arXiv subjects

D. G. Hinks

Publications and source records attributed to D. G. Hinks.

At least 37 records · Page 2Linked to original sources

arXiv2005

Persistence of Strong Electron Coupling to a Narrow Boson Spectrum in Overdoped BiSrCaCuO (Bi2212) Tunneling Data

A d-wave, Eliashberg analysis of break junction and STM tunneling spectra on BiSrCaCuO (Bi2212) reveals that a spectral dip feature is directly linked to strong electronic coupling to a narrow boson spectrum, evidenced by a large peak in the boson spectral weight. The tunneling dip feature remains robust in the overdoped regime of Bi2212 with bulk Tc values of 56 K-62 K. This is contrary to recent optical conductivity measurements of the self-energy that suggest the narrow boson spectrum disappears in overdoped Bi2212 and therefore cannot be essential for the pairing mechanism. The discrepancy is resolved by considering the way each technique probes the electron self-energy, in particular, the unique sensitivity of tunneling to the off-diagonal or pairing part of the self-energy.

cond-mat.supr-con↗

arXiv2005

Thermal Expansion and Compressibility in Superconducting NaxCoO2o4xD2O (x?1/3): Evidence for Pressure-Induced Charge Redistribution

We have performed thermal expansion and compressibility measurements on the recently discovered superconducting material NaxCoO2*4xD2O (x=1/3) using neutron powder diffraction over the temperature range 10-295 K and the pressure range 0-0.6 GPa. Pressure measurements were done in a helium-gas pressure cell. Both the thermal expansion and compressibility are very anisotropic, with the largest effects along the c axis, as would be expected for a layered material with weak hydrogen bonding nominally along the c axis. Near room temperature, the anisotropies of the thermal expansion and compressibility of the hexagonal crystal structure are nearly the same [(Dc/c)/(Da/a)=3-4], with a 100 C change in temperature being roughly equivalent to 0.2 GPa pressure. This would imply that changes in atom position parameters are also the same, but this is not the case. While the effects of temperature on the atom positions are essentially what one might expect, the effects of pressure are surprising. With increasing pressure, the thickness of the CoO2 layer increases, due to the combined effects of an increasing Co-O bond length and changes in the O-Co-O angles of the CoO6 octahedra. We conclude that this unusual effect results from pressure-induced strengthening of the hydrogen bonding between the Nax(D2O)4x layers and the CoO2 layers. The strengthening of these hydrogen bonds requires that charge be moved from the somewhere else in the structure; hence, there is a pressure induced charge redistribution that weakens (lengthens) the Co-O bonds and changes the electronic structure of the superconducting CoO2 layers.

cond-mat.supr-con↗

arXiv2005

Superconductivity and Cobalt Oxidation State in Metastable Na(x)CoO(2-delta)*yH2O (x ~ 1/3; y ~ 4x)

We report the synthesis and superconducting properties of a metastable form of the known superconductor NaxCoO2*yH2O (x ~ 1/3, y ~ 4x). Instead of using the conventional bromine-acetonitrile mixture for sodium deintercalation, we use an aqueous bromine solution. Using this method, we oxidize the sample to a point that the sodium cobaltate becomes unstable, leading to formation of other products if not controlled. This compound has the same structure as the reported superconductor, yet it exhibits a systematic variation of the superconducting transition temperature (Tc) as a function of time. Immediately after synthesis, this compound is not a superconductor, even though it contains appropriate amounts of sodium and water. The samples become superconducting with low Tc values after ~ 90 h. Tc continually increases until it reaches a maximum value (4.5 K) after about 260 h. Then Tc drops drastically, becoming non-superconducting approximately 100 h later. Corresponding time-dependent neutron powder diffraction data shows that the changes in superconductivity exhibited by the metastable cobaltate correspond to slow formation of oxygen vacancies in the CoO2 layers. In effect, the formation of these defects continually reduces the cobalt oxidation state causing the sample to evolve through its superconducting life cycle. Thus, the dome-shaped superconducting phase diagram is mapped as a function of cobalt oxidation state using a single sample. The width of this dome based on the formal oxidation state of cobalt is very narrow - approximately 0.1 valence units wide. Interestingly, the maximum Tc in NaxCoO2*yH2O occurs when the cobalt oxidation state is near 3.5. Thus, we speculate that the maximum Tc occurs near the charge ordered insulating state that correlates with the average cobalt oxidation state of 3.5.

cond-mat.mtrl-sci↗

arXiv2004

Single Junction and Intrinsic Josephson Junction Tunneling Spectroscopies of Bi2Sr2CaCu2O8+d

Tunneling spectroscopy measurements are reported on optimally-doped and overdoped Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+δ}$ single crystals. A novel point contact method is used to obtain superconductor-insulator-normal metal (SIN) and SIS break junctions as well as intrinsic Josephson junctions (IJJ) from nanoscale crystals. Three junction types are obtained on the same crystal to compare the quasiparticle peaks and higher bias dip/hump structures which have also been found in other surface probes such as scanning tunneling spectroscopy and angle-resolved photoemission spectroscopy. However, our IJJ quasiparticle spectra consistently reveal very sharp conductance peaks and no higher bias dip structures. The IJJ conductance peak voltage divided by the number of junctions in the stack consistently leads to a significant underestimate of $Δ$ when compared to the single junction values. The comparison of the three methods suggests that the markedly different characteristics of IJJ are a consequence of nonequilibrium effects and are not intrinsic quasiparticle features.

cond-mat.supr-con↗

arXiv2003

Crystal Structure of the Sodium Cobaltate Deuterate Superconductor NaxCoO2o4xD2O (x=1/3)

Neutron and x-ray powder diffraction have been used to investigate the crystal structures of a sample of the newly-discovered superconducting sodium cobaltate deuterate compound with composition Na0.31(3)CoO2o1.25(2)D2O and its anhydrous parent compound Na0.61(1)CoO2. The deuterate superconducting compound is formed by coordinating four D2O molecules (two above and two below) to each Na ion in a way that gives Na-O distances nearly equal to those in the parent compound. One deuteron of the D2O molecule is hydrogen bonded to an oxygen atom in the CoO2 plane and the oxygen atom and the second deuteron of each D2O molecule lie approximately in a plane between the Na layer and the CoO2 layers. This coordination of Na by four D2O molecules leads to ordering of the Na ions and D2O molecules. The sample studied here, which has Tc=4.5 K, has a refined composition of Na0.31(3)CoO2o1.25(2)D2O, in agreement with the expected 1:4 ratio of Na to D2O. These results show that the optimal superconducting composition should be viewed as a specific hydrated compound, not a solid solution of Na and D2O (H2O) in NaxCoO2oyD2O. Studies of physical properties vs. Na or D2O composition should be viewed with caution until it is verified that the compound remains in the same phase over the composition range of the study.

cond-mat.supr-con↗

arXiv2003

Retention of Two-Band Superconductivity in Highly Carbon-Doped MgB2

Tunneling data on MgB_{1.8}C_{0.2} show a reduction in the energy gap of the pi-bands by a factor of two from undoped MgB2 that is consistent with the Tc reduction, but inconsistent with the expectations of the dirty limit. Dirty-limit theory for undoped MgB2 predicts a single gap about three times larger than measured and a reduced Tc comparable to that measured. Our heavily-doped samples exhibit a uniform dispersion of C suggestive of significantly enhanced scattering, and we conclude that the retention of two-band superconductivity in these samples is caused by a selective suppression of interband scattering.

cond-mat.supr-con↗

arXiv2003

Probing the Phase Diagram of Bi2Sr2CaCu2O8+d with Tunneling Spectroscopy

Tunneling measurements are performed on Ca-rich single crystals of Bi2Sr2CaCu2O8+d (Bi2212), with various oxygen doping levels, using a novel point contact method. At 4.2 K, SIN and SIS tunnel junctions are obtained with well-defined quasiparticle peaks, robust dip and hump features and in some cases Josephson currents. The doping dependence of tunneling conductances of Ca-rich Bi2212 are analyzed and compared to stoichiometric Bi2212. A similar profile of energy gap vs. doping concentration is found although the Ca-rich samples have a slighly smaller optimum Tc and therefore smaller gap values for any doping level. The evolution of tunneling conductance peak height to background ratios with hole concentration are compared. For a given doping level, the Ca-rich spectra showed more broadened features compared to the stoichiometric counterparts, most likely due to increased disorder from the excess Ca. Comparison of the dip and hump features has provided some potential insights into their origins.

cond-mat.supr-con↗

arXiv2002

H-T phase diagram of the metamagnetic transition in $URu_2Si_2$, measured in high d. c. magnetic fields

We have studied the ultrasonic velocity and ac susceptibility of $URu_2Si_2$ in d. c. magnetic fields up to 45T. A significant difference between the constructed H-T phase diagram and that extracted from earlier pulsed fields measurements can be explained in terms of a large magnetocaloric effect. A hysteresis of metamagnetic transition at low temperatures and a new phase separation line have been observed for the first time.

cond-mat.str-el↗

arXiv2002

Break-Junction Tunneling on MgB_2

Tunneling data on magnesium diboride, MgB_2, are reviewed with a particular focus on superconductor-insulator-superconductor (SIS) junctions formed by a break-junction method. The collective tunneling literature reveals two distinct energy scales, a large gap, Delta_L~7.2 meV, close to the expected BCS value, and a small gap, Delta_S~2.4 meV. The SIS break junctions show clearly that the small gap closes near the bulk critical temperature, T_c=39 K. The SIS spectra allow proximity effects to be ruled out as the cause for the small gap and therefore make a strong case that MgB_2 is a coupled, two-band superconductor. While the break junctions sometimes reveal parallel contributions to the conductance from both bands, it is more often found that Delta_S dominates the spectra. In these cases, a subtle feature is observed near Delta_S+Delta_L that is reminiscent of strong-coupling effects. This feature is consistent with quasiparticle scattering contributions to the interband coupling which provides an important insight into the nature of two-band superconductivity in MgB_2.

cond-mat.supr-con↗

arXiv2002

Dependence of the superconducting transition temperature of single- and polycrystalline MgB2 on hydrostatic pressure

The dependence of Tc for MgB2 on purely hydrostatic or nearly hydrostatic pressure has been determined to 23 GPa for single-crystalline and to 32 GPa for polycrystalline samples, and found to be in good agreement. Tc decreases from 39 K at ambient pressure to 15 K at 32 GPa with an initial slope dTc/dP = -1.11(2) K/GPa. Evidence is presented that the differing values of dTc/dP reported in the literature result primarily from shear-stress effects in nonhydrostatic pressure media and not differences in the samples. Although comparison of these results with theory supports phonon-mediated superconductivity, a critical test of theory must await volume-dependent calculations based on the solution of the anisotropic Eliashberg equations.

cond-mat.supr-con↗

arXiv2002

Synthesis and Stoichiometry of MgB2

The system MgxB2 has been investigated to investigate possible nonstoichiometry in MgB2. When synthesized at 850oC, MgB2 is a line compound with a possible Mg vacancy content of about 1%. Small changes in lattice constants as a function of starting composition result from grain interaction stresses, whose character is different in the Mg-rich, near-stoichiometric, and Mg-deficient regimes. A small linear decrease of the superconducting transition temperature, Tc, in the Mg-rich regime results from accidental impurity doping.

cond-mat.supr-con↗

arXiv2002

Large Anisotropic Thermal Expansion Anomaly near the Superconducting Transition Temperature in MgB2

An anisotropic lattice anomaly near the superconducting transition temperature, Tc, was observed in MgB2 by high-resolution neutron powder diffraction. The a-axis thermal expansion becomes negative near Tc, while the c-axis thermal expansion is unaffected. This is qualitatively consistent with a depletion of the boron-boron s-band as the superconducting gap opens, resulting in weaker bonding. However, the observed anomaly is much larger than predicted by the Ehrenfest relation, strongly suggesting that the phonon thermal expansion also changes sign, as commonly observed in hexagonal layered crystals. These two effects may be connected through subtle changes in the phonon spectrum at Tc.

cond-mat.supr-con↗

arXiv2002

Two-Band Superconductivity in MgB2

The study of the anisotropic superconductor MgB2 using a combination of scanning tunneling microscopy and spectroscopy reveals two distinct energy gaps at Delta1=2.3 meV and Delta2=7.1 meV. Different spectral weights of the partial superconducting density of states (PDOS) are a reflection of different tunneling directions in this multi-band system. Our experimental observations are consistent with the existence of two-band superconductivity in the presence of interband superconducting pair interaction and quasiparticle scattering. Temperature evolution of the tunneling spectra follows the BCS scenario with both gaps vanishing at the bulk Tc. Indeed, the study of tunneling junctions exhibiting only the small gap (c-axis tunneling) clearly and reproducibly show that this gap persists up to the bulk Tc. The data confirm the importance of Fermi-surface sheet dependent superconductivity in MgB2 proposed in the multigap model by Liu et al.

cond-mat.supr-con↗

arXiv2002

Evidence for Two-Band Superconductivity from Break Junction Tunneling on MgB2

Superconductor-insulator-superconductor tunnel junctions have been fabricated on MgB2 that display Josephson and quasiparticle currents. These junctions exhibit a gap magnitude, Delta~2.5 meV, that is considerably smaller than the BCS value, but which clearly and reproducibly closes near the bulk Tc. In conjunction with fits of the conductance spectra, these results are interpreted as direct evidence of two-band superconductivity.

cond-mat.supr-con↗

arXiv2001

Phenomenological two-gap model for the specific heat of MgB_2

We show that the specific heat of the superconductor MgB_2 (MgB2) in zero field, for which significant non-BCS features have been reported, can be fitted, essentially within experimental error, over the entire range of temperature to T_c by a phenomenological two-gap model. The resulting gap parameters agree with previous determinations from band-structure calculations, and from various spectroscopic experiments. The determination from specific heat, a bulk property, shows that the presence of two superconducting gaps in MgB_2 is a volume effect.

cond-mat.supr-con↗

arXiv2001

Hydrostatic Pressure Dependence of the Superconducting and Structural Properties of MgB2

In this paper we report parallel in situ neutron powder diffraction and Tc(P) measurements versus pressure on the same MgB2 sample in a He-gas apparatus to 0.6 GPa; in addition, we present Tc(P) measurements in a helium-loaded diamond-anvil-cell to 20 GPa on the same sample. Our results are compared with those of other groups. The high precision achieved in these measurements allows a quantitative evaluation of the change in Tc as a function of the changes in structure. Our results are consistent with electron-phonon pairing in MgB2.

cond-mat.supr-con↗

arXiv2001

MgB2 tunnel junctions and 19 K low-noise dc superconducting quantum interference devices

Point contact junctions made from two pieces of MgB2 can be adjusted to exhibit either superconductor-insulator-superconductor (SIS) or superconductor-normal metal-superconductor (SNS) current-voltage characteristics. The SIS characteristics are in good agreement with the standard tunneling model for s-wave superconductors, and yield an energy gap of (2.02 +/- 0.08) meV. The SNS characteristics are in good agreement with the predictions of the resistively-shunted junction model. DC Superconducting QUantum Interference Devices made from two SNS junctions yield magnetic field noise as low as 35 fT/Hz^{1/2} at 19 K.

cond-mat.supr-con↗

arXiv2001

Identification and Characterization of Two Energy Gaps in Superconducting MgB2 by Specific-Heat Measurements

This paper reports specific-heat measurements on superconducting MgB2 in magnetic fields to 9 T. In zero magnetic field the data can be fitted to a two-gap model, which is a generalization of a semi-empirical model for strong-coupled, single-gap superconductors (the alpha-model), to within the precision of the data. Both gaps close at Tc, with one gap larger and one smaller than the BCS weak-coupling-limit. (The two gaps have a ratio ~ 4:1.) Each gap accounts for ~ 50% of the normal electron density of states. The parameters characterizing the fits agree well with those from recent spectroscopic measurements and theory. In magnetic fields the superconductong anomaly is broadened as expected for an anisotropic, randomly-oriented superconductor.

cond-mat.supr-con↗