arXiv subjects

D. Zueco

Publications and source records attributed to D. Zueco.

At least 19 recordsLinked to original sources

arXiv2025

Strong spin-magnon coupling in a van der Waals magnet with tunable chiral symmetry

Quantum technologies require platforms that can coherently interface qubits with bosonic excitations. Photons have traditionally played this role in cavity quantum electrodynamics, but achieving the same goal using solid-state bosons remains challenging. Here we demonstrate strong and tunable spin-magnon coupling between molecular spin qubits and magnons in a van der Waals antiferromagnetic insulator. Using [Gd(W$_5$O$_{18}$)$_{2}$]$^{9-}$ as the spin ensemble and CrSBr as the magnonic resonator, we observe anticrossings and coherent hybridization, realizing magnon quantum electrodynamics for the first time. Crucially, by rotating the magnetic field, we can dynamically change the magnon symmetry from linear to chiral, enabling in-situ tuning of the coupling strength. Our results establish magnonic cavities as a platform for scalable chiral quantum optics with magnetic materials.

quant-ph↗

arXiv2023

Blueprint of a Molecular Spin Quantum Processor

The implementation of a universal quantum processor still poses fundamental issues related to error mitigation and correction, which demand to investigate also platforms and computing schemes alternative to the main stream. A possibility is offered by employing multi-level logical units (qudits), naturally provided by molecular spins. Here we present the blueprint of a Molecular Spin Quantum Processor consisting of single Molecular Nanomagnets, acting as qudits, placed within superconducting resonators adapted to the size and interactions of these molecules to achieve a strong single spin to photon coupling. We show how to implement a universal set of gates in such a platform and to readout the final qudit state. Single-qudit unitaries (potentially embedding multiple qubits) are implemented by fast classical drives, while a novel scheme is introduced to obtain two-qubit gates via resonant photon exchange. The latter is compared to the dispersive approach, finding in general a significant improvement. The performance of the platform is assessed by realistic numerical simulations of gate sequences, such as Deutsch-Josza and quantum simulation algorithms. The very good results demonstrate the feasibility of the molecular route towards a universal quantum processor.

quant-ph↗

arXiv2022

High cooperativity coupling to nuclear spins on a circuit QED architecture

Nuclear spins are candidates to encode qubits or qudits due to their isolation from magnetic noise and potentially long coherence times. However, their weak coupling to external stimuli makes them hard to integrate into circuit-QED architectures, the leading technology for solid-state quantum processors. Here, we study the coupling of $^{173}$Yb(III) nuclear spin states in an [Yb(trensal)] molecule to superconducting cavities. Experiments have been performed on magnetically diluted single crystals placed on the inductors of lumped-element $LC$ superconducting resonators with characteristic frequencies spanning the range of nuclear and electronic spin transitions. We achieve a high cooperative coupling to all electronic and most nuclear [$^{173}$Yb(trensal)] spin transitions. This result is a big leap towards the implementation of qudit protocols with molecular spins using a hybrid architecture.

quant-ph↗

arXiv2021

Non-reciprocal population dynamics in a quantum trimer

We study a quantum trimer of coupled two-level systems beyond the single-excitation sector, where the coherent coupling constants are ornamented by a complex phase. Accounting for losses and gain in an open quantum systems approach, we show how the mean populations of the states in the system crucially depend on the accumulated phase in the trimer. Namely, for nontrivial accumulated phases, the population dynamics and the steady states display remarkable nonreciprocal behavior in both the singly and doubly excited manifolds. Furthermore, while the directionality of the resultant chiral current is primarily determined by the accumulated phase in the loop, the sign of the flow may also change depending on the coupling strength and the amount of gain in the system. This directionality paves the way for experimental studies of chiral currents at the nanoscale, where the phases of the complex hopping parameters are modulated by magnetic or synthetic magnetic fields.14 pages

cond-mat.mes-hall↗

arXiv2021

A perspective on scaling up quantum computation with molecular spins

Artificial magnetic molecules can contribute to progressing towards large scale quantum computation by: a) integrating multiple quantum resources and b) reducing the computational costs of some applications. Chemical design, guided by theoretical proposals, allows embedding nontrivial quantum functionalities in each molecular unit, which then acts as a microscopic quantum processor able to encode error protected logical qubits or to implement quantum simulations. Scaling up even further requires 'wiring-up' multiple molecules. We discuss how to achieve this goal by the coupling to on-chip superconducting resonators. The potential advantages of this hybrid approach and the challenges that still lay ahead are critically reviewed.

quant-ph↗

arXiv2021

Broad-band spectroscopy of a vanadyl porphyrin: a model electronuclear spin qudit

We explore how to encode more than a qubit in vanadyl porphyrin molecules hosting a electronic spin 1/2 coupled to a nuclear spin 7/2. The spin Hamiltonian and its parameters, as well as the spin dynamics, have been determined via a combination of electron paramagnetic resonance, heat capacity, magnetization and on-chip magnetic spectroscopy experiments performed on single crystals. We find low temperature spin coherence times of micro-seconds and spin relaxation times longer than a second. For sufficiently strong magnetic fields (B larger than 0.1 T, corresponding to resonance frequencies of 9 to 10 GHz) these properties make vanadyl porphyrin molecules suitable qubit realizations. The presence of multiple equispaced nuclear spin levels then merely provides 8 alternatives to define the 0 and 1 basis states. For lower magnetic fields (below 0.1 T), and lower frequencies (smaller than 2 GHz), we find spectroscopic signatures of a sizeable electronuclear entanglement. This effect generates a larger set of allowed transitions between different electronuclear spin states and removes their degeneracies. Under these conditions, we show that each molecule fulfills the conditions to act as a universal 4-qubit processor or, equivalently, as a d = 16 qudit. These findings widen the catalogue of chemically designed systems able to implement non-trivial quantum functionalities, such as quantum simulations and, especially, quantum error correction at the molecular level.

quant-ph↗

arXiv2020

Enhanced molecular spin-photon coupling at superconducting nanoconstrictions

We combine top-down and bottom-up nanolithography to optimize the coupling of small molecular spin ensembles to $1.4$ GHz on-chip superconducting resonators. Nanoscopic constrictions, fabricated with a focused ion beam at the central transmission line, locally concentrate the microwave magnetic field. Drops of free-radical molecules have been deposited from solution onto the circuits. For the smallest ones, the molecules were delivered at the relevant circuit areas by means of an atomic force microscope. The number of spins $N_{\rm eff}$ effectively coupled to each device was accurately determined combining Scanning Electron and Atomic Force Microscopies. The collective spin-photon coupling constant has been determined for samples with $N_{\rm eff}$ ranging between $2 \times 10^{6}$ and $10^{12}$ spins, and for temperatures down to $44$ mK. The results show the well-known collective enhancement of the coupling proportional to the square root of $N_{\rm eff}$. The average coupling of individual spins is enhanced by more than four orders of magnitude (from $4$ mHz up to above $180$ Hz) when the transmission line width is reduced from $400$ microns down to $42$ nm, and reaches maximum values near $1$ kHz for molecules located on the smallest nanoconstrictions. This result opens promising avenues for the realization of magnetic spectroscopy experiments at the nanoscale and for the development of hybrid quantum computation architectures based on molecular spin qubits.

quant-ph↗

arXiv2016

A scalable architecture for quantum computation with molecular nanomagnets

A proposal for a magnetic quantum processor that consists of individual molecular spins coupled to superconducting coplanar resonators and transmission lines is carefully examined. We derive a simple magnetic quantum electrodynamics Hamiltonian to describe the underlying physics. It is shown that these hybrid devices can perform arbitrary operations on each spin qubit and induce tunable interactions between any pair of them. The combination of these two operations ensures that the processor can perform universal quantum computations. The feasibility of this proposal is critically discussed using the results of realistic calculations, based on parameters of existing devices and molecular qubits. These results show that the proposal is feasible, provided that molecules with sufficiently long coherence times can be developed and accurately integrated into specific areas of the device. This architecture has an enormous potential for scaling up quantum computation thanks to the microscopic nature of the individual constituents, the molecules, and the possibility of using their internal spin degrees of freedom.

cond-mat.mtrl-sci↗

arXiv2016

Dynamical signatures of bound states in waveguide QED

We study the spontaneous decay of an impurity coupled to a linear array of bosonic cavities forming a single-band photonic waveguide. The average frequency of the emitted photon is different from the frequency for single-photon resonant scattering, which perfectly matches the bare frequency of the excited state of the impurity. We study how the energy of the excited state of the impurity influences the spatial profile of the emitted photon. The farther the energy is from the middle of the photonic band, the farther the wave packet is from the causal limit. In particular, if the energy lies in the middle of the band, the wave packet is localized around the causal limit. Besides, the occupation of the excited state of the impurity presents a rich dynamics: it shows an exponential decay up to intermediate times, this is followed by a power-law tail in the long-time regime, and it finally reaches an oscillatory stationary regime. Finally, we show that this phenomenology is robust under the presence of losses, both in the impurity and the cavities.

quant-ph↗

arXiv2016

Full two-photon downconversion of just a single photon

We demonstrate, both numerically and analytically, that it is possible to generate two photons from one and only one photon. We characterize the output two photon field and make our calculations close to reality by including losses. Our proposal relies on real or artificial three-level atoms with a cyclic transition strongly coupled to a one-dimensional waveguide. We show that close to perfect downconversion with efficiency over 99% is reachable using state-of-the-art Waveguide QED architectures such as photonic crystals or superconducting circuits. In particular, we sketch an implementation in circuit QED, where the three level atom is a transmon.

quant-ph↗

arXiv2015

Tunable and Switchable Coupling Between Two Superconducting Resonators

We realize a device allowing for tunable and switchable coupling between two superconducting resonators mediated by an artificial atom. For the latter, we utilize a persistent current flux qubit. We characterize the tunable and switchable coupling in frequency and time domain and find that the coupling between the relevant modes can be varied in a controlled way. Specifically, the coupling can be tuned by adjusting the flux through the qubit loop or by saturating the qubit. Our time domain measurements allow us to find parameter regimes for optimal switch performance with respect to qubit drive power and the dynamic range of the resonator input power.

cond-mat.mes-hall↗

arXiv2014

Ultrastrong coupling in two-resonator circuit QED

We report on ultrastrong coupling between a superconducting flux qubit and a resonant mode of a system comprised of two superconducting coplanar stripline resonators coupled galvanically to the qubit. With a coupling strength as high as 17% of the mode frequency, exceeding that of previous circuit quantum electrodynamics experiments, we observe a pronounced Bloch-Siegert shift. The spectroscopic response of our multimode system reveals a clear breakdown of the Jaynes-Cummings model. In contrast to earlier experiments, the high coupling strength is achieved without making use of an additional inductance provided by a Josephson junction.

cond-mat.mes-hall↗

arXiv2013

Coupling single molecule magnets to quantum circuits

In this work we study theoretically the coupling of single molecule magnets (SMMs) to a variety of quantum circuits, including microwave resonators with and without constrictions and flux qubits. The main results of this study is that it is possible to achieve strong and ultrastrong coupling regimes between SMM crystals and the superconducting circuit, with strong hints that such a coupling could also be reached for individual molecules close to constrictions. Building on the resulting coupling strengths and the typical coherence times of these molecules (of the order of microseconds), we conclude that SMMs can be used for coherent storage and manipulation of quantum information, either in the context of quantum computing or in quantum simulations. Throughout the work we also discuss in detail the family of molecules that are most suitable for such operations, based not only on the coupling strength, but also on the typical energy gaps and the simplicity with which they can be tuned and oriented. Finally, we also discuss practical advantages of SMMs, such as the possibility to fabricate the SMMs ensembles on the chip through the deposition of small droplets.

cond-mat.mes-hall↗

arXiv2013

Nonequilibrium and nonperturbative dynamics of ultrastrong coupling in open lines

We study the time and space resolved dynamics of a qubit with an Ohmic coupling to propagating 1D photons, from weak coupling to the ultrastrong coupling regime. A nonperturbative study based on Matrix Product States (MPS) shows the following results: (i) The ground state of the combined systems contains excitations of both the qubit and the surrounding bosonic field. (ii) An initially excited qubit equilibrates through spontaneous emission to a state, which under certain conditions, is locally close to that ground state, both in the qubit and the field. (iii) The resonances of the combined qubit-photon system match those of the spontaneous emission process and also the predictions of the adiabatic renormalization [A. J. Leggett et al., Rev. Mod. Phys. 59, 1, (1987)]. Finally, a non-perturbative ab-initio calculations show that this physics can be studied using a flux qubit galvanically coupled to a superconducting transmission line.

quant-ph↗

arXiv2013

From Josephson junction metamaterials to tunable pseudo-cavities

The scattering through a Josephson junction interrupting a superconducting line is revisited including power leakage. We discuss also how to make tunable and broadband resonant mirrors by concatenating junctions. As an application, we show how to construct cavities using these mirrors, thus connecting two research fields: JJ quantum metamaterials and coupled cavity arrays. We finish by discussing the first non-linear corrections to the scattering and their measurable effects.

quant-ph↗

arXiv2013

Weak and Strong coupling regimes in plasmonic-QED

We present a quantum theory for the interaction of a two level emitter with surface plasmon polaritons confined in single-mode waveguide resonators. Based on the Green's function approach, we develop the conditions for the weak and strong coupling regimes by taking into account the sources of dissipation and decoherence: radiative and non-radiative decays, internal loss processes in the emitter, as well as propagation and leakage losses of the plasmons in the resonator. The theory is supported by numerical calculations for several quantum emitters, GaAs and CdSe quantum dots and NV centers together with different types of resonators constructed of hybrid, cylindrical or wedge waveguides. We further study the role of temperature and resonator length. Assuming realistic leakage rates, we find the existence of an optimal length at which strong coupling is possible. Our calculations show that the strong coupling regime in plasmonic resonators is accessible within current technology when working at very low temperatures (<4K). In the weak coupling regime our theory accounts for recent experimental results. By further optimization we find highly enhanced spontaneous emission with Purcell factors over 1000 at room temperature for NV-centers. We finally discuss more applications for quantum nonlinear optics and plasmon-plasmon interactions.

cond-mat.mes-hall↗

arXiv2013

Thermal activation at moderate-to-high and high damping: finite barrier effects and force spectroscopy

We study the thermal escape problem in the moderate-to-high and high damping regime of a system with a parabolic barrier. We present a formula that matches our numerical results accounting for finite barrier effects, and compare it with previous works. We also show results for the full damping range. We quantitatively study some aspects on the relation between mean first passage time and the definition of a escape rate. To finish we apply our results and considerations in the framework of force spectroscopy problems. We study the differences on the predictions using the different theories and discuss the role of $γ\dot{F}$ as the relevant parameter at high damping.

cond-mat.stat-mech↗

arXiv2013

Fast microwave beam splitters from superconducting resonators

Coupled superconducting transmission line resonators have applications in quantum information processing and fundamental quantum mechanics. A particular example is the realization of fast beam splitters, which however is hampered by two-mode squeezer terms. Here, we experimentally study superconducting microstrip resonators which are coupled over one third of their length. By varying the position of this coupling region we can tune the strength of the two-mode squeezer coupling from 2.4% to 12.9% of the resonance frequency of 5.44GHz. Nevertheless, the beam splitter coupling rate for maximally suppressed two-mode squeezing is 810MHz, enabling the construction of a fast and pure beam splitter.

cond-mat.mes-hall↗