arXiv subjects

D. Gupta

Publications and source records attributed to D. Gupta.

At least 19 recordsLinked to original sources

arXiv2025

Simulation Driven Design of a Multilayer Plasmonic Sensor Using Cu Ni and BaTiO3 for Waterborne Pathogen Detection

We present a simulation guided design for a multilayer surface plasmon resonance (SPR) based biosensor capable of detecting refractive index changes in a target induced by analytes. Surface plasmons are excited using a hybrid Kretschmann configuration with a calcium fluoride (CaF2) prism under transverse magnetic polarization illumination. In the sensing architecture, copper (Cu) serves as the plasmonic metal and is overlaid with a thin nickel (Ni) layer to prevent oxidation. To enhance analyte coupling and electromagnetic field confinement, a dielectric layer of barium titanium oxide (BaTiO3) along with a monolayer of graphene oxide (GO) is incorporated. The multilayer structure is iteratively optimized using the transfer matrix method for angular interrogation at a wavelength of 1064 nm, focusing on key performance parameters such as sensitivity, minimum reflectivity, and figure of merit (FOM). Finite element method based simulations confirm efficient surface plasmon excitation, with optimal layer thicknesses of 30 nm for Cu and 5 nm for BaTiO3. The proposed SPR based sensor (CaF2 Cu Ni BaTiO3 GO) achieves a sensitivity of 157.8 deg per RIU and a figure of merit of 17.48 RIU minus one while detecting the presence of Escherichia coli bacteria in water, demonstrating its potential for waterborne pathogen sensing applications.

physics.optics↗

arXiv2025

First experiments with ultrashort, circularly polarized soft X-ray pulses at FLASH2

Time-resolved absorption spectroscopy as well as magnetic circular dichroism with circularly polarized soft X-rays (XAS and XMCD) are powerful tools to probe electronic and magnetic dynamics in magnetic materials element- and site-selectively. Employing these methods, groundbreaking results have been obtained for instance for magnetic alloys, which helped to fundamentally advance the field of ultrafast magnetization dynamics. At the free electron laser facility FLASH key capabilities for ultrafast XAS and XMCD experiments have recently improved: In an upgrade, an APPLE-III helical afterburner undulator was installed at FLASH2 in September 2023. This installation allows for the generation of circularly polarized soft X-ray pulses with a duration of a few tens of femtoseconds covering the L3,2-edges of the important 3d transition metal elements with pulse energies of several uJ. Here, we present first experimental results with such ultrashort X-ray pulses from the FL23 beamline employing XMCD at the L-edges of the 3d metals, Co, Fe and Ni. We obtain significant dichroic difference signals indicating a degree of circular polarization close to 100%. With the pulse-length preserving monochromator at beamline FL23 and an improved pump laser setup, FLASH can offer important and efficient experimental instrumentation for studies on ultrafast spin dynamics in 3d transition metals, multilayers, and alloys.

cond-mat.mtrl-sci↗

arXiv2024

Stability of monodomain III-V crystals and antiphase boundaries over a Si monoatomic step

Here, we compare the stabilities of different III-V crystals configurations on stepped Si substrates, with or without anti-phase boundaries, for abrupt and compensated interfaces, using density functional theory. Thermodynamic stability of the different heterostructures is analyzed with an atomic scale description of charge densities distribution and mechani-cal strain. We show that the configuration where a III-V crystal adapts to a Si monoatomic step through change of charge compensation at the hetero-interface is much more stable than the configuration in which an antiphase boundary is formed. This study thus demonstrates that antiphase boundaries commonly observed in III-V/Si samples are not origi-nating from Si monoatomic step edges but from inevitable kinetically driven coalescence of monophase 3D III-V islands.

cond-mat.mtrl-sci↗

arXiv2024

Study of the $^7$Be($d$,$^3$He)$^6$Li* reaction at 5 MeV/u

The measurement of the $^7$Be($d$,$^3$He)$^6$Li* transfer cross section at 5 MeV/u is carried out. The population of the 2.186 MeV excited state of $^6$Li in this reaction channel is observed for the first time. The experimental angular distributions have been analyzed in the finite range DWBA and coupled-channel frameworks. The effect of the $^7$Be($d$,$^3$He)$^6$Li reaction on both the $^6$Li and $^7$Li abundances are investigated at the relevant big-bang nucleosynthesis energies. The excitation function is calculated by TALYS and normalized to the experimental data. The $S$ factor of the ($d$,$^3$He) channel from the present work is about 50$\%$ lower than existing data at nearby energies. At big-bang energies, the $S$ factor is about three orders of magnitude smaller than that of the ($d,p$) channel. The ($d$,$^3$He) reaction rate is found to have a less than 0.1$\%$ effect on the $^{6,7}$Li abundances.

nucl-ex↗

arXiv2023

Inevitable Si surface passivation prior to III-V/Si epitaxy: A strong impact on wetting properties

Here, we quantitatively estimate the impact of the inevitable Si surface passivation prior to III-V/Si hetero-epitaxy on the surface energy of the Si initial substrate, and explore its consequences for the description of wetting properties. Density Functional Theory is used to determine absolute surface energies of P- and Ga-passivated Si surfaces and their dependencies with the chemical potential. Especially, we show that, while a ~90 meV/$\r{A}^2$ surface energy is usually considered for the nude Si surface, surface passivation by Ga- or P- atoms leads to a strong stabilization of the surface, with a surface energy in the [50-75 meV/$\r{A}^2$] range. The all-ab initio analysis of the wetting properties indicate that a complete wetting situation would become possible only if the initial passivated Si surface could be destabilized by at least 15 meV/$\r{A}^2$ or if the III-V (001) surface could be stabilized by the same amount.

cond-mat.mtrl-sci↗

arXiv2023

Discovery of H$_2$CCCH$^+$ in TMC-1

Based on a novel laboratory method, 14 mm-wave lines of the molecular ion H$_2$CCCH$^+$ have been measured in high resolution, and the spectroscopic constants of this asymmetric rotor determined with high accuracy. Using the Yebes 40 m and IRAM 30 m radio telescopes, we detect four lines of H$_2$CCCH$^+$ towards the cold dense core TMC-1. With a dipole moment of about 0.55 Debye obtained from high-level ab initio calculations, we derive a column density of 5.4$\pm$1$\times$10$^{11}$ cm$^{-2}$ and 1.6$\pm$0.5$\times$10$^{11}$ cm$^{-2}$ for the ortho and para species, respectively, and an abundance ratio N(H$_2$CCC)/N(H$_2$CCCH$^+$)= 2.8$\pm$0.7. The chemistry of H$_2$CCCH$^+$ is modelled using the most recent chemical network for the reactions involving the formation of H$_2$CCCH$^+$. We find a reasonable agreement between model predictions and observations, and new insights into the chemistry of C$_3$ bearing species in TMC-1 are obtained.

astro-ph.GA↗

arXiv2023

Determination of III-V/Si absolute interface energies: impact on wetting properties

Here, we quantitatively determine the impact of III-V/Si interface atomic configuration on the wetting properties of the system. Based on a description at the atomic scale using density functional theory, we first show that it is possible to determine the absolute interface energies in heterogeneous materials systems. A large variety of absolute GaP surface energies and GaP/Si interface energies are then computed, confirming the large stability of charge compensated III-V/Si interfaces with an energy as low as 23 meV/\r{A}$^{2}$. While stable compensated III-V/Si interfaces are expected to promote complete wetting conditions, it is found that this can be easily counterbalanced by the substrate initial passivation, which favors partial wetting conditions.

cond-mat.mtrl-sci↗

arXiv2022

Study of elastic and inelastic scattering of $^7$Be + $^{12}$C at 35 MeV

The elastic and inelastic scattering of $^7$Be from $^{12}$C have been measured at an incident energy of 35 MeV. The inelastic scattering leading to the 4.439 MeV excited state of $^{12}$C has been measured for the first time. The experimental data cover an angular range of $\theta_{cm}$ = 15$^{\circ}$-120$^{\circ}$. Optical model analyses were carried out with Woods-Saxon and double-folding potential using the density dependent M3Y (DDM3Y) effective interaction. The microscopic analysis of the elastic data indicates breakup channel coupling effect. A coupled-channel analysis of the inelastic scattering, based on collective form factors, show that mutual excitation of both $^7$Be and $^{12}$C is significantly smaller than the single excitation of $^{12}$C. The larger deformation length obtained from the DWBA analysis could be explained by including the excitation of $^7$Be in a coupled-channel analysis. The breakup cross section of $^7$Be is estimated to be less than 10$\%$ of the reaction cross section. The intrinsic deformation length obtained for the $^{12}$C$^*$ (4.439 MeV) state is $\delta _2$ = 1.37 fm. The total reaction cross section deduced from the analysis agrees very well with Wong's calculations for similar weakly bound light nuclei on $^{12}$C target.

nucl-ex↗

arXiv2022

Resonance excitations in $^7$Be(d,p)$^8$Be$^\ast$ to address the cosmological lithium problem

The anomaly in lithium abundance is a well-known unresolved problem in nuclear astrophysics. A recent revisit to the problem tried the avenue of resonance enhancement to account for the primordial $^7$Li abundance in standard big-bang nucleosynthesis (BBN). Prior measurements of the $^7$Be(d,p)$^8$Be* reaction could not account for the individual contributions of the different excited states involved, particularly at higher energies close to the Q-value of the reaction. We carried out an experiment at HIE-ISOLDE, CERN to study this reaction at E$_{cm}$ = 7.8 MeV, populating excitations up to 22 MeV in $^8$Be for the first time. The angular distributions of the several excited states have been measured and the contributions of the higher excited states in the total cross section at the relevant big-bang energies were obtained by extrapolation to the Gamow window using the TALYS code. The results show that by including the contribution of the 16.63 MeV state, the maximum value of the total S-factor inside the Gamow window comes out to be 167 MeV b as compared to earlier estimate of 100 MeV b. However, this still does not account for the lithium discrepancy.

nucl-ex↗

arXiv2020

Supersymmetric quantum mechanics to study the 16.8 MeV resonance state of $^{9}$B

The study of a high-lying resonant state of $^{9}$B is carried out using supersymmetric quantum mechanics (SQM). The resulting isospectral potentials are very deep and narrow and the generated wave functions identify the resonance at 16.84 MeV with a width of 69 keV. The present work shows that SQM can be successfully applied for detection of high-lying resonances in unstable nuclei.

nucl-th↗

arXiv2019

Entropy production in systems with unidirectional transitions

The entropy production is one of the most essential features for systems operating out of equilibrium. The formulation for discrete-state systems goes back to the celebrated Schnakenberg's work and hitherto can be carried out when for each transition between two states also the reverse one is allowed. Nevertheless, several physical systems may exhibit a mixture of both unidirectional and bidirectional transitions, and how to properly define the entropy production in this case is still an open question. Here, we present a solution to such a challenging problem. The average entropy production can be consistently defined, employing a mapping that preserves the average fluxes, and its physical interpretation is provided. We describe a class of stochastic systems composed of unidirectional links forming cycles and detailed-balanced bidirectional links, showing that they behave in a pseudo-deterministic fashion. This approach is applied to a system with time-dependent stochastic resetting. Our framework is consistent with thermodynamics and leads to some intriguing observations on the relation between the arrow of time and the average entropy production for resetting events.

cond-mat.stat-mech↗

arXiv2017

One-parameter scaling theory for DNA extension in a nanochannel

Experiments measuring DNA extension in nanochannels are at odds with even the most basic predictions of current scaling arguments for the conformations of confined semiflexible polymers such as DNA. We show that a theory based on a weakly self-avoiding, one-dimensional "telegraph" process collapses experimental data and simulation results onto a single master curve throughout the experimentally relevant region of parameter space and explains the mechanisms at play.

physics.bio-ph↗

arXiv2017

Resonance State Wave Functions of $^{15}$Be using Supersymmetric Quantum Mechanics

The theoretical procedure of supersymmetric quantum mechanics is adopted to generate the resonance state wave functions of the unbound nucleus $^{15}$Be. In this framework, we used a density dependent M3Y microscopic potential and arrived at the energy and width of the 1.8 MeV (5/2$^+$) resonance state. We did not find any other nearby resonances for $^{15}$Be. It becomes apparent that the present framework is a powerful tool to theoretically complement the increasingly important accelerator based experiments with unbound nuclei.

nucl-th↗

arXiv2014

Study of resonance states of $^{11}$Be with isospectral bound state microscopic potential

The theoretical procedure of supersymmetric quantum mechanics (SQM) is adopted for the first time to study quasi-bound states of a weakly bound nuclear system using microscopic potential. The density dependent M3Y (DDM3Y) effective interaction was found earlier to give a satisfactory description of radioactivity, nuclear matter and scattering. In the present work, we have generated a two-body potential microscopically in a single folding model using the DDM3Y effective interaction. From this potential, SQM generated a family of isospectral potentials for $^{11}$Be ($^{10}$Be + n). We investigated the 5/2$^+$, 3/2$^-$ and 3/2$^+$ resonance states of $^{11}$Be. The experimental data and the present calculations of excitation energies of the above resonance states are found to be in good agreement.

nucl-th↗

arXiv2013

Complex fragment emission in low energy light-ion reactions

Inclusive energy spectra of the complex fragments (3 $\leq$ Z $\leq$ 5) emitted in the reactions $^{12}$C (77 MeV)+ $^{28}$Si, $^{11}$B (64 MeV)+ $^{28}$Si and $^{12}$C (73 MeV)+ $^{27}$Al (all having the same excitation energy of $ \sim$ 67 MeV), have been measured in the angular range of 10$^\circ$ $\lesssim θ_{lab} \lesssim$ 60$^\circ$. The fully energy damped (fusion-fission) and the partially energy damped (deep inelastic) components of the fragment energy spectra have been extracted. It has been found that the yields of the fully energy damped fragments for all the above reactions are in conformity with the respective statistical model predictions. The time scales of various deep inelastic fragment emissions have been extracted from the angular distribution data. The angular momentum dissipation in deep inelastic collisions has been estimated from the data and it has been found to be close to the corresponding sticking limit value.

nucl-ex↗

arXiv2013

Deformation in 28Si* produced via 16O + 12C reaction

The energy spectra of the $α$ particles emitted in the reactions $^{16}$O (7-10 MeV/nucleon) + $^{12}$C have been measured in the center of mass angular range of 25$^\circ$ $\lesssim θ_{c.m.} \lesssim$ 70$^\circ$. The experimental energy spectra have been compared with those obtained from the statistical model calculation with "deformability" parameters predicted by rotating liquid drop model (RLDM) and also fitted the same with optimized "deformability" parameters, which are quite different from the respective RLDM values. The data have also been found to be explained quite well using "frozen" deformation approximation, where the "deformability" parameters have been kept fixed at RLDM values of the parent nucleus throughout the decay process. The effective radius in the latter case is smaller compared to that obtained using the optimized parameters; however, in both cases, the deformations (effective radii) are larger than the corresponding RLDM values. So, considering the uncertainties in the estimation of actual compound nucleus deformations, it can, only qualitatively, be said that equilibrium orbiting, which is similar to particle evaporation in time scale, could also be one of the contributing factors for the observed deformation.

nucl-ex↗

arXiv2012

Onset of deformation at $N = 112$ in Bi nuclei

The high spin states in $^{195}$Bi has been studied by $\gamma$-ray spectroscopic method using the $^{181}$Ta($^{20}$Ne, 6n) fusion evaporation reaction at 130 MeV. The $\gamma\gamma$ coincidence data were taken using an array of 8 clover HPGe detectors. The spin and parity assignments of the excited states have been made from the measured directional correlation from oriented states (DCO) ratios and integrated polarization asymmetry (IPDCO) ratios. The results show, for the first time, the evidence of a rotational like band based on a 13/2$^+$ band head in this nucleus, indicating the onset of deformation at neutron number $N = 112$ for the Bismuth isotopes. The results obtained were found to be consistent with the prediction of the total Routhian surface calculations using Woods Saxon potential. The same calculations also predict a change in shape from oblate to triaxial in $^{195}$Bi at high rotational frequency.

nucl-ex↗

arXiv2011

Study of transfer reaction channel in $^{12}$C + $^{27}$Al system

The 1p transfer channel in the $^{27}$Al($^{12}$C, $^{11}$B)$^{28}$Si reaction has been studied at E$_{lab}$ = 73, 81 and 85 MeV. The finite range distorted wave Born approximation calculations have been performed using phenomenological optical model potential to analyze the angular distributions for 3 transitions populating the 0.0, 1.78 and 4.62 MeV states of $^{28}$Si and 2 transitions populating the 2.12 and 4.44 MeV states of $^{11}$B via the $^{27}$Al($^{12}$C, $^{11}$B)$^{28}$Si reaction. The spectroscopic strengths as well as spectroscopic factors have been extracted for all the five states. The extracted strength values are compared with shell model calculations.

nucl-ex↗