arXiv subjects

Ernst Meyer

Publications and source records attributed to Ernst Meyer.

At least 19 recordsLinked to original sources

arXiv2026

Mechanical detection of sub-band mobilities of two-dimensional electron gas on reduced SrTiO$_3$(001) surface

The two-dimensional electron gas (2DEG) in reduced strontium titanate offers a versatile platform for oxide electronics, yet its dissipation mechanisms under field driven charge fluctuations remain poorly understood. Here, we combine low-temperature atomic force microscopy with scanning tunnelling spectroscopy to probe the force and dissipation responses of a mechanical oscillator interacting with the STO 2DEG. The observation of Rydberg like image potential states by tunnelling experiments confirm the 2DEG formation, while dissipation spectroscopy reveals bias-dependent peaks linked to local electrostatic gating and charge redistribution within the 2DEG energy sub-bands. These features are quantitatively explained by variations in quantum capacitance as carrier density is tuned by electric fields. Under magnetic fields, dissipation peaks obey the Kohler's rule, allowing extraction of carrier mobilities in each sub-band. Our results establish a non-invasive AFM - based methodology for quantifying energy losses in quantum oxides, providing new insights into charge dynamics relevant for spintronic applications.

cond-mat.mtrl-sci↗

arXiv2025

Negative differential conductance in triangular molecular assemblies

We report the creation and characterization of a molecular-scale negative differential conductance (NDC) device by assembling a triangular trimer of 4,5,9,10-tetrabromo-1,3,6,8-tetraazapyrene (TBTAP) molecules on a superconducting Pb(111) substrate. Using low-temperature scanning tunneling spectroscopy, we observe robust NDC behavior manifesting as a decrease in current with increasing voltage between 0.7-0.9 V arising from the interplay of Coulomb blockade and strong inter-molecular capacitive coupling within the molecular cluster. Gate-controlled charging and discharging processes are directly visualized via two-dimensional differential conductance mapping, which reveals the emergence of Coulomb rings and spatial regions of NDC. Theoretical modeling using a three-impurity Anderson model and master equation approach quantitatively reproduces the experimental observations and demonstrates that the NDC emerges purely from electron correlations, independent of the underlying superconductivity. By tuning the geometry to a hexamer structure, we further show that cluster topology provides versatile control over electronic properties at the molecular scale. These results establish a functional platform for implementing multifunctional molecular devices and highlight a strategy toward programmable and scalable nanoelectronics.

cond-mat.mes-hall↗

arXiv2025

Superlubricity of Borophene: Tribological Properties in Comparison to hBN

The tribological performance of 2D materials makes them good candidates toward a reduction of friction at the macroscale. Superlubricity has been observed for graphene, MoS\textsubscript{2} and MXenes and hexagonal boron nitride (hBN) is used to reduce or tune friction, but other materials are investigated as potential candidates for low-lubricity applications. Specifically, borophene is predicted to have ultra-low friction. Here, we experimentally investigate frictional properties of borophene and use a borophene-hBN lateral heterostructure to directly compare the tribological properties of the two complementary 2D materials. In particular, we investigate the friction between a sliding tip and (i) the weakly corrugated $\mathcal{X}_6$-borophene layer on Ir(111) or (ii) the hBN/Ir(111) superlattice structures with a strongly corrugated moir\'e reconstruction. Our experimental study performed in ultra-high vacuum at room temperature combined with a Prandtl-Tomlinson (PT) model calculation confirms the superlubricity predicted for borophene, while hBN, which exhibits a higher friction, is nevertheless confirmed as a low friction material. Ab initio calculations show that the lower friction of $\mathcal{X}_6$-borophene with respect to hBN can be rationalized by weaker tip/surface interactions. In addition, we assess structural and electrical properties of borophene and hBN by using scanning probe techniques and compare their dissipation under the oscillating tip to investigate the possible path of energy dissipation occurring during friction. Our study demonstrates the low frictional properties of borophene and the potential of lateral heterostructure investigations to directly compare the properties of these 2D materials.

cond-mat.mtrl-sci↗

arXiv2024

Spin Excitations of High Spin Iron(II) in Metal-Organic Chains on Metal and Superconductor

Many-body interactions in metal-organic frameworks are fundamental for emergent quantum physics. Unlike their solution counterpart, magnetization at surfaces in low-dimensional analogues is strongly influenced by magnetic anisotropy induced by the substrate and still not well understood. Here, we use on-surface coordination chemistry to synthesize on Ag(111) and superconducting Pb(111) an iron-based spin chain by using pyrene-4,5,9,10-tetraone precursors as ligands. Using low-temperature scanning probe microscopy, we compare their structures and low-energy spin excitations of coordinated Fe atoms with high S = 2 spin-state. Although the chain and coordination centers are identical on both substrates, the long-range spin-spin coupling due to a superexchange through the ligand observed on Ag is absent on Pb(111). We ascribe this reduction of spin-spin interactions on Pb to the depletion of electronic states around the Fermi level in the Pb(111) superconductor as compared to silver.

cond-mat.mtrl-sci↗

arXiv2024

Nanoscale Control of Quantum States in Radical Molecules on Superconducting Pb(111)

Magnetic impurities on superconductors present a viable platform for building advanced applications in quantum technologies. However, a controlled manipulation of their quantum states continues to pose a significant challenge, hindering the progress in the field. Here we show the manipulation of magnetic states in the radical molecule 4,5,9,10-tetrabromo-1,3,6,8-tetraazapyrene (TBTAP) on a Pb(111) superconducting surface using low-temperature scanning tunneling microscopy. Tunneling spectra reveal Yu-Shiba-Rusinov (YSR) states near the Fermi energy in isolated molecules. A quantum phase transition from singlet to doublet ground state is induced by changing the tip-molecule distance. Additionally, the presence of a second TBTAP molecule allows tuning of the YSR state position by altering the relative distance and can induce splitting of the YSR states for certain orientations. The construction of molecular chains up to pentamers shows periodic arrangements of charged and neutral molecules, with even-numbered chains forming a charged dimer structure at one end. Information can be encoded in these chains by switching the dimer position. These findings elucidate interactions between molecular assemblies and superconducting substrates, paving the way for advanced quantum-state engineering.

cond-mat.mes-hall↗

arXiv2024

Probing charge redistribution at the interface of self-assembled cyclo-P5 pentamers on Ag(111)

Phosphorus pentamer (cyclo-P5-) ions are unstable in nature but can be synthesized at the Ag(111) surface. Unlike monolayer black phosphorous, little is known about their electronic properties when in contact with metal electrodes, although this is crucial for future applications. Here we characterize the atomic structure of cyclo-P5 assembled on Ag(111) using atomic force microscopy with functionalized tips and density functional theory. Combining force and tunneling spectroscopy, we find that a strong charge transfer induces an inward dipole moment at the cyclo-P5/Ag interface as well as the formation of an interface state. We probe the image potential states by field-effect resonant tunneling and quantify the increase of the local change of work function of 0.46 eV at the cyclo-P5 assembly. Our results suggest that the high-quality of the cyclo-P5/Ag interface might serve as a prototypical system for electric contacts in phosphorus-based semiconductor devices.

cond-mat.mtrl-sci↗

arXiv2023

Gate-tunable topological superconductivity in a supramolecular electron spin lattice

Topological superconductivity emerges in chains or arrays of magnetic atoms coupled to a superconductor. However, the external controllability of such systems with gate voltages is detrimental for their future implementation in a topological quantum computer. Here we showcase the supramolecular assembly of radical molecules on Pb(111), whose discharge is controlled by the tip of a scanning tunneling microscope. Charged molecules carry a spin-1/2 state, as confirmed by observing Yu-Shiba-Rusinov in-gap states by tunneling spectroscopy at millikelvin temperature. Low energy modes are localized at island boundaries with a long decay towards the interior, whose spectral signature is consistent with Majorana zero modes protected by mirror symmetry. Our results open up a vast playground for the synthesis of gate-tunable organic topological superconductors.

cond-mat.supr-con↗

arXiv2023

Daniel Bernoulli's Research in Basel and the "Physikalisches Kabinett" in the "Stachelschützenhaus"

On 22 September 2023 the inauguration of the "Stachelschützenhaus" at Basel's Petersplatz (St. Peter's Square) as an EPS Historic Site was hosted by the University of Basel. In the following article we will focus first on Daniel Bernoulli's career path, before discussing his major scientific achievements and finally adding some aspects of the inauguration ceremony (the colloquium talks, the visit of today's laboratories in the Stachelschützenhaus, and the unveiling of the plaque).

physics.hist-ph↗

arXiv2023

Atomically precise incorporation of BN doped rubicene into graphene nanoribbons

Substituting heteroatoms and non-benzenoid carbons into nanographene structure offers an unique opportunity for atomic engineering of electronic properties. Here we show the bottom-up synthesis of graphene nanoribbons (GNRs) with embedded fused BN-doped rubicene components on a Au(111) surface using on-surface chemistry. Structural and electronic properties of the BN-GNRs are characterized by scanning tunneling microscopy (STM) and atomic force microscopy (AFM) with CO-terminated tips supported by numerical calculations. The periodic incorporation of BN heteroatoms in the GNR leads to an increase of the electronic band gap as compared to its undoped counterpart. This opens avenues for the rational design of semiconducting GNRs with optoelectronic properties.

cond-mat.mtrl-sci↗

arXiv2022

Energy dissipation from confined states in nanoporous molecular networks

Crystalline nanoporous molecular networks are assembled on the Ag(111) surface, where the pores confine electrons originating from the surface state of the metal. Depending on the pore sizes and their coupling, an antibonding level is shifted upwards by 0.1 to 0.3 eV as measured by scanning tunneling microscopy. On molecular sites, a down-shifted bonding state is observed, which is occupied under equilibrium conditions. Low-temperature force spectroscopy reveals energy dissipation peaks and jumps of frequency shifts at bias voltages, which are related to the confined states. The dissipation maps show delocalization on the supra-molecular assembly and a weak distance-dependence of the dissipation peaks. These observations indicate that two-dimensional arrays of coupled quantum dots are formed, which are quantitatively characterized by their quantum capacitances and resonant tunneling rates. Our work provides a method for studying the capacitive and dissipative response of quantum materials with nanomechanical oscillators.

cond-mat.mtrl-sci↗

arXiv2022

Polygonal tessellations as predictive models of molecular monolayers

Molecular self-assembly plays a very important role in various aspects of technology as well as in biological systems. Governed by the covalent, hydrogen or van der Waals interactions - self-assembly of alike molecules results in a large variety of complex patterns even in two dimensions (2D). Prediction of pattern formation for 2D molecular networks is extremely important, though very challenging, and so far, relied on computationally involved approaches such as density functional theory, classical molecular dynamics, Monte Carlo, or machine learning. Such methods, however, do not guarantee that all possible patterns will be considered and often rely on intuition. Here we introduce a much simpler, though rigorous, hierarchical geometric model founded on the mean-field theory of 2D polygonal tessellations to predict extended network patterns based on molecular-level information. Based on graph theory, this approach yields pattern classification and pattern prediction within well-defined ranges. When applied to existing experimental data, our model provides an entirely new view of self-assembled molecular patterns, leading to interesting predictions on admissible patterns and potential additional phases. While developed for hydrogen-bonded systems, an extension to covalently bonded graphene-derived materials or 3D structures such as fullerenes is possible, significantly opening the range of potential future applications.

cond-mat.mtrl-sci↗

arXiv2022

Proximity-Induced Superconductivity in Atomically Precise Nanographene

Obtaining a robust superconducting state in atomically precise nanographene (NG) structures by proximity to a superconductor could foster the discovery of topological superconductivity in graphene. On-surface synthesis of such NGs has been achieved on noble metals or metal oxides, however, it is still absent on superconductors. Here, we present a synthetic method to induce superconductivity to polymeric chains and NGs adsorbed on the superconducting Nb(110) substrate covered by thin Ag films. Using atomic force microscopy at low-temperature, we characterize the chemical structure of each sub-product formed on the superconducting Ag layer. Scanning tunneling spectroscopy further allows us to elucidate electronic properties of these nanostructures, which consistently show a superconducting gap. We foresee our approach to become a promising platform for exploring the interplay between carbon magnetism and superconductivity at the fundamental level.

cond-mat.supr-con↗

arXiv2019

Band Gap of Atomically Precise Graphene Nanoribbons as a Function of Ribbon Length and Termination

We study the band gap of finite $N_A=7$ armchair graphene nanoribbons (7-AGNRs) on Au(111) through scanning tunneling microscopy/spectroscopy combined with density functional theory calculations. The band gap of 7-AGNRs with lengths of 6 nm and more is converged to within 0.1 eV of its bulk value of 2.3 eV, while the band gap opens by several hundred meV in very short 7-AGNRs. The termination has a significant effect on the band gap, doubly hydrogenated termini yielding a lower band gap than singly hydrogenated ones.

cond-mat.mes-hall↗

arXiv2019

Majorana Fermions in Magnetic Chains

Majorana fermions have recently garnered a great attention outside the field of particle physics, in condensed matter physics. In contrast to their particle physics counterparts, Majorana fermions are zero energy, chargeless, spinless, composite quasiparticles, residing at the boundaries of so-called topological superconductors. Furthermore, in opposition to any particles in the standard model, Majorana fermions in solid-state systems obey non-Abelian exchange statistics that make them attractive candidates for decoherence-free implementations of quantum computers. In this review, we report on the recent advances to realize synthetic topological superconductors supporting Majorana fermions with an emphasis on chains of magnetic impurities on the surface of superconductors. After outlining the theoretical underpinning responsible for the formation of Majorana fermions, we report on the subsequent experimental efforts to build topological superconductors and the resulting evidence in favor of Majorana fermions, focusing on scanning tunneling microscopy and the hunt for zero-bias peaks in the measured current. We conclude by summarizing the open questions in the field and propose possible experimental measurements to answer them.

cond-mat.supr-con↗

arXiv2019

Joule meets van der Waals: Mechanical dissipation via image potential states on a topological insulator surface

Dissipation mechanisms are experimentally studied on topological insulator surfaces of Bi2Te3, where common Joule dissipation was observed to be suppressed due to topologically protected surface states. Thus, a novel type of dissipation mechanism is observed by pendulum AFM, which is related to single electron tunneling resonances into image potential states that are slightly above the Bi2Te3 surface. The application of a magnetic field leads to the break down of the topological protection of the surface states and restores the expected Joule dissipation process. Nanomechanical energy dissipation experienced by the cantilever of pendulum AFM provides a novel source of information on the dissipative nature of the quantum-tunneling phenomena on the topological insulator surface.

cond-mat.mes-hall↗

arXiv2019

Characterization of Hydrogen Plasma Defined Graphene Edges

We investigate the quality of hydrogen plasma defined graphene edges by Raman spectroscopy, atomic resolution AFM and low temperature electronic transport measurements. The exposure of graphite samples to a remote hydrogen plasma leads to the formation of hexagonal shaped etch pits, reflecting the anisotropy of the etch. Atomic resolution AFM reveals that the sides of these hexagons are oriented along the zigzag direction of the graphite crystal lattice and the absence of the D-peak in the Raman spectrum indicates that the edges are high quality zigzag edges. In a second step of the experiment, we investigate hexagon edges created in single layer graphene on hexagonal boron nitride and find a substantial D-peak intensity. Polarization dependent Raman measurements reveal that hydrogen plasma defined edges consist of a mixture of zigzag and armchair segments. Furthermore, electronic transport measurements were performed on hydrogen plasma defined graphene nanoribbons which indicate a high quality of the bulk but a relatively low edge quality, in agreement with the Raman data. These findings are supported by tight-binding transport simulations. Hence, further optimization of the hydrogen plasma etching technique is required to obtain pure crystalline graphene edges.

cond-mat.mes-hall↗

arXiv2018

Transoid-to-Cisoid Conformation Changes of Single Molecules on Surfaces Triggered by Metal Coordination

Conformational isomers are stereoisomers that can interconvert over low potential barriers by rotation around a single bond. However, such bond rotation is hampered by geometrical constraints when molecules are adsorbed on surfaces. Here we show that the adsorption of 4,4'-bis(4-carboxyphenyl)-6,6'-dimethyl-2,2'-bipyridine molecules on surfaces leads to the appearance of pro-chiral single-molecules on NiO(001) and to enantiopure supramolecular domains on Au(111) surfaces containing the $transoid$ molecule conformation. Upon additional Fe adatom deposition, molecules undergo a controlled interconversion from a $transoid$ to $cisoid$ conformation as a result of coordination of the Fe atoms to the 2,2'-bipyridine moieties. As confirmed by atomic force microscopy images and X-ray photoelectron spectroscopy measurements, the resulting molecular structures become irreversibly achiral.

cond-mat.mes-hall↗

arXiv2018

Mechanical dissipation from charge and spin transitions in oxygen deficient SrTiO_3

Bodies in relative motion separated by a gap of a few nanometers can experience a tiny friction force. This non-contact dissipation can have various origins and can be successfully measured by a sensitive pendulum atomic force microscope tip oscillating laterally above the surface. Here, we report on the observation of dissipation peaks at selected voltage-dependent tip-surface distances for oxygen-deficient strontium titanate (SrTiO_3) surface at low temperatures (T = 5K). The observed dissipation peaks are attributed to tip-induced charge and spin state transitions in quantum-dot-like entities formed by single oxygen vacancies (and clusters thereof, possibly through a collective mechanism) at the SrTiO_3 surface, which in view of technological and fundamental research relevance of the material opens important avenues for further studies and applications.

cond-mat.str-el↗