arXiv subjects

David C. Catling

Publications and source records attributed to David C. Catling.

At least 19 recordsLinked to original sources

arXiv2025

The Open-Source Photochem Code: A General Chemical and Climate Model for Interpreting (Exo)Planet Observations

With the launch of the James Webb Space Telescope, we are firmly in the era of exoplanet atmosphere characterization. Understanding exoplanet spectra requires atmospheric chemical and climate models that span the diversity of planetary atmospheres. Here, we present a more general chemical and climate model of planetary atmospheres. Specifically, we introduce the open-source, one-dimensional photochemical and climate code Photochem, and benchmark the model against the observed compositions and climates of Venus, Earth, Mars, Jupiter and Titan with a single set of kinetics, thermodynamics and opacities. We also model the chemistry of the hot Jupiter exoplanet WASP-39b. All simulations are open-source and reproducible. To first order, Photochem broadly reproduces the gas-phase chemistry and pressure-temperature profiles of all six planets. The largest model-data discrepancies are found in Venus's sulfur chemistry, motivating future experimental work on sulfur kinetics and spacecraft missions to Venus. We also find that clouds and hazes are important for the energy balance of Venus, Earth, Mars and Titan, and that accurately predicting aerosols with Photochem is challenging. Finally, we benchmark Photochem against the popular VULCAN and HELIOS photochemistry and climate models, finding excellent agreement for the same inputs; we also find that Photochem simulates atmospheres 2 to 100 time more efficiently. These results show that Photochem provides a comparatively general description of atmospheric chemistry and physics that can be leveraged to study Solar System worlds or interpret telescope observations of exoplanets.

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arXiv2025

Detecting Land with Reflected Light Spectroscopy to Rule Out Waterworld O$_2$ Biosignature False Positives

The search for life outside our solar system is at the forefront of modern astronomy, and telescopes such as the Habitable Worlds Observatory (HWO) are being designed to identify biosignatures. Molecular oxygen, O$_2$, is considered a promising indication of life, yet substantial abiotic O$_2$ may accumulate from H$_2$O photolysis and hydrogen escape on a lifeless, fully (100%) ocean-covered terrestrial planet when surface O$_2$ sinks are suppressed. This so-called waterworld false positive scenario could be ruled out with land detection because exposed land precludes extremely deep oceans (~50 Earth oceans) given topographic limits set by the crushing strength of rocks. Land detection is possible because plausible geologic surfaces exhibit increasing reflectance with wavelength in the visible, whereas liquid water and ice/snow have flat or decreasing reflectance, respectively. Here, we present reflected light retrievals to demonstrate that HWO could detect land on an exo-Earth in the disk-averaged spectrum. Given a signal-to-noise ratio of 20 spectrum, Earth-like land fractions can be confidently detected with 0.3-1.1 $\mu$m spectral coverage (resolution R~140 in the visible, R~7 in the UV, with Earth-like atmosphere and clouds). We emphasize the need for UV spectroscopy down to at least 0.3 $\mu$m to break an O$_3$-land degeneracy. We find that the SNR and resolution requirements in the visible/UV imply that a larger aperture (~8 m) will be necessary to ensure the observing times required for land detection are feasible for most HWO terrestrial habitable zone targets. These results strongly inform the HWO minimum requirements to corroborate possible oxygen biosignatures.

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arXiv2025

Statistical geochemical constraints on present-day water outgassing as a source of secondary atmospheres on the TRAPPIST-1 exoplanets

The TRAPPIST-1 planetary system is observationally favorable for studying if planets orbiting M stars can retain atmospheres and host habitable conditions. Recent JWST secondary eclipse observations of TRAPPIST-1 c rule out a thick \ch{CO2} atmosphere but do not rule out atmospheric water vapor or its photochemical product, oxygen. Given the high expected escape rate, maintenance of atmospheric water vapor would require a present-day water source, such as volcanic outgassing. Here, we simulate water outgassing on the TRAPPIST-1 planets over a broad phase space based on solar system terrestrial bodies. We then apply two filters based on observation and geochemistry that narrow this phase space and constrain the plausible outgassing scenarios. For all seven TRAPPIST-1 planets, we find that the water outgassing rate is most likely $\sim$0.03x Earth's but has upper limits of $\sim$8x Earth's. The allowed range also implies low, Mars-like magma emplacement rates and relatively dry, Earth-like mantles, although mantle water mass fractions up to 1 wt\% are possible. We also present scenarios with magma emplacement rates similar to Mars, Earth, and Io, resulting in different preferred mantle water content and outgassing rates. We find that water outgassing rates are potentially high enough to balance water escape rates, providing a theoretical pathway for the TRAPPIST-1 planets to maintain surface water or water-vapor-containing atmospheres over long timescales. The bounds on outgassing rates and interior properties can be used in atmospheric chemistry and escape models to contextualize future observations of the TRAPPIST-1 planets, and may be applicable to other terrestrial exoplanets.

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arXiv2024

Potential technosignature from anomalously low deuterium/hydrogen (D/H) in planetary water depleted by nuclear fusion technology

Deuterium-deuterium (DD) fusion is viewed as an ideal energy source for humanity in the far future, given a vast seawater supply of D. Here, we consider long-lived, extraterrestrial, technological societies that develop DD fusion. If such a society persists over geologic timescales, oceanic deuterium would diminish. For an ocean mass and initial D/H that are Earth-like, fusion power use of only $\sim$10 times that projected for humankind next century would deplete the deuterium-hydrogen ratio (D/H) in $\sim$(a few)$\times 10^8$ years to values below that of the local Interstellar Medium (ISM). Ocean masses of a few percent Earth's would reach anomalously low D/H in $\sim10^6$ to $10^7$ years. The timescale shortens with greater energy consumption, smaller oceans, or lower initial D/H. Here, we suggest that anomalous D/H in planetary water below local ISM values of $\sim16\times 10^{-6}$ (set by Big Bang nucleosynthesis plus deuterium loss onto dust or small admixtures of deuterium-poor stellar material) may be a technosignature. Unlike SETI from radio signals, anomalous D/H would persist for eons, even if civilizations perish or relocate. We discuss wavelengths of strong absorption features for detecting D/H anomalies in atmospheric water vapor. These are vibrational O-D stretching at 3.7 $μ$m in transmission spectroscopy of Earth-like worlds, $\sim1.5$ $μ$m (in the wings of the 1.4 $μ$m water band) in the shorter near-infrared for direct imaging by Habitable Worlds Observatory, and 3.7 $μ$m or $\sim7.5$ $μ$m (in the wings of the broad 6.3 $μ$m bending vibration of water) for concepts like the Large Interferometer for Exoplanets (LIFE).

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arXiv2024

In-situ crystallographic mapping constrains sulfate deposition and timing in Jezero crater, Mars

Late-stage Ca-sulfate-filled fractures are common on Mars. Notably, the Shenandoah formation in the western edge of Jezero crater preserves a variety of Ca-sulfate minerals in the fine-grained siliciclastic rocks explored by the Perseverance rover. However, the depositional environment and timing of the formation of these sulfates is unknown. To address this outstanding problem, we developed a new technique to map the crystal textures of these sulfates in situ at two stratigraphically similar locations in the Shenandoah formation, allowing us to constrain the burial depth and paleoenvironment at the time of their deposition. Our results suggest that some Ca-sulfate analyzed was formed at a burial depth greater than 80m, whereas Ca-sulfates present at another outcrop likely precipitated in a shallow-subsurface environment. These results indicate that samples collected for potential return to Earth at the two studied locations capture two different times and distinct chemical conditions in the depositional history of the Shenandoah formation providing multiple opportunities to evaluate surface and subsurface habitability.

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arXiv2024

Three-stage Formation of Cap Carbonates after Marinoan Snowball Glaciation Consistent with Depositional Timescales and Geochemistry

At least two global "Snowball Earth" glaciations occurred during the Neoproterozoic Era (1000-538.8 million years ago). Post-glacial surface environments during this time are recorded in cap carbonates: layers of limestone or dolostone that directly overlie glacial deposits. Postulated environmental conditions that created the cap carbonates lack consensus largely because single hypotheses fail to explain the cap carbonates' global mass, depositional timescales, and geochemistry of parent waters. Here, we present a global geologic carbon cycle model before, during, and after the second glaciation (i.e. the Marinoan) that explains cap carbonate characteristics. We find a three-stage process for cap carbonate formation: (1) low-temperature seafloor weathering during glaciation generates deep-sea alkalinity; (2) vigorous post-glacial continental weathering supplies alkalinity to a carbonate-saturated freshwater layer, rapidly precipitating cap carbonates; (3) mixing of post-glacial meltwater with deep-sea alkalinity prolongs cap carbonate deposition. We suggest how future geochemical data and modeling refinements could further assess our hypothesis.

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arXiv2023

Inferring Chemical Disequilibrium Biosignatures for Proterozoic Earth-Like Exoplanets

Chemical disequilibrium quantified via available free energy has previously been proposed as a potential biosignature. However, exoplanet biosignature remote sensing work has not yet investigated how observational uncertainties impact the ability to infer a life-generated available free energy. We pair an atmospheric retrieval tool to a thermodynamics model to assess the detectability of chemical disequilibrium signatures of Earth-like exoplanets, emphasizing the Proterozoic Eon where atmospheric abundances of oxygen-methane disequilibrium pairs may have been relatively high. Retrieval model studies applied across a range of gas abundances revealed that order-of-magnitude constraints on disequilibrium energy are achieved with simulated reflected-light observations at the high abundance scenario and signal-to-noise ratios (50) while weak constraints are found at moderate SNRs (20\,--\,30) for med\,--\,low abundance cases. Furthermore, the disequilibrium energy constraints are improved by modest thermal information encoded in water vapor opacities at optical and near-infrared wavelengths. These results highlight how remotely detecting chemical disequilibrium biosignatures can be a useful and metabolism-agnostic approach to biosignature detection.

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arXiv2023

Origin of Life Molecules in the Atmosphere After Big Impacts on the Early Earth

The origin of life on Earth would benefit from a prebiotic atmosphere that produced nitriles, like HCN, which enable ribonucleotide synthesis. However, geochemical evidence suggests that Hadean air was relatively oxidizing with negligible photochemical production of prebiotic molecules. These paradoxes are resolved by iron-rich asteroid impacts that transiently reduced the entire atmosphere, allowing nitriles to form in subsequent photochemistry. Here, we investigate impact-generated reducing atmospheres using new time-dependent, coupled atmospheric chemistry and climate models, which account for gas-phase reactions and surface-catalysis. The resulting H$_2$-, CH$_4$- and NH$_3$-rich atmospheres persist for millions of years, until hydrogen escapes to space. HCN and HCCCN production and rainout to the surface can reach $10^9$ molecules cm$^{-2}$ s$^{-1}$ in hazy atmospheres with a mole ratio of $\mathrm{CH_4} / \mathrm{CO_2} > 0.1$. Smaller $\mathrm{CH_4} / \mathrm{CO_2}$ ratios produce HCN rainout rates $< 10^5$ molecules cm$^{-2}$ s$^{-1}$, and negligible HCCCN. The minimum impactor mass that creates atmospheric $\mathrm{CH_4} / \mathrm{CO_2} > 0.1$ is $4 \times 10^{20}$ to $5 \times 10^{21}$ kg (570 to 1330 km diameter), depending on how efficiently iron reacts with a steam atmosphere, the extent of atmospheric equilibration with an impact-induced melt pond, and the surface area of nickel that catalyzes CH$_4$ production. Alternatively, if steam permeates and deeply oxidizes crust, impactors $\sim 10^{20}$ kg could be effective. Atmospheres with copious nitriles have $> 360$ K surface temperatures, perhaps posing a challenge for RNA longevity, although cloud albedo can produce cooler climates. Regardless, post-impact cyanide can be stockpiled and used in prebiotic schemes after hydrogen has escaped to space.

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arXiv2021

The peak absorbance wavelength of photosynthetic pigments around other stars from spectral optimization

In the search for life on other planets, the presence of photosynthetic vegetation may be detectable from the colors of light it reflects. On the modern Earth, this spectral reflectance is characterized by an increase in reflectance between the red and near-infrared wavelengths, a "red edge". On planets orbiting different stellar types, red edge analogs may occur at other colors than red. Thus, knowing the wavelengths at which photosynthetic organisms preferentially absorb and reflect photons is necessary to detect red edge analogs on other planets. Using a numerical model that predicts the absorbance spectrum of extant photosynthetic pigments on Earth from Marosvölgyi and van Gorkom (2010), we calculate the absorbance spectrum for pigments on an Earth-like planet around F through late M type stars that are adapted for maximal energy production. In this model, cellular energy production is maximized when pigments are tuned to absorb at the wavelength that maximizes energy input from incident photons while minimizing thermal emission and costs to build the photosynthetic apparatus. We find that peak photon absorption for photosynthetic organisms around F type stars tends to be in the blue while for G, K, and early M type stars, red or just beyond is preferred. Around the coolest M type stars, these organisms may preferentially absorb in the near-infrared, possibly past one micron. These predictions are consistent with previous, qualitative estimates of pigment absorptance. Our predicted pigment absorbance spectra depend on both the stellar type and planetary atmospheric composition, especially atmospheric water vapor concentrations, which alter the availability of surface photons and thus the predicted pigment absorption. By constraining the absorbance spectra of alien, photosynthetic organisms, future observations may be better equipped to detect red edge analogs.

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arXiv2021

Anoxic Atmospheres on Mars Driven by Volcanism: Implications for Past Environments and Life

Mars today has no active volcanism and its atmosphere is oxidizing, dominated by the photochemistry of CO2 and H2O. Using a one-dimensional photochemical model, we consider whether plausible volcanic gas fluxes could have switched the redox-state of the past martian atmosphere to reducing conditions. In our model, the total quantity and proportions of volcanic gases depend on the water content, outgassing pressure, and oxygen fugacity of the source melt. We find that with reasonable melt parameters the past martian atmosphere (~3.5 Gyr to present) could have easily reached reducing and anoxic conditions with modest levels of volcanism, >0.14 km^3/yr, well within the range of prior estimates. Counter-intuitively we also find that more reducing melts with lower oxygen fugacity require greater amounts of volcanism to switch a paleo-atmosphere from oxidizing to reducing. The reason is that sulfur is more stable in such melts and lower absolute fluxes of sulfur-bearing gases more than compensate for increases in the proportions of H2 and CO. These results imply that ancient Mars should have experienced periods with anoxic and reducing atmospheres even through the mid-Amazonian whenever volcanic outgassing was sustained at sufficient levels. Reducing anoxic conditions are potentially conducive to the synthesis of prebiotic organic compounds, such as amino acids, and are therefore relevant to the possibility of life on Mars. Also, anoxic reducing conditions should have influenced the type of minerals that were formed on the surface or deposited from the atmosphere such as elemental polysulfur (S8) as a signature of past reducing atmospheres. Finally, our models allow us to estimate the amount of volcanically sourced atmospheric sulfate deposited over Mars' history, approximately 10^6 to 10^9 Tmol, with a spread depending on assumed outgassing rate history and magmatic source conditions.

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arXiv2020

Carbonate-Silicate Cycle Predictions of Earth-like Planetary Climates and Testing the Habitable Zone Concept

In the conventional habitable zone (HZ) concept, a CO$_{2}$-H$_2$O greenhouse maintains surface liquid water. Through the water-mediated carbonate-silicate weathering cycle, atmospheric CO$_{2}$ partial pressure (pCO$_{2}$) responds to changes in surface temperature, stabilizing the climate over geologic timescales. We show that this weathering feedback ought to produce a log-linear relationship between pCO$_{2}$ and incident flux on Earth-like planets in the HZ. However, this trend has scatter because geophysical and physicochemical parameters can vary, such as land area for weathering and CO$_2$ outgassing fluxes. Using a coupled climate and carbonate-silicate weathering model, we quantify the likely scatter in pCO$_2$ with orbital distance throughout the HZ. From this dispersion, we predict a two-dimensional relationship between incident flux and pCO$_2$ in the HZ and show that it could be detected from at least 83 ($2σ$) Earth-like exoplanet observations. If fewer Earth-like exoplanets are observed, testing the HZ hypothesis from this relationship could be difficult.

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arXiv2020

Abundant atmospheric methane from volcanism on terrestrial planets is unlikely and strengthens the case for methane as a biosignature

The disequilibrium combination of abundant methane and carbon dioxide has been proposed as a promising exoplanet biosignature that is readily detectable with upcoming telescopes such as the James Webb Space Telescope. However, few studies have explored the possibility of non-biological CH4 and CO2 and related contextual clues. Here, we investigate whether magmatic volcanic outgassing on terrestrial planets can produce atmospheric CH4 and CO2 with a thermodynamic model. Our model suggests that volcanoes are unlikely to produce CH4 fluxes comparable to biological fluxes. Improbable cases where volcanoes produce biological amounts of CH4 also produce ample carbon monoxide. We show, using a photochemical model, that high abiotic CH4 abundances produced by volcanoes would be accompanied by high CO abundances, which could be a detectable false positive diagnostic. Overall, when considering known mechanisms for generating abiotic CH4 on terrestrial planets, we conclude that observations of atmospheric CH4 with CO2 are difficult to explain without the presence of biology when the CH4 abundance implies a surface flux comparable to modern Earth's biological CH4 flux. A small or negligible CO abundance strengthens the CH4+CO2 biosignature because life readily consumes atmospheric CO, while reducing volcanic gases likely cause CO to build up in a planet's atmosphere. Furthermore, the difficulty of volcanically-generated CH4-rich atmospheres suitable for an origin of life may favor alternatives such as impact-induced reducing atmospheres.

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arXiv2020

Atmospheric Erosion by Giant Impacts onto Terrestrial Planets: A Scaling Law for any Speed, Angle, Mass, and Density

We present a new scaling law to predict the loss of atmosphere from planetary collisions for any speed, angle, impactor mass, target mass, and body compositions, in the regime of giant impacts onto broadly terrestrial planets with relatively thin atmospheres. To this end, we examine the erosion caused by a wide range of impacts, using 3D smoothed particle hydrodynamics simulations with sufficiently high resolution to directly model the fate of low-mass atmospheres around 1% of the target's mass. Different collision scenarios lead to extremely different behaviours and consequences for the planets. In spite of this complexity, the fraction of lost atmosphere is fitted well by a power law. Scaling is independent of the system mass for a constant impactor mass ratio. Slow atmosphere-hosting impactors can also deliver a significant mass of atmosphere, but always accompanied by larger proportions of their mantle and core. Different Moon-forming impact hypotheses suggest that around 10 to 60% of a primordial atmosphere could have been removed directly, depending on the scenario. We find no evident departure from the scaling trends at the extremes of the parameters explored. The scaling law can be incorporated readily into models of planet formation.

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arXiv2018

A Maximum Subsurface Biomass on Mars from Untapped Free Energy: CO and H2 as Potential Antibiosignatures

Whether extant life exists in the martian subsurface is an open question. High concentrations of photochemically produced CO and H2 in the otherwise oxidizing martian atmosphere represent untapped sources of biologically useful free energy. These out-of-equilibrium species diffuse into the regolith, so subsurface microbes could use them as a source of energy and carbon. Indeed, CO oxidation and methanogenesis are relatively simple and evolutionarily ancient metabolisms on Earth. Consequently, assuming CO- or H2- consuming metabolisms would evolve on Mars, the persistence of CO and H2 in the martian atmosphere set limits on subsurface metabolic activity. Here, we constrain such maximum subsurface metabolic activity on Mars using a 1-D photochemical model with a hypothetical global biological sink on atmospheric CO and H2. We increase the biological sink until the model atmospheric composition diverges from observed abundances. We find maximum biological downward subsurface sinks of 1.5e8 molecules/cm^2/s for CO and 1.9e8 molecules/cm^2/s for H2. These covert to a maximum metabolizing biomass of <10^27 cells or <2e11 kg, equivalent to <1e-4 to 1e-5 of Earth's biomass, depending on the terrestrial estimate. Diffusion calculations suggest this upper biomass limit applies to the top few kilometers of the martian crust in communication with the atmosphere at low to mid latitudes. This biomass limit is more robust than previous estimates because we test multiple possible chemoautotrophic ecosystems over a broad parameter space of tunable model variables using an updated photochemical model with precise atmospheric concentrations and uncertainties from Curiosity. Our results of sparse or absent life in the martian subsurface also demonstrate how the atmospheric redox pairs of CO-O2 and H2-O2 may constitute antibiosignatures, which may be relevant to excluding life on exoplanets.

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arXiv2018

Strange messenger: A new history of hydrogen on Earth, as told by Xenon

Atmospheric xenon is strongly mass fractionated, the result of a process that apparently continued through the Archean and perhaps beyond. Previous models that explain Xe fractionation by hydrodynamic hydrogen escape cannot gracefully explain how Xe escaped when Ar and Kr did not, nor allow Xe to escape in the Archean. Here we show that Xe is the only noble gas that can escape as an ion in a photo-ionized hydrogen wind, possible in the absence of a geomagnetic field or along polar magnetic field lines that open into interplanetary space. To quantify the hypothesis we construct new 1-D models of hydrodynamic diffusion-limited hydrogen escape from highly-irradiated CO$_2$-H$_2$-H atmospheres. The models reveal three minimum requirements for Xe escape: solar EUV irradiation needs to exceed $10\times$ that of the modern Sun; the total hydrogen mixing ratio in the atmosphere needs to exceed 1% (equiv. to 0.5% CH$_4$); and transport amongst the ions in the lower ionosphere needs to lift the Xe ions to the base of the outflowing hydrogen corona. The long duration of Xe escape implies that, if a constant process, Earth lost the hydrogen from at least one ocean of water, roughly evenly split between the Hadean and the Archean. However, to account for both Xe's fractionation and also its depletion with respect to Kr and primordial $^{244}$Pu, Xe escape must have been limited to small apertures or short episodes, which suggests that Xe escape was restricted to polar windows by a geomagnetic field, or dominated by outbursts of high solar activity, or limited to transient episodes of abundant hydrogen, or a combination of these. Xenon escape stopped when the hydrogen (or methane) mixing ratio became too small, or EUV radiation from the aging Sun became too weak, or charge exchange between Xe$^+$ and O$_2$ rendered Xe neutral.

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arXiv2018

Detectability of biosignatures in anoxic atmospheres with the James Webb Space Telescope: A TRAPPIST-1e case study

The James Webb Space Telescope (JWST) may be capable of finding biogenic gases in the atmospheres of habitable exoplanets around low mass stars. Considerable attention has been given to the detectability of biogenic oxygen, which could be found using an ozone proxy, but ozone detection with JWST will be extremely challenging, even for the most favorable targets. Here, we investigate the detectability of biosignatures in anoxic atmospheres analogous to those that likely existed on the early Earth. Arguably, such anoxic biosignatures could be more prevalent than oxygen biosignatures if life exists elsewhere. Specifically, we simulate JWST retrievals of TRAPPIST-1e to determine whether the methane plus carbon dioxide disequilibrium biosignature pair is detectable in transit transmission. We find that ~10 transits using the Near InfraRed Spectrograph (NIRSpec) prism instrument may be sufficient to detect carbon dioxide and constrain methane abundances sufficiently well to rule out known, non-biological CH$_{4}$ production scenarios to ~90% confidence. Furthermore, it might be possible to put an upper limit on carbon monoxide abundances that would help rule out non-biological methane-production scenarios, assuming the surface biosphere would efficiently drawdown atmospheric CO. Our results are relatively insensitive to high altitude clouds and instrument noise floor assumptions, although stellar heterogeneity and variability may present challenges.

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arXiv2018

Exoplanet Biosignatures: A Framework for Their Assessment

Finding life on exoplanets from telescopic observations is an ultimate goal of exoplanet science. Life produces gases and other substances, such as pigments, which can have distinct spectral or photometric signatures. Whether or not life is found with future data must be expressed with probabilities, requiring a framework of biosignature assessment. We present a framework in which we advocate using biogeochemical "Exo-Earth System" models to simulate potential biosignatures in spectra or photometry. Given actual observations, simulations are used to find the Bayesian likelihoods of those data occurring for scenarios with and without life. The latter includes "false positives" where abiotic sources mimic biosignatures. Prior knowledge of factors influencing planetary inhabitation, including previous observations, is combined with the likelihoods to give the Bayesian posterior probability of life existing on a given exoplanet. Four components of observation and analysis are necessary. 1) Characterization of stellar (e.g., age and spectrum) and exoplanetary system properties, including "external" exoplanet parameters (e.g., mass and radius) to determine an exoplanet's suitability for life. 2) Characterization of "internal" exoplanet parameters (e.g., climate) to evaluate habitability. 3) Assessment of potential biosignatures within the environmental context (components 1-2) and any corroborating evidence. 4) Exclusion of false positives. The resulting posterior Bayesian probabilities of life's existence map to five confidence levels, ranging from "very likely" (90-100%) to "very unlikely" ($\le$10%) inhabited.

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arXiv2018

Constraining the climate and ocean pH of the early Earth with a geological carbon cycle model

The early Earth's environment is controversial. Climatic estimates range from hot to glacial, and inferred marine pH spans strongly alkaline to acidic. Better understanding of early climate and ocean chemistry would improve our knowledge of the origin of life and its coevolution with the environment. Here, we use a geological carbon cycle model with ocean chemistry to calculate self-consistent histories of climate and ocean pH. Our carbon cycle model includes an empirically justified temperature and pH dependence of seafloor weathering, allowing the relative importance of continental and seafloor weathering to be evaluated. We find that the Archean climate was likely temperate (0-50 °C) due to the combined negative feedbacks of continental and seafloor weathering. Ocean pH evolves monotonically from 6.6 (+0.6,-0.4) (2σ) at 4.0 Ga to 7.0 (+0.7,-0.5) (2σ) at the Archean-Proterozoic boundary, and to 7.9 (+0.1,-0.2) (2σ) at the Proterozoic-Phanerozoic boundary. This evolution is driven by the secular decline of pCO2, which in turn is a consequence of increasing solar luminosity, but is moderated by carbonate alkalinity delivered from continental and seafloor weathering. Archean seafloor weathering may have been a comparable carbon sink to continental weathering, but is less dominant than previously assumed, and would not have induced global glaciation. We show how these conclusions are robust to a wide range of scenarios for continental growth, internal heat flow evolution and outgassing history, greenhouse gas abundances, and changes in the biotic enhancement of weathering.

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