arXiv subjects

E. Molinari

Publications and source records attributed to E. Molinari.

At least 163 records · Page 9Linked to original sources

arXiv2001

Self-assembled guanine ribbons as wide-bandgap semiconductors

We present a first principle study about the stability and the electronic properties of a new biomolecular solid-state material, obtained by the self-assembling of guanine (G) molecules. We consider hydrogen-bonded planar ribbons in isolated and stacked configurations. These aggregates present electronic properties similar to inorganic wide-bandgap semiconductors. The formation of Bloch-type orbitals is observed along the stacking direction, while it is negligible in the ribbon plane. Global band-like conduction may be affected by a dipole-field which spontaneously arises along the ribbon axis. Our results indicate that G-ribbon assemblies are promising materials for biomolecular nanodevices, consistently with recent experimental results.

cond-mat.soft↗

arXiv2001

Ab-initio study of model guanine assemblies: The role of pi-pi coupling and band transport

Several assemblies of guanine molecules are investigated by means of first-principle calculations. Such structures include stacked and hydrogen-bonded dimers, as well as vertical columns and planar ribbons, respectively, obtained by periodically replicating the dimers. Our results are in good agreement with experimental data for isolated molecules, isolated dimers, and periodic ribbons. For stacked dimers and columns, the stability is affected by the relative charge distribution of the pi orbitals in adjacent guanine molecules. pi-pi coupling in some stacked columns induces dispersive energy bands, while no dispersion is identified in the planar ribbons along the connections of hydrogen bonds. The implications for different materials comprised of guanine aggregates are discussed. The bandstructure of dispersive configurations may justify a contribution of band transport (Bloch type) in the conduction mechanism of deoxyguanosine fibres, while in DNA-like configurations band transport should be negligible.

cond-mat.soft↗

arXiv2001

Soft Cores in Late-Type Dwarf and LSB Galaxies from HαObservations

We present high spatial resolution Hαrotation curves of late-type dwarf and LSB galaxies. From our analysis we find good agreement between our Hαdata and the HI observations taken from the literature, concluding that the HI rotation curves for these galaxies suffer very little from beam smearing. A preliminary analysis of our data rules out the CDM model in the inner regions of these galaxies.

astro-ph↗

arXiv2001

The BMW Deep X-ray Cluster Survey

We briefly describe the main features of the Brera Multi-Wavelet (BMW) survey of serendipitous X-ray clusters, based on the still unexploited ROSAT-HRI archival observations. Cluster candidates are selected from the general BMW catalogue of 20,000 sources based exclusively on their X-ray extension. Contrary to common wisdom, a clever selection of the HRI energy channels allows us to significantly reduce the background noise, thus greatly improving the ability to detect low surface-brightness sources as clusters. The resulting sample of ~250 candidates shows a very good sky coverage down to a flux \~3x10^-14 erg/s/cm^2 ([0.5-2.0] keV band), i.e comparable to existing PSPC-based deep survey, with a particularly interesting area of ~100 sq.deg. around fluxes ~10^-13 erg/s/cm^2, i.e. where highly-luminous, rare systems at z~0.6-1 can be detected. At the same time, the superior angular resolution of the instrument should avoid biases against intrinsically small systems, while easing the identification process (e.g. by spotting blends and AGN contaminants). While about 20% of the candidates are already identified with groups/clusters at z<0.3 on the DSS2 images, we have started a deep CCD imaging campaign to observe all sources associated to "blank fields". First results from these observations reveal a distant (z>0.5) bonafide cluster counterpart for ~80% of the targets.

astro-ph↗

arXiv2001

Optical excitations of a self assembled artificial ion

By use of magneto-photoluminescence spectroscopy we demonstrate bias controlled single-electron charging of a single quantum dot. Neutral, single, and double charged excitons are identified in the optical spectra. At high magnetic fields one Zeeman component of the single charged exciton is found to be quenched, which is attributed to the competing effects of tunneling and spin-flip processes. Our experimental data are in good agreement with theoretical model calculations for situations where the spatial extent of the hole wave functions is smaller as compared to the electron wave functions.

cond-mat.mes-hall↗

arXiv2000

Optical follow-up of the REFLEX survey: a new perspective in cluster studies

After the completion of the catalogue built with ESO key program (REFLEX), we are beginning to explore the multiband optical characteristics of a subsample of those clusters selected in a statistically independent way. We have already observed in B, V, R, 9 of the about 50 clusters of the subsample, with 0.15 \le z \le 0.18. More time has been allocated by ESO for our project in March 2001. We will therefore be able to compare X-ray and optical morphologies and luminosities and, thanks to the large field of view of the WFI instrument, assess the luminosity function and the color segregation in the cluster on a robust statistical basis. In this poster we present the project, the technical problems we are facing in the reduction phase, and show the first preliminary results, which seem very encouraging.

astro-ph↗

arXiv2000

Local absorption spectra of artificial atoms and molecules

We investigate theoretically the spatial dependence of the linear absorption spectra of single and coupled semiconductor quantum dots, where the strong three-dimensional quantum confinement leads to an overall enhancement of Coulomb interaction and, in turn, to a pronounced renormalization of the excitonic properties. We show that -because of such Coulomb correlations and the spatial interference of the exciton wavefunctions- unexpected spectral features appear whose intensity depends on spatial resolution in a highly non-monotonic way when the spatial resolution is comparable with the excitonic Bohr radius. We finally discuss how the optical near-field properties of double quantum dots are affected by their coupling.

cond-mat.mtrl-sci↗

arXiv2000

Local optical spectroscopy of semiconductor nanostructures in the linear regime

We present a theoretical approach to calculate the {\it local} absorption spectrum of excitons confined in a semiconductor nanostructure. Using the density-matrix formalism, we derive a microscopic expression for the non-local susceptibility, both in the linear and non-linear regimes, which includes a three-dimensional description of electronic quantum states and their Coulomb interaction. The knowledge of the non-local susceptibility allows us to calculate a properly defined local absorbed power, that depends on the electro-magnetic field distribution. We report on explicit calculations of the local linear response of excitons confined in single and coupled T-shaped quantum wires with realistic geometry and composition. We show that significant interference effects in the interacting electron-hole wavefunction induce new features in the space-resolved optical spectra, particularly in coupled nanostructures. When the spatial extension of the electromagnetic field is comparable to the exciton Bohr radius, Coulomb effects on the local spectra must be taken into account for a correct assignment of the observed features.

cond-mat.mtrl-sci↗

arXiv2000

Transport in hybrid electronic devices based on a modified DNA nucleoside (deoxyguanosine)

We report on a new class of hybrid electronic devices based on a DNA nucleoside (deoxyguanosine lipophilic derivative) whose assembled polymeric ribbons interconnect a submicron metallic gate. The device exhibits large conductivity at room temperature, rectifying behaviour and strong current-voltage hysteresis. The transport mechanism through the molecules is investigated by comparing films with different self-assembling morphology. We found that the main transport mechanism is connected to pi-pi interactions between guanosine molecules in adjacent ribbons, consistently with the results of our first-principles calculations.

cond-mat.soft↗

arXiv1999

The luminosity function of cluster galaxies. II. Data reduction procedures applied to the cluster Abell 496

We initiated a large project aimed to estimate the Luminosity Function of galaxies in clusters and to evaluate its relation to cluster morphology. With this paper we deem necessary to outline the general procedures of the data reduction and details of the data analysis. The cluster sample includes the brightest southern ROSAT all-sky survey clusters with z < 0.1. These have been observed in three colours g, r, i, and mapped up to a few core radii using a mosaic of CCD frames. E/S0 galaxies in the cluster core are singled out both by morphology (for the brightest galaxies), and by colour. The details of the data reduction procedure are illustrated via the analysis of the cluster Abell 496, which has been used as a pilot cluster for the whole program. The related photometric catalogue consists of 2355 objects. The limiting magnitudes (the reference Surface Brightness is given in parenthesis) in the various colours are respectively g(25.5) = 24.14, r(25.5) = 24.46, i(25.0) = 23.75$. These correspond to the limiting absolute magnitudes -12.28, -11.96 and -12.67 (H_0=50 km/sec/Mpc).

astro-ph↗

arXiv1999

Multiple quantum phases in artificial double-dot molecules

We study coupled semiconductor quantum dots theoretically through a generalized Hubbard approach, where intra- and inter-dot Coulomb Correlation, as well as tunneling effects are described on the basis of realistic electron wavefunctions. We find that the ground-state configuration of vertically-coupled double dots undergoes non-trivial quantum transitions as a function of the inter-dot distance d; at intermediate values of d we predict a new phase that should be observable in the addition spectra and in the magnetization changes.

cond-mat.mes-hall↗

arXiv1999

Enhancement of Coulomb interactions in semiconductor nanostructures by dielectric confinement

We present a theoretical analysis of the effect of dielectric confinement on the Coulomb interaction in dielectrically modulated quantum structures. We discuss the implications of the strong enhancement of the electron-hole and electron-electron coupling for two specific examples: (i) GaAs-based quantum wires with remote oxide barriers, where combined quantum and dielectric confinements are predicted to lead to room temperature exciton binding, and (ii) semiconductor quantum dots in colloidal environments, where the many-body ground states and the addition spectra are predicted to be drastically altered by the dielectric environment.

cond-mat.mtrl-sci↗

arXiv1998

Local Optical Spectroscopy in Quantum Confined Systems: A Theoretical Description

A theoretical description of local absorption is proposed in order to investigate spectral variations on a length scale comparable with the extension of the relevant quantum states. A general formulation is derived within the density-matrix formalism including Coulomb correlation, and applied to the prototypical case of coupled quantum wires. The results show that excitonic effects may have a crucial impact on the local absorption with implications for the spatial resolution and the interpretation of near-field optical spectra.

cond-mat.mtrl-sci↗

arXiv1998

Strong exciton binding in quantum structures through remote dielectric confinement

We propose a new type of hybrid systems formed by conventional semiconductor nanostructures with the addition of remote insulating layers, where the electron-hole interaction is enhanced by combining quantum and dielectric confinement over different length scales. Due to the polarization charges induced by the dielectric mismatch at the semiconductor/insulator interfaces, we show that the exciton binding energy can be more than doubled. For conventional III-V quantum wires such remote dielectric confinement allows exciton binding at room temperature.

cond-mat.mtrl-sci↗

arXiv1997

Excitonic Effects in Quantum Wires

We review the effects of Coulomb correlation on the linear and non-linear optical properties of semiconductor quantum wires, with emphasis on recent results for the bound excitonic states. Our theoretical approach is based on generalized semiconductor Bloch equations, and allows full three-dimensional multisubband description of electron-hole correlation for arbitrary confinement profiles. In particular, we consider V- and T-shaped structures for which significant experimental advances were obtained recently. Above band gap, a very general result obtained by this approach is that electron-hole Coulomb correlation removes the inverse-square-root single-particle singularity in the optical spectra at band edge, in agreement with previous reports from purely one-dimensional models. Strong correlation effects on transitions in the continuum are found to persist also at high densities of photoexcited carriers. Below bandgap, we find that the same potential- (Coulomb) to kinetic-energy ratio holds for quite different wire cross sections and compositions. As a consequence, we identify a shape- and barrier-independent parameter that governs a universal scaling law for exciton binding energy with size. Previous indications that the shape of the wire cross-section may have important effects on exciton binding are discussed in the light of the present results.

cond-mat.mtrl-sci↗

arXiv1997

Quantum interference in nanometric devices: ballistic transport across arrays of T-shaped quantum wires

We propose that the recently realized T-shaped semiconductor quantum wires (T-wires) could be exploited as three-terminal quantum interference devices. T-wires are formed by intersecting two quantum wells (QWs). By use of a scattering matrix approach and the Landauer-Büttiker theory, we calculate the conductance for ballistic transport in the parent QWs and across the wire region as a function of the injection energy. We show that different conductance profiles can be selected by tailoring the widths of the QWs and/or combining more wires on the scale of the Fermi wavelength. Finally, we discuss the possibility of obtaining spin-dependent conductance of ballistic holes in the same structures.

cond-mat↗

arXiv1997

Shape-independent scaling of excitonic confinement in realistic quantum wires

The scaling of exciton binding energy in semiconductor quantum wires is investigated theoretically through a non-variational, fully three-dimensional approach for a wide set of realistic state-of-the-art structures. We find that in the strong confinement limit the same potential-to-kinetic energy ratio holds for quite different wire cross-sections and compositions. As a consequence, a universal (shape- and composition-independent) parameter can be identified that governs the scaling of the binding energy with size. Previous indications that the shape of the wire cross-section may have important effects on exciton binding are discussed in the light of the present results.

cond-mat↗

arXiv1996

Band structure and optical anisotropy in V-shaped and T-shaped semiconductor quantum wires

We present a theoretical investigation of the electronic and optical properties of V- and T-shaped quantum wires. Valence band mixing as well as realistic sample geometries are fully included through an accurate and efficient approach that is described here in detail. We investigate the resulting valence band structure, which shows some significant peculiarities, such as an anomalously large spin splitting in the lowest heavy hole subband of T-shaped wires. For both classes of wires we obtain good agreement between calculated optical absorption and recent experimental spectra, and we demonstrate that the analysis of optical anisotropy can be used as an effective tool to extract information on valence states, usually very difficult to obtain otherwise.

cond-mat↗