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Eliza M. -R. Kempton

Publications and source records attributed to Eliza M. -R. Kempton.

At least 55 records · Page 3Linked to original sources
arXiv2024

A new lever on exoplanetary B fields: measuring heavy ion velocities

Magnetic fields connect an array of planetary processes, from atmospheric escape to interior convection. Despite their importance, exoplanet magnetic fields are largely unconstrained by both theory and observation. In this Letter, we propose a novel method for constraining the B field strength of hot gas giants: comparing the velocities of heavy ions and neutral gas with high-resolution spectroscopy. The core concept of this method is that ions are directly deflected by magnetic fields. While neutrals are also affected by B fields via friction with field-accelerated ions, ionic gas should be more strongly coupled to the underlying magnetic field than bulk neutral flow. Hence, measuring the difference between the two velocities yields rough constraints on the B field, provided an estimate of the stellar UV flux is known. We demonstrate that heavy ions are particularly well suited for this technique, because they are less likely to be entrained in complex hydrodynamic outflows than their lighter counterparts. We perform a proof-of-concept calculation with Ba II, an ion whose velocity has been repeatedly measured at high confidence with high-resolution spectroscopy. Our work shows that a 10G magnetic field would produce ~ km/s ion--neutral velocity differences at a microbar, whereas a 50G magnetic field would produce ~20km/s velocity difference. With new leverage on magnetic fields, we will be able to investigate magnetic field generation in the extreme edge cases of hot gas giants, with wide-ranging consequences for planetary interior structure, dynamo theory, and habitability.

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arXiv2024

The metallicity and carbon-to-oxygen ratio of the ultra-hot Jupiter WASP-76b from Gemini-S/IGRINS

Measurements of the carbon-to-oxygen (C/O) ratios of exoplanet atmospheres can reveal details about their formation and evolution. Recently, high-resolution cross-correlation analysis has emerged as a method of precisely constraining the C/O ratios of hot Jupiter atmospheres. We present two transits of the ultra-hot Jupiter WASP-76b observed between 1.4-2.4 $μ$m with Gemini-S/IGRINS. We detected the presence of H$_{2}$O, CO, and OH at signal-to-noise ratios of 6.93, 6.47, and 3.90, respectively. We performed two retrievals on this data set. A free retrieval for abundances of these three species retrieved a volatile metallicity of $\left[\frac{\mathrm{C}+\mathrm{O}} {\mathrm{H}}\right]=-0.70^{+1.27}_{-0.93}$, consistent with the stellar value, and a super-solar carbon-to-oxygen ratio of C/O$=0.80^{+0.07}_{-0.11}$. We also ran a chemically self-consistent grid retrieval, which agreed with the free retrieval within $1σ$ but favored a slightly more sub-stellar metallicity and solar C/O ratio ($\left[\frac{\mathrm{C}+\mathrm{O}} {\mathrm{H}}\right]=-0.74^{+0.23}_{-0.17}$ and C/O$=0.59^{+0.13}_{-0.14}$). A variety of formation pathways may explain the composition of WASP-76b. Additionally, we found systemic ($V_{sys}$) and Keplerian ($K_{p}$) velocity offsets which were broadly consistent with expectations from 3D general circulation models of WASP-76b, with the exception of a redshifted $V_{sys}$ for H$_{2}$O. Future observations to measure the phase-dependent velocity offsets and limb differences at high resolution on WASP-76b will be necessary to understand the H$_{2}$O velocity shift. Finally, we find that the population of exoplanets with precisely constrained C/O ratios generally trends toward super-solar C/O ratios. More results from high-resolution observations or JWST will serve to further elucidate any population-level trends.

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arXiv2024

Transiting Exoplanet Atmospheres in the Era of JWST

The field of exoplanet atmospheric characterization has recently made considerable advances with the advent of high-resolution spectroscopy from large ground-based telescopes and the commissioning of the James Webb Space Telescope (JWST). We have entered an era in which atmospheric compositions, aerosol properties, thermal structures, mass loss, and three-dimensional effects can be reliably constrained. While the challenges of remote sensing techniques imply that individual exoplanet atmospheres will likely never be characterized to the degree of detail that is possible for solar system bodies, exoplanets present an exciting opportunity to characterize a diverse array of worlds with properties that are not represented in our solar system. This review article summarizes the current state of exoplanet atmospheric studies for transiting planets. We focus on how observational results inform our understanding of exoplanet properties and ultimately address broad questions about planetary formation, evolution, and diversity. This review is meant to provide an overview of the exoplanet atmospheres field for planetary- and geo-scientists without astronomy backgrounds, and exoplanet specialists, alike. We give special attention to the first year of JWST data and recent results in high-resolution spectroscopy that have not been summarized by previous review articles.

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arXiv2024

Methods for Incorporating Model Uncertainty into Exoplanet Atmospheric Analysis

A key goal of exoplanet spectroscopy is to measure atmospheric properties, such as abundances of chemical species, in order to connect them to our understanding of atmospheric physics and planet formation. In this new era of high-quality JWST data, it is paramount that these measurement methods are robust. When comparing atmospheric models to observations, multiple candidate models may produce reasonable fits to the data. Typically, conclusions are reached by selecting the best-performing model according to some metric. This ignores model uncertainty in favour of specific model assumptions, potentially leading to measured atmospheric properties that are overconfident and/or incorrect. In this paper, we compare three ensemble methods for addressing model uncertainty by combining posterior distributions from multiple analyses: Bayesian model averaging, a variant of Bayesian model averaging using leave-one-out predictive densities, and stacking of predictive distributions. We demonstrate these methods by fitting the HST+Spitzer transmission spectrum of the hot Jupiter HD 209458b using models with different cloud and haze prescriptions. All of our ensemble methods lead to uncertainties on retrieved parameters that are larger, but more realistic, and consistent with physical and chemical expectations. Since they have not typically accounted for model uncertainty, uncertainties of retrieved parameters from HST spectra have likely been underreported. We recommend stacking as the most robust model combination method. Our methods can be used to combine results from independent retrieval codes, and from different models within one code. They are also widely applicable to other exoplanet analysis processes, such as combining results from different data reductions.

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arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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arXiv2023

Optical Properties of Organic Haze Analogues in Water-rich Exoplanet Atmospheres Observable with JWST

JWST has begun its scientific mission, which includes the atmospheric characterization of transiting exoplanets. Some of the first exoplanets to be observed by JWST have equilibrium temperatures below 1000 K, which is a regime where photochemical hazes are expected to form. The optical properties of these hazes, which controls how they interact with light, are critical for interpreting exoplanet observations, but relevant experimental data are not available. Here we measure the density and optical properties of organic haze analogues generated in water-rich exoplanet atmosphere experiments. We report optical constants (0.4 to 28.6 μm) of organic haze analogues for current and future observational and modeling efforts covering the entire wavelength range of JWST instrumentation and a large part of Hubble. We use these optical constants to generate hazy model atmospheric spectra. The synthetic spectra show that differences in haze optical constants have a detectable effect on the spectra, impacting our interpretation of exoplanet observations. This study emphasizes the need to investigate the optical properties of hazes formed in different exoplanet atmospheres, and establishes a practical procedure to determine such properties.

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arXiv2023

Identification of the Top TESS Objects of Interest for Atmospheric Characterization of Transiting Exoplanets with JWST

JWST has ushered in an era of unprecedented ability to characterize exoplanetary atmospheres. While there are over 5,000 confirmed planets, more than 4,000 TESS planet candidates are still unconfirmed and many of the best planets for atmospheric characterization may remain to be identified. We present a sample of TESS planets and planet candidates that we identify as "best-in-class" for transmission and emission spectroscopy with JWST. These targets are sorted into bins across equilibrium temperature $T_{\mathrm{eq}}$ and planetary radius $R{_\mathrm{p}}$ and are ranked by transmission and emission spectroscopy metric (TSM and ESM, respectively) within each bin. In forming our target sample, we perform cuts for expected signal size and stellar brightness, to remove sub-optimal targets for JWST. Of the 194 targets in the resulting sample, 103 are unconfirmed TESS planet candidates, also known as TESS Objects of Interest (TOIs). We perform vetting and statistical validation analyses on these 103 targets to determine which are likely planets and which are likely false positives, incorporating ground-based follow-up from the TESS Follow-up Observation Program (TFOP) to aid the vetting and validation process. We statistically validate 23 TOIs, marginally validate 33 TOIs to varying levels of confidence, deem 29 TOIs likely false positives, and leave the dispositions for 4 TOIs as inconclusive. 14 of the 103 TOIs were confirmed independently over the course of our analysis. We provide our final best-in-class sample as a community resource for future JWST proposals and observations. We intend for this work to motivate formal confirmation and mass measurements of each validated planet and encourage more detailed analysis of individual targets by the community.

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arXiv2023

Where are the Water Worlds?: Self-Consistent Models of Water-Rich Exoplanet Atmospheres

It remains to be ascertained whether sub-Neptune exoplanets primarily possess hydrogen-rich atmospheres or whether a population of H$_2$O-rich "water worlds" lurks in their midst. Addressing this question requires improved modeling of water-rich exoplanetary atmospheres, both to predict and interpret spectroscopic observations and to serve as upper boundary conditions on interior structure calculations. Here we present new models of hydrogen-helium-water atmospheres with water abundances ranging from solar to 100% water vapor. We improve upon previous models of high water content atmospheres by incorporating updated prescriptions for water self-broadening and a non-ideal gas equation of state. Our model grid (https://umd.box.com/v/water-worlds) includes temperature-pressure profiles in radiative-convective equilibrium, along with their associated transmission and thermal emission spectra. We find that our model updates primarily act at high pressures, significantly impacting bottom-of-atmosphere temperatures, with implications for the accuracy of interior structure calculations. Upper atmosphere conditions and spectroscopic observables are less impacted by our model updates, and we find that under most conditions, retrieval codes built for hot Jupiters should also perform well on water-rich planets. We additionally quantify the observational degeneracies among both thermal emission and transmission spectra. We recover standard degeneracies with clouds and mean molecular weight for transmission spectra, and we find thermal emission spectra to be more readily distinguishable from one another in the water-poor (i.e. near-solar) regime.

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arXiv2023

Constraining the Thickness of the Atmosphere of TRAPPIST-1 b from its JWST Secondary Eclipse Observation

Recently, the first JWST measurement of thermal emission from a rocky exoplanet was reported. The inferred dayside brightness temperature of TRAPPIST-1 b at 15 $μ$m is consistent with the planet having no atmosphere and therefore no mechanism by which to circulate heat to its nightside. In this Letter, we compare the measured secondary eclipse depth of TRAPPIST-1 b to predictions from a suite of self-consistent radiative-convective equilibrium models in order to quantify the maximum atmospheric thickness consistent with the observation. We find that plausible atmospheres (i.e., those that contain at least 100 ppm CO$_2$) with surface pressures greater than 0.01 bar (0.1 bar) are ruled out at 1$σ$ (3$σ$), regardless of the choice of background atmosphere. Thicker atmospheres of up to 10 bar (100 bar) at 1$σ$ (3$σ$) are only allowed if the atmosphere lacks any strong absorbers across the mid-IR wavelength range, a scenario that we deem unlikely. We additionally model the emission spectra for bare-rock planets of various compositions. We find that a variety of silicate surfaces match the measured eclipse depth to within 1$σ$, and the best-fit grey albedo is $0.02 \pm 0.11$. We conclude that planned secondary eclipse observations at 12.8 $μ$m will serve to validate the high observed brightness temperature of TRAPPIST-1 b, but are unlikely to further distinguish among the consistent atmospheric and bare-rock scenarios.

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arXiv2023

A reflective, metal-rich atmosphere for GJ 1214b from its JWST phase curve

There are no planets intermediate in size between Earth and Neptune in our Solar System, yet these objects are found around a substantial fraction of other stars. Population statistics show that close-in planets in this size range bifurcate into two classes based on their radii. It is hypothesized that the group with larger radii (referred to as "sub-Neptunes") is distinguished by having hydrogen-dominated atmospheres that are a few percent of the total mass of the planets. GJ 1214b is an archetype sub-Neptune that has been observed extensively using transmission spectroscopy to test this hypothesis. However, the measured spectra are featureless, and thus inconclusive, due to the presence of high-altitude aerosols in the planet's atmosphere. Here we report a spectroscopic thermal phase curve of GJ 1214b obtained with JWST in the mid-infrared. The dayside and nightside spectra (average brightness temperatures of 553 $\pm$ 9 and 437 $\pm$ 19 K, respectively) each show >3$σ$ evidence of absorption features, with H$_2$O as the most likely cause in both. The measured global thermal emission implies that GJ 1214b's Bond albedo is 0.51 $\pm$ 0.06. Comparison between the spectroscopic phase curve data and three-dimensional models of GJ 1214b reveal a planet with a high metallicity atmosphere blanketed by a thick and highly reflective layer of clouds or haze.

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arXiv2023

Photochemically-produced SO$_2$ in the atmosphere of WASP-39b

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $μ$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $μ$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$σ$) and G395H (4.5$σ$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.

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arXiv2023

A Lack of Variability Between Repeated Spitzer Phase Curves of WASP-43b

Though the global atmospheres of hot Jupiters have been extensively studied using phase curve observations, the level of time variability in these data is not well constrained. To investigate possible time variability in a planetary phase curve, we observed two full-orbit phase curves of the hot Jupiter WASP-43b at 4.5 microns using the Spitzer Space Telescope, and reanalyzed a previous 4.5 micron phase curve from Stevenson et al. (2017). We find no significant time variability between these three phase curves, which span timescales of weeks to years. The three observations are best fit by a single phase curve with an eclipse depth of 3907 +- 85 ppm, a dayside-integrated brightness temperature of 1479 +- 13 K, a nightside-integrated brightness temperature of 755 +- 46 K, and an eastward-shifted peak of 10.4 +- 1.8 degrees. To model our observations, we performed 3D general circulation model simulations of WASP-43b with simple cloud models of various vertical extents. In comparing these simulations to our observations, we find that WASP-43b likely has a cloudy nightside that transitions to a relatively cloud-free dayside. We estimate that any change in WASP-43bs vertical cloud thickness of more than three pressure scale heights is inconsistent with our observed upper limit on variation. These observations, therefore, indicate that WASP-43bs clouds are stable in their vertical and spatial extent over timescales up to several years. These results strongly suggest that atmospheric properties derived from previous, single Spitzer phase curve observations of hot Jupiters likely show us the equilibrium properties of these atmospheres.

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arXiv2023

A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $μ$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$σ$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$σ$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

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arXiv2023

Emergent Spectral Fluxes of Hot Jupiters: an Abrupt Rise in Day Side Brightness Temperature Under Strong Irradiation

We study the emergent spectral fluxes of transiting hot Jupiters, using secondary eclipses from Spitzer. To achieve a large and uniform sample, we have re-analyzed all secondary eclipses for all hot Jupiters observed by Spitzer at 3.6- and/or 4.5 microns. Our sample comprises 457 eclipses of 122 planets, including eclipses of 13 planets not previously published. We use these eclipse depths to calculate the spectral fluxes emergent from the exoplanetary atmospheres, and thereby infer temperature and spectral properties of hot Jupiters. We find that an abrupt rise in brightness temperature, similar to a phase change, occurs on the day side atmospheres of the population at an equilibrium temperature between 1714K and 1818K (99-percent confidence limits). The amplitude of the rise is 291 +/-49 Kelvins, and two viable causes are the onset of magnetic drag that inhibits longitudinal heat redistribution, and/or the rapid dissipation of day side clouds. We also study hot Jupiter spectral properties with respect to metallicity and temperature inversions. Models exhibiting 4.5 micron emission from temperature inversions reproduce our fluxes statistically for the hottest planets, but the transition to emission is gradual, not abrupt. The Spitzer fluxes are sensitive to metallicity for planets cooler than approximately 1200 Kelvins, and most of the hot Jupiter population falls between model tracks having solar to 30X-solar metallicity.

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arXiv2023

Diagnosing limb asymmetries in hot and ultra-hot Jupiters with high-resolution transmission spectroscopy

Due to their likely tidally synchronized nature, (ultra)hot Jupiter atmospheres should experience strongly spatially heterogeneous instellation. The large irradiation contrast and resulting atmospheric circulation induce temperature and chemical gradients that can produce asymmetries across the eastern and western limbs of these atmospheres during transit. By observing an (ultra)hot Jupiter's transmission spectrum at high spectral resolution, these asymmetries can be recovered -- namely through net Doppler shifts originating from the exoplanet's atmosphere yielded by cross-correlation analysis. Given the range of mechanisms at play, identifying the underlying cause of observed asymmetry is nontrivial. In this work, we explore sources and diagnostics of asymmetries in high-resolution cross-correlation spectroscopy of hot and ultra-hot Jupiters using both parameterized and self-consistent atmospheric models. If an asymmetry is observed, we find that it can be difficult to attribute it to equilibrium chemistry gradients because many other processes can produce asymmetries. Identifying a molecule that is chemically stable over the temperature range of a planetary atmosphere can help establish a ``baseline'' to disentangle the various potential causes of limb asymmetries observed in other species. We identify CO as an ideal molecule, given its stability over nearly the entirety of the ultra-hot Jupiter temperature range. Furthermore, we find that if limb asymmetry is due to morning terminator clouds, blueshifts for a number of species should decrease during transit. Finally, by comparing our forward models to Kesseli et al. (2022), we demonstrate that binning high-resolution spectra into two phase bins provides a desirable trade-off between maintaining signal to noise and resolving asymmetries.

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arXiv2023

Photochemical hazes can trace the C/O ratio in exoplanet atmospheres

Photochemical hazes are suspected to obscure molecular features, such as water, from detection in the transmission spectra of exoplanets with atmospheric temperatures < 800 K. The opacities of laboratory produced organic compounds (tholins) from Khare et al. (1984) have become a standard for modeling haze in exoplanet atmospheres. However, these tholins were grown in an oxygen-free, Titan-like environment that is very different from typical assumptions for exoplanets, where C/O~0.5. This work presents the 0.13-10 micron complex refractive indices derived from laboratory transmission measurements of tholins grown in environments with different oxygen abundances. With the increasing uptake of oxygen, absorption increases across the entire wavelength range, and a scattering feature around 6 micron shifts towards shorter wavelengths and becomes more peaked around 5.8 micron, due to a C=O stretch resonance. Using GJ 1214b as a test-case, we examine the transmission spectra of a sub-Neptune planet with C/O ratios of solar, 1, and 1000 to evaluate the effective differences between our opacities and those of Khare. For an atmosphere with solar hydrogen and helium abundances, we find a difference of 200-1500 ppm, but for high-metallicity (Z=1000) environments, the difference may only be 20 ppm. The 1-2 micron transmission data for GJ 1214b rule out the Titan-like haze model, and are more consistent with C/O=1 and C/O=solar haze models. This work demonstrates that using haze opacities that are more consistent with underlying assumptions about bulk atmospheric composition are important for building self-consistent models that appropriately constrain the atmospheric C/O ratio, even when molecular features are obscured.

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arXiv2022

Evidence for the volatile-rich composition of a 1.5-$R_\oplus$ planet

The population of planets smaller than approximately $1.7~R_\oplus$ is widely interpreted as consisting of rocky worlds, generally referred to as super-Earths. This picture is largely corroborated by radial-velocity (RV) mass measurements for close-in super-Earths but lacks constraints at lower insolations. Here we present the results of a detailed study of the Kepler-138 system using 13 Hubble and Spitzer transit observations of the warm-temperate $1.51\pm0.04~R_\oplus$ planet Kepler-138 d ($T_{\mathrm{eq, A_B=0.3}}$~350 K) combined with new Keck/HIRES RV measurements of its host star. We find evidence for a volatile-rich "water world" nature of Kepler-138 d, with a large fraction of its mass contained in a thick volatile layer. This finding is independently supported by transit timing variations, RV observations ($M_d=2.1_{-0.7}^{+0.6}~M_\oplus$), as well as the flat optical/IR transmission spectrum. Quantitatively, we infer a composition of $11_{-4}^{+3}$\% volatiles by mass or ~51% by volume, with a 2000 km deep water mantle and atmosphere on top of a core with an Earth-like silicates/iron ratio. Any hypothetical hydrogen layer consistent with the observations ($<0.003~M_\oplus$) would have swiftly been lost on a ~10 Myr timescale. The bulk composition of Kepler-138 d therefore resembles those of the icy moons rather than the terrestrial planets in the solar system. We conclude that not all super-Earth-sized planets are rocky worlds, but that volatile-rich water worlds exist in an overlapping size regime, especially at lower insolations. Finally, our photodynamical analysis also reveals that Kepler-138 c ($R_c=1.51 \pm 0.04~R_\oplus$, $M_c=2.3_{-0.5}^{+0.6}~M_\oplus$) is a slightly warmer twin of Kepler-138 d, i.e., another water world in the same system, and we infer the presence of Kepler-138 e, a likely non-transiting planet at the inner edge of the habitable zone.

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arXiv2022

Water and an escaping helium tail detected in the hazy and methane-depleted atmosphere of HAT-P-18b from JWST NIRISS/SOSS

JWST is here. The early release observation program (ERO) provides us with the first look at the scientific data and the spectral capabilities. One of the targets from ERO is HAT-P-18b, an inflated Saturn-mass planet with an equilibrium temperature of $\sim$850K. We present the NIRISS/SOSS transmission spectrum of HAT-P-18b from 0.6 to 2.8$μm$ and reveal the planet in the infrared beyond 1.6$μm$ for the first time. From the spectrum, we see clear water and escaping helium tail features in an otherwise very hazy atmosphere. Our free chemistry retrievals with ATMO show moderate Bayesian evidence (3.79) supporting the presence of methane, but the spectrum does not display any clearly identifiable methane absorption features. The retrieved methane abundance is $\sim$2 orders of magnitude lower than that of solar composition. The methane-depleted atmosphere strongly rejects simple equilibrium chemistry forward models with solar metallicity and C/O ratio and disfavors high metallicity (100 times) and low C/O ratio (0.3). This calls for additional physical processes such as vertical mixing and photochemistry which can remove methane from the atmosphere.

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