arXiv subjects

Ernst Meyer

Publications and source records attributed to Ernst Meyer.

27 records · Page 2Linked to original sources

arXiv2018

Conformation And Mechanical Response of Spray Deposited Single Strand DNA on Gold

Single molecule force spectroscopy of DNA strands adsorbed at surfaces is a powerful technique used in air or liquid environments to quantify their mechanical properties. Although the force responses are limited to unfolding events so far, single base detection might be possible in more drastic cleanliness conditions such as ultra high vacuum. Here, we report on high resolution imaging and pulling attempts at low temperature (5K) of a single strand DNA (ssDNA) molecules composed of 20 cytosine bases adsorbed on Au(111) by scanning probe microscopy and numerical calculations. Using electrospray deposition technique, the ssDNA were successfully transferred from solution onto a surface kept in ultra high vacuum. Real space characterizations reveal that the ssDNA have an amorphous structure on gold in agreement with numerical calculations. Subsequent substrate annealing promotes the desorption of solvent molecules, DNA as individual molecules as well as the formation of DNA self assemblies. Furthermore, pulling experiments by force spectroscopy have been conducted to measure the mechanical response of the ssDNA while detaching. A periodic pattern of 0.2 to 0.3nm is observed in the force curve which arises from the stick slip of single nucleotide bases over the gold. Although an intra molecular response is obtained in the force curve, a clear distinction of each nucleotide detachment is not possible due the complex structure of ssDNA adsorbed on gold.

cond-mat.soft↗

arXiv2016

CDW slips and giant frictional dissipation peaks at the NbSe$_2$ surface

Accessing, controlling and understanding nanoscale friction and dissipation is a crucial issue in nanotechnology, where moving elements are central. Recently, ultra-sensitive noncontact pendulum Atomic Force Microscope (AFM) succeeded in detecting the electronic friction drop caused by the onset of superconductivity in Nb, raising hopes that a wider variety of mechanisms of mechanical dissipation arising from electron organization into different collective phenomena will become accessible through this unconventional surface probe. Among them, the driven phase dynamics of charge-density-waves (CDWs) represents an outstanding challenge as a source of dissipation. Here we report a striking multiplet of AFM dissipation peaks arising at nanometer distances above the surface of NbSe$_2$ - a layered compound exhibiting an incommensurate CDW. Each peak appears at a well defined tip-surface interaction force of the order of a nN, and persists until T=70K where CDW short-range order is known to disappear. A theoretical model is presented showing that the peaks are connected to tip-induced local 2$π$ CDW phase slips. Under the attractive potential of the approaching tip, the local CDW surface phase landscape deforms continuously until a series of 2$π$ jumps occur between different values of the local phase. As the tip oscillates to and fro, each slip gives rise to a hysteresis cycle, appearing at a selected distance, the dissipation corresponding to "pumping" in and out a local slip in the surface CDW phase of NbSe$_2$.

cond-mat.mes-hall↗

arXiv2016

Superlubricity of Graphene Nanoribbons on Gold Surfaces

The state of vanishing friction known as superlubricity has important applications for energy saving and increasing the lifetime of devices. Superlubricity detected with atomic force microscopy appears in examples like sliding large graphite flakes or gold nanoclusters across surfaces. However, the origin of the behavior is poorly understood due to the lack of a controllable nano-contact. We demonstrate graphene nanoribbons superlubricity when sliding on gold with a joint experimental and computational approach. The atomically well-defined contact allows us to trace the origin of superlubricity, unravelling the role played by edges, surface reconstruction and ribbon elasticity. Our results pave the way to the scale-up of superlubricity toward the realization of frictionless coatings.

cond-mat.mes-hall↗

arXiv2015

Probing Atomic Structure and Majorana Wavefunctions in Mono-Atomic Fe-chains on Superconducting Pb-Surface

Motivated by the striking promise of quantum computation, Majorana bound states (MBSs) in solid-state systems have attracted wide attention in recent years. In particular, the wavefunction localization of MBSs is a key feature and crucial for their future implementation as qubits. Here, we investigate the spatial and electronic characteristics of topological superconducting chains of iron atoms on the surface of Pb(110) by combining scanning tunneling microscopy (STM) and atomic force microscopy (AFM). We demonstrate that the Fe chains are mono-atomic, structured in a linear fashion, and exhibit zero-bias conductance peaks at their ends which we interprete as signature for a Majorana bound state. Spatially resolved conductance maps of the atomic chains reveal that the MBSs are well localized at the chain ends (below 25 nm), with two localization lengths as predicted by theory. Our observation lends strong support to use MBSs in Fe chains as qubits for quantum computing devices.

physics.atm-clus↗

arXiv2014

Plasma cleaning of ITER first mirrors in magnetic field

To avoid reflectivity losses in ITER optical diagnostic systems, plasma sputtering of metallic First Mirrors is foreseen in order to remove deposits coming from the main wall (mainly beryllium and tungsten). Therefore plasma cleaning has to work on large mirrors (up to a size of 200*300 mm) and under the influence of strong magnetic fields (several Tesla). This work presents the results of plasma cleaning of aluminium and aluminium oxide (used as beryllium proxy) deposited on molybdenum mirrors. Using radio frequency (13.56 MHz) argon plasma, the removal of a 260 nm mixed aluminium/aluminium oxide film deposited by magnetron sputtering on a mirror (98 mm diameter) was demonstrated. 50 nm of pure aluminium oxide were removed from test mirrors (25 mm diameter) in a magnetic field of 0.35 T for various angles between the field lines and the mirrors surfaces. The cleaning efficiency was evaluated by performing reflectivity measurements, Scanning Electron Microscopy and X-ray Photoelectron Spectroscopy.

physics.ins-det↗

arXiv2012

A Multi-scale Approach for Simulations of Kelvin Probe Force Microscopy with Atomic Resolution

The distance dependence and atomic-scale contrast observed in nominal contact potential difference (CPD) signals recorded by KPFM on surfaces of insulating and semiconducting samples, have stimulated theoretical attempts to explain such effects. We attack this problem in two steps. First, the electrostatics of the macroscopic tip-cantilever-sample system is treated by a finite-difference method on an adjustable nonuniform mesh. Then the resulting electric field under the tip apex is inserted into a series of atomistic wavelet-based density functional theory (DFT) calculations. Results are shown for a realistic neutral but reactive silicon nano-scale tip interacting with a NaCl(001) sample. Bias-dependent forces and resulting atomic displacements are computed to within an unprecedented accuracy. Theoretical expressions for amplitude modulation (AM) and frequency modulation (FM) KPFM signals and for the corresponding local contact potential differences (LCPD) are obtained by combining the macroscopic and atomistic contributions to the electrostatic force component generated at the voltage modulation frequency, and evaluated for several tip oscillation amplitudes A up to 10 nm. Being essentially constant over a few Volts, the slope of atomistic force versus bias is the basic quantity which determines variations of the atomic-scale LCPD contrast. Already above A = 0.1 nm, the LCPD contrasts in both modes exhibit almost the same spatial dependence as the slope. In the AM mode, this contrast is approximately proportional to $A^{-1/2}$, but remains much weaker than the contrast in the FM mode, which drops somewhat faster as A is increased. These trends are a consequence of the macroscopic contributions to the KPFM signal, which are stronger in the AM-mode and especially important if the sample is an insulator even at sub-nanometer separations where atomic-scale contrast appears.

cond-mat.mtrl-sci↗

arXiv2007

Noncontact atomic force microscopy simulator with phase-locked-loop controlled frequency detection and excitation

A simulation of an atomic force microscope operating in the constant amplitude dynamic mode is described. The implementation mimics the electronics of a real setup including a digital phase-locked loop (PLL). The PLL is not only used as a very sensitive frequency detector, but also to generate the time-dependent phase shifted signal driving the cantilever. The optimum adjustments of individual functional blocks and their joint performance in typical experiments are determined in detail. Prior to testing the complete setup, the performances of the numerical PLL and of the amplitude controller were ascertained to be satisfactory compared to those of the real components. Attention is also focused on the issue of apparent dissipation, that is, of spurious variations in the driving amplitude caused by the nonlinear interaction occurring between the tip and the surface and by the finite response times of the various controllers. To do so, an estimate of the minimum dissipated energy that is detectable by the instrument upon operating conditions is given. This allows us to discuss the relevance of apparent dissipation that can be conditionally generated with the simulator in comparison to values reported experimentally. The analysis emphasizes that apparent dissipation can contribute to the measured dissipation up to 15% of the intrinsic dissipated energy of the cantilever interacting with the surface, but can be made negligible when properly adjusting the controllers, the PLL gains and the scan speed. It is inferred that the experimental values of dissipation usually reported in the literature cannot only originate in apparent dissipation, which favors the hypothesis of "physical" channels of dissipation.

physics.atm-clus↗

arXiv2005

Observation of individual molecules trapped on a nanostructured insulator

For the first time, ordered polar molecules confined in monolayer-deep rectangular pits produced on an alkali halide surface by electron irradiation have been resolved at room temperature by non-contact atomic force microscopy. Molecules self-assemble in a specific fashion inside pits of width smaller than 15 nm. By contrast no ordered aggregates of molecules are observed on flat terraces. Conclusions regarding nucleation and ordering mechanisms are drawn. Trapping in pits as small as 2 nm opens a route to address single molecules.

physics.atm-clus↗

arXiv2005

Distance dependence of force and dissipation in non-contact atomic force microscopy on Cu(100) and Al(111)

The dynamic characteristics of a tip oscillating in the nc-AFM mode in close vicinity to a Cu(100)-surface are investigated by means of phase variation experiments in the constant amplitude mode. The change of the quality factor upon approaching the surface deduced from both frequency shift and excitation versus phase curves yield to consistent values. The optimum phase is found to be independent of distance. The dependence of the quality factor on distance is related to 'true' damping, because artefacts related to phase misadjustment can be excluded. The experimental results, as well as on-resonance measurements at different bias voltages on an Al(111) surface, are compared to Joule dissipation and to a model of dissipation in which long-range forces lead to viscoelastic deformations.

physics.atm-clus↗