arXiv subjects

Emmanuel Dartois

Publications and source records attributed to Emmanuel Dartois.

At least 19 recordsLinked to original sources

arXiv2026

PDRs4All XXII. Near-Infrared continuum in the Orion Bar

Conspicuous excess emission is present in the near-infrared (NIR) region in various objects, including reflection nebulae, planetary nebulae, and nearby galaxies. However, the spatial distribution and spectral shape of the excess emission remain poorly understood. We studied the NIR continuum emission spectroscopically and obtained its spatial distribution relative to the aromatic infrared band (AIB) at 3.3um in the Orion Bar prototypical photodissociation region (PDR). We aim to characterize its spectral shape and discuss its origin. We employed 3D spectroscopic data of the Orion Bar taken with the integrated field unit of NIRSpec on JWST from the Early Release Science program "PDRs4All." Contribution from the foreground ionized gas was estimated using the Cloudy code and subtracted. The observed regions were divided into nine physically distinct regions and an average spectrum was derived for each region. The nine regions, including the ionized gas, atomic PDR, and molecular PDR, clearly show remaining continuum in the region 1--4.5um. The continuum at wavelengths longer than 2.7um shows good correlations with the 3.3um AIB, while the correlation of the continuum at 1.2um is not significant. We further find that the NIR continuum in the Orion Bar can be approximated by a summation of two blackbodies. The low-temperature component correlates with the AIB well, while the high-temperature component does not. The average spectra also show absorption features at 3.0 and 4.27um, which are attributed to the presence in the spectra of water ice and CO2 ice. We discuss possible origins of the NIR continuum, among which recurrent fluorescence from carbon clusters better explains the observed low-temperature component. The presence of ice species suggests a contribution from a deeper layer of the PDR along the line of sight producing characteristic ice absorption features.

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arXiv2026

JWST Edge-on Disk Ice (JEDIce): Vibrationally hot, rotationally cold H$_2$ in the outer disk of Oph 163131 non-thermally excited by UV and cosmic rays

Constraining ionization and excitation processes in protoplanetary disks is essential for understanding the chemical structure and evolution of disk material, shaping planet formation pathways. We present JWST/NIRSpec IFU observations of the edge-on disk Oph 163131, which reveal a unusual ro-vibrational H$_2$ spectrum dominated by the 1--0 O(2) line (2.627 $μ$m), with suppressed higher-$J$ emission despite excitation to $v=2$ and $3$. This vibrationally hot, rotationally cold H$_2$ emission is spatially extended, broadly following the molecular disk traced by CO($J{=}2$--1), with emission increasing above and below a thin midplane dark lane and extending radially beyond $\sim$200 au, where near-IR scattered-light emission is no longer dominant. We interpret the observed H$_2$ emission as arising from non-thermal excitation in cold, dense outer-disk gas, where collisions depopulate higher-$J$ rotational levels within each vibrational manifold prior to emission, producing the characteristic ``$v$-hot, $J$-cold" spectrum. We consider both ultraviolet irradiation and cosmic-ray excitation as contributors to the H$_2$ emission and find that their combined action, together with collisional de-excitation of high-$J$ level populations, broadly reproduces the observed line ratios and morphology. Within this framework, we infer a rather high effective cosmic-ray ionization rate of $\sim(1$-$10)\times10^{-15}$ s$^{-1}$ in the presence of a moderate UV field ($χ_{UV}=100-1000$, in Draine units). These results for disks, together with the recent findings by Bialy et al. 2025 for the lower-density starless core B68, highlight the potential of ro-vibrational H$_2$ emission as a novel probe of cosmic-ray ionization.

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arXiv2026

JWST Edge-on Disk Ice (JEDIce): Program overview and ice survey results

The icy material within protoplanetary disks plays a central role in planet formation, yet remains poorly characterized by observations. We present 1.6-28$μ$m spectra of five disks obtained as part of the JWST Edge-on Disk Ice (JEDIce) program, representing the largest survey of disk ices to date. The major ice species H$_2$O, CO$_2$, and CO are detected towards all disks, and exhibit a wide range of absolute optical depths and optical depth ratios across the sample. This is suggestive of a range of ice abundances and compositions, but quantitative constraints will require radiative transfer modeling. All disks exhibit ice features across the entire spatial region where the IR continuum is detected; vertically elevated ice grains therefore seem to be ubiquitous in disks. The CO ice is consistently dominated by apolar CO:CO$_2$ mixtures, implying that the disk ice compositions are neither completely reset nor pristinely inherited from the protostellar stage. The presence of these mixtures also suggests that entrapment may be important in shaping the spatial distribution of CO within the disks. Small molecules commonly seen in protostellar ices (CH$_4$, CH$_3$OH, NH$_3$) are generally not detected in our sample, though tracers of ammonium salts (OCN$^-$ and the 6.85 $μ$m band) are common, potentially reflecting an evolution towards comet-like ice compositions. The spectra also contain a wealth of information about the micron-sized dust, atomic and molecular gas, and PAH content, which together with the ice constraints will provide a comprehensive picture of the chemical, physical, and dynamical state of these systems.

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arXiv2026

Simulation of proton radiolysis of H2O and O2 ices with the Nautilus code

The radiolysis effect of cosmic rays (CRs) plays an important role in the chemistry in molecular clouds. CRs can dissociate the molecules on dust grains, producing reactive suprathermal species and radicals which facilitate the formation of large molecules. We add the radiolysis process and some relevant reactions into the Nautilus astrochemical code. By adjusting some parameters, we investigate the sensitivity of the simulation results of the H2O ice on the removal of reaction-diffusion competition, the removal of non-diffusive chemistry, and the desorption energies of the suprathermal species. We find the model, with a few adjustments of the chemistry, can reproduce the steady-state [H2O2]/[H2O] and [O3]/[O2]_0 abundance ratios in the H2O and O2 radiolysis experiments at any CR flux in the experiments. These adjustments in the model do not fully reproduce the fluence required to reach the steady state. It tends also to overestimate the destruction of H2O as measured in H2O radiolysis experiments. We show that reducing the G-values of H2O radiolysis, which implies an increase in the efficiency of immediate reformation of water locally after ion impact, leads to simulated H2O destruction rates closer to the experiments. The effect of reaction-diffusion competition on the simulation results of H2O ice is significant at $ζ\lesssim 10^{-14}\ \rm s^{-1}$. The non-diffusive chemistry affects the simulation results at 16 K but not 77K, while the results are sensitive to the desorption energies of suprathermal H, O, O3 and OH at 77 K. Our results show that the steady-state [H2O2]/[H2O] and [O3]/[O2]_0 in experiments can be reproduced by fine-tuning the chemical model, but still call for more constraints on the intermediate pathways in the radiolysis processes, especially the ion chemistry in the ice bulk, as well as activation barriers and branching ratios of the reactions in the network.

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arXiv2026

PDRs4All: XVIII. The evolution of the PAH ionisation and PAH size distribution across the Orion Bar

We investigate the evolution of the PAH population's charge state and size across key physical zones in the Orion Bar, which include the HII region, the atomic PDR (APDR), and three HI/H2 dissociation fronts (DF1, DF2, and DF3). Utilising the NASA Ames PAH Infrared Spectroscopic Database (PAHdb) and the pyPAHdb spectral modelling tool, we analysed the MIRI-MRS observations of the Orion Bar from the "PDRs4All" ERS Program. pyPAHdb modelling reveals the fractional contribution of the different PAH charge states and sizes to the total PAH emission across the Orion Bar. Cationic PAH emission peaks in the APDR region, where neutral PAHs have minimal contribution. Emission from neutral PAHs peaks in the HII region that consists of emission from a face-on PDR associated to the background OMC-1 molecular cloud, and in the molecular cloud regions past DF2. PAH anions are observed deep within the DF2 and DF3 zones. The average PAH size ranges between ~$60-74$ Nc. The modelling reveals regions of top-down PAH formation at the ionisation front, and bottom-up PAH formation within the molecular cloud region. The PAH ionisation parameter $γ$ ranges between ~$2-9 x 10^4$. Intensity ratios tracing PAH ionisation scale well with $γ$ in regions encompassing edge-on or face-on PDR emission, but their correlation weakens within the molecular cloud zone. Modelling of the $5-15$ $μ$m PAH spectrum with pyPAHdb achieves comprehensive characterization of the net contribution of neutral and cationic PAHs across different environments, whereas empirical PAH proxy intensity ratio tracers can be highly variable and unreliable outside regions dominated by PDR emission. The derived average PAH size in the different physical zones is consistent with a view of PAHs being more extensively subjected to ultraviolet processing closer to the ionisation front, and less affected within the molecular cloud.

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arXiv2025

The Flying Saucer edge-on disc's Near Infrared silhouette revealed by the JWST JEDIce program

Edge-on discs offer a unique opportunity to probe radial and vertical dust and gas distributions in the protoplanetary phase. This study aims to investigate the distribution of micron-sized dust particles in the Flying Saucer (BKLT J162813-243139) in Rho Ophiuchi, leveraging the unique observational conditions of a bright infrared background that enables the edge-on disc to be seen in both silhouette and scattered light at certain, specific wavelengths. As part of the JWST Edge-on Disc Ice program ('JEDIce'), we use NIRSpec IFU observations of the Flying Saucer, serendipitously observed against a PAH-emitting background, to constrain the dust distribution and grain sizes through radiative transfer modelling. Observation of the Flying Saucer in silhouette at 3.29 microns reveals that the midplane radial extent of small dust grains is ~235 au, larger than the large-grain disc extent previously determined to be 190 au from millimetre data. The scattered light observed in emission probes micron sized icy grains at large vertical distances above the midplane. The vertical extent of the disc silhouette is similar at visible, near-IR, and mid-IR wavelengths, corroborating the conclusion that dust settling is inefficient for grains as large as tens of microns, vertically and radially.

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arXiv2025

Variation of the disk thickness across ice bands: A method to determine ice abundances in highly inclined protoplanetary disks

The James Webb Space Telescope provides unprecedented information to study ices in protoplanetary disks. However, the saturation of ice bands in highly inclined disks hinders the measurement of ice abundances using classical spectroscopy. This is unfortunate as the presence and more importantly abundance of ices plays a key role in, e.g., the evolution of dust (because it modifies the sticking properties) and the composition of planetesimals and exoplanetary atmospheres. To overcome this issue and quantify the ice abundance within disks, we introduce a new method based on measuring the changes in the apparent disk thickness as a function of wavelength, which is directly and quantitatively related to the grain opacity. Specifically, we expect i) that the increased opacity within ice bands should result in a thicker disk than in the adjacent continuum, and ii) the thickness variations to be proportional to the abundance of ice. We extracted the disk thickness in model images of edge-on disks containing different abundances of water ice, as well as in James Webb Space Telescope spectral imaging of four edge-on disks. For both models and observations, the disk thickness decreases toward longer wavelengths except across the positions of ice absorption features where the thickness is enhanced across the band. In the model images, we demonstrate that this effect increases with ice abundance without any hint of saturation. This definitely demonstrates the presence of the ice species within each disk and confirms our expectation that this method can be applied to estimate ice abundances. Thanks to this method, it will thus be possible to constrain the ice abundance in highly inclined disks with disks model fitting. Unlike spectroscopic analysis, this method is not subject to saturation and should therefore be more robust and applicable to all disks for which the two surfaces can be resolved.

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arXiv2025

PDRs4All XIX. The 6 to 9 $μ$m region as a probe of PAH charge and size in the Orion Bar

Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of molecular clouds. We aim to investigate the distribution and sizes of charged PAHs across the key zones of the Orion Bar PDR. We employ JWST MIRI-MRS observations of the Orion Bar from the Early Release Science program ''PDRs4All'' and synthetic images in the JWST MIRI filters. We investigate the spatial morphology of the AIBs at 6.2, 7.7, 8.6, and 11.0 $μ$m that commonly trace PAH cations, and the neutral PAH-tracing 11.2 $μ$m AIB, their (relative) correlations, and the relationship with existing empirical prescriptions for AIBs. The 6.2. 7.7, 8.6, 11.0, and 11.2 $μ$m AIBs are similar in spatial morphology, on larger scales. Analyzing three-feature intensity correlations, two distinct groups emerge: the 8.6 and 11.0 $μ$m vs. the 6.2 and 7.7 $μ$m AIBs. We attribute these correlations to PAH size. The 6.2 and 7.7 $μ$m AIBs trace cationic, medium-sized PAHs. Quantum chemical calculations reveal that the 8.6 $μ$m AIB is carried by large, compact, cationic PAHs, and the 11.0 $μ$m AIB's correlation to it implies, so is this band. The 6.2/8.6 and 7.7/8.6 PAH band ratios thus probe PAH size. We conclude that the 6.2/11.2 AIB ratio is the most reliable proxy for charged PAHs, within the cohort. We outline JWST MIRI imaging prescriptions that serve as effective tracers of the PAH ionization fraction as traced. This study showcases the efficacy of the 6-9 $μ$m AIBs to probe the charge state and size distribution of the emitting PAHs, offering insights into the physical conditions of their host environments. JWST MIRI photometry offers a viable alternative to IFU spectroscopy for characterizing this emission in extended objects.

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arXiv2025

PDRs4All XVI. Tracing aromatic infrared band characteristics in photodissociation region spectra with PAHFIT in the JWST era

Photodissociation regions (PDRs) exhibit emission between 3-20 um known as the Aromatic Infrared Bands (AIBs), originating from small carbonaceous species such as polycyclic aromatic hydrocarbons (PAHs). The AIB spectra observed in Galactic PDRs, such as the Orion Bar observations by the PDRs4All JWST program, are considered a local analog for those seen in extragalactic star-forming regions. We present the Python version of PAHFIT, a spectral decomposition tool that separates the contributions by AIB subcomponents, thermal dust emission, gas lines, stellar light, and dust extinction. By fitting segments of the Orion Bar spectra, we provide a configuration to decompose JWST spectra of PDRs in detail. The resulting central wavelengths and FWHM of the AIB subcomponents are compiled into a "PDR pack" for PAHFIT. We applied PAHFIT with this PDR pack and the default continuum model to spectra of the central star forming ring of the galaxy NGC7469. We introduce an alternate dust continuum model to fit the Orion Bar spectra, as the default PAHFIT continuum model mismatches the intensity at 15-26 um. Using the PDR pack and the alternate continuum model, PAHFIT reproduces the Orion Bar spectra with residuals of a few percent, and similar performance is achieved for the NGC7469 spectra. We provide PAHFIT-based diagnostics that trace the profile variations of the 3.3, 3.4, 5.7, 6.2, and 7.7 um AIBs, and thus the photochemical evolution of the AIB carriers. The 5.7 um AIB emission originates from at least two subpopulations, one more prominent in highly irradiated environments and one preferring more shielded environments. Smaller PAHs as well as very small grains or PAH clusters both thrive in the more shielded environments of the molecular zone in the Orion Bar. Based on these new diagnostics, we quantify the similarities between the AIB profiles observed in the Orion Bar and NGC7469.

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arXiv2025

Solar C/O ratio in planet-forming gas at 1 au in a highly irradiated disk

The chemical composition of exoplanets is thought to be influenced by the composition of the disks in which they form. JWST observations have unveiled a variety of species in numerous nearby disks, showing significant variations in the C/O abundance ratio. However, little is known about the composition and C/O ratio of disks around young stars in clusters exposed to strong ultraviolet (UV) radiation from nearby massive stars, which are representative of the environments where most planetary systems form, including ours. We present JWST spectroscopy of d203-504, a young 0.7 $\rm M_{\odot}$ star in the Orion Nebula with a 30 au disk irradiated by nearby massive stars. These observations reveal spectroscopic signatures of CO, H$_2$O, CH$_3^+$, and PAHs. Water and CO are detected in absorption in the inner disk ($r\lesssim 1$ au), where the estimated gas-phase C/O ratio is 0.48, consistent with the Solar value and that of the Orion Nebula. In contrast, \ch{CH3+} and PAHs are found in the extended surface layers of the disk. These results suggest that gas in the inner disk is chemically shielded from UV radiation while the surface layers of the disk experience UV-induced chemistry, potentially depleting their carbon content.

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arXiv2025

PDRs4All XIII. Empirical prescriptions for the interpretation of JWST imaging observations of star-forming regions

(Abridged) JWST continues to deliver incredibly detailed infrared (IR) images of star forming regions in the Milky Way and beyond. IR emission from star-forming regions is very spectrally rich due to emission from gas-phase atoms, ions, and polycyclic aromatic hydrocarbons (PAHs). Physically interpreting IR images of these regions relies on assumptions about the underlying spectral energy distribution in the imaging bandpasses. We aim to provide empirical prescriptions linking line, PAH, and continuum intensities from JWST images, to facilitate the interpretation of JWST images in a wide variety of contexts. We use JWST PDRs4All Near-Infrared Camera (NIRCam) and Mid-Infrared Instrument (MIRI) imaging and Near-Infrared Spectrograph (NIRSpec) integral field unit (IFU) and MIRI Medium Resolution Spectrograph (MRS) spectroscopic observations of the Orion Bar photodissociation region (PDR), to directly compare and cross-calibrate imaging and IFU data at ~100 AU resolution over a region where the radiation field and ISM environment evolves from the hot ionized gas to the cold molecular gas. We measure the relative contributions of line, PAH, and continuum emission to the NIRCam and MIRI filters as functions of local physical conditions. We provide empirical prescriptions based on NIRCam and MIRI images to derive intensities of emission lines and PAH features. Within the range of the environments probed in this study, these prescriptions accurately predict Pa-$α$, Br-$α$, PAH 3.3 $μ$m and 11.2 $μ$m intensities, while those for FeII 1.644 $μ$m, H$_2$ 1--0 S(1) 2.12 $μ$m and 1--0 S(9) 4.96 $μ$m, and PAH 7.7 $μ$m show more complicated environmental dependencies. Linear combinations of JWST NIRCam and MIRI images provide effective tracers of ionized gas, H$_2$, and PAH emission in PDRs. We expect these recipes to be useful for both the Galactic and extragalactic communities.

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arXiv2025

Modelling methanol and hydride formation in the JWST Ice Age era

(Abridged) JWST observations have measured the ice composition toward two highly-extinguished field stars in the Chamaeleon I cloud. The observed extinction excess on the long-wavelength side of the H2O ice band at 3 micron has been attributed to a mixture of CH3OH with ammonia hydrates, which suggests that CH3OH ice could have formed in a water-rich environment with little CO depletion. Laboratory experiments and quantum chemical calculations suggest that CH3OH could form via the grain surface reactions CH3+OH and/or C+H2O in water-rich ices. However, no dedicated chemical modelling has been carried out thus far to test their efficiency and dependence on the astrochemical code employed. We model the ice chemistry in the Chamaeleon I cloud using a set of astrochemical codes (MAGICKAL, MONACO, Nautilus, UCLCHEM, and KMC simulations) to test the effects of the different code architectures and of the assumed ice chemistry. Our models show that the JWST ice observations are better reproduced for gas densities >1e5 cm-3 and collapse times >1e5 yr. CH3OH ice forms predominantly (>99%) via CO hydrogenation. The contribution of reactions CH3+OH and C+H2O, is negligible. The CO2 ice may form either via CO+OH or CO+O depending on the code. However, KMC simulations reveal that both mechanisms are efficient despite the low rate constant of the CO+O surface reaction. CH4 is largely underproduced for all codes except for UCLCHEM, for which a higher amount of atomic C is available during the initial translucent cloud phase. Large differences in the ice abundances are found at Tdust<12 K between diffusive and non-diffusive chemistry codes. This is due to the fact that non-diffusive chemistry takes over diffusive chemistry at such low Tdust. This could explain the rather constant ice chemical composition found in Chamaeleon I and other dense cores despite the different visual extinctions probed.

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arXiv2025

PDRs4All XI. Detection of infrared CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and disk d203-506: evidence of chemical pumping

The methylidyne cation (CH$^+$) and the methyl cation (CH$_3^+$) are building blocks of organic molecules, yet their coupled formation and excitation mechanisms remain mainly unprobed. The James Webb Space Telescope (JWST), with its high spatial resolution and good spectral resolution, provides unique access to the detection of these molecules. Our goal is to use the first detection of CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and in the protoplanetary disk d203-506, irradiated by the Trapezium cluster, to probe their formation and excitation mechanisms and constrain the physico-chemical conditions. We use spectro-imaging acquired using both the NIRSpec and MIRI-MRS instruments to study the CH$^+$ and CH$_3^+$ spatial distribution at very small scales, and compare it to excited H$_2$ emission. CH$^+$ and CH$_3^+$ emissions originate from the same region as highly excited H$_2$. Our comparison between the Bar and d203-506 reveals that both CH$^+$ and CH$_3^+$ excitation and/or formation are highly dependent on gas density. The excitation temperature of the observed CH$^+$ and CH$_3^+$ rovibrational lines is around $T$ ~ 1500 K in the Bar and $T$ ~ 800 K in d203-506. Moreover, the column densities derived from the rovibrational emission are less than 0.1 % of the total known (CH$^+$) and expected (CH$_3^+$) column densities. These results show that CH$^+$ and CH$_3^+$ level populations strongly deviate from ETL. CH$^+$ rovibrational emission can be explained by chemical formation pumping with excited H$_2$ via C$^+$ + H$_2^*$ = CH$^+$ + H. These results support a gas phase formation pathway of CH$^+$ and CH$_3^+$ via successive hydrogen abstraction reactions. However, we do not find any evidence of CH$_2^+$ emission in the JWST spectrum. Finally, observed CH$^+$ intensities coupled with chemical formation pumping model provide a diagnostic tool to trace the local density.

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arXiv2024

Microscale Hydrogen, Carbon, and Nitrogen Isotopic Diversity of Organic Matter in Asteroid Ryugu

We report the H, C, and N isotopic compositions of microscale (0.2 to 2$μ$m) organic matter in samples of asteroid Ryugu and the Orgueil CI carbonaceous chondrite. Three regolith particles of asteroid Ryugu, returned by the Hayabusa2 spacecraft, and several fragments of Orgueil were analyzed by NanoSIMS isotopic imaging. The isotopic distributions of the Ryugu samples from two different collection spots are closely similar to each other and to the Orgueil samples, strengthening the proposed Ryugu-CI chondrite connection. Most individual sub-$μ$m organic grains have isotopic compositions within error of bulk values, but 2-8% of them are outliers exhibiting large isotopic enrichments or depletions in D, $^{15}$N, and/or $^{13}$C. The H, C and N isotopic compositions of the outliers are not correlated with each other: while some C-rich grains are both D- and $^{15}$N-enriched, many are enriched or depleted in one or the other system. This most likely points to a diversity in isotopic fractionation pathways and thus diversity in the local formation environments for the individual outlier grains. The observation of a relatively small population of isotopic outlier grains can be explained either by escape from nebular and/or parent body homogenization of carbonaceous precursor material or addition of later isotopic outlier grains. The strong chemical similarity of isotopically typical and isotopically outlying grains, as reflected by synchrotron x-ray absorption spectra, suggests a genetic connection and thus favors the former, homogenization scenario. However, the fact that even the least altered meteorites show the same pattern of a small population of outliers on top of a larger population of homogenized grains indicates that some or most of the homogenization occurred prior to accretion of the macromolecular organic grains into asteroidal parent bodies.

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arXiv2024

PDRs4All VIII: Mid-IR emission line inventory of the Orion Bar

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations.

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arXiv2024

A far-ultraviolet-driven photoevaporation flow observed in a protoplanetary disk

Most low-mass stars form in stellar clusters that also contain massive stars, which are sources of far-ultraviolet (FUV) radiation. Theoretical models predict that this FUV radiation produces photo-dissociation regions (PDRs) on the surfaces of protoplanetary disks around low-mass stars, impacting planet formation within the disks. We report JWST and Atacama Large Millimetere Array observations of a FUV-irradiated protoplanetary disk in the Orion Nebula. Emission lines are detected from the PDR; modelling their kinematics and excitation allows us to constrain the physical conditions within the gas. We quantify the mass-loss rate induced by the FUV irradiation, finding it is sufficient to remove gas from the disk in less than a million years. This is rapid enough to affect giant planet formation in the disk.

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arXiv2024

Formation of the Methyl Cation by Photochemistry in a Protoplanetary Disk

Forty years ago it was proposed that gas phase organic chemistry in the interstellar medium was initiated by the methyl cation CH3+, but hitherto it has not been observed outside the Solar System. Alternative routes involving processes on grain surfaces have been invoked. Here we report JWST observations of CH3+ in a protoplanetary disk in the Orion star forming region. We find that gas-phase organic chemistry is activated by UV irradiation.

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arXiv2023

OH as a probe of the warm water cycle in planet-forming disks

Water is a key ingredient for the emergence of life as we know it. Yet, its destruction and reformation in space remains unprobed in warm gas. Here, we detect the hydroxyl radical (OH) emission from a planet-forming disk exposed to external far-ultraviolet (FUV) radiation with the James Webb Space Telescope. The observations are confronted with the results of quantum dynamical calculations. The highly excited OH infrared rotational lines are the tell-tale signs of H2O destruction by FUV. The OH infrared ro-vibrational lines are attributed to chemical excitation via the key reaction O+H=OH+H which seeds the formation of water in the gas-phase. We infer that the equivalent of the Earth ocean's worth of water is destroyed per month and replenished. These results show that under warm and irradiated conditions water is destroyed and efficiently reformed via gas-phase reactions. This process, assisted by diffusive transport, could reduce the HDO/H2O ratio in the warm regions of planet-forming disks.

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