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arXiv · 2607.26187

A tale of two isotopes: Spatial variation in HCN fractionation toward young cores

Sigurd S. Jensen·Silvia Spezzano·Olli Sipilä·Paola Caselli·Laura Colzi·Elena Redaelli
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Abstract

Context. Isotopic fractionation can serve as a powerful tracer of the chemical evolution during star and planet formation. To accurately interpret observations, it is crucial to identify the dominant pathways of nitrogen and carbon fractionation at different evolutionary stages. Aims. We aim to study nitrogen and carbon fractionation in a sample of young cores at the onset of star formation. Methods. We map H$^{13}$CN and HC$^{15}$N around one starless and three pre-stellar cores. We compute the $N$(H$^{13}$CN)/$N$(HC$^{15}$N) column density ratio across the cores and compare the distribution with $N$(H$_2$) maps from $\textit{Herschel}$/SPIRE. In addition, we calculate $^{14}$N/$^{15}$N maps using the double isotope method for comparison with earlier studies. The results are compared with astrochemical modeling of carbon and nitrogen fractionation for a one-dimensional pre-stellar core model. Results. The computed $N$(H$^{13}$CN)/$N$(HC$^{15}$N) ratio exhibit clear spatial variation across the maps. This variation is correlated with $N$(H$_2$) in three out of four cores. Conclusions. Our analysis reveals a correlation between the H$^{13}$CN/HC$^{15}$N ratios and the $N$(H$_2$) maps. According to the astrochemical model, the correlation is mainly due to variations in the $^{12}$C/$^{13}$C ratio. Consequently, the results caution against applying the double-isotope method to derive $^{14}$N/$^{15}$N ratios without independently assessing possible spatial variations in the $^{12}$C/$^{13}$C ratio. Furthermore, the leading cause of the isotopic variation in the model is not isotope-selective photodissociation, but rather more efficient fractionation through exchange reactions at lower temperatures in the denser regions of the cores.

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Sigurd S. Jensen, Silvia Spezzano, Olli Sipilä, Paola Caselli, Laura Colzi, Elena Redaelli. 2026-07-28. A tale of two isotopes: Spatial variation in HCN fractionation toward young cores. https://arxiv.org/abs/2607.26187

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