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Conel M. O'D. Alexander

Publications and source records attributed to Conel M. O'D. Alexander.

At least 19 recordsLinked to original sources
arXiv2026

OSIRIS-REx Returned a Pristine Sample of Asteroid Bennu: Takeaways from the Mission's Contamination Control and Knowledge Program

NASA's OSIRIS-REx mission had the objective of delivering a pristine sample from asteroid (101955) Bennu to Earth for scientific analysis--where "pristine" signifies the absence of foreign materials that could affect sample measurements. OSIRIS-REx returned 121.6 g of regolith in September 2023; this study documents the systematic investigation of suspected contaminants encountered during the mission's sample analysis phase. Most suspected contaminants did not originate from the spacecraft or sample curation. Some were introduced during laboratory analyses, reinforcing the importance of procedural blanks and a strategic approach to sharing samples across laboratories with different analytical targets. Several suspected contaminants, such as phosphate and sodium fluoride particles, were ultimately identified as indigenous to Bennu, highlighting the critical role of contamination knowledge in preventing the dismissal of valuable scientific data. We find that the returned sample meets the definition of pristine, except for an isolated 1.24% (by mass) that escaped the sample container and was thereby contaminated with spacecraft particulates. These findings demonstrate the effectiveness of systematically applied contamination science and engineering practices and provide lessons and approaches to help maximize the scientific integrity of future planetary sample return missions.

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arXiv2026

New NanoSIMS Multielement Isotope Data Reveal CO Novae As Key Sources Of 13C-rich Presolar Silicon Carbide Grains

We present new multielement NanoSIMS isotopic measurements (C, N, Si, Mg-Al, Ti, and Ni) for four putative nova SiC grains and 79 AB SiC grains from the Murchison meteorite to reassess their stellar origins. High-resolution imaging and a revised Mg/Al relative sensitivity factor for SiC yield substantially improved 26Al/27Al ratios and the most reliable multielement characterization to date for 13C-rich presolar SiC grains. To interpret these data, we computed an expanded suite of hydrodynamic CO, ONe, and recurrent nova models spanning a range of white-dwarf masses and pre-enrichment parameters. When all isotopic systems are considered together (C, N, Mg-Al, Si, Ti, and Ni), the CO nova models provide the closest and most self-consistent match to both the putative nova grains and the subset of AB grains lacking s-process signatures. CO novae of low- to intermediate-mass naturally reproduce the observed 14N/15N-26Al/27Al trend, the Si isotope compositions of AB grains which dominantly reflect Galactic chemical evolution (GCE), and the mild Si isotope shifts in putative nova grains relative to the GCE trend defined by AB grains. In contrast, ONe and recurrent nova models fail multiple isotopic constraints simultaneously. These results demonstrate that low- to intermediate-mass CO novae (0.6-1.0 Msun) are the most plausible stellar sources of 13C-rich SiC dust lacking s-process signatures (1-2\% of all presolar SiC), and they establish a multielement, model-anchored framework for quantifying nova contributions to the dust reservoir in the interstellar medium.

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arXiv2026

Constraints for Nuclear Astrophysics from an Unusual Presolar Silicate-Oxide Aggregate Grain Found in Primitive Ordinary Chondrite Meteorite Hills 00526

We report O, Mg-Al, Si, Ca, and Ti isotopic data for an unusual presolar oxide/silicate aggregate grain, M526-69, previously reported in the primitive ordinary chondrite Meteorite Hills 00526. The $\approx 1μ$m aggregate consists of a Mg- and Ca-rich silicate, a Al-rich oxide, and a tiny TiO$_2$ grain. A large $^{18}$O depletion and high inferred $^{26}$Al/$^{27}$Al classifies M526-69 as a Group 2 grain. Both low-mass (LM) and intermediate-mass (IM) asymptotic giant branch (AGB) stars are considered viable candidate parent stars of Group 2 grains based on their O isotopes and inferred $^{26}$Al/$^{27}$Al ratios. The lack of a large $^{30}$Si excess in M526-69 strongly supports an LM-AGB origin for it and other Group 2 grains. The stable Mg, Ca, and Ti isotopes all reflect the initial composition of the parent star, set by galactic chemical evolution (GCE) processes. Presolar O-rich grains provide a better measure of the GCE trends for Ti isotopes than presolar SiC grains as the latter are also affected by neutron capture reactions in the parent stars. Most of the Mg, Ca, and Ti isotopic ratios in M526-69 are consistent with its parent star having metallicity lower than solar. However, small excesses in stable non-radiogenic $^{26}$Mg, $^{46}$Ti, and $^{44}$Ca do not fit this pattern and instead point to heterogeneous GCE processes, though quantitative modeling is needed to test this hypothesis. Multi-phase presolar grains are extremely valuable for nuclear astrophysics as they can both provide isotopic compositions for multiple elements that must be matched at a single time and place in a single star.

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arXiv2025

The rapid formation of macromolecules in irradiated ice of protoplanetary disk dust traps

Organic macromolecular matter is the dominant carrier of volatile elements such as carbon, nitrogen, and noble gases in chondrites -- the rocky building blocks from which Earth formed. How this macromolecular substance formed in space is unclear. We show that its formation could be associated with the presence of dust traps, which are prominent mechanisms for forming planetesimals in planet-forming disks. We demonstrate the existence of heavily irradiated zones in dust traps, where small frozen molecules that coat large quantities of microscopic dust grains could be rapidly converted into macromolecular matter by receiving radiation doses of up to several 10s of eV molecule$^{-1}$ year$^{-1}$. This allows for the transformation of simple molecules into complex macromolecular matter within several decades. Up to roughly 4$\%$ of the total disk ice reservoir can be processed this way and subsequently incorporated into the protoplanetary disk midplane where planetesimals form. This finding shows that planetesimal formation and the production of organic macromolecular matter, which provides the essential elemental building blocks for life, might be linked.

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arXiv2024

Experimental heating of complex organic matter at Titan's interior conditions supports contributions to atmospheric N2 and CH4

Titan's abundant atmospheric N2 and CH4 gases are notable characteristics of the moon that may help constrain its origins and evolution. Previous work suggests that atmospheric CH4 is lost on geologically short timescales and may be replenished from an interior source. Isotopic and noble gas constraints indicate that N2 may derive from a mixture of NH3 ice and heating of organic matter. Here, we report experimental results from hydrothermal alteration of insoluble organic matter from the Murchison meteorite and analog insoluble organic matter at temperatures and pressures that are relevant to Titan's interior. Our results indicate both CH4 and CO2 are formed, with the ratio between the two depending on a multitude of factors, particularly temperature and, to a lesser degree, the dielectric constant of water and carbonyl abundance in the starting material. Sufficient CH4 is produced to source Titan's atmospheric reservoir if temperatures are greater than 250°C. Nitrogen is volatilized, primarily in the form of NH3, in sufficient abundances to source at least 50% of Titan's atmospheric N2. The isotopic characteristics of volatilized material relative to the starting organics are consistent with current constraints for the nature of the accreted complex organics and Titan's evolved atmosphere.

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arXiv2024

The Ni isotopic composition of Ryugu reveals a common accretion region for carbonaceous chondrites

The isotopic compositions of samples returned from Cb-type asteroid Ryugu and Ivuna-type (CI) chondrites are distinct from other carbonaceous chondrites, which has led to the suggestion that Ryugu and CI chondrites formed in a different region of the accretion disk, possibly around the orbits of Uranus and Neptune. We show that, like for Fe, Ryugu and CI chondrites also have indistinguishable Ni isotope anomalies, which differ from those of other carbonaceous chondrites. We propose that this unique Fe and Ni isotopic composition reflects different accretion efficiencies of small FeNi metal grains among the carbonaceous chondrite parent bodies. The CI chondrites incorporated these grains more efficiently, possibly because they formed at the end of the disk's lifetime, when planetesimal formation was also triggered by photoevaporation of the disk. Isotopic variations among carbonaceous chondrites may thus reflect fractionation of distinct dust components from a common reservoir, implying CI chondrites and Ryugu may have formed in the same region of the accretion disk as other carbonaceous chondrites.

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arXiv2023

Explosive Nucleosynthesis in Core-Collapse Type II Supernovae: Insights from new C, N, Si, and Al-Mg isotopic compositions of presolar grains

We report C, N, Si, and Al-Mg isotope data for 39 presolar X silicon carbide (SiC) and four silicon nitride grains - a group of presolar grains that condensed in the remnants of core-collapse Type II supernovae (CCSNe) - isolated from the Murchison meteorite. Energy dispersive X-ray (EDX) data were used to determine the Mg and Al contents of the X SiC grains for comparison with the Mg/Al ratios determined by secondary ion mass spectroscopy (SIMS). Previous SIMS studies have used O-rich standards in the absence of alternatives. In this study, the correlated isotopic and elemental data of the X SiC grains enabled accurate determination of the initial 26Al/27Al ratios for the grains. Our new grain data suggest that (i) the literature data for X grains are affected to varying degrees by asteroidal/terrestrial contamination, and (ii) the Al/Mg ratios in SiC are a factor of two (with +/-6% 1 sigma uncertainties) lower than estimated based on the SIMS analyses that used O-rich standards. The lowered Al/Mg ratios result in proportionally higher inferred initial 26Al/27Al ratios for presolar SiC grains. In addition, the suppression of asteroidal/terrestrial contamination in this study leads to the observation of negative trends for 12C/13C-30Si/28Si and 26Al/27Al-30Si/28Si among our CCSN grains. We discuss these isotope trends in the light of explosive CCSN nucleosynthesis models, based on which we provide new insights into several non-traditional CCSN nucleosynthesis processes, including explosive H burning, the existence of a C/Si zone in the outer regions of CCSNe, and neutrino-nucleus reactions in deep CCSN regions.

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arXiv2023

Equilibrium Condensation from Chondritic Porous IDP Enriched Vapor: Implications for Mercury and Enstatite Chondrite Origins

The origin of Mercury's anomalous core and low FeO surface mineralogy are outstanding questions in planetary science. Mercury's composition may result from cosmochemical controls on the precursor solids that accreted to form Mercury. High temperatures and enrichment in solid condensates are likely conditions near the midplane of the inner solar protoplanetary disk. Silicate liquids similar to the liquids quenched in ferromagnesian chondrules are thermodynamically stable in oxygen-rich systems that are highly enriched in dust of CI-chondrite composition. In contrast, the solids surviving into the orbit of Mercury's accretion zone were probably similar to highly unequilibrated, anhydrous, interstellar organic- and presolar grain-bearing chondritic, porous interplanetary dust particles (C-IDPs). Chemical systems enriched in an assumed C-IDP composition dust produce condensates (solid + liquid assemblages in equilibrium with vapor) with super-chondritic atomic Fe/Si ratios at high temperatures, approaching 50% of that estimated for bulk Mercury. Sulfur behaves as a refractory element, but at lower temperatures, in these chemical systems. Stable minerals are FeO-poor, and include CaS and MgS, species found in enstatite chondrites. Disk gradients in volatile compositions of planetary and asteroidal precursors can explain Mercury's anomalous composition, as well as enstatite chondrite and aubrite parent body compositions. This model predicts high sulfur content, and very low FeO content of Mercury's surface rocks.

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arXiv2023

Vapor-Melt Exchange -- Constraints on Chondrite Formation Conditions and Processes

The bulk volatile contents of chondritic meteorites provide clues to their origins. Matrix and chondrules carry differing abundances of moderately volatile elements, with chondrules carrying a refractory signature. At the high temperatures of chondrule formation and the low pressures of the solar nebula, many elements, including Na and Fe, should have been volatile. Yet the evidence is that even at peak temperatures, at or near the liquidus, Na and Fe (as FeO and Fe-metal) were present in about their current abundances in molten chondrules. This seems to require very high solid densities during chondrule formation to prevent significant evaporation. Evaporation should also be accompanied by isotopic mass fractionation. Evidence from a wide range of isotopic systems indicates only slight isotopic mass fractionations of moderately vola-tile elements, further supporting high solid densities. However, olivine-rich, FeO-poor chondrules commonly have pyroxene-dominated outer zones that have been interpreted as the prod-ucts of late condensation of SiO2 into chondrule melts. Late condensation of more refractory SiO2 is inconsistent with the apparent abundances of more volatile Na, FeO and Fe-metal in many chondrules. Despite significant recent experimental work bearing on this problem, the conditions under which chondrules behaved as open systems remain enigmatic.

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arXiv2022

Presolar O- and C-anomalous grains in unequilibrated ordinary chondrite matrices

Presolar grains are trace components in chondrite matrices. Their abundances and compositions have been systematically studied in carbonaceous chondrites but rarely in situ in other major chondrite classes. We have conducted a NanoSIMS isotopic search for presolar grains with O- and C-anomalous isotopic compositions in the matrices of the unequilibrated ordinary chondrites Semarkona, Meteorite Hills 00526, and Northwest Africa 8276. The matrices of even the most primitive ordinary chondrites have been aqueously altered and/or thermally metamorphosed, destroying their presolar grain populations to varying extents. In addition to randomly placed isotope maps, we targeted recently reported, relatively pristine Semarkona matrix areas to better explore the original inventory of presolar grains. In all samples, we found a total of 122 O-anomalous grains (silicates + oxides), 79 SiC grains, and 22 C-anomalous carbonaceous grains (organics, graphites). Average matrix-normalized abundances are 151 ppm O-anomalous grains, 53 ppm SiC grains and 56 ppm carbonaceous grains in Semarkona, 55 ppm (O-anom.), 22 ppm (SiC) and 3 ppm (carb.) in MET 00526 and 12 ppm (O-anom.), 15 ppm (SiC) and 1 ppm (carb.) in NWA 8276. In relatively pristine ordinary chondrites and in primitive carbonaceous and C-ungrouped chondrites, the O and C isotopic composition of presolar grains and their matrix-normalized abundances are similar, despite the likely differences in chondrite-formation time and nebular location. These results suggest a relatively homogenous distribution of presolar dust across major chondrite-forming reservoirs in the solar nebula. Secondary asteroidal processes are mainly responsible for differences in presolar grain abundances between and within chondrites, highlighting the need to identify and target the most pristine chondrite matrices for such studies.

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arXiv2022

Presolar stardust in asteroid Ryugu

We have conducted a NanoSIMS-based search for presolar material in samples recently returned from C-type asteroid Ryugu as part of JAXA's Hayabusa2 mission. We report the detection of all major presolar grain types with O- and C-anomalous isotopic compositions typically identified in carbonaceous chondrite meteorites: 1 silicate, 1 oxide, 1 O-anomalous supernova grain of ambiguous phase, 38 SiC, and 16 carbonaceous grains. At least two of the carbonaceous grains are presolar graphites, whereas several grains with moderate C isotopic anomalies are probably organics. The presolar silicate was located in a clast with a less altered lithology than the typical extensively aqueously altered Ryugu matrix. The matrix-normalized presolar grain abundances in Ryugu are 4.8$^{+4.7}_{-2.6}$ ppm for O-anomalous grains, 25$^{+6}_{-5}$ ppm for SiC grains and 11$^{+5}_{-3}$ ppm for carbonaceous grains. Ryugu is isotopically and petrologically similar to carbonaceous Ivuna-type (CI) chondrites. To compare the in situ presolar grain abundances of Ryugu with CI chondrites, we also mapped Ivuna and Orgueil samples and found a total of SiC grains and 6 carbonaceous grains. No O-anomalous grains were detected. The matrix-normalized presolar grain abundances in the CI chondrites are similar to those in Ryugu: 23 $^{+7}_{-6}$ ppm SiC and 9.0$^{+5.3}_{-4.6}$ ppm carbonaceous grains. Thus, our results provide further evidence in support of the Ryugu-CI connection. They also reveal intriguing hints of small-scale heterogeneities in the Ryugu samples, such as locally distinct degrees of alteration that allowed the preservation of delicate presolar material.

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arXiv2021

TEM analyses of unusual presolar silicon carbide: Insights into the range of circumstellar dust condensation conditions

Presolar silicon carbide (SiC) grains in meteoritic samples can help constrain circumstellar condensation processes and conditions in C-rich stars and core-collapse supernovae. This study presents our findings on eight presolar SiC grains from AGB stars (four mainstream and one Y grain) and core-collapse supernovae (three X grains), chosen on the basis of μ-Raman spectral features that were indicative of their having unusual non-3C polytypes and/or high degrees of crystal disorder. Analytical transmission electron microscopy (TEM), which provides elemental compositional and structural information, shows evidence for complex histories for the grains. Our TEM results confirm the presence of non-3C,2H crystal domains. Minor element heterogeneities and/or subgrains were observed in all grains analyzed for their compositions. The C/O ratios inferred for the parent stars varied from 0.98 to greater than or equal to 1.03. Our data show that SiC condensation can occur under a wide range of conditions, in which environmental factors other than temperature (e.g., pressure, gas composition, heterogeneous nucleation on pre-condensed phases) play a significant role. Based on previous μ-Raman studies, about 10% of SiC grains may have infrared (IR) spectral features that are influenced by crystal defects, porosity, and/or subgrains. Future sub-diffraction limited IR measurements of complex SiC grains might shed further light on the relative contributions of each of these features to the shape and position of the characteristic IR 11-μm SiC feature and thus improve the interpretation of IR spectra of AGB stars like those that produced the presolar SiC grains.

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arXiv2020

Presolar Stardust in Highly Pristine CM Chondrites Asuka 12169 and Asuka 12236

We report a NanoSIMS search for presolar grains in the CM chondrites Asuka (A) 12169 and A12236. We found 90 presolar O-rich grains and 25 SiC grains in A12169, giving matrix-normalized abundances of 275 (+55/-50, 1$σ$) ppm or, excluding an unusually large grain, 236 (+37/-34) ppm for O-rich grains and 62 (+15/-12) ppm for SiC grains. For A12236, 18 presolar silicates and 6 SiCs indicate abundances of 58 (+18/-12) and 20 (+12/-8) ppm, respectively. The SiC abundances are in the typical range of primitive chondrites. The abundance of presolar O-rich grains in A12169 is essentially identical to that in CO3.0 Dominion Range 08006, higher than in any other chondrites, while in A12236 it is higher than found in other CMs. These abundances provide further strong support that A12169 and A12236 are the least-altered CMs as indicated by petrographic investigations. The similar abundances, isotopic distributions, silicate/oxide ratio, and grain sizes of the presolar O-rich grains found here to those of presolar grains in highly primitive CO, CR and ungrouped carbonaceous chondrites (CCs) indicate that the CM parent body(ies) accreted a similar population of presolar oxides and silicates in their matrices to those accreted by the parent bodies of the other CC groups. The lower abundances and larger grain sizes seen in some other CMs are thus most likely a result of parent-body alteration and not heterogeneity in nebular precursors. Presolar silicates are unlikely to be present in high abundances in returned samples from asteroids Ryugu and Bennu since remote-sensing data indicate that they have experienced substantial aqueous alteration.

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arXiv2020

The effects of atmospheric entry heating on organic matter in interplanetary dust particles

Interplanetary dust particles (IDPs) were likely major sources of extraterrestrial organics to the early Earth. However, IDPs experience heating to > 500 $°$C for up to several seconds during atmospheric entry. In this study, we aim to understand the effects of atmospheric entry heating on the dominant organic component in IDPs by conducting flash heating experiments (4 s to 400 °C, 600 °C, 800 °C, and 1000 °C) on insoluble organic matter (IOM) extracted from the meteorite Cold Bokkeveld (CM2). For each of the experimental charges, the bulk isotopic compositions of H, N, and C were analyzed using IRMS, the H isotopic heterogeneities (occurrence of hotspots) of the samples were measured by NanoSIMS, and the functional group chemistry and ordering of the IOM was evaluated using FTIR and Raman spectroscopy, respectively. IOM in particles heated to > 600 °C experienced loss of isotopically heavy, labile H and N groups, resulting in decreases in bulk $δ$D, $δ$15N, H/C and, upon heating > 800 °C, in N/C. The H heterogeneity was not greatly affected by flash heating to < 600 °C, although the hotspots tended to be less isotopically anomalous in the 600 °C sample than in the 400 °C sample. However, the hotspots all but disappeared in the 800 °C sample. Loss of C=O groups occurred at 800 °C. Based on the Raman G-band characteristics, the heating resulted in increased ordering of the polyaromatic component of the IOM. The data presented in this study show that all aspects of the composition of IOM in IDPs are affected by atmospheric entry heating. Modelling and temperature estimates from stepwise release of He has shown that most IDPs are heated to > 500°C (Love and Brownlee, 1991; Nier and Schlutter, 1993), hence, atmospheric entry heating is expected to have altered the organic matter in most IDPs.

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arXiv2019

Presolar Grains in Primitive Ungrouped Carbonaceous Chondrite Northwest Africa 5958

We report a correlated NanoSIMS-transmission electron microscopy study of the ungrouped carbonaceous chondrite Northwest Africa (NWA) 5958. We identified 10 presolar SiC grains, 2 likely presolar graphite grains, and 20 presolar silicate and/or oxide grains in NWA 5958. We suggest a slight modification of the commonly used classification system for presolar oxides and silicates that better reflects the grains' likely stellar origins. The matrix-normalized presolar SiC abundance in NWA 5958 is $18_{-10}^{+15}$ ppm (2$σ$), similar to that seen in many classes of unmetamorphosed chondrites. In contrast, the matrix-normalized abundance of presolar O-rich phases (silicates and oxides) is $30.9_{-13.1}^{+17.8}$ ppm (2$σ$), much lower than seen in interplanetary dust particles and the least altered CR, CO and ungrouped C chondrites, but close to that reported for CM chondrites. NanoSIMS mapping also revealed an unusual $^{13}$C-enriched ($δ^{13}$C$\sim$ 100--200 permil) carbonaceous rim surrounding a 1.4 $μ$m diameter phyllosilicate grain. TEM analysis of two presolar grains with a likely origin in asymptotic giant branch stars identified one as enstatite and one as Al-Mg spinel with minor Cr. The enstatite grain amorphized rapidly under the electron beam, suggesting partial hydration. TEM data of NWA 5958 matrix confirm that it has experienced aqueous alteration and support the suggestion of Jacquet et al. (2016) that this meteorite has affinities to CM2 chondrites.

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arXiv2018

The Effect of Jupiter's Formation on the Distribution of Refractory Elements and Inclusions in Meteorites

We present a comprehensive evolutionary model of the Sun's protoplanetary disk, constructed to resolve the "CAI Storage" problem of meteoritics. We predict the abundances of calcium-rich, aluminum-rich inclusions (CAIs) and refractory lithophile elements under the central assumption that Jupiter's $\sim 30 \, M_{\oplus}$ core forms at about 3 AU at around 0.6 Myr and opened a gap CAIs are trapped in the pressure maximum beyond Jupiter; carbonaceous chondrites formed there. Inside Jupiter's orbit, CAIs were depleted by aerodynamic drag; ordinary and enstatite chondrites formed there. For 16 chondrites and achondrites, we review meteoritic data on their CAI and refractory abundances and their times of formation, constrained by radiometric dating and thermal models. We predict their formation locations, finding excellent consistency with other location information (water content, asteroid spectra and parent bodies). We predict the size of particle concentrated by turbulence for each chondrite, finding excellent matches to each chondrites's mean chondrule diameter. These consistencies imply meteorite parent bodies assembled quickly from local materials concentrated by turbulence, and usually did not migrate far. We predict CI chondrites are depleted in refractory lithophile elements relative to the Sun, by about 12% (0.06 dex). We constrain the variation of turbulence parameter $α$ in the disk, and find a limited role for magnetorotational instability, favoring hydrodynamical instabilities in the outer disk, plus magnetic disk winds in the inner disk. Between 3 and 4 Myr at least, gas persisted outside Jupiter but was depleted inside it, and the solar nebula was a transition disk.

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arXiv2018

Extremely $^{54}$Cr- and $^{50}$Ti-rich presolar oxide grains in a primitive meteorite: Formation in rare types of supernovae and implications for the astrophysical context of solar system birth

We report the identification of 19 presolar oxide grains from the Orgueil CI meteorite with substantial enrichments in $^{54}$Cr, with $^{54}$Cr/$^{52}$Cr ratios ranging from 1.2 to 56 times the solar value. The most enriched grains also exhibit enrichments at mass 50, most likely due in part to $^{50}$Ti, but close-to-normal or depleted $^{53}$Cr/$^{52}$Cr ratios. There is a strong inverse relationship between $^{54}$Cr enrichment and grain size; the most extreme grains are all <80 nm in diameter. Comparison of the isotopic data with predictions of nucleosynthesis calculations indicate that these grains most likely originated in either rare, high-density Type Ia supernovae (SNIa), or in electron-capture supernovae (ECSN) which may occur as the end stage of evolution for stars of mass 8-10 M$_\odot$. This is the first evidence for preserved presolar grains from either type of supernova. An ECSN origin is attractive since these likely occur much more frequently than high-density SNIa, and their evolutionary timescales ($\sim$20 Myr) are comparable to those of molecular clouds. Self-pollution of the Sun's parent cloud from an ECSN may explain the heterogeneous distribution of n-rich isotopic anomalies in planetary materials, including a recently reported dichotomy in Mo isotopes in the solar system. The stellar origins of three grains with solar $^{54}$Cr/$^{52}$Cr, but anomalies in $^{50}$Cr or $^{53}$Cr, as well as of a grain enriched in $^{57}$Fe, are unclear.

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arXiv2018

High Abundances of Presolar Grains and $^{15}$N-rich Organic Matter in CO3.0 Chondrite Dominion Range 08006

NanoSIMS C-, N-, and O-isotopic mapping of matrix in CO3.0 chondrite Dominion Range (DOM) 08006 revealed it to have in its matrix the highest abundance of presolar O-rich grains (257 +76 / -96 ppm, 2$σ$) of any meteorite. It also has a matrix abundance of presolar SiC of 35 (+25 / -17, 2$σ$) ppm, similar to that seen across primitive chondrite classes. This provides additional support to bulk isotopic and petrologic evidence that DOM 08006 is the most primitive known CO meteorite. Transmission electron microscopy of five presolar silicate grains revealed one to have a composite mineralogy similar to larger amoeboid olivine aggregates and consistent with equilibrium condensation, two non-stoichiometric amorphous grains and two olivine grains, though one is identified as such solely based on its composition. We also found insoluble organic matter (IOM) to be present primarily as sub-micron inclusions with ranges of C- and N-isotopic anomalies similar to those seen in primitive CR chondrites and interplanetary dust particles. In contrast to other primitive extraterrestrial materials, H isotopic imaging showed normal and homogeneous D/H. Most likely, DOM 08006 and other CO chondrites accreted a similar complement of primitive and isotopically anomalous organic matter to that found in other chondrite classes and IDPs, but the very limited amount of thermal metamorphism experienced by DOM 08006 has caused loss of D-rich organic moieties, while not substantially affecting either the molecular carriers of C and N anomalies or most inorganic phases in the meteorite. One C-rich grain that was highly depleted in $^{13}$C and $^{15}$N was identified; we propose it originated in the Sun's parental molecular cloud.

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