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D. L. Carroll

Publications and source records attributed to D. L. Carroll.

5 recordsLinked to original sources

Magnetic Force Imaging of 2D Topological Insulators

Two-dimensional topological insulators are central to our understanding of the connection between topological symmetries in a material and its band electronics. Within this class of materials, a breadth of complex quantum behaviors, such as persistent spin-polarized current states in the presence of a broken time reversal symmetry, and temperature-independent topological protection of quantum states, are thought to exist. However, current studies using photoemission and spectroscopic analyses or transport experiments fail to provide insight into the interplay between the physical 2D manifold and the band topology itself, since they do not provide spatial resolution of the phenomena to be understood. In this work, we develop a methodology for applying magnetic force microscopy to such systems to address this issue. Using well-characterized 2D crystallites of bismuth telluride ($Bi_2$$Te_3$), we image the magnetic signal directly associated with topological edge states. The observed phase contrast is remarkably robust at a temperature of 25°C and occurs across crystallite sizes and shapes. A detailed analysis of the magnetic imaging suggests that the current observed is composed of two parts: the first is a persistent current ($I_{Persistent}$) as predicted by theory, and the second is due to Faraday induction, $I_{Faraday}$. Damping dynamics of the cantilever during imaging further suggest that this Faraday EMF is established by spin accumulation along the 1D edge channel of the crystal, which then converts to a charge current in the presence of time reversal symmetry breaking, creating a novel form of rectification in the channel. This unexpected result can prompt new ideas for topology-based circuit elements with extremely low losses and power consumption.

cond-mat.mes-hall

Methanofullerene Elongated Nanostructure Formation for Enhanced Organic Solar Cells

Using transmission electron microscopy (TEM) and Z-contrast imaging we have demonstrated elongated nanostructure formation of fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) within an organic host through annealing. The annealing provides an enhanced mobility of the PCBM molecules and, with good initial dispersion, allows for the formation of exaggerated grain growth within the polymer host. We have assembled these nanostructures within the regioregular conjugated polymer poly(3-hexylthiophene) (P3HT). This PCBM elongated nanostructure formation maybe responsible for the very high efficiencies observed, at very low loadings of PCBM (1:0.6, polymer to PCBM), in annealed photovoltaics. Moreover, our high resolution TEM and electron energy loss spectroscopy studies clearly show that the PCBM crystals remain crystalline and are unaffected by the 200-keV electron beam

cond-mat.mtrl-sci

Nonlinear behavior in the Thermopower of Doped Carbon Nanotubes Due to Strong, Localized States

The temperature dependent thermoelectric power (TEP) of boron and nitrogen doped multi-walled carbon nanotube mats has been measured showing that such dopants can be used to modify the majority conduction from p-type to n-type. The TEP of boron doped nanotubes is positive, indicating hole-like carriers. In contrast, the nitrogen doped material exhibits negative TEP over the same temperature range, suggesting electron-like conduction. Therefore, the TEP distinct nonlinearites are primarily due to the formation of donor and acceptor states in the B- and N- doped materials. The sharply varying density of states used in our model can be directly correlated to the scanning tunneling spectroscopy studies of these materials.

cond-mat

Substrate Interface Interactions

By utilizing the current transients in scanning tunneling spectroscopy, the local interfacial electronics between multiwalled carbon nanotubes and several supporting substrates has been investigated. Voltage offsets in the tunneling spectra are directly correlated with the formation of a dipole layer at the nanotube-substrate interface strongly suggesting the formation of interface states. Further, a systematic variation in this local potential, as a function of tube diameter, is observed for both metallic substrates (Au) and semi-metallic substrates (graphite). In both cases, tubes with diameters between ~ 5 nm and 30 nm, the interfacial potential is nearly constant as a function of tube diameter. However, for tube diameters < 5 nm, a dramatic change in the local potential is observed. Using ab initio techniques, this diameter dependent electronic interaction is shown to derive from changes in the tube-substrate hybridization that results from the curvature of the nanotubes.

cond-mat

Identification of Electron Donor States in N-doped Carbon Nanotubes

Nitrogen doped carbon nanotubes have been synthesized using pyrolysis and characterized by Scanning Tunneling Spectroscopy and transmission electron microscopy. The doped nanotubes are all metallic and exhibit strong electron donor states near the Fermi level. Using tight-binding and ab initio calculations, we observe that pyridine-like N structures are responsible for the metallic behavior and the prominent features near the Fermi level. These electron rich structures are the first example of n-type nanotubes, which could pave the way to real molecular hetero-junction devices.

cond-mat.mtrl-sci