arXiv subjects

Eliza M. -R. Kempton

Publications and source records attributed to Eliza M. -R. Kempton.

At least 37 records · Page 2Linked to original sources

arXiv2025

Assessing robustness and bias in 1D retrievals of 3D Global Circulation Models at high spectral resolution: a WASP-76 b simulation case study in emission

High-resolution spectroscopy (HRS) of exoplanet atmospheres has successfully detected many chemical species and is quickly moving toward detailed characterization of the chemical abundances and dynamics. HRS is highly sensitive to the line shape and position, thus, it can detect three-dimensional (3D) effects such as winds, rotation, and spatial variation of atmospheric conditions. At the same time, retrieval frameworks are increasingly deployed to constrain chemical abundances, pressure-temperature (P-T) structures, orbital parameters, and rotational broadening. To explore the multidimensional parameter space, they need computationally fast models that are consequently mostly one-dimensional (1D). However, this approach risks introducing interpretation bias since the planet's true nature is 3D. We investigate the robustness of this methodology at high spectral resolution by running 1D retrievals on simulated observations in emission within an observational framework using 3D Global Circulation Models of the quintessential HJ WASP-76 b. We find that the retrieval broadly recovers conditions present in the atmosphere, but that the retrieved P-T and chemical profiles are not a homogeneous average of all spatial and phase-dependent information. Instead, they are most sensitive to spatial regions with large thermal gradients, which do not necessarily coincide with the strongest emitting regions. Our results further suggest that the choice of parameterization for the P-T and chemical profiles, as well as Doppler offsets among opacity sources, impact retrieval results. These factors should be carefully considered in future retrieval analyses.

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arXiv2025

Population-level Hypothesis Testing with Rocky Planet Emission Data: A Tentative Trend in the Brightness Temperatures of M-Earths

Determining which rocky exoplanets have atmospheres, and why, is a key goal for the James Webb Space Telescope. So far, emission observations of individual rocky exoplanets orbiting M stars (M-Earths) have not provided definitive evidence for atmospheres. Here, we synthesize emission data for M-Earths and find a trend in measured brightness temperatures (ratioed to its theoretical maximum value) as a function of instellation. However, the statistical evidence of this trend is dependent on the choice of stellar model, and we consider its identification tentative. We show that this trend can be explained by either the onset of thin/tenuous (<1 bar) CO2-rich atmospheres on colder worlds, or a population of bare rocks with stronger space weathering and/or coarser regolith on closer-in worlds. Such grain coarsening may be caused by sintering near the melting point of rock or frequent volcanic resurfacing. Furthermore, we highlight considerations when testing rocky planet hypotheses at the population level, including the choice of instrument, stellar modeling, and how brightness temperatures are derived. We also find that fresh (unweathered) fine-grained surfaces can serve as a false positive to the detection of moderate atmospheric heat redistribution through eclipse observations. However, we argue that such surfaces are unlikely given the ubiquity of space weathering in the Solar System, the low albedo of Solar System airless bodies, and the high stellar wind environments of M-Earths. Emission data from a larger sample of M-Earths will be able to confirm or reject this tentative trend and diagnose its cause through spectral characterization.

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arXiv2025

Evolution of steam worlds: energetic aspects

Sub-Neptunes occupy an intriguing region of planetary mass-radius space, where theoretical models of interior structure predict that they could be water-rich, where water is in steam and supercritical state. Such planets are expected to evolve according to the same principles as canonical H$_2$-He rich planets, but models that assume a water-dominated atmosphere consistent with the interior have not been developed yet. Here, we present a state of the art structure and evolution model for water-rich sub-Neptunes. Our set-up combines an existing atmosphere model that controls the heat loss from the planet, and an interior model that acts as the reservoir of energy. We compute evolutionary tracks of planetary radius over time. We find that planets with pure water envelopes have smaller radii than predicted by previous models, and the change in radius is much slower (within $\sim$10\%). We also find that water in the deep interior is colder than previously suggested, and can transition from plasma state to superionic ice, which can have additional implications for their evolution. We provide a grid of evolutionary tracks that can be used to infer the bulk water content of sub-Neptunes. We compare the bulk water content inferred by this model and other models available in the literature, and find statistically significant differences between models when the uncertainty on measured mass and radius are both smaller than 10\%. This study shows the importance of pursuing efforts in the modeling of volatile-rich planets, and how to connect them to observations.

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arXiv2025

Out on a Limb: The Signatures of East-West Asymmetries in Transmission Spectra from General Circulation Models

In the era of JWST, observations of hot Jupiter atmospheres are becoming increasingly precise. As a result, the signature of limb asymmetries due to temperature or abundance differences and the presence of aerosols can now be directly measured using transmission spectroscopy. Using a grid of general circulation models (GCMs) with varying irradiation temperature (1500 K - 4000 K) and prescriptions of cloud formation, we simulate 3D ingress/egress and morning/evening-limb transmission spectra. We aim to assess the impact that clouds, 3D temperature structure, and non-uniform distribution of gases have on the observed spectra, and how these inhomogeneities can be identified. A second goal is to assess the relative merits of two separate methods (ingress/egress v.s. morning/evening-limb spectroscopy) for isolating atmospheric asymmetries. From our models, it is evident that an east-west temperature difference is the leading order effect for producing ingress/egress or morning/evening-limb spectral differences. We additionally find that clouds contribute strongly to the observed limb asymmetry at moderate irradiation temperatures in our grid ($\sim 2000 \mathrm{K} < T_{\mathrm{irr}} < 3500 \mathrm{K}). At lower temperatures clouds equally dominate the optical depth on both limbs, while at higher temperatures the entire terminator region remains cloud-free. We develop limb asymmetry metrics that can be used to assess the degree of east-west asymmetry for a given planet and predict trends in these metrics with respect to irradiation temperature that are indicative of various physical processes. Our results are useful for predicting and diagnosing the signatures of limb asymmetries in JWST spectra.

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arXiv2025

The radiative effects of photochemical hazes on the atmospheric circulation and phase curves of sub-Neptunes

Measuring the atmospheric composition of hazy sub-Neptunes like GJ~1214b through transmission spectroscopy is difficult because of the degeneracy between mean molecular weight and haziness. It has been proposed that phase curve observations can break this degeneracy because of the relationship between mean molecular weight (MMW) and phase curve amplitude. However, photochemical hazes can strongly affect phase curve amplitudes as well. We present a large set of GCM simulations of the sub-Neptune GJ~1214b that include photochemical hazes with varying atmospheric composition, haze opacity and haze optical properties. In our simulations, photochemical hazes cause temperature changes of up to 200~K, producing thermal inversions and cooling deeper regions. This results in increased phase curve amplitudes and adds a considerable scatter to the phase curve amplitude--metallicity relationship. However, we find that if the haze production rate is high enough to significantly alter the phase curve, the secondary eclipse spectrum will exhibit either emission features or strongly muted absorption features. Thus, the combination of a white-light phase curve and a secondary eclipse spectrum can successfully distinguish between a hazy, lower MMW and a clear, high MMW scenario.

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arXiv2025

Clouds and Hazes in GJ 1214b's Metal-Rich Atmosphere

The sub-Neptune GJ 1214b has an infamously flat transmission spectrum, likely due to thick aerosols in its atmosphere. A recent JWST MIRI spectroscopic phase curve of GJ 1214 b added to this picture, suggesting a highly reflective and metal-rich atmosphere. Using a 3D General Circulation Model with both photochemical hazes and condensate clouds, we characterize how different aerosol types affect the atmospheric structure of GJ 1214 b and manifest in its spectroscopic phase curve. Additionally, we reanalyze the original GJ 1214 b JWST phase curve. The reanalysis shows a hotter nightside, similar dayside temperature, and a lower, but still elevated, Bond albedo (0.42 +/- 0.11) than the original results. We find that a scenario with both clouds and hazes is most consistent with the JWST phase curve. Reflective clouds or hazes are needed to explain the large Bond albedo, and hazes or a super-solar metallicity help account for the several hundred Kelvin day-night temperature difference measured by the phase curve.

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arXiv2025

An Analysis of Spitzer Phase Curves for WASP-121b and WASP-77Ab

We present analyses of Spitzer InfraRed Array Camera (IRAC) 3.6 $μ$m and 4.5 $μ$m phase curve observations of hot Jupiters WASP-77Ab and WASP-121b. For WASP-121b, we find amplitudes of 1771 $\pm$ 95 ppm (3.6 $μ$m) and 2048 $\pm$ 109 ppm (4.5 $μ$m), and near-zero offsets of -0.78 $\pm$ 1.87$^{\circ}$ (3.6 $μ$m) and 0.42 $\pm$ 1.74$^{\circ}$ (4.5 $μ$m), consistent within 2.2$σ$ and 1.3$σ$, respectively, with JWST NIRSpec results. For WASP-77Ab, we find amplitudes of 535 $\pm$ 52 ppm (3.6 $μ$m) and 919 $\pm$ 40 ppm (4.5 $μ$m), and offsets of 33.45 $\pm$ 2.79$^{\circ}$ (3.6 $μ$m) and 16.28 $\pm$ 2.52$^{\circ}$ (4.5 $μ$m). We report day- and nightside brightness temperatures: for WASP-121b, 2779 $\pm$ 40 K (3.6 $μ$m) and 2905 $\pm$ 51 K (4.5 $μ$m) (day) and 1259 $\pm$ 67 K (3.6 $μ$m) and 1349 $\pm$ 54 K (4.5 $μ$m) (night), and for WASP-77Ab, 1876 $\pm$ 23 K (3.6 $μ$m) and 1780 $\pm$ 25 K (day) and 1501 $\pm$ 22 K (3.6 $μ$m) and 1234 $\pm$ 20 K (4.5 $μ$m) (night). Comparing WASP-121b data to general circulation models, we find evidence for drag inhibiting day-to-night heat transfer, which our model reproduces using magnetic circulation. Further, comparing both planets' data to Energy Balance Models, we show suppressed circulation in WASP-121b and potential evidence for an unusually high Bond albedo in WASP-77Ab. We add both planets to the Spitzer population study of previously identified trends in offset versus orbital period, finding that a positive trend is weakened, but not eliminated, by including these planets.

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arXiv2025

Peering into the black box: forward-modeling the uncertainty budget of high-resolution spectroscopy of exoplanet atmospheres

Ground-based high-resolution cross-correlation spectroscopy (HRCCS; R >~ 15,000) is a powerful complement to space-based studies of exoplanet atmospheres. By resolving individual spectral lines, HRCCS can precisely measure chemical abundance ratios, directly constrain atmospheric dynamics, and robustly probe multidimensional physics. But the subtleties of HRCCS datasets -- e.g., the lack of exoplanetary spectra visible by eye and the statistically complex process of telluric removal -- can make interpreting them difficult. In this work, we seek to clarify the uncertainty budget of HRCCS with a forward-modeling approach. We present a HRCCS observation simulator, scope (https://github.com/arjunsavel/scope), that incorporates spectral contributions from the exoplanet, star, tellurics, and instrument. This tool allows us to control the underlying dataset, enabling controlled experimentation with complex HRCCS methods. Simulating a fiducial hot Jupiter dataset (WASP-77Ab emission with IGRINS), we first confirm via multiple tests that the commonly used principal components analysis does not bias the planetary signal when few components are used. Furthermore, we demonstrate that mildly varying tellurics and moderate wavelength solution errors induce only mild decreases in HRCCS detection significance. However, limiting-case, strongly varying tellurics can bias the retrieved velocities and gas abundances. Additionally, in the low-SNR limit, constraints on gas abundances become highly non-Gaussian. Our investigation of the uncertainties and potential biases inherent in HRCCS data analysis enables greater confidence in scientific results from this maturing method.

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arXiv2025

TOI-421 b: A Hot Sub-Neptune with a Haze-Free, Low Mean Molecular Weight Atmosphere

Common features of sub-Neptunes atmospheres observed to date include signatures of aerosols at moderate equilibrium temperatures (~500-800 K), and a prevalence of high mean molecular weight atmospheres, perhaps indicating novel classes of planets such as water worlds. Here we present a 0.83-5 micron JWST transmission spectrum of the sub-Neptune TOI-421 b. This planet is unique among previously observed counterparts in its high equilibrium temperature ($T_{eq} \approx 920$) and its Sun-like host star. We find marked differences between the atmosphere of TOI-421 b and those of sub-Neptunes previously characterized with JWST, which all orbit M stars. Specifically, water features in the NIRISS/SOSS bandpass indicate a low mean molecular weight atmosphere consistent with solar metallicity, and no appreciable aerosol coverage. Hints of SO$_2$ and CO (but not CO$_2$ or CH$_4$) also exist in our NIRSpec/G395M observations, but not at sufficient signal-to-noise to draw firm conclusions. Our results support a picture in which sub-Neptunes hotter than ~850 K do not form hydrocarbon hazes due to a lack of methane to photolyze. TOI-421 b additionally fits the paradigm of the radius valley for planets orbiting FGK stars being sculpted by mass loss processes, which would leave behind primordial atmospheres overlying rock/iron interiors. Further observations of TOI-421 b and similar hot sub-Neptunes will confirm whether haze-free atmospheres and low mean molecular weights are universal characteristics of such objects.

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arXiv2024

The Roasting Marshmallows Program with IGRINS on Gemini South II -- WASP-121 b has super-stellar C/O and refractory-to-volatile ratios

A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet's initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultra hot Jupiter WASP-121 b using the high resolution (R=45,000) IGRINS instrument on Gemini South. Probing the planet's direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly super-stellar C/O ratio of 0.70$^{+0.07}_{-0.10}$ and a moderately super-stellar refractory-to-volatile ratio at 3.83$^{+3.62}_{-1.67} \times$ stellar. This combination is most consistent with formation between the soot line and H$_2$O snow line, but we cannot rule out formation between the H$_2$O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H$_2$O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet day side. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high resolution spectroscopy in the near-infrared H and K bands.

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arXiv2024

No Thick Atmosphere on the Terrestrial Exoplanet Gl 486b

A primary science goal for JWST is to detect and characterize the atmospheres of terrestrial planets orbiting M dwarfs (M-Earths). The existence of atmospheres on M-Earths is highly uncertain because their host stars' extended history of high XUV irradiation may act to completely remove their atmospheres. We present two JWST secondary eclipse observations of the M-Earth Gl 486b (also known as GJ 486b) between 5-12 $μ$m. We combined these observations with a precise analysis of the host star parameters to derive a planetary dayside temperature of $T_{p}=865 \pm 14$ K. We compared this temperature to the maximum expected temperature for a zero albedo, zero heat redistribution bare rock and derived a temperature ratio of $R=\frac{T_{p,dayside}}{T_{p,max}}=0.97 \pm 0.01$. This value is consistent with an airless body with a slight non-zero albedo or a thin atmosphere with $<1$% H$_{2}$O or $<1$ ppm CO$_{2}$. However, it is inconsistent with an Earth- or Venus-like atmosphere, and the spectrum shows no clear emission or absorption features. Additionally, our observations are inconsistent with the water-rich atmospheric scenario allowed by previous transit observations and suggest the transmission spectrum was instead shaped by stellar contamination (Moran et al. 2023). Given the potential for atmospheric escape throughout the system's $\geq6.6$-Gyr lifetime (Diamond-Lowe et al. 2024), we conclude that the observations are likely best explained by an airless planet. This result is the most precise measurement yet of terrestrial exoplanet thermal emission with JWST, which places a strong constraint on the position of the "Cosmic Shoreline" between airless bodies and those with atmospheres.

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arXiv2024

The Featherweight Giant: Unraveling the Atmosphere of a 17 Myr Planet with JWST

The characterization of young planets (< 300 Myr) is pivotal for understanding planet formation and evolution. We present the 3-5$μ$m transmission spectrum of the 17 Myr, Jupiter-size ($R$ $\sim$10$R_{\oplus}$) planet, HIP 67522 b, observed with JWST/NIRSpec/G395H. To check for spot contamination, we obtain a simultaneous $g$-band transit with SOAR. The spectrum exhibits absorption features 30-50% deeper than the overall depth, far larger than expected from an equivalent mature planet, and suggests that HIP 67522 b's mass is $<$20 $M_{\oplus}$ irrespective of cloud cover and stellar contamination. A Bayesian retrieval analysis returns a mass constraint of $13.8\pm1.0M_{\oplus}$. This challenges the previous classification of HIP 67522 b as a hot Jupiter and instead, positions it as a precursor to the more common sub-Neptunes. With a density of $<$0.10g/cm$^{3}$, HIP 67522 b is one of the lowest density planets known. We find strong absorption from H$_{2}$O and CO$_{2}$ ($\ge7σ$), a modest detection of CO (3.5$σ$), and weak detections of H$_2$S and SO$_2$ ($\simeq2σ$). Comparisons with radiative-convective equilibrium models suggest supersolar atmospheric metallicities and solar-to-subsolar C/O ratios, with photochemistry further constraining the inferred atmospheric metallicity to 3$\times$10 Solar due to the amplitude of the SO$_2$ feature. These results point to the formation of HIP 67522 b beyond the water snowline, where its envelope was polluted by icy pebbles and planetesimals. The planet is likely experiencing substantial mass loss (0.01-0.03 M$_{\oplus}$ Myr$^{-1}$), sufficient for envelope destruction within a Gyr. This highlights the dramatic evolution occurring within the first 100 Myr of its existence.

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arXiv2024

A Comprehensive Analysis Spitzer 4.5 $μ$m Phase Curve of Hot Jupiters

Although exoplanetary science was not initially projected to be a substantial part of the Spitzer mission, its exoplanet observations set the stage for current and future surveys with JWST and Ariel. We present a comprehensive reduction and analysis of Spitzer's 4.5 micron phase curves of 29 hot Jupiters on low-eccentricity orbits. The analysis, performed with the Spitzer Phase Curve Analysis (SPCA) pipeline, confirms that BLISS mapping is the best detrending scheme for most, but not all, observations. Visual inspection remains necessary to ensure consistency across detrending methods due to the diversity of phase curve data and systematics. Regardless of the model selection scheme - whether using the lowest-BIC or a uniform detrending approach - we observe the same trends, or lack thereof. We explore phase curve trends as a function of irradiation temperature, orbital period, planetary radius, mass, and stellar effective temperature. We discuss the trends that are robustly detected and provide potential explanations for those that are not observed. While it is almost tautological that planets receiving greater instellation are hotter, we are still far from confirming dynamical theories of heat transport in hot Jupiter atmospheres due to the sample's diversity. Even among planets with similar temperatures, other factors like rotation and metallicity vary significantly. Larger, curated sample sizes and higher-fidelity phase curve measurements from JWST and Ariel are needed to firmly establish the parameters governing day-night heat transport on synchronously rotating planets.

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arXiv2024

JWST Thermal Emission of the Terrestrial Exoplanet GJ 1132b

We present thermal emission measurements of GJ 1132b spanning 5--12 um obtained with the Mid-Infrared Instrument Low-Resolution Spectrometer (MIRI/LRS) on the James Webb Space Telescope (JWST). GJ 1132b is an M-dwarf rocky planet with Teq=584 K and an orbital period of 1.6 days. We measure a white-light secondary eclipse depth of 140+/-17 ppm, which corresponds to a dayside brightness temperature of Tp,dayside= 709+/-31 K using improved star and planet parameters. This measured temperature is only 1 sigma below the maximum possible dayside temperature of a bare rock (i.e., assuming a zero albedo planet with no heat redistribution, Tmax = 746+14/-11 K). The emission spectrum is consistent with a featureless blackbody, which agrees with a wide range of possible surface compositions. By comparing forward models to the dayside emission spectrum, we rule out Earth-thickness (P ~ 1 bar) atmospheres with at least 1% H2O, atmospheres of any modeled thickness (10^-4 -- 10^2 bar) that contain at least 1% CO2, and thick, Venus-like atmospheres (P>~100 bar) with at least 1 ppm CO2 or H2O. We therefore conclude that GJ 1132b likely does not have a significant atmosphere. This finding supports the concept of a universal 'Cosmic Shoreline' given the high level of bolometric and XUV irradiation received by the planet.

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arXiv2024

cortecs: A Python package for compressing opacities

The absorption and emission of light by exoplanet atmospheres encode details of atmospheric composition, temperature, and dynamics. Fundamentally, simulating these processes requires detailed knowledge of the opacity of gases within an atmosphere. When modeling broad wavelength ranges at high resolution, such opacity data, for even a single gas, can take up multiple gigabytes of system random-access memory (RAM). This aspect can be a limiting factor when considering the number of gases to include in a simulation, the sampling strategy used for inference, or even the architecture of the system used for calculations. Here, we present cortecs, a Python tool for compressing opacity data. cortecs provides flexible methods for fitting the temperature, pressure, and wavelength dependencies of opacity data and for evaluating the opacity with accelerated, GPU-friendly methods. The package is actively developed on GitHub (https://github.com/arjunsavel/cortecs), and it is available for download with pip and conda.

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arXiv2024

New insights into the internal structure of GJ 1214 b informed by JWST

Recent JWST observations of the sub-Neptune GJ 1214 b suggest that it hosts a high-metallicity (>100x solar), hazy atmosphere. Emission spectra of the planet show molecular absorption features, most likely due to atmospheric H2O. In light of this new information, we conduct a thorough reevaluation of the planet's internal structure. We consider interior models with mixed H/He/H2O envelopes of varying composition, informed by atmospheric constraints from the JWST phase curve, in order to determine possible bulk compositions and internal structures. Self-consistent atmospheric models consistent with the JWST observations are used to set boundary conditions for the interior. We find that a total envelope mass fraction of at least 8.1% is required to explain the planet's mass and radius. Regardless of H2O content, the maximum H/He mass fraction of the planet is 5.8%. We find that a 1:1 ice-to-rock ratio along with 3.4-4.8% H/He is also a permissible solution. In addition, we consider a pure H2O (steam) envelope and find that such a scenario is possible, albeit with a high ice-to-rock ratio of at least 3.76:1, which may be unrealistic from a planet formation standpoint. We discuss possible formation pathways for the different internal structures that are consistent with observations. Since our results depend strongly on the atmospheric composition and haze properties, more precise observations of the planet's atmosphere would allow for further constraints on its internal structure. This type of analysis can be applied to any sub-Neptune with atmospheric constraints to better understand its interior.

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arXiv2024

Inhomogeneous terminators on the exoplanet WASP-39 b

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ μ$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator.

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arXiv2024

Hydrogen sulfide and metal-enriched atmosphere for a Jupiter-mass exoplanet

As the closest transiting hot Jupiter to Earth, HD 189733b has been the benchmark planet for atmospheric characterization. It has also been the anchor point for much of our theoretical understanding of exoplanet atmospheres from composition, chemistry, aerosols to atmospheric dynamics, escape, and modeling techniques. Prior studies of HD 189733b have detected carbon and oxygen-bearing molecules H2O and CO in the atmosphere. The presence of CO2 and CH4 has been claimed but later disputed. The inferred metallicity based on these measurements, a key parameter in tracing planet formation locations, varies from depletion to enhancement, hindered by limited wavelength coverage and precision of the observations. Here we report detections of H2O (13.4 sigma), CO2 (11.2 sigma), CO (5 sigma), and H2S (4.5 sigma) in the transmission spectrum (2.4-5 micron) of HD 189733b. With an equilibrium temperature of ~1200K, H2O, CO, and H2S are the main reservoirs for oxygen, carbon, and sulfur. Based on the measured abundances of these three major volatile elements, we infer an atmospheric metallicity of 3-5 times stellar. The upper limit on the methane abundance at 5 sigma is 0.1 ppm which indicates a low carbon-to-oxygen ratio (<0.2), suggesting formation through the accretion of water-rich icy planetesimals. The low oxygen-to-sulfur and carbon-to-sulfur ratios also support the planetesimal accretion formation pathway.

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