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Everett Schlawin

Publications and source records attributed to Everett Schlawin.

At least 19 recordsLinked to original sources

Inhomogeneous Cloud Coverage and Altitude-Dependent Heat Transport on the Hot-Jupiter NGTS-10 Ab from its Optical-to-Infrared Phase Curve

Hot-Jupiters, gas giant planets with equilibrium temperatures above 1,000 K, host large temperature gradients between their permanent day- and nightsides, resulting in circulation regimes that have no Solar System analogs. Past Kepler and Spitzer measurements show that the phase curves of these objects typically peak westward of the substellar point at optical wavelengths and eastward in the infrared, indicative of an interaction between circulation and cloud coverage. However, few hot-Jupiters have joint reflected light and thermal emission measurements, preventing a definitive statement as to the link between these phenomena. Here, we present the first phase curve of a hot-Jupiter that separates thermal emission and reflected light through JWST observations of NGTS-10 Ab with the NIRSpec PRISM instrument ($λ$=0.5-5.5 $μ$m). Using the spectrally-resolved phase curve, we jointly retrieve the planet's thermal and reflected light maps. We show that the temperature and reflectance distributions are anti-correlated, best explained by clouds evaporating from the eastern substellar region ($φ\approx$-17 to 48$^\circ$) where temperatures are highest. This is confirmed by comparisons of the phase-resolved spectra with three-dimensional circulation models, which show that NGTS-10 Ab's atmosphere hosts inhomogeneous cloud coverage, likely made-up of $μ$m-sized silicate particles, and weak atmospheric drag ($τ_\mathrm{drag}\gt 10^6$ s). Finally, by measuring the spectral variation of the thermal phase curve offsets, we infer a slope of 7.1$\pm$1.9 degrees per pressure dex, indicative of heat transport that becomes more efficient at depth. Future optical and infrared hot-Jupiter phase curve measurements over a wide range of equilibrium temperatures will enable a complete mapping of the interplay between heat transport and cloud formation in highly-irradiated exoplanet atmospheres.

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The Lazuli Space Observatory: Architecture & Capabilities

The Lazuli Space Observatory is a 3-meter aperture astronomical facility designed for rapid-response observations and precision astrophysics across visible to near-infrared wavelengths (400-1700 nm bandpass). An off-axis, freeform telescope delivers diffraction-limited image quality (Strehl $>$0.8 at 633 nm) to three instruments across a wide, flat focal plane. The three instruments provide complementary capabilities: a Wide-field Context Camera (WCC) delivers multi-band imaging over a 35' $\times$ 12' footprint with high-cadence photometry; an Integral Field Spectrograph (IFS) provides continuous 400-1700 nm spectroscopy at R $\sim$ 100-500 for stable spectrophotometry; and an ExtraSolar Coronagraph (ESC) enables high-contrast imaging expected to reach raw contrasts of $10^{-8}$ and post-processed contrasts approaching $10^{-9}$. Operating from a 3:1 lunar-resonant orbit, Lazuli will respond to targets of opportunity in under four hours--a programmatic requirement designed to enable routine temporal responsiveness that is unprecedented for a space telescope of this size. Lazuli's technical capabilities are shaped around three broad science areas: (1) time-domain and multi-messenger astronomy, (2) stars and planets, and (3) cosmology. These capabilities enable a potent mix of science spanning gravitational wave counterpart characterization, fast-evolving transients, Type Ia supernova cosmology, high-contrast exoplanet imaging, and spectroscopy of exoplanet atmospheres. While these areas guide the observatory design, Lazuli is conceived as a general-purpose facility capable of supporting a wide range of astrophysical investigations, with open time for the global community. We describe the observatory architecture and capabilities in the preliminary design phase, with science operations anticipated following a rapid development cycle from concept to launch. [Abstract abridged]

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The Identification of CS2 and Evidence for Carbon-Sulfur Chemical Coupling in a Warm Giant Exoplanet Atmosphere

Transmission spectroscopy with the James Webb Space Telescope (JWST) is revealing growing chemical complexity in giant exoplanet atmospheres. Of particular interest is sulfur, which had essentially no observational constraints before JWST. Recent work has shown that a planet's atmospheric sulfur content traces its refractory budget and is therefore a sensitive indicator of formation pathways. But despite the growing library of JWST data, the sulfur inventory of giant exoplanets remains poorly constrained: sulfur-bearing species are governed by disequilibrium chemistry and by kinetic networks that are still being revised. Here we present a transmission spectrum of the warm giant planet WASP-80 b obtained with JWST/NIRCam and MIRI over 2.4 $μ$m--10$μ$m in three transits. We uniquely identify CS$_2$ in our transmission spectrum using the combination of the two absorption features in NIRCam and MIRI at a significance of $\ln (B)=17.89$ ($σ= 6.3$). Our grid-based retrievals yield $\mathrm{[M/H] = \:} 0.54^{+0.17}_{-0.12}$ and $\mathrm{C/O =\:}0.43^{+0.12}_{-0.08}$ which result in $\log(\mathrm{X_{CS_2}})$ abundances of $\sim-4.5$. The latest carbon-sulfur kinetics networks produce substantially greater amounts of CS$_2$ than past works, enabling good fits ($χ^2/\mathrm{N_{data}}\sim1.2$) to the data without invoking extreme abundance patterns. These results identify CS$_2$ as an observable tracer of sulfur disequilibrium chemistry and provide observational support for theoretically predicted carbon-sulfur chemical coupling in giant exoplanet atmospheres.

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Breaking the brightness barrier: JWST/NIRCam DHS spectroscopy for high-precision time-series observations

Many of the most scientifically compelling exoplanets orbit bright nearby stars that exceed the brightness limits of existing JWST spectroscopic observing modes. To address this limitation, a new NIRCam Short Wavelength Grism Time-Series mode has been developed by combining the Dispersed Hartmann Sensor (DHS) with a new on-board multistripe detector readout capability. The DHS disperses the incoming light through multiple pupil sub-apertures, reducing the incident flux and providing slitless spectroscopy between approximately 1.0 and 2.3 um. The multistripe readout mode further increases the accessible brightness range (K ~ 2.5 - 5.7 mag, depending on the spectral type of the object), with the previous limit being K ~ 5.7 mag at 1.5 um, by reading only the detector regions containing the DHS spectra, reducing the detector frame time with the standard RAPID readout mode from 10.74 s to 1.36 s over even less when using smaller substripe sizes. Together with the simultaneous long-wavelength grism observations, the new mode provides spectroscopic continuous coverage from approximately 1.0 to 5.0 um for targets as bright as K ~ 2.5 mag. We present the first results of on-orbit commissioning of this new observing mode with the final stage consisting of observations of a full transit of the exoplanet WASP-18b, which allowed us to demonstrate the feasibility of using NIRCam DHS for high-precision time-series observations. The commissioning presented in this paper marks the first deployment of the multistripe detector readout on JWST. Beyond NIRCam DHS, this new capability will be extended to other spectroscopic modes, including NIRISS SOSS and NIRSpec PRISM. Bright nearby stars host many of the highest-priority targets for exoplanet atmospheric characterization, making multistripe an important new capability for maximizing the scientific return of JWST.

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Horizontal transport as a source of disequilibrium chemistry on the nightside of a hot exoplanet

Hot Jupiters have temperature gradients of several hundreds of degrees between their permanent day and nightsides. In equilibrium, the primary carbon reservoir is expected to transition from CO on the dayside to CH4 on the nightside. Theory predicts that the atmospheric circulation, characterised by km/s winds, can advect chemical species from the dayside to the nightside faster than the time needed for the CO-to-CH4 chemical reaction to reach equilibrium. However direct evidence of this process has, so far, remained elusive, partly because it is often degenerate with other processes, such as vertical mixing or non-stellar elemental abundances. Here, we present observational evidence for such day-to-night transport of chemical species by observing both the dayside and the nightside of the hot Jupiter NGTS-10A b with the JWST/NIRSpec instrument. We constrain the presence of H2O and CO with similar abundances on both the dayside and nightside. Our observations are compatible with a solar-composition atmosphere at chemical equilibrium on the dayside, but indicative of disequilibrium chemistry for the nightside as it is significantly depleted in CH4 compared to equilibrium chemistry predictions. We further show that the lack of CH4 on the planet's nightside cannot be attributed to non-solar elemental abundances or to vertical mixing mechanisms and must therefore be due to horizontal chemical quenching. Our study shows the fundamental role atmospheric transport plays in shaping the distribution of chemical species on exoplanet atmospheres.

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The tale of the 3 planets: 3D cloud feedback enhances the spectral diversity of warm Jupiters

JWST has shown a large diversity in warm Jupiter spectra, despite only small variations in the planetary parameters. However, the main driver of this diversity remains unclear. We aim to identify the mechanisms responsible for the spectral difference of three warm Jupiter-size exoplanets observed by JWST: whereas WASP-80b appears mostly cloud-free, both WASP-107b and WASP-69b have spectra dominated by clouds. We model each planet using the same framework, ADAM (formerly SPARC/MITgcm), which solves for the interactions among cloud transport, radiative transfer, and atmospheric circulation in 3D. We investigate the role of three condensate species, Na$_2$S, KCl, and MgSiO$_3$, and four particle sizes (0.1, 1, 5, and 10 $μ$m). Clouds settle deeper in the atmosphere of the higher-gravity planet WASP-80b than in WASP-107b, reproducing their spectral difference naturally. For WASP-107b, three clouds can reproduce the NIRCam observations: 5 $μ$m Na$_2$S, 1 $μ$m KCl, and 5 $μ$m MgSiO$_3$ models. However, these cannot match the scattering slope observed at shorter wavelengths in NIRISS and the possible silicate feature in the MIRI bandpass, suggesting a multi-modal distribution of clouds. Our model predicts that small silicate particles should be homogeneously distributed and thus cannot account for the difference between the two limb spectra in the MIRI bandpass. Finally, applying the same model to WASP-69b does not yield a partially cloudy dayside solution that fits the emission spectra, as proposed in a previous study. Coupling among 3D circulation, clouds, and radiative transfer can enhance the spectral diversity of warm Jupiter exoplanets, particularly through changes in cloudiness with gravity. The combination of multi-phase, wide-wavelength coverage and models that couple clouds, circulation, and radiative transfer is key to advancing our understanding of these new objects.

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Cloudy solutions for the clear skies of WASP-80b: 3D cloud feedback on the atmosphere and spectra of a warm Jupiter

Close-in warm Jupiters orbiting M dwarf stars are expected to exhibit diverse atmospheric chemistry, with clouds playing a key role in shaping their albedo, heat distribution, and spectral properties. We study WASP-80b, a warm Jupiter orbiting an M dwarf star, using the latest JWST panchromatic emission and transmission spectra to comprehensively characterise its atmosphere, including cloud coverage, chemical composition, and particle sizes, and compare the observations with predictions from the general circulation models (GCMs). We used a GCM, ADAM (ADvanced Atmospheric MITgcm, formerly known as SPARC/MITgcm), combined with the latest JWST data to study the atmosphere of WASP-80b. A cloud module with radiatively active, tracer-based clouds was integrated with the GCM to study the effects on the atmosphere and the spectrum. We find that the emission and transmission spectra of WASP-80b are only compatible with cloudless atmospheres or with clouds composed of sufficiently large particles, namely Na$_2$S ($\geq 10 μ$m), KCl ($\geq 1 μ$m), and MgSiO$_3$ ($\geq 5 μ$m). For these large-particle cloud cases, efficient gravitational settling confines the clouds to deeper atmospheric layers, resulting in weak spectral signatures. Smaller particles are ruled out due to their strong radiative feedback on the atmospheric structure. Overall, our results suggest that WASP-80b's atmosphere is either effectively cloud-free or contains clouds composed of large, settled particles whose opacity has little impact on the observable atmosphere. This underscores the importance of particle size and vertical cloud distribution in interpreting exoplanet spectra. Future observations at shorter wavelengths may help distinguish between large-particle cloud scenarios and a truly cloudless atmosphere.

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Horizontal and vertical exoplanet thermal structure from a JWST spectroscopic eclipse map

Highly-irradiated giant exoplanets known as "ultra-hot Jupiters" are anticipated to exhibit large variations of atmospheric temperature and chemistry as a function of longitude, latitude, and altitude. Previous observations have hinted at these variations, but the existing data have been fundamentally restricted to probing hemisphere-integrated spectra, thereby providing only coarse information on atmospheric gradients. Here we present a spectroscopic eclipse map of an extrasolar planet, resolving the atmosphere in multiple dimensions simultaneously. We analyze a secondary eclipse of the ultra-hot Jupiter WASP-18b observed with the NIRISS instrument on JWST. The mapping reveals weaker longitudinal temperature gradients than were predicted by theoretical models, indicating the importance of hydrogen dissociation and/or nightside clouds in shaping global thermal emission. Additionally, we identify two thermally distinct regions of the planet's atmosphere: a "hotspot" surrounding the substellar point and a "ring" near the dayside limbs. The hotspot region shows a strongly inverted thermal structure due to the presence of optical absorbers and a water abundance marginally lower than the hemispheric average, in accordance with theoretical predictions. The ring region shows colder temperatures and poorly constrained chemical abundances. Similar future analyses will reveal three-dimensional thermal, chemical, and dynamical properties of a broad range of exoplanet atmospheres.

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A Precise Metallicity and Carbon-to-Oxygen Ratio for a Warm Giant Exoplanet from its Panchromatic JWST Emission Spectrum

WASP-80 b, a warm sub-Jovian (equilibrium temperature ~820 K, 0.5 Jupiter masses), presents an opportunity to characterize a rare gas giant exoplanet around a low-mass star. In addition, its moderate temperature enables its atmosphere to host a range of carbon and oxygen species (H$_2$O, CH$_4$, CO, CO$_2$, NH$_3$). In this paper, we present a panchromatic emission spectrum of WASP-80 b, the first gas giant around a late K/early M-dwarf star and the coolest planet for which the James Webb Space Telescope has obtained a complete emission spectrum spanning 2.4-12 $μ$m, including NIRCam F322W2 (2.4-4 $μ$m) and F444W (4-5 $μ$m), and MIRI LRS (5-12 $μ$m). We report confident detections of H$_2$O, CH$_4$, CO, and CO$_2$, and a tentative detection of NH$_3$. We estimate WASP-80 b's atmospheric metallicity and carbon-to-oxygen ratio and compare them with estimates for other gas giants. Despite the relative rarity of giant planets around low-mass stars, we find that WASP-80 b's composition is consistent with other hot gas giants, suggesting that the formation pathway of WASP-80 b may not be dissimilar from hot gas giants around higher-mass stars.

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A Panchromatic Characterization of the Evening and Morning Atmosphere of WASP-107 b: Composition and Cloud Variations, and Insight into the Effect of Stellar Contamination

Limb-resolved transmission spectroscopy has the potential to transform our understanding of exoplanetary atmospheres. By separately measuring the transmission spectra of the evening and morning limbs, these atmospheric regions can be individually characterized, shedding light into the global distribution and transport of key atmospheric properties from transit observations alone. In this work, we follow up the recent detection of limb asymmetry on the exoplanet WASP-107 b (Murphy et al. 2024) by reanalyzing literature observations of WASP-107 b using all of JWST's science intruments (NIRISS, NIRCam, NIRSpec, and MIRI) to measure its limb transmission spectra from $\sim$1-12 $μ$m. We confirm the evening--morning temperature difference inferred previously and find that it is qualitatively consistent with predictions from global circulation models. We find evidence for evening--morning variation in SO$_2$ and CO$_2$ abundance, and significant cloud coverage only on WASP-107 b's morning limb. We find that the NIRISS and NIRSpec observations are potentially contaminated by occulted starspots, which we leverage to investigate stellar contamination's impact on limb asymmetry measurements. We find that starspot crossings can significantly bias the inferred evening and morning transmission spectra depending on when they occur during the transit, and develop a simple correction model which successfully brings these instruments' spectra into agreement with the uncontaminated observations.

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A JWST Panchromatic Thermal Emission Spectrum of the Warm Neptune Archetype GJ 436b

GJ 436b is the archetype warm Neptune exoplanet. The planet's thermal emission spectrum was previously observed via intensive secondary eclipse campaigns with Spitzer. The atmosphere has long been interpreted to be extremely metal-rich, out of chemical equilibrium, and potentially tidally heated. We present the first panchromatic emission spectrum of GJ 436b observed with JWST's NIRCAM (F322W2 and F444W) and MIRI (LRS) instruments between 2.4 and 11.9 $μ$m. Surprisingly, the JWST spectrum appears significantly fainter around 3.6 $μ$m than that implied by Spitzer photometry. The molecular absorption features in the spectrum are relatively weak, and we only find tentative evidence of CO$_2$ absorption at 2$σ$ significance. Under the assumption of a day-side blackbody, we find $T_{\rm day}$=662.8$\pm$5.0 K, which is similar to the zero Bond albedo equilibrium temperature. We use it to obtain a 3$σ$ upper limit on the Bond albedo of $A_B{\le}$0.66. To understand the spectrum we employ 1D radiative-convective models but find that atmospheric constraints depend strongly on model assumptions. If thermochemical equilibrium is assumed, we find a cloudy metal-enriched atmosphere (metallicity $\ge$ 300$\times$solar). We employ 1D photochemical modeling to show that the observed spectrum is also consistent with a cloud-free, relatively lower-metallicity atmosphere (metallicity $\ge$ 80$\times$solar) with a cold internal temperature ($T_{\rm int}$$\sim$60 K). These are much lower metallicities and internal temperatures than inferences from Spitzer photometry. The low $T_{\rm day}$ and non-detection of transmission features at high spectral resolution does suggest a role for cloud opacity, but this is not definitive.

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A Possible Metal-Dominated Atmosphere Below the Thick Aerosols of GJ 1214 b Suggested by its JWST Panchromatic Transmission Spectrum

GJ1214b is the archetype sub-Neptune for which thick aerosols have prevented us from constraining its atmospheric properties for over a decade. In this study, we leverage the panchromatic transmission spectrum of GJ1214b established by HST and JWST to investigate its atmospheric properties using a suite of atmospheric radiative transfer, photochemistry, and aerosol microphysical models. We find that the combined HST, JWST/NIRSpec and JWST/MIRI spectrum can be well-explained by atmospheric models with an extremely high metallicity of [M/H]$\sim$3.5 and an extremely high haze production rate of $F_{\rm haze}{\sim}10^{-8}$--$10^{-7}$ g cm$^{-2}$ s$^{-1}$. Such high atmospheric metallicity is suggested by the relatively strong CO2 feature compared to the haze absorption feature or the CH4 feature in the NIRSpec-G395H bandpass of 2.5--5 $μ$m. The flat 5--12 $μ$m MIRI spectrum also suggests a small scale height with a high atmospheric metallicity that is needed to suppress a prominent 6 $μ$m haze feature. We tested the sensitivity of our interpretation to various assumptions for uncertain haze properties, such as optical constants and production rate, and all models tested here consistently suggest extremely high metallicity. Thus, we conclude that GJ1214b likely has a metal-dominated atmosphere where hydrogen is no longer the main atmospheric constituent. We also find that different assumptions for the haze production rate lead to distinct inferences for the atmospheric C/O ratio. We stress the importance of high precision follow-up observations to confirm the metal-dominated atmosphere and to constrain the C/O ratio, which provides further insights on the planet formation process. The confirmation of the metal-dominated atmosphere is particularly crucial, as it challenges the conventional understanding of interior structure and evolution of sub-Neptunes.

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Evidence for Morning-to-Evening Limb Asymmetry on the Cool Low-Density Exoplanet WASP-107b

The atmospheric properties of hot exoplanets are expected to be different between the morning and the evening limb due to global atmospheric circulation. Ground-based observations at high spectral resolution have detected this limb asymmetry in several ultra-hot (>2000 K) exoplanets, but the prevalence of the phenomenon in the broader exoplanetary population remains unexplored. Here we use JWST/NIRCam transmission spectra between 2.5 and 4.0 $μ$m to find evidence of limb asymmetry on exoplanet WASP-107 b. With its equilibrium temperature of 770 K and low density of 0.126 gm c$^{-3}$, WASP-107 b probes a very different regime compared to ultra-hot giant planets and was not expected to exhibit substantial spatial heterogeneity according to atmospheric models. We infer instead a morning-evening temperature difference on the order of 100 K with a hotter evening limb. Further observations on other cooler exoplanets are needed to determine whether WASP-107 b is an outlier or the models underestimate the presence of limb asymmetry in exoplanets.

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Possible Carbon Dioxide Above the Thick Aerosols of GJ 1214 b

Sub-Neptune planets with radii smaller than Neptune (3.9 Re) are the most common type of planet known to exist in The Milky Way, even though they are absent in the Solar System. These planets can potentially have a large diversity of compositions as a result of different mixtures of rocky material, icy material and gas accreted from a protoplanetary disk. However, the bulk density of a sub-Neptune, informed by its mass and radius alone, cannot uniquely constrain its composition; atmospheric spectroscopy is necessary. GJ 1214 b, which hosts an atmosphere that is potentially the most favorable for spectroscopic detection of any sub-Neptune, is instead enshrouded in aerosols (thus showing no spectroscopic features), hiding its composition from view at previously observed wavelengths in its terminator. Here, we present a JWST NIRSpec transmission spectrum from 2.8 to 5.1 um that shows signatures of carbon dioxide and methane, expected at high metallicity. A model containing both these molecules is preferred by 3.3 and 3.6 sigma as compared to a featureless spectrum for two different data analysis pipelines, respectively. Given the low signal-to-noise of the features compared to the continuum, however, more observations are needed to confirm the carbon dioxide and methane signatures and better constrain other diagnostic features in the near-infrared. Further modeling of the planet's atmosphere, interior structure and origins will provide valuable insights about how sub-Neptunes like GJ 1214 b form and evolve.

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Toward Exoplanet Transit Spectroscopy Using JWST/MIRI's Medium Resolution Spectrometer

The Mid-Infrared Instrument (MIRI)'s Medium Resolution Spectrometer (the MRS) on JWST has potentially important advantages for transit and eclipse spectroscopy of exoplanets, including lack of saturation for bright host stars, wavelength span to longward of 20 microns, and JWST's highest spectral resolving power. We here test the performance of the MRS for time series spectroscopy by observing the secondary eclipse of the bright stellar eclipsing binary R Canis Majoris. Our observations push the MRS into saturation at the shortest wavelength, more than for any currently known exoplanet system. We find strong charge migration between pixels that we mitigate using a custom data analysis pipeline. Our data analysis recovers much of the spatial charge migration by combining detector pixels at the group level, via weighting by the point spread function. We achieve nearly photon-limited performance in time series data at wavelengths longward of 5.2 microns. In 2017, Snellen et al. suggested that the MRS could be used to detect carbon dioxide absorption from the atmosphere of the temperate planet orbiting Proxima Centauri. We infer that the relative spectral response of the MRS versus wavelength is sufficiently stable to make that detection feasible. As regards the secondary eclipse of this Algol-type binary, we measure the eclipse depth by summing our spectra over the wavelengths in four channels, and also measuring the eclipse depth as observed by TESS. Those eclipse depths require a temperature for the secondary star that is significantly hotter than previous observations in the optical to near-IR, probably due to irradiation by the primary star. At full spectral resolution of the MRS, we find atomic hydrogen recombination emission lines in the secondary star, from principal quantum levels n = 7, 8, 10, and 14.

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Hydrogen sulfide and metal-enriched atmosphere for a Jupiter-mass exoplanet

As the closest transiting hot Jupiter to Earth, HD 189733b has been the benchmark planet for atmospheric characterization. It has also been the anchor point for much of our theoretical understanding of exoplanet atmospheres from composition, chemistry, aerosols to atmospheric dynamics, escape, and modeling techniques. Prior studies of HD 189733b have detected carbon and oxygen-bearing molecules H2O and CO in the atmosphere. The presence of CO2 and CH4 has been claimed but later disputed. The inferred metallicity based on these measurements, a key parameter in tracing planet formation locations, varies from depletion to enhancement, hindered by limited wavelength coverage and precision of the observations. Here we report detections of H2O (13.4 sigma), CO2 (11.2 sigma), CO (5 sigma), and H2S (4.5 sigma) in the transmission spectrum (2.4-5 micron) of HD 189733b. With an equilibrium temperature of ~1200K, H2O, CO, and H2S are the main reservoirs for oxygen, carbon, and sulfur. Based on the measured abundances of these three major volatile elements, we infer an atmospheric metallicity of 3-5 times stellar. The upper limit on the methane abundance at 5 sigma is 0.1 ppm which indicates a low carbon-to-oxygen ratio (<0.2), suggesting formation through the accretion of water-rich icy planetesimals. The low oxygen-to-sulfur and carbon-to-sulfur ratios also support the planetesimal accretion formation pathway.

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Multiple Clues for Dayside Aerosols and Temperature Gradients in WASP-69 b from a Panchromatic JWST Emission Spectrum

WASP-69 b is a hot, inflated, Saturn-mass planet 0.26 Mjup with a zero-albedo equilibrium temperature of 963 K. Here, we report the JWST 2 to 12 um emission spectrum of the planet consisting of two eclipses observed with NIRCam grism time series and one eclipse observed with MIRI LRS. The emission spectrum shows absorption features of water vapor, carbon dioxide and carbon monoxide, but no strong evidence for methane. WASP-69 b's emission spectrum is poorly fit by cloud-free homogeneous models. We find three possible model scenarios for the planet: 1) a Scattering Model that raises the brightness at short wavelengths with a free Geometric Albedo parameter 2) a Cloud Layer model that includes high altitude silicate aerosols to moderate long wavelength emission and 3) a Two-Region model that includes significant dayside inhomogeneity and cloud opacity with two different temperature-pressure profiles. In all cases, aerosols are needed to fit the spectrum of the planet. The Scattering model requires an unexpectedly high Geometric Albedo of 0.64. Our atmospheric retrievals indicate inefficient redistribution of heat and an inhomogeneous dayside distribution, which is tentatively supported by MIRI LRS broadband eclipse maps that show a central concentration of brightness. Our more plausible models (2 and 3) retrieve chemical abundances enriched in heavy elements relative to solar composition by 6x to 14x solar and a C/O ratio of 0.65 to 0.94, whereas the less plausible highly reflective scenario (1) retrieves a slightly lower metallicity and lower C/O ratio.

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Sulfur Dioxide and Other Molecular Species in the Atmosphere of the Sub-Neptune GJ 3470 b

We report observations of the atmospheric transmission spectrum of the sub-Neptune exoplanet GJ 3470 b taken using the Near-Infrared Camera (NIRCam) on JWST. Combined with two archival HST/WFC3 transit observations and fifteen archival Spitzer transit observations, we detect water, methane, sulfur dioxide, and carbon dioxide in the atmosphere of GJ 3470 b, each with a significance of >3-sigma. GJ 3470 b is the lowest mass -- and coldest -- exoplanet known to show a substantial sulfur dioxide feature in its spectrum, at $M_{p}$=11.2${\,{\rm M}_{\oplus}}$ and $T_{eq}$=600$\,$K. This indicates disequilibrium photochemistry drives sulfur dioxide production in exoplanet atmospheres over a wider range of masses and temperatures than has been reported or expected. The water, carbon dioxide, and sulfur dioxide abundances we measure indicate an atmospheric metallicity of approximately $100\times$ Solar. We see further evidence for disequilibrium chemistry in our inferred methane abundance, which is significantly lower than expected from equilibrium models consistent with our measured water and carbon dioxide abundances.

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