arXiv subjects

David A. Neufeld

Publications and source records attributed to David A. Neufeld.

At least 19 recordsLinked to original sources

arXiv2026

IPA: Morphology and Kinematics of Molecular Hydrogen Winds in Five Young Protostars across the Mass Spectrum Observed with JWST

Molecular winds may play a key role in governing angular momentum transport and accretion during the early evolution of protostars. We present the morphology and kinematic properties of the H$_2$ emission in five young, envelope-dominated, protostars across a broad bolometric luminosity range, from 0.2 to $10^4~L_{\odot}$, observed with the NIRSpec/IFU and MIRI/MRS onboard JWST as part of the Investigating Protostellar Accretion (IPA) program. A rich set of pure rotational lines of H$_2$, up to $v=0-0$ S(18), and a few ro-vibrational lines are detected in the winds, revealing bipolar structures. The H$_2$ lines show a stratified/onion-like structure morphologically and kinematically, where the lines with higher $E_{\rm up}$ show a higher degree of collimation and higher velocities. Additionally, the wind velocity scales with the $L_{\rm bol}$ of the host protostellar system. In 4 out of 5 protostars, H$_2$ emission fills the outflow cavity without showing pronounced limb brightening. We also report a tentative detection of H$_2$ wind rotation in IRAS 16253, which suggests a launch radius of $\sim4$ au and the magnetic lever arm parameter of $\sim5-10$. Taken together, these properties of the H$_2$ winds can be explained by the magnetohydrodynamic disk wind models. We detect a collimated, high-velocity H$_2$ jet toward HOPS 370, which is more evolved than the extremely young source HH 211, but is accreting at a high accretion rate. This suggests that the presence of collimated molecular jets in protostars is more closely connected to accretion rate than system age.

astro-ph.SR↗

arXiv2026

JWST Edge-on Disk Ice (JEDIce): Vibrationally hot, rotationally cold H$_2$ in the outer disk of Oph 163131 non-thermally excited by UV and cosmic rays

Constraining ionization and excitation processes in protoplanetary disks is essential for understanding the chemical structure and evolution of disk material, shaping planet formation pathways. We present JWST/NIRSpec IFU observations of the edge-on disk Oph 163131, which reveal a unusual ro-vibrational H$_2$ spectrum dominated by the 1--0 O(2) line (2.627 $\mu$m), with suppressed higher-$J$ emission despite excitation to $v=2$ and $3$. This vibrationally hot, rotationally cold H$_2$ emission is spatially extended, broadly following the molecular disk traced by CO($J{=}2$--1), with emission increasing above and below a thin midplane dark lane and extending radially beyond $\sim$200 au, where near-IR scattered-light emission is no longer dominant. We interpret the observed H$_2$ emission as arising from non-thermal excitation in cold, dense outer-disk gas, where collisions depopulate higher-$J$ rotational levels within each vibrational manifold prior to emission, producing the characteristic ``$v$-hot, $J$-cold" spectrum. We consider both ultraviolet irradiation and cosmic-ray excitation as contributors to the H$_2$ emission and find that their combined action, together with collisional de-excitation of high-$J$ level populations, broadly reproduces the observed line ratios and morphology. Within this framework, we infer a rather high effective cosmic-ray ionization rate of $\sim(1$-$10)\times10^{-15}$ s$^{-1}$ in the presence of a moderate UV field ($\chi_{UV}=100-1000$, in Draine units). These results for disks, together with the recent findings by Bialy et al. 2025 for the lower-density starless core B68, highlight the potential of ro-vibrational H$_2$ emission as a novel probe of cosmic-ray ionization.

astro-ph.SR↗

arXiv2026

Excitation of warm HD and H$_2$ and implications for the interstellar deuterium abundance

Rotational emission from HD provides a direct probe of deuterium in warm molecular gas, but the conversion of HD line fluxes to total column densities is sensitive to non-LTE excitation. I present calculations of the non-LTE rotational excitation of HD and H$_2$ and a method for fitting their rotational diagrams simultaneously. Because HD remains subthermally excited to higher densities than H$_2$, the combined analysis constrains the thermal pressure as well as the HD/H$_2$ abundance ratio. I apply this method to JWST/MIRI observations of 26 positions in 10 protostellar outflows from the JOYS survey, published previously by Francis et al. (2025), including 17 positions with secure detections of at least three HD lines. Two-temperature, isobaric models generally provide good fits to the measured H$_2$ and HD level populations. For 11 positions with HD detections, the inferred pressures span $p/k_B=8.4\times10^7$ - $5.1\times10^9\ {\rm K\,cm^{-3}}$; for the remaining six, the HD populations approach LTE and provide only lower limits on the gas pressure. Excluding two positions toward IRAS 4B with comparatively poor fits, the median and mean inferred HD/H$_2$ abundance ratios are $1.42\times10^{-5}$ and $1.47\times10^{-5}$, respectively, only 28$\%$ and 29$\%$ of the value expected if all primordial deuterium were present as HD. These results confirm that HD/H$_2$ is generally low in shocked molecular gas while demonstrating that pressure-dependent non-LTE excitation must be modeled explicitly. Translating the measured HD/H$_2$ ratios into elemental D/H requires additional modeling of shock chemistry.

astro-ph.GA↗

arXiv2026

Investigating the Nested Structure of the Outflow from the Low Luminosity Protostar IRAS 16253-2429 using JWST and ALMA

Understanding the earliest stage of star and planet formation requires detailed observations to address the connection and interplay between the accretion, outflow and disk evolution. We present results from the observations of the low luminosity ($L_\mathrm{bol}\sim~0.2~L_\odot$) and mass (M$_*\sim$\,0.15~M$_\odot$) Class~0 protostar IRAS 16253$-$2429, conducted as part of the \textit{eDisk} ALMA large program and the JWST cycle-1 GO program \textit{IPA}. Observations reveal a wide hourglass-shaped continuum cavity traced in scattered light (at $\leq$~5~$μ$m), with a brighter, extended northern side. We detect 15 pure rotational H$_2$ transitions (E$_\mathrm{up}$:~1015--21411~K), revealing a wide-angle molecular outflow. {The outflow width (as traced in H$_2$~0-0~S(11)) at the protostellar location measures $\leq$35 au, slightly larger than the dust and Keplerian disk diameters ($\sim$30 au) but wider than the 20--23~au jet width in [Fe II].} {The opening angle narrows from 40--35\arcdeg{} for the low-J H$_2$ lines (up to S(5)) and the cold gas component (ALMA $^{12}$CO) to $\sim$28--19\arcdeg{} for the high-J H$_2$ lines (S(7)--S(11)).} Position-velocity diagrams of H$_2$ reveal higher velocities for higher E$_{up}$, ranging from ~12.5 km~s$^{-1}$ for H$_2$~0-0~S(1) and S(2) to ~28.5 km~s$^{-1}$ for H$_2$~0-0~S(5)~and~S(7) with respect to the mean flow velocity. The nested excitation and velocity structure of the collimated jet and wide angle wind suggest a magnetohydrodynamic wind as a likely launching mechanism, similar to the findings in other protostars and Class II sources. The lower velocity mm CO may be gas from the infalling envelope accelerated outwards by the wide angle wind along the cavity walls.

astro-ph.SR↗

arXiv2025

IPA. Accretion rate of a low-mass Class 0 protostar, measured via mid-infrared fluorescent OH emission

The earliest stages of star formation are highlighted by complex interactions between accretion, outflow, and radiative processes, which shape the chemical and physical environment of the emerging protostar. James Webb Space Telescope observations of the low-mass, low-luminosity Class 0 protostar IRAS 16253-2429 reveal a central compact source. This object exhibits a rich mid-infrared emission spectrum of OH pure rotational lines and $\rm CO_2$ ro-vibrational lines. Unusually for a young stellar object, it has no mid-infrared line emission from $\rm H_2O$ to match the other molecules. We demonstrate that the emitting OH molecules arise from UV photodissociation of $\rm H_2O$ in its second absorption band at $λ= 114-145$ nm, and that the OH emission is a fluorescent cascade starting with highest-excitation rotational states. This situation offers the opportunity of using the infrared OH spectrum to measure the UV flux from the central protostar. Thereby we determine the disk-star accretion rate to be $3 \times 10^{-10} \ M_\sun \ {\rm year^{-1}}$, and demonstrate that the system luminosity arises mostly from the protostar's photosphere rather than from accretion luminosity. The result is in accord with the measured outflow rate of IRAS 16253-2429 and lies within the outflow/accretion-flow rate trend often inferred for protostars; and with episodic accretion as the dominant mechanism by which this protostar has grown.

astro-ph.SR↗

arXiv2025

JWST observations of cosmic-ray-excited H$_2$ in Barnard 68: spatial variations and constraints on cosmic-ray attenuation

We present James Webb Space Telescope (JWST) NIRSpec observations of the starless dark cloud Barnard 68 that reveal the spatially-resolved signature of cosmic-ray excited molecular hydrogen (CRXH$_2$) emissions for the first time. Following up on our initial detection of CRXH$_2$ emissions from B68 (Bialy et al. 2025), we now exploit JWST's sensitivity and spatial multiplexing to map CRXH$_2$ rovibrational lines across 16 sight lines through the cloud. By disentangling the CRXH$_2$ and UV-pumped H$_2$ components, we isolate the para-H$_2$-dominated spectrum attributable to cosmic-ray excitation. We find that there are significant spatial variations in the ratio of the CRXH$_2$ line intensity to the line-of-sight H$_2$ column density; these cannot be accounted for by dust extinction alone and demonstrate a clear attenuation of the cosmic-ray flux with increasing shielding column. Modeling B68 as a Bonnor-Ebert sphere, we constrain both the unshielded cosmic-ray ionization rate, $ζ_{\rm H_2}$, and how it decreases with shielding column. At a reference depth of $N({\rm H}_2) = 3 \times 10^{21}$ cm$^{-2}$, we infer $ζ_{\rm H_2} \approx 1.4 \times 10^{-16}$ s$^{-1}$, a factor of $\approx 3$ higher than the average value derived from H$_3^+$ absorption studies. These results provide the most direct probe to date of cosmic-ray penetration into cold, dense gas, offering new constraints on both the microphysics of CR-H$_2$ interactions and the attenuation of low-energy cosmic rays in molecular clouds. Our findings establish CRXH$_2$ emission as a powerful new diagnostic of the cosmic-ray environment in interstellar space.

astro-ph.GA↗

arXiv2025

The first detection of cosmic-ray excited H$_2$ in interstellar space

Stars and planets form within cold, dark molecular clouds. In these dense regions, where starlight cannot penetrate, cosmic rays (CRs) are the dominant source of ionization -- driving interstellar chemistry(Dalgarno (2006, PNAS, 103, 12269)), setting the gas temperature(Goldsmith et al. (1969, ApJ, 158, 173)), and enabling coupling to magnetic fields(McKee & Ostriker (2007, ARA&A, 45, 565; arXiv:0707.3514)). Together, these effects regulate the collapse of clouds and the onset of star formation. Despite this importance, the cosmic-ray ionization rate, $ζ$, has never been measured directly. Instead, this fundamental parameter has been loosely inferred from indirect chemical tracers and uncertain assumptions, leading to published values that span nearly two orders of magnitude and limiting our understanding of star formation physics. Here, we report the first direct detection of CR-excited vibrational H$_2$ emission, using \textit{James Webb Space Telescope} (JWST) observations of the starless core Barnard 68 (B68). The observed emission pattern matches theoretical predictions for CR excitation precisely, confirming a decades-old theoretical proposal long considered observationally inaccessible. This result enables direct measurement of $ζ$, effectively turning molecular clouds into natural, light-year-sized, cosmic-ray detectors. It opens a transformative observational window into the origin, propagation, and role of cosmic rays in star formation and galaxy evolution.

astro-ph.GA↗

arXiv2024

Revisiting rotationally excited CH at radio wavelengths: A case study towards W51

Ever since they were first detected in the interstellar medium, the radio wavelength (3.3 GHz) hyperfine-structure splitting transitions in the rotational ground state of CH have been observed to show anomalous excitation. Astonishingly, this behaviour has been uniformly observed towards a variety of different sources probing a wide range of physical conditions. While the observed level inversion can be explained globally by a pumping scheme involving collisions, a description of the extent of 'over-excitation' observed in individual sources requires the inclusion of radiative processes, involving transitions at higher rotational levels. Therefore, a complete description of the excitation mechanism in the CH ground state, observed towards individual sources entails observational constraints from the rotationally excited levels of CH and in particular that of its first rotationally excited state. Given the limited detections of these lines, the objective of this work is to characterise the physical and excitation properties of the rotationally excited lines of CH near 700 MHz, and investigate their influence on the pumping mechanisms of the ground-state lines of CH. This work presents the first interferometric search for the rotationally excited lines of CH near 700 MHz carried out using the uGMRT array and jointly models the physical and excitation conditions traced by lines from both the ground and first rotationally excited states of CH.

astro-ph.GA↗

arXiv2024

H2 fluorescent emission from the diffuse interstellar medium

A simple analytic model is presented to predict the near-IR H2 fluorescent line intensities emitted by diffuse interstellar clouds with a Plummer density profile. It is applicable to sightlines where (1) the column densities of H and H2 have been measured and (2) the peak gas density can be estimated from extinction maps or observations of C2 absorption.

astro-ph.GA↗

arXiv2024

JWST-IPA: Chemical Inventory and Spatial Mapping of Ices in the Protostar HOPS370 -- Evidence for an Opacity Hole and Thermal Processing of Ices

The composition of protoplanetary disks, and hence the initial conditions of planet formation, may be strongly influenced by the infall and thermal processing of material during the protostellar phase. Composition of dust and ice in protostellar envelopes, shaped by energetic processes driven by the protostar, serves as the fundamental building material for planets and complex organic molecules. As part of the JWST GO program, "Investigating Protostellar Accretion" (IPA), we observed an intermediate-mass protostar HOPS 370 (OMC2-FIR3) using NIRSpec/IFU and MIRI/MRS. This study presents the gas and ice phase chemical inventory revealed with the JWST in the spectral range of $\sim$2.9 to 28 $μ$m and explores the spatial variation of volatile ice species in the protostellar envelope. We find evidence for thermal processing of ice species throughout the inner envelope. We present the first high-spatial resolution ($\sim 80$ au) maps of key volatile ice species H$_{2}$O, CO$_{2}$, $^{13}$CO$_2$, CO, and OCN$^-$, which reveal a highly structured and inhomogeneous density distribution of the protostellar envelope, with a deficiency of ice column density that coincides with the jet/outflow shocked knots. Further, we observe high relative crystallinity of H$_{2}$O ice around the shocked knot seen in the H$_2$ and OH wind/outflow, which can be explained by a lack of outer colder material in the envelope along the line of sight due to the irregular structure of the envelope. These observations show clear evidence of thermal processing of the ices in the inner envelope, close to the outflow cavity walls, heated by the luminous protostar.

astro-ph.SR↗

arXiv2024

SOFIA/EXES observations of warm H2 at high spectral resolution: II. IC443C, NGC2071, and 3C391

Using the EXES instrument on SOFIA, we have obtained velocity-resolved spectra of several pure rotational lines of H2 toward shocked molecular gas within three Galactic sources: the supernova remnant (SNR) IC443 (Clump C), a protostellar outflow in the intermediate-mass star-forming region NGC 2071, and the SNR 3C391. These observations had the goal of searching for expected velocity shifts between ortho- and para-H2 transitions emitted by C-type shocks. In contrast in our previous similar study of HH7, the result of our search was negative: no velocity shifts were reliably detected. Several possible explanations for the absence of such shifts are discussed: these include a preshock ortho-to-para ratio that is already close to the high-temperature equilibrium value of 3 (in the case of IC443C), the more complex shock structures evident in all these sources, and the larger projected aperture sizes relative to those in the observations of HH7.

astro-ph.GA↗

arXiv2024

The densities in diffuse and translucent molecular clouds: estimates from observations of C$_2$ and from 3-dimensional extinction maps

Newly-computed collisional rate coefficients for the excitation of C$_2$ in collisions with H$_2$, presented recently by Najar and Kalugina (2020), are significantly larger than the values adopted previously in models for the excitation of the C$_2$ molecule, a widely used probe of the interstellar gas density. With these new rate coefficients, we have modeled the C$_2$ rotational distributions inferred from visible and ultraviolet absorption observations of electronic transitions of C$_2$ towards a collection of 46 nearby background sources. The inferred gas densities in the foreground interstellar clouds responsible for the observed C$_2$ absorption are a factor 4 to 7 smaller than those inferred previously, a direct reflection of the larger collisional rate coefficients computed by Najar and Kalugina (2020). These lower density estimates are generally in good agreement with the peak densities inferred from 3D extinction maps for the relevant sightlines. In cases where H$_3^+$ absorption has also been observed and used to estimate the cosmic-ray ionization rate (CRIR), our estimates of the latter will also decrease accordingly because the H$_3^+$ abundance is a function of the ratio of the CRIR to the gas density.

astro-ph.GA↗

arXiv2024

Dissociative recombination of rotationally cold ArH$^+$

We have experimentally studied dissociative recombination (DR) of electronically and vibrationally relaxed ArH$^+$ in its lowest rotational levels, using an electron--ion merged-beams setup at the Cryogenic Storage Ring. We report measurements for the merged-beams rate coefficient of ArH$^+$ and compare it to published experimental and theoretical results. In addition, by measuring the kinetic energy released to the DR fragments, we have determined the internal state of the DR products after dissociation. At low collision energies, we find that the atomic products are in their respective ground states, which are only accessible via non-adiabatic couplings to neutral Rydberg states. Published theoretical results for ArH$^+$ have not included this DR pathway. From our measurements, we have also derived a kinetic temperature rate coefficient for use in astrochemical models.

physics.atom-ph↗

arXiv2024

JWST/MIRI detection of suprathermal OH rotational emissions: probing the dissociation of the water by Lyman alpha photons near the protostar HOPS 370

Using the MIRI/MRS spectrometer on JWST, we have detected pure rotational, suprathermal OH emissions from the vicinity of the intermediate-mass protostar HOPS 370 (OMC2/FIR3). These emissions are observed from shocked knots in a jet/outflow, and originate in states of rotational quantum number as high as 46 that possess excitation energies as large as $E_U/k = 4.65 \times 10^4$ K. The relative strengths of the observed OH lines provide a powerful diagnostic of the ultraviolet radiation field in a heavily-extinguished region ($A_V \sim 10 - 20$) where direct UV observations are impossible. To high precision, the OH line strengths are consistent with a picture in which the suprathermal OH states are populated following the photodissociation of water in its $\tilde B - X$ band by ultraviolet radiation produced by fast ($\sim 80\,\rm km\,s^{-1}$) shocks along the jet. The observed dominance of emission from symmetric ($A^\prime$) OH states over that from antisymmetric ($A^{\prime\prime}$) states provides a distinctive signature of this particular population mechanism. Moreover, the variation of intensity with rotational quantum number suggests specifically that Ly$α$ radiation is responsible for the photodissociation of water, an alternative model with photodissociation by a 10$^4$ K blackbody being disfavored at a high level of significance. Using measurements of the Br$α$ flux to estimate the Ly$α$ production rate, we find that $\sim 4\%$ of the Ly$α$ photons are absorbed by water. Combined with direct measurements of water emissions in the $ν_2 = 1 -0$ band, the OH observations promise to provide key constraints on future models for the diffusion of Ly$α$ photons in the vicinity of a shock front.

astro-ph.GA↗

arXiv2023

JWST detection of extremely excited outflowing CO and H2O in VV 114 E SW: a possible rapidly accreting IMBH

Mid-infrared (mid-IR) gas-phase molecular bands are powerful diagnostics of the warm interstellar medium. We report the James Webb Space Telescope detection of the CO v=1-0 (4.4-5.0 um) and H2O nu2=1-0 (5.0-7.8um) ro-vibrational bands, both in absorption, toward the ``s2'' core in the southwest nucleus of the merging galaxy VV 114 E. All ro-vibrational CO lines up to J_low=33 (E_low~3000 K) are detected, as well as a forest of H2O lines up to 13_{0,13} (E_low~2600 K). The highest-excitation lines are blueshifted by ~180 km s^{-1} relative to the extended molecular cloud, which is traced by the rotational CO J=3-2 346 GHz line observed with the Atacama Large Millimeter/submillimeter Array. The bands also show absorption in a low-velocity component (blueshifted by ~30 km s^{-1}) with lower excitation. The analysis shows that the bands are observed against a continuum with effective temperature of T_bck~550 K extinguished with tau_6um^ext~ 2.5-3 (A_k~6.9-8.3 mag). The high-excitation CO and H2O lines are consistent with v=0 thermalization with T_rot~450 K and column densities of N_CO~(1.7-3.5)x10^{19} cm^{-2} and N_H2O~(1.5-3.0)x10^{19} cm$^{-2}$. Thermalization of the v=0 levels of H2O requires either an extreme density of n_H2>~10^9 cm^{-3}, or radiative excitation by the mid-IR field in a very compact (<1 pc) optically thick source emitting ~10^{10} L_sun. The latter alternative is favored, implying that the observed absorption probes the very early stages of a fully enshrouded active black hole (BH). On the basis of a simple model for BH growth and applying a lifetime constraint to the s2 core, an intermediate-mass BH (IMBH, M_BH~4.5x10^4 M_sun) accreting at super-Eddington rates is suggested, where the observed feedback has not yet been able to break through the natal cocoon.

astro-ph.GA↗

arXiv2023

Dissociative Recombination of Rotationally Cold OH$^+$ and Its Implications for the Cosmic Ray Ionization Rate in Diffuse Clouds

Observations of OH$^+$ are used to infer the interstellar cosmic ray ionization rate in diffuse atomic clouds, thereby constraining the propagation of cosmic rays through and the shielding by interstellar clouds, as well as the low energy cosmic ray spectrum. In regions where the H$_2$ to H number density ratio is low, dissociative recombination (DR) is the dominant destruction process for OH$^+$ and the DR rate coefficient is important for predicting the OH$^+$ abundance and inferring the cosmic ray ionization rate. We have experimentally studied DR of electronically and vibrationally relaxed OH$^+$ in its lowest rotational levels, using an electron--ion merged-beams setup at the Cryogenic Storage Ring. From these measurements, we have derived a kinetic temperature rate coefficient applicable to diffuse cloud chemical models, i.e., for OH$^+$ in its electronic, vibrational, and rotational ground level. At typical diffuse cloud temperatures, our kinetic temperature rate coefficient is a factor of $\sim 5$ times larger than the previous experimentally derived value and a factor of $\sim 33$ times larger than the value calculated by theory. Our combined experimental and modelling results point to a significant increase for the cosmic ray ionization rate inferred from observations of OH$^+$ and H$_2$O$^+$, corresponding to a geometric mean of $(6.6 \pm 1.0) \times 10^{-16}\,\mathrm{s}^{-1}$, which is more than a factor of two larger than the previously inferred values of the cosmic ray ionization rate in diffuse atomic clouds. Combined with observations of diffuse and dense molecular clouds, these findings indicate a greater degree of cosmic ray shielding in interstellar clouds than has been previously inferred.

astro-ph.GA↗

arXiv2022

Experimental determination of the dissociative recombination rate coefficient for rotationally-cold CH$^{+}$ and its implications for the diffuse cloud chemistry

Observations of CH$^+$ are used to trace the physical properties of diffuse clouds, but this requires an accurate understanding of the underlying CH$^+$ chemistry. Until this work, the most uncertain reaction in that chemistry was dissociative recombination (DR) of CH$^+$. Using an electron-ion merged-beams experiment at the Cryogenic Storage Ring, we have determined the DR rate coefficient of the CH$^+$ electronic, vibrational, and rotational ground state applicable for different diffuse cloud conditions. Our results reduce the previously unrecognized order-of-magnitude uncertainty in the CH$^+$ DR rate coefficient to $\sim \pm 20\%$ and are applicable at all temperatures relevant to diffuse clouds, ranging from quiescent gas to gas locally heated by processes such as shocks and turbulence. Based on a simple chemical network, we find that DR can be an important destruction mechanism at temperatures relevant to quiescent gas. As the temperature increases locally, DR can continue to be important up to temperatures of $ \sim 600\,\mathrm{K} $ if there is also a corresponding increase in the electron fraction of the gas. Our new CH$^+$ DR rate coefficient data will increase the reliability of future studies of diffuse cloud physical properties via CH$^+$ abundance observations.

astro-ph.GA↗

arXiv2022

Infrared line emissions from atoms and atomic ions in NGC 7027: improved wavelength determinations for infrared metal lines and a probable detection of Zn$^{5+}$

An infrared L- and M-band spectral survey, performed toward the young planetary nebula NGC 7027 with the iSHELL instrument on NASA's Infrared Telescope Facility (IRTF), has revealed more than 20 vibrational lines of the molecules HeH$^+$, H$_2$, and CH$^+$ and more than 50 spectral lines of atoms and atomic ions. The present paper focuses on the atomic line emissions, the molecular lines having been discussed in two previous publications (Neufeld et al. 2020, 2021). The atomic lines detected with high confidence in the 2.951 - 5.24 micron region covered (incompletely) by this survey comprise (1) six collisionally-excited lines of metal ions that had previously been identified in astrophysical nebulae but for which the present observations provide the most accurate wavelength determinations obtained to date; (2) a spectral line at 4.6895 micron, not previously reported, for which the probable identification is the $^4F_{7/2} - $ $^4F_{9/2}$ fine structure transition of [Zn VI]; (3) 39 recombination lines of H and He$^+$, with upper states of principal quantum number up to 38 (H) or 24 (He$^+$); (4) 10 recombination lines of the multielectron species He, C$^{2+}$, and C$^{3+}$.

astro-ph.GA↗