arXiv subjects

Elena Redaelli

Publications and source records attributed to Elena Redaelli.

At least 19 recordsLinked to original sources

arXiv2026

A tale of two isotopes: Spatial variation in HCN fractionation toward young cores

Context. Isotopic fractionation can serve as a powerful tracer of the chemical evolution during star and planet formation. To accurately interpret observations, it is crucial to identify the dominant pathways of nitrogen and carbon fractionation at different evolutionary stages. Aims. We aim to study nitrogen and carbon fractionation in a sample of young cores at the onset of star formation. Methods. We map H$^{13}$CN and HC$^{15}$N around one starless and three pre-stellar cores. We compute the $N$(H$^{13}$CN)/$N$(HC$^{15}$N) column density ratio across the cores and compare the distribution with $N$(H$_2$) maps from $\textit{Herschel}$/SPIRE. In addition, we calculate $^{14}$N/$^{15}$N maps using the double isotope method for comparison with earlier studies. The results are compared with astrochemical modeling of carbon and nitrogen fractionation for a one-dimensional pre-stellar core model. Results. The computed $N$(H$^{13}$CN)/$N$(HC$^{15}$N) ratio exhibit clear spatial variation across the maps. This variation is correlated with $N$(H$_2$) in three out of four cores. Conclusions. Our analysis reveals a correlation between the H$^{13}$CN/HC$^{15}$N ratios and the $N$(H$_2$) maps. According to the astrochemical model, the correlation is mainly due to variations in the $^{12}$C/$^{13}$C ratio. Consequently, the results caution against applying the double-isotope method to derive $^{14}$N/$^{15}$N ratios without independently assessing possible spatial variations in the $^{12}$C/$^{13}$C ratio. Furthermore, the leading cause of the isotopic variation in the model is not isotope-selective photodissociation, but rather more efficient fractionation through exchange reactions at lower temperatures in the denser regions of the cores.

astro-ph.SR↗

arXiv2026

Chemical Complexity in the Early Stages of Star Formation in the SKAO Era

About 350 molecules have been identified in the interstellar medium (ISM), including complex molecules relevant to prebiotic chemistry. A remarkable level of molecular diversity has been observed from the earliest stages of star formation, providing the initial chemical inventory inherited by planetary systems. Radio observations have played a pivotal role in these discoveries, starting with the identification of the first polyatomic molecule, $\text{NH}_3$ (Cheung et al. 1968). (Sub-)millimeter observations have revealed complex organic molecules of prebiotic relevance, including formamide ($\text{NH}_2\text{CHO}$), glycolaldehyde ($\text{CH}_2\text{OHCHO}$), and even urea ($(\text{NH}_2)_2\text{CO}$), and hydroxylamine ($\text{NH}_2\text{OH}$), which are possible precursors of RNA nucleotides (Ceccarelli et al. 2023; Jim\'enez-Serra et al. 2020). However, in dense protostellar regions, dust opacity hampers the detection of molecular emission. Additionally, large molecules and those containing heavy atoms, which have rotational transitions at lower frequencies, often remain inaccessible to current instruments. The Square Kilometre Array Observatory (SKAO) will provide an unprecedented combination of sensitivity and angular resolution at radio wavelengths. This will allow for the detection of prebiotic species and offer new insights into the chemical pathways that shape emerging planetary systems (Jim\'enez-Serra et al. 2022). This chapter details the scientific questions and advancements that the SKAO, and more specifically, SKA-Mid equipped with the Band 5 receivers, will pursue in the field of astrochemistry, focusing on the chemical complexity in both high-mass and solar-type star-forming regions.

astro-ph.SR↗

arXiv2026

Probing the ion-neutral drift velocity towards the L1544 prestellar core: Detection of ambipolar diffusion using N$_2$D$^+$ and para-NH$_2$D

The dynamical role of the magnetic field in the star formation process is tightly linked to the coupling between matter and the field. This coupling is due to the interaction between ions and neutrals in the partially ionized interstellar medium. When the ionization degree drops in the dense environment of prestellar cores, the magnetic field and the matter may decouple, leading to differences in the infalling velocities of ions and neutrals known as ambipolar diffusion. The onset of gravitational collapse resulting from ion-neutral decoupling has never been observed. The aim of this work is to search for signatures of ambipolar diffusion within a prestellar core. We observed the deuterated N$_2$D$^+$ ion and the neutral para-NH$_2$D species towards the prototypical prestellar core L1544. These two species are ideal tracers of prestellar cores sampling the same high densities in the core interior. We compared the velocity centroid and linewidth maps of the ion-neutral pair. We find a mean ion-neutral velocity difference of $\sim$0.05 km/s towards the core. By comparing with predictions from self-consistent calculations of the ambipolar resistivity including dust grain growth, we interpret the observed ion-neutral velocity difference in L1544 as a signature of ambipolar diffusion. We do not detect a significant ion-neutral linewidth difference that may be attributed to the subsonic infall motions of the gas in L1544 and geometrical effects in the presence of inclination. These results emphasize the role of dust grain growth at the prestellar core stage in setting the ambipolar resistivity and regulating the dynamical evolution of dense cores towards their collapse into protostars. We propose that measurements of ion-neutral drift velocities provide new constraints on the total magnetic field strength and the dust size distribution within prestellar cores.

astro-ph.GA↗

arXiv2025

Mass Assembly and Chemical Complexity in the Milky Way

(Sub-)millimeter spectral lines can be used not only to understand the chemical complexity and enrichment history of an observed portion of our Galaxy, but with spectrally resolved lines, they reveal the physical conditions, dynamics, and even the ionisation state and magnetic field strengths of the gas component of our Galaxy. They are prime tracers of mass assembly and structure formation across scales.

astro-ph.GA↗

arXiv2025

The Emergence of Prebiotic Chemistry in the ISM

Contrary to popular belief, the interstellar medium (ISM) is not empty; it is filled with atoms, dust particles, and molecules. Some of these molecules may have been the very building blocks of life that, delivered to Earth via comets and meteorites, could have given rise to Life itself. A large-area single-dish telescope with superb sensitivity, field-of-view and multi-band instruments will allow us to explore the limits of chemical complexity in the interstellar medium, across our Galaxy and in external galaxies, determining whether amino acids, sugars, or RNA/DNA nucleobases can form in space.

astro-ph.IM↗

arXiv2025

The Green Bank Ammonia Survey: Data Release 2

We present an overview of the final data release (DR2) from the Green Bank Ammonia Survey (GAS). GAS is a Large Program at the Green Bank Telescope to map all Gould Belt star-forming regions with $A_\mathrm{V} \gtrsim 7$~mag visible from the northern hemisphere in emission from NH$_3$ and other key molecular tracers. This final release includes the data for all the regions observed: Heiles Cloud 2 and B18 in Taurus; Barnard 1, Barnard 1-E, IC348, NGC 1333, L1448, L1451, and Per7/34 in Perseus; L1688 and L1689 in Ophiuchus; Orion A (North and South) and Orion B in Orion; Cepheus, B59 in Pipe; Corona Australis (CrA) East and West; IC5146; and Serpens Aquila and MWC297 in Serpens. Similar to what was presented in GAS DR1, we find that the NH$_3$ emission and dust continuum emission from Herschel correspond closely. We find that the NH$_3$ emission is generally extended beyond the typical 0.1 pc length scales of dense cores, and we find that the transition between coherent core and turbulent cloud is a common result. This shows that the regions of coherence are common throughout different star forming regions, with a substantial fraction of the high column density regions displaying subsonic non-thermal velocity dispersions. We produce maps of the gas kinematics, temperature, and NH$_3$ column densities through forward modeling of the hyperfine structure of the NH$_3$ (1,1) and (2,2) lines. We show that the NH$_3$ velocity dispersion, $\sigma_v$, and gas kinetic temperature, $T_{\rm kin}$, vary systematically between the regions included in this release, with an increase in both the mean value and spread of $\sigma_v$ and $T_{\rm kin}$ with increasing star formation activity. The data presented in this paper are publicly available via \dataset[DOI: 10.11570/24.0091]{https://doi.org/10.11570/24.0091}.

astro-ph.GA↗

arXiv2025

The Snake Filament: A study of polarization and kinematics

The role of magnetic fields in the formation of dense filamentary structures in molecular clouds is critical for understanding the star formation process. The Snake filament in or close to the Pipe Nebula s neighboring, a prominent example of such structures, offers an ideal environment to study the interplay between magnetic fields and gas dynamics in the early stages of star formation. This study aims to investigate how magnetic fields influence the structure and dynamics of the Snake filament, using both polarization data and molecular line observations. Our goal is to understand the role of magnetic fields in shaping the filamentary structure and explore the kinematics within the filament. We conducted polarization observations in the optical and near-infrared bands using the 1.6 m and 60 cm telescopes at the Observatorio do Pico dos Dias/Laboratorio Nacional de Astrof\isica (OPD/LNA). Molecular line observations of the C18O and 13CO lines were obtained using the IRAM 30m telescope. We analyzed the data to characterize polarization and gas properties within the filament, with a focus on understanding the magnetic field orientation and its relationship with the filament s structure. Our findings reveal that the polarization vectors align with the filament s spine, indicating a magnetic field structure that is predominantly parallel to the filament at lower-density regions. A velocity gradient along the filament is observed in both C18O and 13CO lines, with C18O tracing the denser regions of the gas. The polarization efficiency decreases with increasing visual extinction, consistent with reduced grain alignment in higher-density regions. The filament s mass-to-length ratio is below the critical value required for gravitational collapse, indicating stability.

astro-ph.GA↗

arXiv2025

Statistical nuclear spin ratios of deuterated ammonia in the pre-stellar core L1544

We determined the ortho/para (o/p) ratios of NH2D and NHD2 in the archetypical pre-stellar core L1544. The core was observed in the two lowest rotational lines of ortho- and para-NH2D using the APEX and the IRAM 30 m telescopes. The ground-state lines of ortho- and para-NHD2 were observed with APEX. The distributions of chemical abundances in the core were predicted using a gas-grain chemistry model with two different scenarios concerning proton transfer reactions in the gas. One of the scenarios, the so-called full scrambling (FS), allows protons and deuterons to be completely mixed in the intermediate reaction complex before dissociation, whereas the other describes these reactions as proton or deuteron hops (PH). We also tested assumed abundance profiles independent of the chemistry models. Radiative transfer calculations were used to simulate the observed NH2D and NHD2 lines from the predicted and assumed abundance profiles. Our modelling efforts suggest that the ground-state lines of NH2D and NHD2 at the wavelength 0.9 mm that are observable with the same beam and in the same spectrometer band are the most reliable probes of the o/p ratios. Simulations using the PH reaction scheme show systematically better agreement with the observations than simulations with the FS model. Simulations using a broken power law abundance profile as a function of the gas density give spin ratios that are close to the predictions of the PH scenario: o/p-NH2D=2.85+-0.05, o/p-NHD2=2.10+-0.06 (1 sigma). The o/p ratios predicted by the PH scenario in the gas phase correspond to the nuclear spin statistical weights, that is, o/p-NH2D=3, o/p-NHD2=2. In view of the fact that H and D atom addition reactions on grain surfaces also result in these ratios, it is reasonable to assume that the spin ratios of interstellar ammonia and its deuterated forms are in general equal to their statistical values.

astro-ph.GA↗

arXiv2024

AtLAST Science Overview Report

Submillimeter and millimeter wavelengths provide a unique view of the Universe, from the gas and dust that fills and surrounds galaxies to the chromosphere of our own Sun. Current single-dish facilities have presented a tantalising view of the brightest (sub-)mm sources, and interferometers have provided the exquisite resolution necessary to analyse the details in small fields, but there are still many open questions that cannot be answered with current facilities. In this report we summarise the science that is guiding the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST). We demonstrate how tranformational advances in topics including star formation in high redshift galaxies, the diffuse circumgalactic medium, Galactic ecology, cometary compositions and solar flares motivate the need for a 50m, single-dish telescope with a 1-2 degree field of view and a new generation of highly multiplexed continuum and spectral cameras. AtLAST will have the resolution to drastically lower the confusion limit compared to current single-dish facilities, whilst also being able to rapidly map large areas of the sky and detect extended, diffuse structures. Its high sensitivity and large field of view will open up the field of submillimeter transient science by increasing the probability of serendipitous detections. Finally, the science cases listed here motivate the need for a highly flexible operations model capable of short observations of individual targets, large surveys, monitoring programmes, target of opportunity observations and coordinated observations with other observatories. AtLAST aims to be a sustainable, upgradeable, multipurpose facility that will deliver orders of magnitude increases in sensitivity and mapping speeds over current and planned submillimeter observatories.

astro-ph.IM↗

arXiv2024

Unveiling the role of magnetic fields in an accreting filament onto a young protocluster

In order to develop a more comprehensive picture of star formation, it is essential to understand the physical relationship between dense cores and the filaments embedding them. There is evidence that magnetic fields play a crucial role in this context. We aim to understand how magnetic fields influence the properties and kinematics of an isolated filament located east of the Barnard 59 clump, belonging to the Pipe Nebula. We use near infrared polarization observations to determine the magnetic field configuration, and we apply the Davis Chandrasekhar Fermi method to infer the magnetic field strength in the plane of the sky. Furthermore, we use complementary data from the James Clerk Maxwell Submillimetre Telescope (JCMT) of C18O and 13CO J=3-2 transition to determine the filament's kinematics. Finally, we model the radial density profile of the filament with polytropic cylindrical models. Our results indicate that the filament is stable to radial collapse and is radially supported by agents other than thermal pressure. In addition, based on previous observations of emission lines on this source, we suggest that gas is flowing toward the hub, while C18O (3-2) non-thermal motions indicate that the cloud is in a quiescent state.

astro-ph.GA↗

arXiv2024

A low cosmic-ray ionisation rate in the prestellar core Ophiuchus/H-MM1. Mapping of the molecular ions ortho-H2D+, N2H+, and DCO+

(abridged) We have mapped the prestellar core H-MM1 in Ophiuchus in rotational lines of ortho-H2D+ (oH2D+), N2H+, and DCO+ at the wavelength 0.8 mm with the Large APEX sub-Millimeter Array (LAsMA) multibeam receiver of the Atacama Pathfinder EXperiment (APEX) telescope. We also ran a series of chemistry models to predict the abundance distributions of the observed molecules, and to estimate the effect of the cosmic-ray ionisation rate on their abundances. The three line maps show different distributions. The oH2D+ map is extended and outlines the general structure of the core, while N2H+ mainly shows the density maxima, and the DCO+ emission peaks are shifted towards one edge of the core where a region of enhanced desorption has been found previously. According to the chemical simulation, the fractional oH2D+ abundance remains relatively high in the centre of the core, and its column density correlates strongly with the cosmic-ray ionisation rate. Simulated line maps constrain the cosmic-ray ionisation rate per hydrogen molecule to be low, between 5e-18/s and 1e-17/s in the H-MM1 core. This estimate agrees with the gas temperature measured in the core. Modelling line emission of oH2D+ provides a straightforward method of determining the cosmic-ray ionisation rate in dense clouds, where the primary ion, H3+, is not observable.

astro-ph.GA↗

arXiv2024

Atacama Large Aperture Submillimeter Telescope (AtLAST) Science: Our Galaxy

As we learn more about the multi-scale interstellar medium (ISM) of our Galaxy, we develop a greater understanding for the complex relationships between the large-scale diffuse gas and dust in Giant Molecular Clouds (GMCs), how it moves, how it is affected by the nearby massive stars, and which portions of those GMCs eventually collapse into star forming regions. The complex interactions of those gas, dust and stellar populations form what has come to be known as the ecology of our Galaxy. Because we are deeply embedded in the plane of our Galaxy, it takes up a significant fraction of the sky, with complex dust lanes scattered throughout the optically recognisable bands of the Milky Way. These bands become bright at (sub-)millimetre wavelengths, where we can study dust thermal emission and the chemical and kinematic signatures of the gas. To properly study such large-scale environments, requires deep, large area surveys that are not possible with current facilities. Moreover, where stars form, so too do planetary systems, growing from the dust and gas in circumstellar discs, to planets and planetesimal belts. Understanding the evolution of these belts requires deep imaging capable of studying belts around young stellar objects to Kuiper belt analogues around the nearest stars. Here we present a plan for observing the Galactic Plane and circumstellar environments to quantify the physical structure, the magnetic fields, the dynamics, chemistry, star formation, and planetary system evolution of the galaxy in which we live with AtLAST; a concept for a new, 50m single-dish sub-mm telescope with a large field of view which is the only type of facility that will allow us to observe our Galaxy deeply and widely enough to make a leap forward in our understanding of our local ecology.

astro-ph.GA↗

arXiv2023

Nuclear spin ratios of deuterated ammonia in prestellar cores. LAsMA observations of H-MM1 and Oph D

We determine the ortho/para ratios of NH2D and NHD2 in two dense, starless cores, where their formation is supposed to be dominated by gas-phase reactions, which, in turn, is predicted to result in deviations from the statistical spin ratios. The Large APEX sub-Millimeter Array (LAsMA) multibeam receiver of the Atacama Pathfinder EXperiment (APEX) telescope was used to observe the prestellar cores H-MM1 and Oph D in Ophiuchus in the ground-state lines of ortho and para NH2D and NHD2. The fractional abundances of these molecules were derived employing 3D radiative transfer modelling, using different assumptions about the abundance profiles as functions of density. We also ran gas-grain chemistry models with different scenarios concerning proton or deuteron exchanges and chemical desorption from grains to find out if one of these models can reproduce the observed spin ratios. The observationally deduced ortho/para ratios of NH2D and NHD2 are in both cores within 10% of their statistical values 3 and 2, respectively, and taking 3-sigma limits, deviations from these of about 20% are allowed. Of the chemistry models tested here, the model that assumes proton hop (as opposed to full scrambling) in reactions contributing to ammonia formation, and a constant efficiency of chemical desorption, comes nearest to the observed abundances and spin ratios. The nuclear spin ratios derived here are in contrast with spin-state chemistry models that assume full scrambling in proton donation and hydrogen abstraction reactions leading to deuterated ammonia. The efficiency of chemical desorption influences strongly the predicted abundances of NH3, NH2D, and NHD2, but has a lesser effect on their ortho/para ratios. For these the proton exchange scenario in the gas is decisive. We suggest that this is because of rapid re-processing of ammonia and related cations by gas-phase ion-molecule reactions.

astro-ph.GA↗

arXiv2023

Nitrogen fractionation in ammonia and its insights on nitrogen chemistry

Context. Observations of $\rm ^{14}N/^{15}N$ in the interstellar medium are becoming more frequent thanks to the increased telescope capabilities. However, interpreting these data is still puzzling. In particular, measurements of $\rm ^{14}N/^{15}N$ in diazenylium revealed high levels of anti-fractionation in cold cores. Aims. Furuya & Aikawa (2018), using astrophysical simulations coupled with a gas-grain chemical code, concluded that the $^{15}$N-depletion in prestellar cores could be inherited from the initial stages, when $\rm ^{14}N^{15}N$ is selectively photodissociated and 15N atoms deplete onto the dust grain, forming ammonia ices. We aim to test this hypothesis. Methods. We targeted three sources (the prestellar core L1544, the protostellar envelope IRAS4A, and the shocked region L1157-B1) with distinct degrees of desorption or sputtering of the ammonia ices. We observed the NH3 isotopologues with the GBT, and we inferred the $\rm ^{14}N/^{15}N$ via a spectral fitting of the observed inversion transitions. Results. $^{15}$NH3(1,1) is detected in L1544 and IRAS4A, whilst only upper limits are deduced in L1157-B1. The NH3 isotopic ratio is significantly lower towards the protostar than at the centre of L1544, where it is consistent with the elemental value. We also present the first spatially resolved map of NH3 nitrogen isotopic ratio towards L1544. Conclusions. Our results are in agreement with the hypothesis that ammonia ices are enriched in $^{15}$N, leading to a decrease of the $\rm ^{14}N/^{15}N$ ratio when the ices are sublimated into the gas phase for instance due to the temperature rise in protostellar envelopes. The ammonia $\rm ^{14}N/^{15}N$ value at the centre of L1544 is a factor of 2 lower than that of N2H+, suggesting that the dominant formation pathway is hydrogenation of N atoms on dust grains, followed by non-thermal desorption.

astro-ph.GA↗

arXiv2023

First ALMA maps of cosmic ray ionisation rate in high-mass star-forming regions

Low-energy cosmic rays ($<1$ TeV) are a pivotal source of ionisation of the interstellar medium, where they play a central role in determining the gas chemical composition and drastically influence the formation of stars and planets. Over the last few decades, H$_3^+$ absorption lines observations in diffuse clouds have provided reliable estimates of the cosmic ray ionisation rate relative to H$_2$ ($\zeta^{\rm ion}_{{\rm H}_2}$). However, in denser clouds, where stars and planets form, this method is often inefficient due to the lack of H$_3^+$ rotational transitions. The $\zeta^{\rm ion}_{{\rm H}_2}$ estimates are, therefore, still provisional in this context and represent one of the least understood components when it comes to defining general models of star and planet formation. In this Letter, we present the first high-resolution maps of the $\zeta^{\rm ion}_{{\rm H}_2}$ in two high-mass clumps obtained with a new analytical approach recently proposed to estimate the $\zeta^{\rm ion}_{{\rm H}_2}$ in the densest regions of molecular clouds. We obtain $\langle\zeta^{\rm ion}_{{\rm H}_2}\rangle$ that span from $3\times10^{-17}$ to $10^{-16}\rm~s^{-1}$, depending on the different distribution of the main ion carriers, in excellent agreement with the most recent cosmic rays propagation models. The cores belonging to the same parental clump show comparable $\zeta^{\rm ion}_{{\rm H}_2}$, suggesting that the ionisation properties of prestellar regions are determined by global rather than local effects. These results provide important information for the chemical and physical modelling of star-forming regions.

astro-ph.GA↗

arXiv2023

The kinematics of the magnetised protostellar core IRAS15398-3359

Observations of protostellar envelopes are essential to understand better the process of gravitational collapse toward star and planet formation. From a theoretical perspective, magnetic fields are considered an important factor during the early stages of star formation, especially during the main accretion phase. We aim to study the relation between kinematics and magnetic fields at a very early stage of the star formation process by using data from the Atacama Pathfinder EXperiment (APEX) single dish antenna with the angular resolution of 28". We observed the two molecular lines C18O(2-1) and DCO+(3-2), toward the Class 0 young stellar object IRAS15398-3359. We implement a multi-component Gaussian fitting on the molecular data to study the kinematics. Also, we use previous polarization observations on this source to predict the influence of the magnetic field on the core. The velocity gradient along the central object can be explained as an ongoing outflow motion. We report flowing of material from the filament toward the central object, and of the merging of two velocity components in the C18O (2-1) emission around the protostar position, probably due to the merging of filamentary clouds. Our analysis shows that the large-scale magnetic field line observed previously is preferentially aligned to the rotation axis of the core.

astro-ph.GA↗

arXiv2022

The ALMA Survey of 70 μm Dark High-mass Clumps in Early Stages (ASHES). VI. The core-scale CO-depletion

Studying the physical and chemical properties of cold and dense molecular clouds is crucial for the understanding of how stars form. Under the typical conditions of infrared dark clouds, CO is removed from the gas phase and trapped on to the surface of dust grains by the so-called depletion process. This suggests that the CO depletion factor ($f_{\rm D}$) can be a useful chemical indicator for identifying cold and dense regions (i.e., prestellar cores). We have used the 1.3 mm continuum and C$^{18}$O(2-1) data observed at the resolution of $\sim$5000 au in the ALMA Survey of 70 $μ$m Dark High-mass Clumps in Early Stages (ASHES) to construct averaged maps of $f_{\rm D}$ in twelve clumps to characterise the earliest stages of the high-mass star formation process. The average $f_{\rm D}$ determined for 277 of the 294 ASHES cores follows an unexpected increase from the prestellar to the protostellar stage. If we exclude the temperature effect due to the slight variations in the NH$_3$ kinetic temperature among different cores, we explain this result as a dependence primarily on the average gas density, which increases in cores where protostellar conditions prevail. This shows that $f_{\rm D}$ determined in high-mass star-forming regions at the core scale is insufficient to distinguish among prestellar and protostellar conditions for the individual cores, and should be complemented by information provided by additional tracers. However, we confirm that the clump-averaged $f_{\rm D}$ values correlates with the luminosity-to-mass ratio of each source, which is known to trace the evolution of the star formation process.

astro-ph.GA↗

arXiv2022

The Central 1000 au of a Pre-stellar Core Revealed with ALMA. II. Almost Complete Freeze-out

Pre-stellar cores represent the initial conditions in the process of star and planet formation. Their low temperatures ($<$10 K) allow the formation of thick icy dust mantles, which will be partially preserved in the future protoplanetary disks, ultimately affecting the chemical composition of planetary systems. Previous observations have shown that carbon- and oxygen-bearing species, in particular CO, are heavily depleted in pre-stellar cores due to the efficient molecular freeze-out onto the surface of cold dust grains. However, N-bearing species such as NH$_3$ and, in particular, its deuterated isotopologues, appear to maintain high abundances where CO molecules are mainly in solid phase. Thanks to ALMA, we present here the first clear observational evidence of NH$_2$D freeze-out toward the L1544 pre-stellar core, suggestive of the presence of a"complete-depletion zone" within a $\simeq$1800 au radius, in agreement with astrochemical pre-stellar core model predictions. Our state-of-the-art chemical model coupled with a non-LTE radiative transfer code demonstrates that NH$_2$D becomes mainly incorporated in icy mantles in the central 2000 au and starts freezing-out already at $\simeq$7000 au. Radiative transfer effects within the pre-stellar core cause the NH$_2$D(1$_{11}$-1$_{01}$) emission to appear centrally concentrated, with a flattened distribution within the central $\simeq$3000 au, unlike the 1.3 mm dust continuum emission which shows a clear peak within the central $\simeq$1800 au. This prevented NH$_2$D freeze-out to be detected in previous observations, where the central 1000 au cannot be spatially resolved.

astro-ph.SR↗