Competition between carboxylic and unsaturated termination for chemisorption on H:Si: a first-principles analysis
This paper has been withdrawn by the author(s), due to incompleteness.
cond-mat.mtrl-sci↗
arXiv subjects
E. Molinari
Publications and source records attributed to E. Molinari.
A rapid and dramatic outburst in Blazar 3C 454.3 during May 2005 - Optical and infrared observations with REM and AIT
The flat-spectrum radio quasar 3C 454.3 is well known to be a highly active and variable source with outbursts occurring across the whole electromagnetic spectrum over the last decades. In spring 2005, 3C 454.3 has been reported to exhibit a strong optical outburst which subsequently triggered multi-frequency observations of the source covering the radio up to gamma-ray bands. Here, we present first results of our near-IR/optical (V, R, I, H band) photometry performed between May 11 and August 5, 2005 with the Rapid Eye Mount (REM) at La Silla in Chile and the Automatic Imaging Telescope (AIT) of the Perugia University Observatory. 3C 454.3 was observed during an exceptional and historical high state with a subsequent decrease in brightness over our 86 days observing period. The continuum spectral behaviour during the flaring and declining phase suggests a synchrotron peak below the near-IR band as well as a geometrical origin of the variations e.g. due to changes in the direction of forward beaming.
astro-ph↗
Multiband Photometry of the Blazar PKS 0537-441: A Major Active State in December 2004 - March 2005
Multiband VRIJHK photometry of the Blazar PKS 0537-441 obtained with the REM telescope from December 2004 to March 2005 is presented. A major period of activity is found with more than four magnitudes variability in the V filter in 50 days and of 2.5 in 10 days. In intensity and duration the activity is similar to that of 1972 reported by Eggen (1973), but it is much better documented. No clear evidence of variability on time-scale of minutes is found. The spectral energy distribution is roughly described by a power-law, with the weaker state being the softer.
astro-ph↗
Surface nano-patterning through styrene adsorption on Si(100)
We present an ab initio study of the structural and electronic properties of styrene molecules adsorbed on the dimerized Si(100) surface at different coverages, ranging from the single-molecule to the full monolayer. The adsorption mechanism primarily involves the vinyl group via a [2+2] cycloaddition process that leads to the formation of covalent Si-C bonds and a local surface derelaxation, while it leaves the phenyl group almost unperturbed. The investigation of the functionalized surface as a function of the coverage (e.g. 0.5 -- 1 ML) and of the substrate reconstruction reveals two major effects. The first results from Si dimer-vinyl interaction and concerns the controlled variation of the energy bandgap of the interface. The second is associated to phenyl-phenyl interactions, which gives rise to a regular pattern of electronic wires at surface, stemming from the pi-pi coupling. These findings suggest a rationale for tailoring the surface nano-patterning of the surface, in a controlled way.
cond-mat.soft↗
FAVOR (FAst Variability Optical Registration) -- A Two-telescope Complex for Detection and Investigation of Short Optical Transients
An astronomical complex intended to detect optical transients (OTs) in a wide field and follow them up with high time resolution investigation is described.
astro-ph↗
Reduced electron relaxation rate in multi-electron quantum dots
We use a configuration-interaction approach and Fermi golden rule to investigate electron-phonon interaction in realistic multi-electron quantum dots. Lifetimes are computed in the low-density, highly correlated regime. We report numerical evidence that electron-electron interaction generally leads to reduced decay rates of excited electronic states in weakly confined quantum dots, where carrier relaxation is dominated by the interaction with longitudinal acoustic phonons.
cond-mat.mes-hall↗
Exciton binding energies in carbon nanotubes from two-photon photoluminescence
One- and two-photon luminescence excitation spectroscopy showed a series of distinct excitonic states in single-walled carbon nanotubes. The energy splitting between one- and two-photon-active exciton states of different wavefunction symmetry is the fingerprint of excitonic interactions in carbon nanotubes. We determine exciton binding energies of 0.3-0.4 eV for different nanotubes with diameters between 0.7 and 0.9 nm. Our results, which are supported by ab-initio calculations of the linear and non-linear optical spectra, prove that the elementary optical excitations of carbon nanotubes are strongly Coulomb-correlated, quasi-one dimensionally confined electron-hole pairs, stable even at room temperature. This alters our microscopic understanding of both the electronic structure and the Coulomb interactions in carbon nanotubes, and has direct impact on the optical and transport properties of novel nanotube devices.
cond-mat.mtrl-sci↗
First principle theory of correlated transport through nano-junctions
We report the inclusion of electron-electron correlation in the calculation of transport properties within an ab initio scheme. A key step is the reformulation of Landauer's approach in terms of an effective transmittance for the interacting electron system. We apply this framework to analyze the effect of short range interactions on Pt atomic wires and discuss the coherent and incoherent correction to the mean-field approach.
cond-mat.str-el↗
Quantum Interferences in the Raman Cross Section for the Radial Breathing Mode in Metalic Carbon Nanotubes
The lineshapes of the Raman excitation profiles for radial breathing modes in carbon nanotubes are shown to be strongly affected by interference effects that arise whenever strong optical transitions are separated by a small energy. This is the case in metallic zigzag and chiral tubes, where one-dimensional singularities in the electronic joint density of states are split due to the trigonal warping of the electronic band structure of two-dimensional graphene. It is shown that the proper modeling of these interferences is crucial for the identification of the (n,m) indices using Raman spectroscopy.
cond-mat.mtrl-sci↗
Molecular phases in coupled quantum dots
We present excitation energy spectra of few-electron vertically coupled quantum dots for strong and intermediate inter-dot coupling. By applying a magnetic field, we induce ground state transitions and identify the corresponding quantum numbers by comparison with few-body calculations. In addition to atomic-like states, we find novel "molecular-like" phases. The isospin index characterizes the nature of the bond of the artificial molecule and this we control. Like spin in a single quantum dot, transitions in isospin leading to full polarization are observed with increasing magnetic field.
cond-mat.mes-hall↗
Dust and dark Gamma-Ray Bursts: mutual implications
In a cosmological context dust has been always poorly understood. That is true also for the statistic of GRBs so that we started a program to understand its role both in relation to GRBs and in function of z. This paper presents a composite model in this direction. The model considers a rather generic distribution of dust in a spiral galaxy and considers the effect of changing some of the parameters characterizing the dust grains, size in particular. We first simulated 500 GRBs distributed as the host galaxy mass distribution, using as model the Milky Way. If we consider dust with the same properties as that we observe in the Milky Way, we find that due to absorption we miss about 10% of the afterglows assuming we observe the event within about 1 hour or even within 100s. In our second set of simulations we placed GRBs randomly inside giants molecular clouds, considering different kinds of dust inside and outside the host cloud and the effect of dust sublimation caused by the GRB inside the clouds. In this case absorption is mainly due to the host cloud and the physical properties of dust play a strong role. Computations from this model agree with the hypothesis of host galaxies with extinction curve similar to that of the Small Magellanic Cloud, whereas the host cloud could be also characterized by dust with larger grains. To confirm our findings we need a set of homogeneous infrared observations. The use of coming dedicated infrared telescopes, like REM, will provide a wealth of cases of new afterglow observations.
astro-ph↗
Integral results on GRB030320: a long gamma-ray burst detected at the edge of the field of view
GRB030320 is the 5th Gamma-ray burst (GRB) detected by INTEGRAL in the field of view (FoV). It is so far the GRB with the largest off-axis angle with respect to the INTEGRAL pointing direction, near to the edge of the FoV of both main instruments, IBIS and SPI. Nevertheless, it was possible to determine its position and to extract spectra and fluxes. The GRB nature of the event was confirmed by an IPN triangulation. It is a ~ 60 s long GRB with two prominent peaks separated by ~ 35 s. The spectral shape of the GRB is best represented by a single power law with a photon index Gamma ~ 1.7. The peak flux in the 20 - 200 keV band is determined to ~ 5.7 photons cm-2 s-1 and the GRB fluence to 1.1 x 10-5 erg cm-2. Analysing the spectral evolution of the GRB, a ``hard-to-soft'' behaviour emerges. A search for an optical counterpart has been carried out, but none was found.
astro-ph↗
The Luminosity Function of Cluster Galaxies. III
We investigated the optical properties of 7 clusters of galaxies observed in three colors over the range of absolute magnitudes -24 < M < -12. Our aim is to estimate the Luminosity Function and the total cluster luminosity of our sample in order to have information about the formation and the evolution of galaxies in clusters. In this paper, we present the main points of our analysis and give the formal parameters obtained by fitting the data using the maximum likelihood algorithm. We find consistency between our results and other works in literature confirming the bimodal nature of the luminosity function of cluster galaxies. More important, we find that the relation L_opt/ L_X versus L_X is color dependent: Low X ray Luminosity clusters have a bluer galaxy population.
astro-ph↗
Tunneling and Electric-Field Effects on Electron-Hole Localization in Artificial Molecules
We theoretically investigate the Stark shift of the exciton goundstate in two vertically coupled quantum dots as a function of the interdot distance. The coupling is shown to enhance the tuneability of the linear optical properties, including energy and oscillator strength, as well as the exciton polarizability. The coupling regime that maximizes these properties results from the detailed balance between the effects of the single-particle tunneling, of the electric field and of the carrier-carrier interaction. We discuss the relevance of these results to the possible implementation of quantum-information processing based on semiconductor quantum dots: in particular, we suggest the identification of the qubits with the exciton levels in coupled- rather than single-dots.
cond-mat.mes-hall↗
High-finesse optical quantum gates for electron spins in artificial molecules
A doped semiconductor double-quantum-dot molecule is proposed as a qubit realization. The quantum information is encoded in the electron spin, thus benefiting from the long relevant decoherence times; the enhanced flexibility of the molecular structure allows to map the spin degrees of freedom onto the orbital ones and vice versa, and opens the possibility for high-finesse (conditional and unconditional) quantum gates by means of stimulated Raman adiabatic passage.
cond-mat.mes-hall↗
Halpha rotation curves: the soft core question
We present high resolution Halpha rotation curves of 4 late-type dwarf galaxies and 2 low surface brightness galaxies (LSB) for which accurate HI rotation curves are available from the literature. Observations are carried out at Telescopio Nazionale Galileo (TNG). For LSB F583-1 an innovative dispersing element was used, the Volume Phase Holographic (VPH) with a dispersion of about 0.35 A/pxl. We find good agreement between the Halpha data and the HI observations and conclude that the HI data for these galaxies suffer very little from beam smearing. We show that the optical rotation curves of these dark matter dominated galaxies are best fitted by the Burkert profile. In the centers of galaxies, where the N-body simulations predict cuspy cores and fast rising rotation curves, our data seem to be in better agreement with the presence of soft cores.
astro-ph↗
G-quartet biomolecular nanowires
We present a first-principle investigation of quadruple helix nanowires, consisting of stacked planar hydrogen-bonded guanine tetramers. Our results show that long wires form and are stable in potassium-rich conditions. We present their electronic bandstructure and discuss the interpretation in terms of effective wide-bandgap semiconductors. The microscopic structural and electronic properties of the guanine quadruple helices make them suitable candidates for molecular nanoelectronics.
cond-mat.soft↗
A new concept and a preliminary design for a high resolution (HR) and very-high resolution (VHR) spectrograph for the LBT
A way to fully exploit the large collecting area of modern 8-10m class telescopes is high resolution spectroscopy. Many astrophysical problems from planetary science to cosmology benefit from spectroscopic observations at the highest resolution currently achievable and would benefit from even higher resolutions. Indeed in the era of 8-10m class telescopes no longer the telescope collecting area but the size of the beam - which is related to the maximum size in which reflection gratings are manufactured - is what mainly limits the resolution. A resolution-slit product Rphi ~ 40,000 is the maximum currently provided by a beam of 20 cm illuminating the largest grating mosaics. We present a conceptual design for a spectrograph with Rphi ~ 80,000, i.e. twice as large as that of existing instruments. Examples of the possible exploitation of such a high Rphi value, including spectropolarimetry and very high resolution (R ~ 300,000), are discussed in detail. The new concept is illustrated through the specific case of a high resolution spectropolarimeter for the Large Binocular Telescope.
astro-ph↗