arXiv subjects

Dries Van De Putte

Publications and source records attributed to Dries Van De Putte.

At least 19 recordsLinked to original sources

arXiv2026

PDRs4All XXII. Near-Infrared continuum in the Orion Bar

Conspicuous excess emission is present in the near-infrared (NIR) region in various objects, including reflection nebulae, planetary nebulae, and nearby galaxies. However, the spatial distribution and spectral shape of the excess emission remain poorly understood. We studied the NIR continuum emission spectroscopically and obtained its spatial distribution relative to the aromatic infrared band (AIB) at 3.3um in the Orion Bar prototypical photodissociation region (PDR). We aim to characterize its spectral shape and discuss its origin. We employed 3D spectroscopic data of the Orion Bar taken with the integrated field unit of NIRSpec on JWST from the Early Release Science program "PDRs4All." Contribution from the foreground ionized gas was estimated using the Cloudy code and subtracted. The observed regions were divided into nine physically distinct regions and an average spectrum was derived for each region. The nine regions, including the ionized gas, atomic PDR, and molecular PDR, clearly show remaining continuum in the region 1--4.5um. The continuum at wavelengths longer than 2.7um shows good correlations with the 3.3um AIB, while the correlation of the continuum at 1.2um is not significant. We further find that the NIR continuum in the Orion Bar can be approximated by a summation of two blackbodies. The low-temperature component correlates with the AIB well, while the high-temperature component does not. The average spectra also show absorption features at 3.0 and 4.27um, which are attributed to the presence in the spectra of water ice and CO2 ice. We discuss possible origins of the NIR continuum, among which recurrent fluorescence from carbon clusters better explains the observed low-temperature component. The presence of ice species suggests a contribution from a deeper layer of the PDR along the line of sight producing characteristic ice absorption features.

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arXiv2026

Detection of C$_{60}$ Combination Bands in the Near-IR Spectrum of Tc 1

We report the detection of a set of new near-infrared emission features between 3.5 and 5.2 $μ$m in JWST/NIRSpec observations of Tc 1, the planetary nebula known for displaying the cleanest and most prominent mid-infrared cosmic fullerene spectrum. These broad features share the same spatial distribution as the well-known C$_{60}$ and C$_{70}$ mid-infrared emission bands, peaking in an asymmetric ring approximately 5-6" from the central star. Through comparison with new anharmonic quantum chemical calculations, we demonstrate that these features arise from C$_{60}$ combination bands, marking their first detection in an astrophysical environment. The total energy radiated in the combination bands amounts to ~17% of the total energy emitted from all C$_{60}$ modes, with direct implications for fullerene cooling models. These near-infrared combination bands offer a promising new window for identifying and studying the molecular astrophysics of C$_{60}$ in sources where mid-infrared spectra are more complex.

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arXiv2026

Survival of very small carbonaceous dust grains in the inner-CGM of NGC 891 from JWST/MIRI MRS

We present new spectroscopic observations of the inner circumgalactic medium (CGM) of NGC 891 taken with the Mid-Infrared Imager/Medium Resolution Spectroscopy instrument onboard JWST, in four positions: two near the bulge and two at galactocentric radii (r) of ~ 1.5, 4.7 kpc. Each pair of pointings has one position along the minor axis (h) at ~ 0.5 kpc and one at ~ 1 kpc away from the mid-plane. We analyse both 1D spectra and 3D cubes using the dust emission model PAHFIT to extract properties of typical mid-IR features. These spectra reveal that the earlier reported mid-IR emission out to 4 kpc is dominated by the emission of polycyclic aromatic hydrocarbons (PAHs), and not hot dust continuum, providing direct evidence of the survival of PAHs in the inner CGM of NGC 891. Comparing PAH band ratios with other environments (Orion, M51), it is obvious that the 11.2 $μ$m PAH feature -- and not the usual 7.7 $μ$m -- dominates in NGC 891, which seems to imply the presence of more neutral, large PAHs in the CGM. Overall, PAH-to-continuum ratios show little variations with scale-height and radius in NGC 891, which suggests little PAH processing. However, we do see a decrease in the PAH feature strengths with the [Ne III]/[Ne II] ratio, pointing at elevated dust processing with increased radiation field hardness. We also confirm a tight correlation between H2 and PAH features, suggesting that both tracers must be co-spatial and, hence, implying that PAH emission predominantly arises from cool dense parts of cloudlets entrained in galactic outflows. Finally, we report the clear detection of a previously unidentified PAH feature at 16.72 $μ$m.

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arXiv2026

PDRs4All: XVIII. The evolution of the PAH ionisation and PAH size distribution across the Orion Bar

We investigate the evolution of the PAH population's charge state and size across key physical zones in the Orion Bar, which include the HII region, the atomic PDR (APDR), and three HI/H2 dissociation fronts (DF1, DF2, and DF3). Utilising the NASA Ames PAH Infrared Spectroscopic Database (PAHdb) and the pyPAHdb spectral modelling tool, we analysed the MIRI-MRS observations of the Orion Bar from the "PDRs4All" ERS Program. pyPAHdb modelling reveals the fractional contribution of the different PAH charge states and sizes to the total PAH emission across the Orion Bar. Cationic PAH emission peaks in the APDR region, where neutral PAHs have minimal contribution. Emission from neutral PAHs peaks in the HII region that consists of emission from a face-on PDR associated to the background OMC-1 molecular cloud, and in the molecular cloud regions past DF2. PAH anions are observed deep within the DF2 and DF3 zones. The average PAH size ranges between ~$60-74$ Nc. The modelling reveals regions of top-down PAH formation at the ionisation front, and bottom-up PAH formation within the molecular cloud region. The PAH ionisation parameter $γ$ ranges between ~$2-9 x 10^4$. Intensity ratios tracing PAH ionisation scale well with $γ$ in regions encompassing edge-on or face-on PDR emission, but their correlation weakens within the molecular cloud zone. Modelling of the $5-15$ $μ$m PAH spectrum with pyPAHdb achieves comprehensive characterization of the net contribution of neutral and cationic PAHs across different environments, whereas empirical PAH proxy intensity ratio tracers can be highly variable and unreliable outside regions dominated by PDR emission. The derived average PAH size in the different physical zones is consistent with a view of PAHs being more extensively subjected to ultraviolet processing closer to the ionisation front, and less affected within the molecular cloud.

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arXiv2025

JWST Captures Growth of Aromatic Hydrocarbon Dust Particles in the Extremely Metal-poor Galaxy Sextans A

The mid-infrared spectrum of star-forming, high metallicity galaxies is dominated by emission features from aromatic and aliphatic bonds in small carbonaceous dust grains, often referred to as polycyclic aromatic hydrocarbons (PAHs). In metal-poor galaxies, the abundance of PAHs relative to the total dust sharply declines, but the origin of this deficit is unknown. We present JWST observations that detect and resolve emission from PAHs in the 7% Solar metallicity galaxy Sextans A, representing the lowest metallicity detection of PAH emission to date. In contrast to higher metallicity galaxies, the clumps of PAH emission are compact (0.5-1.5'' or 3-10 pc), which explains why PAH emission evaded detection by lower resolution instruments like Spitzer. Ratios between the 3.3, 7.7, and 11.3 $μ$m PAH features indicate that the PAH grains in Sextans A are small and neutral, with no evidence of significant processing from the hard radiation fields within the galaxy. These results favor inhibited grain growth over enhanced destruction as the origin of the low PAH abundance in Sextans A. The compact clumps of PAH emission are likely active sites of in-situ PAH growth within a dense, well-shielded phase of the interstellar medium. Our results show that PAHs can form and survive in extremely metal-poor environments common early in the evolution of the Universe.

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arXiv2025

PDRs4All XX. Haute Couture: Spectral stitching of JWST MIRI-IFU cubes with matrix completion

MIRI is the imager and spectrograph covering wavelengths from $4.9$ to $27.9$ $μ$m onboard the James Webb Space Telescope (JWST). The Medium-Resolution Spectrometer (MRS) consists of four integral field units (IFU), each of which has three sub-channels. The twelve resulting spectral data cubes have different fields of view, spatial, and spectral resolutions. The wavelength range of each cube partially overlaps with the neighboring bands, and the overlap regions typically show flux mismatches which have to be corrected by spectral stitching methods. Stitching methods aim to produce a single data cube incorporating the data of the individual sub-channels, which requires matching the spatial resolution and the flux discrepancies. We present Haute Couture, a novel stitching algorithm which uses non-negative matrix factorization (NMF) to perform a matrix completion, where the available MRS data cubes are treated as twelve sub-matrices of a larger incomplete matrix. Prior to matrix completion, we also introduce a novel pre-processing to homogenize the global intensities of the twelve cubes. Our pre-processing consists in jointly optimizing a set of global scale parameters that maximize the fit between the cubes where spectral overlap occurs. We apply our novel stitching method to JWST data obtained as part of the PDRs4All observing program of the Orion Bar, and produce a uniform cube reconstructed with the best spatial resolution over the full range of wavelengths.

astro-ph.IM↗

arXiv2025

PDRs4All XVII: Formation and excitation of HD in photodissociation regions. Application to the Orion Bar

The James Webb Space Telescope enabled the first detection of several rovibrational emission lines of HD in the Orion Bar, a prototypical photodissociation region. This provides an incentive to examine the physics of HD in dense and strong PDRs. Using the latest data available on HD excitation by collisional, radiative and chemical processes, our goal is to unveil HD formation and excitation processes in PDRs by comparing our state-of-the-art PDR model with observations made in the Orion Bar and discuss if and how HD can be used as a complementary tracer of physical parameters in the emitting region. We compute detailed PDR models, using an upgraded version of the Meudon PDR code, which are compared to NIRSpec data using excitation diagrams and synthetic emission spectra. The models predict that HD is mainly produced in the gas phase via the reaction D + H2 = H + HD at the front edge of the PDR and that the D/HD transition is located slightly closer to the edge than the H/H2 transition. Rovibrational levels are excited by UV pumping. In the observations, HD rovibrational emission is detected close to the H/H2 dissociation fronts of the Orion Bar and peaks where vibrationally excited H2 peaks, rather than at the maximum emission of pure rotational H2 levels. We derive an excitation temperature around Tex ~ 480 - 710 K. Due to high continuum in the Orion Bar, fringes lead to high noise levels beyond 15 $μ$m, no pure rotational lines of HD are detected. The comparison to PDR models shows that a range of thermal pressure P = (3-9)x10$^7$ K cm$^{-3}$ with no strong constraints on the intensity of the UV field are compatible with HD observations. This range of pressure is compatible with previous estimates from H2 observations with JWST. This is the first time that observations of HD emission lines in the near-infrared are used to put constraints on the thermal pressure in the PDR.

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arXiv2025

PDRs4All XIX. The 6 to 9 $μ$m region as a probe of PAH charge and size in the Orion Bar

Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of molecular clouds. We aim to investigate the distribution and sizes of charged PAHs across the key zones of the Orion Bar PDR. We employ JWST MIRI-MRS observations of the Orion Bar from the Early Release Science program ''PDRs4All'' and synthetic images in the JWST MIRI filters. We investigate the spatial morphology of the AIBs at 6.2, 7.7, 8.6, and 11.0 $μ$m that commonly trace PAH cations, and the neutral PAH-tracing 11.2 $μ$m AIB, their (relative) correlations, and the relationship with existing empirical prescriptions for AIBs. The 6.2. 7.7, 8.6, 11.0, and 11.2 $μ$m AIBs are similar in spatial morphology, on larger scales. Analyzing three-feature intensity correlations, two distinct groups emerge: the 8.6 and 11.0 $μ$m vs. the 6.2 and 7.7 $μ$m AIBs. We attribute these correlations to PAH size. The 6.2 and 7.7 $μ$m AIBs trace cationic, medium-sized PAHs. Quantum chemical calculations reveal that the 8.6 $μ$m AIB is carried by large, compact, cationic PAHs, and the 11.0 $μ$m AIB's correlation to it implies, so is this band. The 6.2/8.6 and 7.7/8.6 PAH band ratios thus probe PAH size. We conclude that the 6.2/11.2 AIB ratio is the most reliable proxy for charged PAHs, within the cohort. We outline JWST MIRI imaging prescriptions that serve as effective tracers of the PAH ionization fraction as traced. This study showcases the efficacy of the 6-9 $μ$m AIBs to probe the charge state and size distribution of the emitting PAHs, offering insights into the physical conditions of their host environments. JWST MIRI photometry offers a viable alternative to IFU spectroscopy for characterizing this emission in extended objects.

astro-ph.GA↗

arXiv2025

PDRs4All XVI. Tracing aromatic infrared band characteristics in photodissociation region spectra with PAHFIT in the JWST era

Photodissociation regions (PDRs) exhibit emission between 3-20 um known as the Aromatic Infrared Bands (AIBs), originating from small carbonaceous species such as polycyclic aromatic hydrocarbons (PAHs). The AIB spectra observed in Galactic PDRs, such as the Orion Bar observations by the PDRs4All JWST program, are considered a local analog for those seen in extragalactic star-forming regions. We present the Python version of PAHFIT, a spectral decomposition tool that separates the contributions by AIB subcomponents, thermal dust emission, gas lines, stellar light, and dust extinction. By fitting segments of the Orion Bar spectra, we provide a configuration to decompose JWST spectra of PDRs in detail. The resulting central wavelengths and FWHM of the AIB subcomponents are compiled into a "PDR pack" for PAHFIT. We applied PAHFIT with this PDR pack and the default continuum model to spectra of the central star forming ring of the galaxy NGC7469. We introduce an alternate dust continuum model to fit the Orion Bar spectra, as the default PAHFIT continuum model mismatches the intensity at 15-26 um. Using the PDR pack and the alternate continuum model, PAHFIT reproduces the Orion Bar spectra with residuals of a few percent, and similar performance is achieved for the NGC7469 spectra. We provide PAHFIT-based diagnostics that trace the profile variations of the 3.3, 3.4, 5.7, 6.2, and 7.7 um AIBs, and thus the photochemical evolution of the AIB carriers. The 5.7 um AIB emission originates from at least two subpopulations, one more prominent in highly irradiated environments and one preferring more shielded environments. Smaller PAHs as well as very small grains or PAH clusters both thrive in the more shielded environments of the molecular zone in the Orion Bar. Based on these new diagnostics, we quantify the similarities between the AIB profiles observed in the Orion Bar and NGC7469.

astro-ph.GA↗

arXiv2025

Photometric Mapping of Carbonaceous/Siliceous Dust and Water Ice in the ISM with JWST: Applications to the Dense Sightlines

We introduce a new photometric mapping method for the James Webb Space Telescope (JWST) to measure the spatial distribution of carbonaceous dust, siliceous dust and water ice by using absorption features arising from the grains in the dense interstellar medium (ISM). Employing NIRCam and MIRI imaging filters, low-resolution spectroscopic data can be obtained to measure the optical depths of the 3.0-$μ$m water ice -OH feature, the 3.4-$μ$m aliphatic hydrocarbon -CH feature, and the 10-$μ$m silicate -SiO feature for large fields of view. This method provides extensive statistical data of the grains across wide fields in the ISM at minimal observing cost. In this study, we present its application on observational data from the literature to validate the measured optical depths and simulations to assess the accuracy of the method under various conditions. We showed that the photometric method can be employed to obtain reasonably accurate measurements of optical depth. We demonstrate that JWST optical depth maps enable the independent exploration of abundance distributions of major grain components across a wide spatial coverage in the ISM.

astro-ph.IM↗

arXiv2025

The Resolved Structure of a Low Metallicity Photodissociation Region

Photodissociation Regions (PDRs) are key to understanding the feedback processes that shape interstellar matter in galaxies. One important type of PDR is the interface between HII regions and molecular clouds, where far-ultraviolet (FUV) radiation from massive stars heats gas and dissociates molecules. Photochemical models predict that the C/CO transition occurs deeper in the PDR compared to the H/H$_2$ transition in low-metallicity environments, increasing the extent of CO-dark H$_2$ gas. This prediction has been difficult to test outside the Milky Way due to the lack of high spatial resolution observations tracing H$_2$ and CO. This study examines a low-metallicity PDR in the N13 region of the Small Magellanic Cloud (SMC) where we spatially resolve the ionization front, the H$_2$ dissociation front, and the C/CO transition using 12CO J=2-1, 3-2 and [CI] (1-0) observations from the Atacama Large Millimeter/sub-mm Array (ALMA) and near-infrared spectroscopy of the H$_2$ 2.12 1-0S(1) vibrational line, and H recombination lines from the James Webb Space Telescope (JWST). Our analysis shows that the separation between the H/H$_2$ and C/CO boundaries is approximately 0.043 $\pm$ 0.013(stat.) $\pm$ 0.0036(syst.) pc (equivalent to 0".146 $\pm$ 0".042(stat.) $\pm$ 0".012(syst.) at the SMC's distance of 62 kpc), defining the spatial extent of the CO-dark H$_2$ region. Compared to our plane-parallel PDR models, we find that a constant pressure model matches the observed structure better than a constant density one. Overall, we find that the PDR model does well at predicting the extent of the CO-dark H$_2$ layer in N13. This study represents the first resolved benchmark for low metallicity PDRs.

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arXiv2025

PDRs4All XIII. Empirical prescriptions for the interpretation of JWST imaging observations of star-forming regions

(Abridged) JWST continues to deliver incredibly detailed infrared (IR) images of star forming regions in the Milky Way and beyond. IR emission from star-forming regions is very spectrally rich due to emission from gas-phase atoms, ions, and polycyclic aromatic hydrocarbons (PAHs). Physically interpreting IR images of these regions relies on assumptions about the underlying spectral energy distribution in the imaging bandpasses. We aim to provide empirical prescriptions linking line, PAH, and continuum intensities from JWST images, to facilitate the interpretation of JWST images in a wide variety of contexts. We use JWST PDRs4All Near-Infrared Camera (NIRCam) and Mid-Infrared Instrument (MIRI) imaging and Near-Infrared Spectrograph (NIRSpec) integral field unit (IFU) and MIRI Medium Resolution Spectrograph (MRS) spectroscopic observations of the Orion Bar photodissociation region (PDR), to directly compare and cross-calibrate imaging and IFU data at ~100 AU resolution over a region where the radiation field and ISM environment evolves from the hot ionized gas to the cold molecular gas. We measure the relative contributions of line, PAH, and continuum emission to the NIRCam and MIRI filters as functions of local physical conditions. We provide empirical prescriptions based on NIRCam and MIRI images to derive intensities of emission lines and PAH features. Within the range of the environments probed in this study, these prescriptions accurately predict Pa-$α$, Br-$α$, PAH 3.3 $μ$m and 11.2 $μ$m intensities, while those for FeII 1.644 $μ$m, H$_2$ 1--0 S(1) 2.12 $μ$m and 1--0 S(9) 4.96 $μ$m, and PAH 7.7 $μ$m show more complicated environmental dependencies. Linear combinations of JWST NIRCam and MIRI images provide effective tracers of ionized gas, H$_2$, and PAH emission in PDRs. We expect these recipes to be useful for both the Galactic and extragalactic communities.

astro-ph.GA↗

arXiv2025

PDRs4All XI. Detection of infrared CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and disk d203-506: evidence of chemical pumping

The methylidyne cation (CH$^+$) and the methyl cation (CH$_3^+$) are building blocks of organic molecules, yet their coupled formation and excitation mechanisms remain mainly unprobed. The James Webb Space Telescope (JWST), with its high spatial resolution and good spectral resolution, provides unique access to the detection of these molecules. Our goal is to use the first detection of CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and in the protoplanetary disk d203-506, irradiated by the Trapezium cluster, to probe their formation and excitation mechanisms and constrain the physico-chemical conditions. We use spectro-imaging acquired using both the NIRSpec and MIRI-MRS instruments to study the CH$^+$ and CH$_3^+$ spatial distribution at very small scales, and compare it to excited H$_2$ emission. CH$^+$ and CH$_3^+$ emissions originate from the same region as highly excited H$_2$. Our comparison between the Bar and d203-506 reveals that both CH$^+$ and CH$_3^+$ excitation and/or formation are highly dependent on gas density. The excitation temperature of the observed CH$^+$ and CH$_3^+$ rovibrational lines is around $T$ ~ 1500 K in the Bar and $T$ ~ 800 K in d203-506. Moreover, the column densities derived from the rovibrational emission are less than 0.1 % of the total known (CH$^+$) and expected (CH$_3^+$) column densities. These results show that CH$^+$ and CH$_3^+$ level populations strongly deviate from ETL. CH$^+$ rovibrational emission can be explained by chemical formation pumping with excited H$_2$ via C$^+$ + H$_2^*$ = CH$^+$ + H. These results support a gas phase formation pathway of CH$^+$ and CH$_3^+$ via successive hydrogen abstraction reactions. However, we do not find any evidence of CH$_2^+$ emission in the JWST spectrum. Finally, observed CH$^+$ intensities coupled with chemical formation pumping model provide a diagnostic tool to trace the local density.

astro-ph.GA↗

arXiv2024

PDRs4All IX. Sulfur elemental abundance in the Orion Bar

One of the main problems in astrochemistry is determining the amount of sulfur in volatiles and refractories in the interstellar medium. The detection of the main sulfur reservoirs (icy H$_2$S and atomic gas) has been challenging, and estimates are based on the reliability of models to account for the abundances of species containing less than 1% of the total sulfur. The high sensitivity of the James Webb Space Telescope provides an unprecedented opportunity to estimate the sulfur abundance through the observation of the [S I] 25.249 $μ$m line. We used the [S III] 18.7 $μ$m, [S IV] 10.5 $μ$m, and [S l] 25.249 $μ$m lines to estimate the amount of sulfur in the ionized and molecular gas along the Orion Bar. For the theoretical part, we used an upgraded version of the Meudon photodissociation region (PDR) code to model the observations. New inelastic collision rates of neutral atomic sulfur with ortho- and para- molecular hydrogen were calculated to predict the line intensities. The [S III] 18.7 $μ$m and [S IV] 10.5 $μ$m lines are detected over the imaged region with a shallow increase (by a factor of 4) toward the HII region. We estimate a moderate sulfur depletion, by a factor of $\sim$2, in the ionized gas. The corrugated interface between the molecular and atomic phases gives rise to several edge-on dissociation fronts we refer to as DF1, DF2, and DF3. The [S l] 25.249 $μ$m line is only detected toward DF2 and DF3, the dissociation fronts located farthest from the HII region. The detailed modeling of DF3 using the Meudon PDR code shows that the emission of the [S l] 25.249 $μ$m line is coming from warm ($>$ 40 K) molecular gas located at A$_{\rm V}$ $\sim$ 1$-$5 mag from the ionization front. Moreover, the intensity of the [S l] 25.249 $μ$m line is only accounted for if we assume the presence of undepleted sulfur.

astro-ph.GA↗

arXiv2024

PDRs4All VIII: Mid-IR emission line inventory of the Orion Bar

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations.

astro-ph.GA↗

arXiv2024

A far-ultraviolet-driven photoevaporation flow observed in a protoplanetary disk

Most low-mass stars form in stellar clusters that also contain massive stars, which are sources of far-ultraviolet (FUV) radiation. Theoretical models predict that this FUV radiation produces photo-dissociation regions (PDRs) on the surfaces of protoplanetary disks around low-mass stars, impacting planet formation within the disks. We report JWST and Atacama Large Millimetere Array observations of a FUV-irradiated protoplanetary disk in the Orion Nebula. Emission lines are detected from the PDR; modelling their kinematics and excitation allows us to constrain the physical conditions within the gas. We quantify the mass-loss rate induced by the FUV irradiation, finding it is sufficient to remove gas from the disk in less than a million years. This is rapid enough to affect giant planet formation in the disk.

astro-ph.GA↗

arXiv2024

Formation of the Methyl Cation by Photochemistry in a Protoplanetary Disk

Forty years ago it was proposed that gas phase organic chemistry in the interstellar medium was initiated by the methyl cation CH3+, but hitherto it has not been observed outside the Solar System. Alternative routes involving processes on grain surfaces have been invoked. Here we report JWST observations of CH3+ in a protoplanetary disk in the Orion star forming region. We find that gas-phase organic chemistry is activated by UV irradiation.

astro-ph.GA↗

arXiv2023

OH as a probe of the warm water cycle in planet-forming disks

Water is a key ingredient for the emergence of life as we know it. Yet, its destruction and reformation in space remains unprobed in warm gas. Here, we detect the hydroxyl radical (OH) emission from a planet-forming disk exposed to external far-ultraviolet (FUV) radiation with the James Webb Space Telescope. The observations are confronted with the results of quantum dynamical calculations. The highly excited OH infrared rotational lines are the tell-tale signs of H2O destruction by FUV. The OH infrared ro-vibrational lines are attributed to chemical excitation via the key reaction O+H=OH+H which seeds the formation of water in the gas-phase. We infer that the equivalent of the Earth ocean's worth of water is destroyed per month and replenished. These results show that under warm and irradiated conditions water is destroyed and efficiently reformed via gas-phase reactions. This process, assisted by diffusive transport, could reduce the HDO/H2O ratio in the warm regions of planet-forming disks.

astro-ph.EP↗