arXiv subjects

D. Vion

Publications and source records attributed to D. Vion.

At least 19 recordsLinked to original sources

arXiv2026

Precision hyperfine spectroscopy of an individual nuclear-spin-9/2

Single-spin magnetic resonance spectroscopy promises to yield structural and chemical information at the level of individual atoms or molecules, in a non-invasive way. Here, we use an Er3+ paramagnetic center in a CaWO4 crystal, detected by microwave photon counting at 10 mK, as a nanoscale magnetic sensor to measure the NMR spectrum of a proximal individual nuclear-spin-9/2 93Nb impurity with Hertz spectral resolution. From these measurements, we determine the 93Nb insertion site, its position relative to the Er3+ , and its complete quadrupolar tensor. We moreover harness the high spectral resolution of our measurements to establish the presence of two previously unobserved terms in the spin Hamiltonian. The first describes a coupling between the Er3+ spin and the 93Nb nuclear quadrupole; it possibly originates from a spin-dependent electrostatic interaction between the two systems. The second is a nuclear hexadecapolar term, and may be caused by the coupling of the electric field third derivative to the 93Nb nuclear hexadecapolar moment.

quant-ph↗

arXiv2025

Addressing spins at the clock transitions with a frequency- and bandwidth-tunable superconducting resonator

Solid-state spin ensembles addressed via superconducting circuits are promising candidates for quantum memory applications, offering multimodal storage capability and second-long coherence times at their clock transition. Implementing practical memory schemes requires dynamic control over both the resonator frequency and bandwidth. In this letter, we report measurements of a superconducting resonator whose frequency can be tuned by passing a DC current through the high-kinetic-inductance thin film, and whose bandwidth can be tuned by parametric coupling to a low-Q buffer resonator. Using this resonator, we address an ensemble of bismuth donors at their clock transition, measuring a Hahn-echo coherence time of 450 ms. We demonstrate RF driving of the bismuth donor hyperfine transitions, as well as dynamic bandwidth control of the resonator.

quant-ph↗

arXiv2024

All-microwave spectroscopy and polarization of individual nuclear spins in a solid

We report magnetic resonance spectroscopy measurements of individual nuclear spins in a crystal coupled to a neighbouring paramagnetic center, detected using microwave fluorescence at millikelvin temperatures. We observe real-time quantum jumps of the nuclear spin state, a proof of their individual nature. By driving the forbidden transitions of the coupled electron-nuclear spin system, we also achieve single-spin solid-effect dynamical nuclear polarization. Relying exclusively on microwave driving and microwave photon counting, the methods reported here are in principle applicable to a large number of electron-nuclear spin systems, in a wide variety of samples.

quant-ph↗

arXiv2024

Electron Paramagnetic Resonance spectroscopy of a scheelite crystal using microwave photon counting

Counting the microwave photons emitted by an ensemble of electron spins when they relax radiatively has recently been introduced as a sensitive new method for electron paramagnetic resonance spectroscopy at millikelvin temperatures. Here, we apply this spin fluorescence method to a scheelite crystal of CaWO4, finding some known ($\mathrm{Er}^{3+}$, $\mathrm{Yb}^{3+}$, $\mathrm{Nd}^{3+}$ and $\mathrm{Fe}^{3+}$) and other unknown paramagnetic impurities. Investigating the zero nuclear spin isotope ($I=0$) transition of $\mathrm{Er}^{3+}:\mathrm{CaWO}_4$ as a model system, we provide a quantitative analysis of the time-dependent photon counting rate following an excitation pulse, as a function of its power. The achieved signal-to-noise ratio is found to be an order of magnitude higher than the one obtained by inductively-detected Hahn echo under identical conditions. Finally, we use spin fluorescence spectroscopy at low excitation power to probe the properties of rare-earth-ions close to a metallic wire deposited on the surface; our data reveal line distortion caused by the mechanical strain imparted by the thermal contractions of the metal relative to the underlying crystal. Coherent oscillations are also observed for the most highly strained ions.

quant-ph↗

arXiv2021

Emission of photon multiplets by a dc-biased superconducting circuit

We observe the emission of bunches of $k \geqslant 1$ photons by a circuit made of a microwave resonator in series with a voltage-biased tunable Josephson junction. The bunches are emitted at specific values $V_k$ of the bias voltage, for which each Cooper pair tunneling across the junction creates exactly k photons in the resonator. The latter is a micro-fabricated spiral coil which resonates and leaks photons at 4.4~GHz in a measurement line. Its characteristic impedance of 1.97~k$\Omega$ is high enough to reach a strong junction-resonator coupling and a bright emission of the k-photon bunches. We show that a RWA treatment of the system accounts quantitatively for the observed radiation intensity, from $k=1$ to $6$, and over three orders of magnitude when varying the Josephson energy $E_J$. We also measure the second order correlation function of the radiated microwave to determine its Fano factor $F_k$, which in the low $E_J$ limit, confirms with $F_k=k$ the emission of $k$ photon bunches. At larger $E_J$, a more complex behavior is observed in quantitative agreement with numerical simulations.

cond-mat.supr-con↗

arXiv2021

Hyperfine spectroscopy in a quantum-limited spectrometer

We report measurements of electron spin echo envelope modulation (ESEEM) performed at millikelvin temperatures in a custom-built high-sensitivity spectrometer based on superconducting micro-resonators. The high quality factor and small mode volume (down to 0.2pL) of the resonator allow to probe a small number of spins, down to $5\cdot 10^2$. We measure 2-pulse ESEEM on two systems: erbium ions coupled to $^{183}$W nuclei in a natural-abundance $\text{CaWO}_4$ crystal, and bismuth donors coupled to residual $^{29}$Si nuclei in a silicon substrate that was isotopically enriched in the $^{28}$Si isotope. We also measure 3- and 5-pulse ESEEM for the bismuth donors in silicon. Quantitative agreement is obtained for both the hyperfine coupling strength of proximal nuclei, and the nuclear spin concentration.

quant-ph↗

arXiv2021

Spatially-resolved decoherence of donor spins in silicon strained by a metallic electrode

Electron spins are amongst the most coherent solid-state systems known, however, to be used in devices for quantum sensing and information processing applications, they must be typically placed near interfaces. Understanding and mitigating the impacts of such interfaces on the coherence and spectral properties of electron spins is critical to realize such applications, but is also challenging: inferring such data from single-spin studies requires many measurements to obtain meaningful results, while ensemble measurements typically give averaged results that hide critical information. Here, we report a comprehensive study of the coherence of near-surface bismuth donor spins in 28-silicon at millikelvin temperatures. In particular, we use strain-induced frequency shifts caused by a metallic electrode to make spatial maps of spin coherence as a function of depth and position relative to the electrode. By measuring magnetic-field-insensitive clock transitions we separate magnetic noise caused by surface spins from charge noise. Our results include quantitative models of the strain-split spin resonance spectra and extraction of paramagnetic impurity concentrations at the silicon surface. The interplay of these decoherence mechanisms for such near-surface electron spins is critical for their application in quantum technologies, while the combination of the strain splitting and clock transition extends the coherence lifetimes by up to two orders of magnitude, reaching up to 300 ms at a mean depth of only 100nm. The technique we introduce here to spatially map coherence in near-surface ensembles is directly applicable to other spin systems of active interest, such as defects in diamond, silicon carbide, and rare earth ions in optical crystals.

quant-ph↗

arXiv2020

Determining the position of a single spin relative to a metallic nanowire

The nanoscale localization of individual paramagnetic defects near an electrical circuit is an important step for realizing hybrid quantum devices with strong spin-microwave photon coupling. Here, we demonstrate the fabrication of an array of individual NV centers in diamond near a metallic nanowire deposited on top of the substrate. We determine the relative position of each NV center with $\sim$10\,nm accuracy, using it as a vector magnetometer to measure the field generated by passing a dc current through the wire.

quant-ph↗

arXiv2020

Generating two continuous entangled microwave beams using a dc-biased Josephson junction

We show experimentally that a dc-biased Josephson junction in series with two microwave resonators emits entangled beams of microwaves leaking out of the resonators. In the absence of a stationary phase reference for characterizing the entanglement of the outgoing beams, we measure second-order coherence functions for proving entanglement up to an emission rate of 2.5 billion photon pairs per second. The experimental results are found in quantitative agreement with theory, proving that the low frequency noise of the dc bias is the main limitation for the coherence time of the entangled beams. This agreement allows us to evaluate the entropy of entanglement of the resonators, and to identify the improvements that could bring this device closer to a useful bright source of entangled microwaves for quantum-technological applications.

cond-mat.mes-hall↗

arXiv2020

Multimode storage of quantum microwave fields in electron spins over 100 ms

A long-lived multi-mode qubit register is an enabling technology for modular quantum computing architectures. For interfacing with superconducting qubits, such a quantum memory should be able to store incoming quantum microwave fields at the single-photon level for long periods of time, and retrieve them on-demand. Here, we demonstrate the partial absorption of a train of weak microwave fields in an ensemble of bismuth donor spins in silicon, their storage for 100 ms, and their retrieval, using a Hahn-echo-like protocol. The long storage time is obtained by biasing the bismuth donors at a clock transition. Phase coherence and quantum statistics are preserved in the storage.

quant-ph↗

arXiv2019

Antibunched photons emitted by a dc biased Josephson junction

We show experimentally that a dc biased Josephson junction in series with a high-enough impedance microwave resonator emits antibunched photons. Our resonator is made of a simple micro-fabricated spiral coil that resonates at 4.4 GHz and reaches a 1.97 k$Ω$ characteristic impedance. The second order correlation function of the power leaking out of the resonator drops down to 0.3 at zero delay, which demonstrates the antibunching of the photons emitted by the circuit at a rate of 6 $10^7$ photons per second. Results are found in quantitative agreement with our theoretical predictions. This simple scheme could offer an efficient and bright single-photon source in the microwave domain.

cond-mat.mes-hall↗

arXiv2017

Magnetic resonance with squeezed microwaves

Vacuum fluctuations of the electromagnetic field set a fundamental limit to the sensitivity of a variety of measurements, including magnetic resonance spectroscopy. We report the use of squeezed microwave fields, which are engineered quantum states of light for which fluctuations in one field quadrature are reduced below the vacuum level, to enhance the detection sensitivity of an ensemble of electronic spins at millikelvin temperatures.} By shining a squeezed vacuum state on the input port of a microwave resonator containing the spins, we obtain a $1.2$\,dB noise reduction at the spectrometer output compared to the case of a vacuum input. This result constitutes a proof of principle of the application of quantum metrology to magnetic resonance spectroscopy.

cond-mat.mes-hall↗

arXiv2017

Inductive-detection electron-spin resonance spectroscopy with $\mathbf{65}\,$spins$/\sqrt{\text{Hz}}$ sensitivity

We report electron spin resonance spectroscopy measurements performed at millikelvin temperatures in a custom-built spectrometer comprising a superconducting micro-resonator at $7$ GHz and a Josephson parametric amplifier. Owing to the small ${\sim}10^{-12}λ^3$ magnetic resonator mode volume and to the low noise of the parametric amplifier, the spectrometer sensitivity reaches $260\pm40$ spins$/$echo and $65\pm10$ $\mathrm{spins}/\sqrt{\text{Hz}}$, respectively.

quant-ph↗

arXiv2017

Quantum limited amplification from inelastic Cooper pair tunneling

Nature sets fundamental limits regarding how accurate the amplification of analog signals may be. For instance, a linear amplifier unavoidably adds some noise which amounts to half a photon at best. While for most applications much higher noise levels are acceptable, the readout of microwave quantum systems, such as spin or superconducting qubits, requires noise as close as possible to this ultimate limit. To date, it is approached only by parametric amplifiers exploiting non-linearities in superconducting circuits and driven by a strong microwave pump tone. However, this microwave drive makes them much more difficult to implement and operate than conventional DC powered amplifiers, which so far suffer from much higher noise. Here we present the first experimental proof that a simple DC-powered setup allows for amplification close to the quantum limit. Our amplification scheme is based on the stimulated microwave photon emission accompanying inelastic Cooper pair tunneling through a DC-biased Josephson junction, with the key to low noise lying in a well defined auxiliary idler mode, in analogy to parametric amplifiers.

cond-mat.mes-hall↗

arXiv2017

Emission of non-classical radiation by inelastic Cooper pair tunneling

We show that a properly dc-biased Josephson junction in series with two microwave resonators of different frequencies emits photon pairs in the resonators. By measuring auto- and inter-correlations of the power leaking out of the resonators, we demonstrate two-mode amplitude squeezing below the classical limit. This non-classical microwave light emission is found to be in quantitative agreement with our theoretical predictions, up to an emission rate of 2 billion photon pairs per second.

cond-mat.mes-hall↗

arXiv2015

Towards a spin-ensemble quantum memory for superconducting qubits

This article reviews efforts to build a new type of quantum device, which combines an ensemble of electronic spins with long coherence times, and a small-scale superconducting quantum processor. The goal is to store over long times arbitrary qubit states in orthogonal collective modes of the spin-ensemble, and to retrieve them on-demand. We first present the protocol devised for such a multi-mode quantum memory. We then describe a series of experimental results using NV center spins in diamond, which demonstrate its main building blocks: the transfer of arbitrary quantum states from a qubit into the spin ensemble, and the multi-mode retrieval of classical microwave pulses down to the single-photon level with a Hahn-echo like sequence. A reset of the spin memory is implemented in-between two successive sequences using optical repumping of the spins.

quant-ph↗

arXiv2015

Coherent manipulation of Andreev states in superconducting atomic contacts

Coherent control of quantum states has been demonstrated in a variety of superconducting devices. In all these devices, the variables that are manipulated are collective electromagnetic degrees of freedom: charge, superconducting phase, or flux. Here, we demonstrate the coherent manipulation of a quantum system based on Andreev bound states, which are microscopic quasiparticle states inherent to superconducting weak links. Using a circuit quantum electrodynamics setup we perform single-shot readout of this "Andreev qubit". We determine its excited state lifetime and coherence time to be in the microsecond range. Quantum jumps and parity switchings are observed in continuous measurements. In addition to possible quantum information applications, such Andreev qubits are a testbed for the physics of single elementary excitations in superconductors.

cond-mat.mes-hall↗

arXiv2015

Controlling spin relaxation with a cavity

Spontaneous emission of radiation is one of the fundamental mechanisms by which an excited quantum system returns to equilibrium. For spins, however, spontaneous emission is generally negligible compared to other non-radiative relaxation processes because of the weak coupling between the magnetic dipole and the electromagnetic field. In 1946, Purcell realized that the spontaneous emission rate can be strongly enhanced by placing the quantum system in a resonant cavity -an effect which has since been used extensively to control the lifetime of atoms and semiconducting heterostructures coupled to microwave or optical cavities, underpinning single-photon sources. Here we report the first application of these ideas to spins in solids. By coupling donor spins in silicon to a superconducting microwave cavity of high quality factor and small mode volume, we reach for the first time the regime where spontaneous emission constitutes the dominant spin relaxation mechanism. The relaxation rate is increased by three orders of magnitude when the spins are tuned to the cavity resonance, showing that energy relaxation can be engineered and controlled on-demand. Our results provide a novel and general way to initialise spin systems into their ground state, with applications in magnetic resonance and quantum information processing. They also demonstrate that, contrary to popular belief, the coupling between the magnetic dipole of a spin and the electromagnetic field can be enhanced up to the point where quantum fluctuations have a dramatic effect on the spin dynamics; as such our work represents an important step towards the coherent magnetic coupling of individual spins to microwave photons.

quant-ph↗