arXiv subjects

D. Zueco

Publications and source records attributed to D. Zueco.

33 records · Page 2Linked to original sources

arXiv2012

Non-adiabatic effects within a single thermally-averaged potential energy surface: Thermal expansion and reaction rates of small molecules

At non-zero temperature and when a system has low-lying excited electronic states, the ground-state Born--Oppenheimer approximation breaks down and the low-lying electronic states are involved in any chemical process. In this work, we use a temperature-dependent effective potential for the nuclei which can accomodate the influence of an arbitrary number of electronic states in a simple way, while at the same time producing the correct Boltzmann equibrium distribution for the electronic part. With the help of this effective potential, we show that thermally-activated low-lying electronic states can have a significant effect in molecular properties for which electronic excitations are oftentimes ignored. We study the thermal expansion of the Manganese dimer, Mn$_2$, where we find that the average bond length experiences a change larger than the present experimental accuracy upon the inclusion of the excited states into the picture. We also show that, when these states are taken into account, reaction rate constants are modified. In particular, we study the opening of the ozone molecule, O$_3$, and show that in this case the rate is modified as much as a 20% with respect to the ground-state Born--Oppenheimer prediction.

physics.chem-ph↗

arXiv2012

Tunable coupling engineering between superconducting resonators: from sidebands to effective gauge fields

In this work we show that a tunable coupling between microwave resonators can be engineered by means of simple Josephson junctions circuits, such as dc- and rf-SQUIDs. We show that by controlling the time dependence of the coupling it is possible to switch on and off and modulate the cross-talk, boost the interaction towards the ultrastrong regime, as well as to engineer red and blue sideband couplings, nonlinear photon hopping and classical gauge fields. We discuss how these dynamically tunable superconducting circuits enable key applications in the fields of all optical quantum computing, continuous variable quantum information and quantum simulation - all within the reach of state of the art in circuit-QED experiments.

cond-mat.supr-con↗

arXiv2011

Molecular prototypes for spin-based CNOT quantum gates

We show that a chemically engineered structural asymmetry in [Tb2] molecular clusters renders the two weakly coupled Tb3+ spin qubits magnetically inequivalent. The magnetic energy level spectrum of these molecules meets then all conditions needed to realize a universal CNOT quantum gate.

cond-mat.mes-hall↗

arXiv2010

Ab Initio Molecular Dynamics on the Electronic Boltzmann Equilibrium Distribution

We prove that for a combined system of classical and quantum particles, it is possible to write a dynamics for the classical particles that incorporates in a natural way the Boltzmann equilibrium population for the quantum subsystem. In addition, these molecular dynamics do not need to assume that the electrons immediately follow the nuclear motion (in contrast to any adiabatic approach), and do not present problems in the presence of crossing points between different potential energy surfaces (conical intersections or spin-crossings). A practical application of this molecular dynamics to study the effect of temperature in molecular systems presenting (nearly) degenerate states - such as the avoided crossing in the ring-closure process of ozone - is presented.

cond-mat.other↗

arXiv2010

Non-equilibrium Effects in the Thermal Switching of Underdamped Josephson Junctions

We study the thermal escape problem in the low damping limit. We find that finiteness of the barrier is crucial for explaining the thermal activation results. In this regime low barrier non-equilibrium corrections to the usual theories become necessary. We propose a simple theoretical extension accounting for these non-equilibrium processes which agrees numerical results. We apply our theory to the understanding of switching current curves in underdamped Josephson junctions.

cond-mat.supr-con↗

arXiv2010

Creation and manipulation of entanglement in spin chains far from equilibrium

We investigate creation, manipulation, and steering of entanglement in spin chains from the viewpoint of quantum communication between distant parties. We demonstrate how global parametric driving of the spin-spin coupling and/or local time-dependent Zeeman fields produce a large amount of entanglement between the first and the last spin of the chain. This occurs whenever the driving frequency meets a resonance condition, identified as "entanglement resonance". Our approach marks a promising step towards an efficient quantum state transfer or teleportation in solid state system. Following the reasoning of Zueco et al. [1], we propose generation and routing of multipartite entangled states by use of symmetric tree-like structures of spin chains. Furthermore, we study the effect of decoherence on the resulting spin entanglement between the corresponding terminal spins.

quant-ph↗

arXiv2010

Beyond the Jaynes-Cummings model: circuit QED in the ultrastrong coupling regime

In cavity quantum electrodynamics (QED), light-matter interaction is probed at its most fundamental level, where individual atoms are coupled to single photons stored in three-dimensional cavities. This unique possibility to experimentally explore the foundations of quantum physics has greatly evolved with the advent of circuit QED, where on-chip superconducting qubits and oscillators play the roles of two-level atoms and cavities, respectively. In the strong coupling limit, atom and cavity can exchange a photon frequently before coherence is lost. This important regime has been reached both in cavity and circuit QED, but the design flexibility and engineering potential of the latter allowed for increasing the ratio between the atom-cavity coupling rate and the cavity transition frequency above the percent level. While these experiments are well described by the renowned Jaynes-Cummings model, novel physics is expected in the ultrastrong coupling limit. Here, we report on the first experimental realization of a superconducting circuit QED system in the ultrastrong coupling limit and present direct evidence for the breakdown of the Jaynes-Cummings model.

cond-mat.mes-hall↗

arXiv2008

Electromagnetic wave transmission through a small hole in a perfect electric conductor of finite thickness

The non-resonant electromagnetic transmission of a normal-incident plane wave through a single hole in a perfect conductor metal slab of finite width is studied. The cases of rectangular and circular holes are treated in detail. For holes in the extreme subwavelength regime, in a film of finite thickness, the transmittance is shown to have the Rayleigh dependency upon the wavelength and, in addition, is mainly suppressed due to attenuation of the fundamental waveguide mode. In the limit of an infinitesimally thin screen Bethe's result is recovered for the circular hole. The numerical computations are fitted, providing expressions for the transmission in a wide region of parameters. We reformulate our results in terms of multipole expansion, interpreting the waveguide modes inside the hole as induced multipole moments. This result provides the link between the modal expansion method and the one based on a multipole expansion.

cond-mat.mtrl-sci↗

arXiv2007

Bopp operators and phase-space spin dynamics: Application to rotational quantum brownian motion

As already known for nonrelativistic spinless particles, Bopp operators give an elegant and simple way to compute the dynamics of quasiprobability distributions in the phase space formulation of Quantum Mechanics. In this work, we present a generalization of Bopp operators for spins and apply our results to the case of open spin systems. This approach allows to take the classical limit in a transparent way, recovering the corresponding Fokker-Planck equation.

quant-ph↗

arXiv2006

Solving spin quantum-master equations with matrix continued-fraction methods: application to superparamagnets

We implement continued-fraction techniques to solve exactly quantum master equations for a spin with arbitrary S coupled to a (bosonic) thermal bath. The full spin density matrix is obtained, so that along with relaxation and thermoactivation, coherent dynamics is included (precession, tunnel, etc.). The method is applied to study isotropic spins and spins in a bistable anisotropy potential (superparamagnets). We present examples of static response, the dynamical susceptibility including the contribution of the different relaxation modes, and of spin resonance in transverse fields.

cond-mat.stat-mech↗

arXiv2006

Non-linear response of single-molecule magnets: field-tuned quantum-to-classical crossovers

Quantum nanomagnets can show a field dependence of the relaxation time very different from their classical counterparts, due to resonant tunneling via excited states (near the anisotropy barrier top). The relaxation time then shows minima at the resonant fields H_{n}=n D at which the levels at both sides of the barrier become degenerate (D is the anisotropy constant). We showed that in Mn12, near zero field, this yields a contribution to the nonlinear susceptibility that makes it qualitatively different from the classical curves [Phys. Rev. B 72, 224433 (2005)]. Here we extend the experimental study to finite dc fields showing how the bias can trigger the system to display those quantum nonlinear responses, near the resonant fields, while recovering an classical-like behaviour for fields between them. The analysis of the experiments is done with heuristic expressions derived from simple balance equations and calculations with a Pauli-type quantum master equation.

cond-mat.mes-hall↗

arXiv2005

Longitudinal relaxation and thermoactivation of quantum superparamagnets

The relaxation mechanisms of a quantum nanomagnet are discussed in the frame of linear response theory. We use a spin Hamiltonian with a uniaxial potential barrier plus a Zeeman term. The spin, having arbitrary $S$, is coupled to a bosonic environment. From the eigenstructure of the relaxation matrix, we identify two main mechanisms, namely, thermal activation over the barrier, with a time scale $\eival_1^{-1}$, and a faster dynamics inside the potential wells, with characteristic time $\eivalW^{-1}$. This allows to introduce a simple analytical formula for the response, which agrees well with the exact numerical results, and cover experiments even under moderate to strong fields in the superparamagnetic range. In passing, we generalize known classical results for a number of quantities (e.g., integral relaxation times, initial decay time, Kramers rate), results that are recovered in the limit $S\to\infty$.

cond-mat.mes-hall↗

arXiv2005

Mode-Locking of mobile discrete breathers

We study numerically synchronization phenomena of mobile discrete breathers in dissipative nonlinear lattices periodically forced. When varying the driving intensity, the breather velocity generically locks at rational multiples of the driving frequency. In most cases, the locking plateau coincides with the linear stability domain of the resonant mobile breather and the desynchronization occurs by regular appearance of type I intermittencies. However, some plateaux also show chaotic mobile breathers with locked velocity in the locking region. The addition of a small subharmonic driving tames the locked chaotic solution and enhances the stability of resonant mobile breathers.

nlin.PS↗

arXiv2004

Quantum Ratchets at High Temperatures

Using the continued-fraction method we solve the Caldeira-Leggett master equation in the phase-space (Wigner) representation to study Quantum ratchets. Broken spatial symmetry, irreversibility and periodic forcing allows for a net current in these systems. We calculate this current as a function of the force under adiabatic conditions. Starting from the classical limit we make the system quantal. In the quantum regime tunnel events and over-barrier wave reflection phenomena modify the classical result. Finally, using the phase-space formalism we give some insights about the decoherence in these systems.

cond-mat.other↗

arXiv2004

Caldeira--Leggett quantum master equation in Wigner phase space: continued-fraction solution and application to Brownian motion in periodic potentials

The continued-fraction method to solve classical Fokker--Planck equations has been adapted to tackle quantum master equations of the Caldeira--Leggett type. This can be done taking advantage of the phase-space (Wigner) representation of the quantum density matrix. The approach differs from those in which some continued-fraction expression is found for a certain quantity, in that the full solution of the master equation is obtained by continued-fraction methods. This allows to study in detail the effects of the environment (fluctuations and dissipation) on several classes of nonlinear quantum systems. We apply the method to the canonical problem of quantum Brownian motion in periodic potentials both for cosine and ratchet potentials (lacking inversion symmetry).

cond-mat.stat-mech↗