/cm^2 (Ic = 180 A) in self-field and 3.5x10^3 A/cm^2 (Ic = 25.5 A) in 10 T have been measured. These values are the highest ever reported so far for Fe-based superconducting wires and tapes. We believe the superior Jc in our tape samples are due to well textured grains and strengthened intergrain coupling achieved by Sn addition. Our results demonstrated an encouraging prospect for application of iron based superconductors.

cond-mat.supr-con↗

Synthesis and properties of La-doped CaFe2As2 single crystals with Tc = 42.7 K

Large single crystals of La-doped CaFe2As2 were successfully synthesized by the FeAs self-flux method. The x-ray diffraction patterns suggest high crystalline quality and c-axis orientation. By substitution of trivalent La3+ ions for divalent Ca2+, the resistivity anomaly in the parent compound CaFe2As2 is completely suppressed and a superconducting transition reaches the value of 42.7 K, which is higher than that of about 30 K reported in Saha S. R. et al., arXiv:1105.4798v1. The upper critical field has been determined with the magnetic field along ab-plane and c-axis, yielding an anisotropy of about 3.3.

cond-mat.supr-con↗

Transport properties and anisotropy in rare earth doped CaFe2As2 single crystals with Tc above 40 K

In this paper we report the superconductivity above 40 K in the electron doping single crystal Ca1-xRexFe2As2 (Re = La, Ce, Pr). The x-ray diffraction patterns indicate high crystalline quality and c-axis orientation. the resistivity anomaly in the parent compound CaFe2As2 is completely suppressed by partial replacement of Ca by rare earth and a superconducting transition reaches as high as 43 K, which is higher than the value in electron doping FeAs-122 compounds by substituting Fe ions with transition metal, even surpasses the highest values observed in hole doping systems with a transition temperature up to 38 K. The upper critical field has been determined with the magnetic field along ab-plane and c-axis, yielding the anisotropy of 2~3. Hall-effect measurements indicate that the conduction in this material is dominated by electron like charge carriers. Our results explicitly demonstrate the feasibility of inducing superconductivity in Ca122 compounds via electron doping using aliovalent rare earth substitution into the alkaline earth site, which should add more ingredients to the underlying physics of the iron-based superconductors.

cond-mat.supr-con↗