arXiv subjects

David C. Catling

Publications and source records attributed to David C. Catling.

27 records · Page 2Linked to original sources

arXiv2018

Disequilibrium biosignatures over Earth history and implications for detecting exoplanet life

Chemical disequilibrium in planetary atmospheres has been proposed as a generalized method for detecting life on exoplanets through remote spectroscopy. Among solar system planets with substantial atmospheres, the modern Earth has the largest thermodynamic chemical disequilibrium due to the presence of life. However, how this disequilibrium changed over time and, in particular, the biogenic disequilibria maintained in the anoxic Archean or less oxic Proterozoic eons are unknown. We calculate the atmosphere-ocean disequilibrium in the Precambrian using conservative proxy- and model-based estimates of early atmospheric and oceanic compositions. We omit crustal solids because subsurface composition is not detectable on exoplanets, unlike above-surface volatiles. We find that (i) disequilibrium increased through time in step with the rise of oxygen; (ii) both the Proterozoic and Phanerozoic may have had remotely detectable biogenic disequilibria due to the coexistence of O$_{2}$, N$_{2}$, and liquid water; and (iii) the Archean had a biogenic disequilibrium caused by the coexistence of N$_2$, CH$_4$, CO$_2$, and liquid water, which, for an exoplanet twin, may be remotely detectable. On the basis of this disequilibrium, we argue that the simultaneous detection of abundant CH$_{4}$ and CO$_{2}$ in a habitable exoplanet's atmosphere is a potential biosignature. Specifically, we show that methane mixing ratios greater than 0.001 are potentially biogenic, whereas those exceeding 0.01 are likely biogenic due to the difficulty in maintaining large abiotic methane fluxes to support high methane levels in anoxic atmospheres. Biogenicity would be strengthened by the absence of abundant CO, which should not coexist in a biological scenario.

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arXiv2018

Life Beyond the Solar System: Remotely Detectable Biosignatures

For the first time in human history, we will soon be able to apply the scientific method to the question "Are We Alone?" The rapid advance of exoplanet discovery, planetary systems science, and telescope technology will soon allow scientists to search for life beyond our Solar System through direct observation of extrasolar planets. This endeavor will occur alongside searches for habitable environments and signs of life within our Solar System. While the searches are thematically related and will inform each other, they will require separate observational techniques. The search for life on exoplanets holds potential through the great diversity of worlds to be explored beyond our Solar System. However, there are also unique challenges related to the relatively limited data this search will obtain on any individual world. This white paper reviews the scientific community's ability to use data from future telescopes to search for life on exoplanets. This material summarizes products from the Exoplanet Biosignatures Workshop Without Walls (EBWWW). The EBWWW was constituted by a series of online and in person activities, with participation from the international exoplanet and astrobiology communities, to assess state of the science and future research needs for the remote detection of life on planets outside our Solar System.

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arXiv2017

The cosmic shoreline: the evidence that escape determines which planets have atmospheres, and what this may mean for Proxima Centauri b

The planets of the Solar System divide neatly between those with atmospheres and those without when arranged by insolation ($I$) and escape velocity ($v_{\mathrm{esc}}$). The dividing line goes as $I \propto v_{\mathrm{esc}}^4$. Exoplanets with reported masses and radii are shown to crowd against the extrapolation of the Solar System trend, making a metaphorical cosmic shoreline that unites all the planets. The $I \propto v_{\mathrm{esc}}^4$ relation may implicate thermal escape. We therefore address the general behavior of hydrodynamic thermal escape models ranging from Pluto to highly-irradiated Extrasolar Giant Planets (EGPs). Energy-limited escape is harder to test because copious XUV radiation is mostly a feature of young stars, and hence requires extrapolating to historic XUV fluences ($I_{\mathrm{xuv}}$) using proxies and power laws. An energy-limited shoreline should scale as $I_{\mathrm{xuv}} \propto v_{\mathrm{esc}}^3\sqrtρ$, which differs distinctly from the apparent $I_{\mathrm{xuv}} \propto v_{\mathrm{esc}}^4$ relation. Energy-limited escape does provide good quantitative agreement to the highly irradiated EGPs. Diffusion-limited escape implies that no planet can lose more than 1% of its mass as H$_2$. Impact erosion, to the extent that impact velocities $v_{\mathrm{imp}}$ can be estimated for exoplanets, fits to a $v_{\mathrm{imp}} \approx 4\,-\,5\, v_{\mathrm{esc}}$ shoreline. The proportionality constant is consistent with what the collision of comet Shoemaker-Levy 9 showed us we should expect of modest impacts in deep atmospheres. With respect to the shoreline, Proxima Centauri b is on the metaphorical beach. Known hazards include its rapid energetic accretion, high impact velocities, its early life on the wrong side of the runaway greenhouse, and Proxima Centauri's XUV radiation. In its favor is a vast phase space of unknown unknowns.

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arXiv2017

A warm or a cold early Earth? New insights from a 3-D climate-carbon model

Oxygen isotopes in marine cherts have been used to infer hot oceans during the Archean with temperatures between 60°C (333 K) and 80°C (353 K). Such climates are challenging for the early Earth warmed by the faint young Sun. The interpretation of the data has therefore been controversial. 1D climate modeling inferred that such hot climates would require very high levels of CO2 (2-6 bars). Previous carbon cycle modeling concluded that such stable hot climates were impossible and that the carbon cycle should lead to cold climates during the Hadean and the Archean. Here, we revisit the climate and carbon cycle of the early Earth at 3.8 Ga using a 3D climate-carbon model. We find that CO2 partial pressures of around 1 bar could have produced hot climates given a low land fraction and cloud feedback effects. However, such high CO2 partial pressures should not have been stable because of the weathering of terrestrial and oceanic basalts, producing an efficient stabilizing feedback. Moreover, the weathering of impact ejecta during the Late Heavy Bombardment (LHB) would have strongly reduced the CO2 partial pressure leading to cold climates and potentially snowball Earth events after large impacts. Our results therefore favor cold or temperate climates with global mean temperatures between around 8°C (281 K) and 30°C (303 K) and with 0.1-0.36 bar of CO2 for the late Hadean and early Archean. Finally, our model suggests that the carbon cycle was efficient for preserving clement conditions on the early Earth without necessarily requiring any other greenhouse gas or warming process.

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arXiv2017

The longevity of water ice on Ganymedes and Europas around migrated giant planets

The gas giant planets in the Solar System have a retinue of icy moons, and we expect giant exoplanets to have similar satellite systems. If a Jupiter-like planet were to migrate toward its parent star the icy moons orbiting it would evaporate, creating atmospheres and possible habitable surface oceans. Here, we examine how long the surface ice and possible oceans would last before being hydrodynamically lost to space. The hydrodynamic loss rate from the moons is determined, in large part, by the stellar flux available for absorption, which increases as the giant planet and icy moons migrate closer to the star. At some planet-star distance the stellar flux incident on the icy moons becomes so great that they enter a runaway greenhouse state. This runaway greenhouse state rapidly transfers all available surface water to the atmosphere as vapor, where it is easily lost from the small moons. However, for icy moons of Ganymede's size around a Sun-like star we found that surface water (either ice or liquid) can persist indefinitely outside the runaway greenhouse orbital distance. In contrast, the surface water on smaller moons of Europa's size will only persist on timescales greater than 1 Gyr at distances ranging 1.49 to 0.74 AU around a Sun-like star for Bond albedos of 0.2 and 0.8, where the lower albedo becomes relevant if ice melts. Consequently, small moons can lose their icy shells, which would create a torus of H atoms around their host planet that might be detectable in future observations.

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arXiv2016

Is the Pale Blue Dot unique? Optimized photometric bands for identifying Earth-like exoplanets

The next generation of ground and space-based telescopes will image habitable planets around nearby stars. A growing literature describes how to characterize such planets with spectroscopy, but less consideration has been given to the usefulness of planet colors. Here, we investigate whether potentially Earth-like exoplanets could be identified using UV-visible-to-NIR wavelength broadband photometry (350-1000 nm). Specifically, we calculate optimal photometric bins for identifying an exo-Earth and distinguishing it from uninhabitable planets including both Solar System objects and model exoplanets. The color of some hypothetical exoplanets - particularly icy terrestrial worlds with thick atmospheres - is similar to Earth's because of Rayleigh scattering in the blue region of the spectrum. Nevertheless, subtle features in Earth's reflectance spectrum appear to be unique. In particular, Earth's reflectance spectrum has a 'U-shape' unlike all our hypothetical, uninhabitable planets. This shape is partly biogenic because O2-rich, oxidizing air is transparent to sunlight, allowing prominent Rayleigh scattering, while ozone absorbs visible light, creating the bottom of the 'U'. Whether such uniqueness has practical utility depends on observational noise. If observations are photon limited or dominated by astrophysical sources (zodiacal light or imperfect starlight suppression), then the use of broadband visible wavelength photometry to identify Earth twins has little practical advantage over obtaining detailed spectra. However, if observations are dominated by dark current then optimized photometry could greatly assist preliminary characterization. We also calculate the optimal photometric bins for identifying extrasolar Archean Earths, and find that the Archean Earth is more difficult to unambiguously identify than a modern Earth twin.

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arXiv2015

On detecting biospheres from chemical thermodynamic disequilibrium in planetary atmospheres

Atmospheric chemical disequilibrium has been proposed as a method for detecting extraterrestrial biospheres from exoplanet observations. Chemical disequilibrium is potentially a generalized biosignature since it makes no assumptions about particular biogenic gases or metabolisms. Here, we present the first rigorous calculations of the thermodynamic chemical disequilibrium in Solar System atmospheres, in which we quantify the available Gibbs energy: the Gibbs free energy of an observed atmosphere minus that of atmospheric gases reacted to equilibrium. The purely gas phase disequilibrium in Earth's atmosphere is mostly attributable to O2 and CH4. The available Gibbs energy is not unusual compared to other Solar System atmospheres and smaller than that of Mars. However, Earth's fluid envelope contains an ocean, allowing gases to react with water and requiring a multiphase calculation with aqueous species. The disequilibrium in Earth's atmosphere-ocean system (in joules per mole of atmosphere) ranges from 20 to 2E6 times larger than the disequilibria of other atmospheres in the Solar System. Only on Earth is the chemical disequilibrium energy comparable to the thermal energy per mole of atmosphere. Earth's disequilibrium is biogenic, mainly caused by the coexistence of N2, O2 and liquid water instead of more stable nitrate. In comparison, the O2-CH4 disequilibrium is minor. We identify abiotic processes that cause disequilibrium in the other atmospheres. Our metric requires minimal assumptions and could potentially be calculated using observations of exoplanet atmospheres. However, further work is needed to establish whether thermodynamic disequilibrium is a practical exoplanet biosignature, requiring an assessment of false positives, noisy observations, and other detection challenges. Our Matlab code and databases for these calculations are available, open source.

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arXiv2013

Common 0.1 bar Tropopause in Thick Atmospheres Set by Pressure-Dependent Infrared Transparency

A minimum atmospheric temperature, or tropopause, occurs at a pressure of around 0.1 bar in the atmospheres of Earth, Titan, Jupiter, Saturn, Uranus and Neptune, despite great differences in atmospheric composition, gravity, internal heat and sunlight. In all these bodies, the tropopause separates a stratosphere with a temperature profile that is controlled by the absorption of shortwave solar radiation, from a region below characterised by convection, weather, and clouds. However, it is not obvious why the tropopause occurs at the specific pressure near 0.1 bar. Here we use a physically-based model to demonstrate that, at atmospheric pressures lower than 0.1 bar, transparency to thermal radiation allows shortwave heating to dominate, creating a stratosphere. At higher pressures, atmospheres become opaque to thermal radiation, causing temperatures to increase with depth and convection to ensue. A common dependence of infrared opacity on pressure, arising from the shared physics of molecular absorption, sets the 0.1 bar tropopause. We hypothesize that a tropopause at a pressure of approximately 0.1 bar is characteristic of many thick atmospheres, including exoplanets and exomoons in our galaxy and beyond. Judicious use of this rule could help constrain the atmospheric structure, and thus the surface environments and habitability, of exoplanets.

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arXiv2012

An Analytic Radiative-Convective Model for Planetary Atmospheres

We present an analytic 1-D radiative-convective model of the thermal structure of planetary atmospheres. Our model assumes that thermal radiative transfer is gray and can be represented by the two-stream approximation. Model atmospheres are assumed to be in hydrostatic equilibrium, with a power law scaling between the atmospheric pressure and the gray thermal optical depth. The convective portions of our models are taken to follow adiabats that account for condensation of volatiles through a scaling parameter to the dry adiabat. By combining these assumptions, we produce simple, analytic expressions that allow calculations of the atmospheric pressure-temperature profile, as well as expressions for the profiles of thermal radiative flux and convective flux. We explore the general behaviors of our model. These investigations encompass (1) worlds where atmospheric attenuation of sunlight is weak, which we show tend to have relatively high radiative-convective boundaries, (2) worlds with some attenuation of sunlight throughout the atmosphere, which we show can produce either shallow or deep radiative-convective boundaries, depending on the strength of sunlight attenuation, and (3) strongly irradiated giant planets (including Hot Jupiters), where we explore the conditions under which these worlds acquire detached convective regions in their mid-tropospheres. Finally, we validate our model and demonstrate its utility through comparisons to the average observed thermal structure of Venus, Jupiter, and Titan, and by comparing computed flux profiles to more complex models.

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