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Ewine F. van Dishoeck

Publications and source records attributed to Ewine F. van Dishoeck.

At least 181 records · Page 10Linked to original sources

Cosmic-ray induced destruction of CO in star-forming galaxies

We explore the effects of the expected higher cosmic ray (CR) ionization rates $ζ_{\rm CR}$ on the abundances of carbon monoxide (CO), atomic carbon (C), and ionized carbon (C$^+$) in the H$_2$ clouds of star-forming galaxies. The study of Bisbas et al. (2015) is expanded by: a) using realistic inhomogeneous Giant Molecular Cloud (GMC) structures, b) a detailed chemical analysis behind the CR-induced destruction of CO, and c) exploring the thermal state of CR-irradiated molecular gas. CRs permeating the interstellar medium with $ζ_{\rm CR}$$\gtrsim 10\times$(Galactic) are found to significantly reduce the [CO]/[H$_2$] abundance ratios throughout the mass of a GMC. CO rotational line imaging will then show much clumpier structures than the actual ones. For $ζ_{\rm CR}$$\gtrsim 100\times$(Galactic) this bias becomes severe, limiting the utility of CO lines for recovering structural and dynamical characteristics of H$_2$-rich galaxies throughout the Universe, including many of the so-called Main Sequence (MS) galaxies where the bulk of cosmic star formation occurs. Both C$^+$ and C abundances increase with rising $ζ_{\rm CR}$, with C remaining the most abundant of the two throughout H$_2$ clouds, when $ζ_{\rm CR}\sim (1-100)\times$(Galactic). C$^+$ starts to dominate for $ζ_{\rm CR}$$\gtrsim 10^3\times$(Galactic). The thermal state of the gas in the inner and denser regions of GMCs is invariant with $T_{\rm gas}\sim 10\,{\rm K}$ for $ζ_{\rm CR}\sim (1-10)\times$(Galactic). For $ζ_{\rm CR}$$\sim 10^3\times$(Galactic) this is no longer the case and $T_{\rm gas}\sim 30-50\,{\rm K}$ are reached. Finally we identify OH as the key species whose $T_{\rm gas}-$sensitive abundance could mitigate the destruction of CO at high temperatures.

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An ALMA survey of DCN/H$^{13}$CN and DCO$^+$/H$^{13}$CO$^+$ in protoplanetary disks

The deuterium enrichment of molecules is sensitive to their formation environment. Constraining patterns of deuterium chemistry in protoplanetary disks is therefore useful for probing how material is inherited or reprocessed throughout the stages of star and planet formation. We present ALMA observations at $\sim0.6"$ resolution of DCO$^+$, H$^{13}$CO$^+$, DCN, and H$^{13}$CN in the full disks around T Tauri stars AS 209 and IM Lup, the transition disks around T Tauri stars V4046 Sgr and LkCa 15, and the full disks around Herbig Ae stars MWC 480 and HD 163296. We also present ALMA observations of HCN in the IM Lup disk. DCN, DCO$^+$, and H$^{13}$CO$^+$ are detected in all disks, and H$^{13}$CN in all but the IM Lup disk. We find efficient deuterium fractionation for the sample, with estimates of disk-averaged DCO$^+$/HCO$^+$ and DCN/HCN abundance ratios ranging from $\sim0.02-0.06$ and $\sim0.005-0.08$, respectively, which is comparable to values reported for other ISM environments. The relative distributions of DCN and DCO$^+$ vary between disks, suggesting that multiple formation pathways may be needed to explain the diverse emission morphologies. In addition, gaps and rings observed in both H$^{13}$CO$^+$ and DCO$^+$ emission provide new evidence that DCO$^+$ bears a complex relationship with the location of the midplane CO snowline.

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CO2 infrared emission as a diagnostic of planet-forming regions of disks

[Abridged] The infrared ro-vibrational emission lines from organic molecules in the inner regions of protoplanetary disks are unique probes of the physical and chemical structure of planet forming regions and the processes that shape them. The non-LTE excitation effects of carbon dioxide (CO2) are studied in a full disk model to evaluate: (i) what the emitting regions of the different CO2 ro-vibrational bands are; (ii) how the CO2 abundance can be best traced using CO2 ro-vibrational lines using future JWST data and; (iii) what the excitation and abundances tell us about the inner disk physics and chemistry. CO2 is a major ice component and its abundance can potentially test models with migrating icy pebbles across the iceline. A full non-LTE CO2 excitation model has been built. The characteristics of the model are tested using non-LTE slab models. Subsequently the CO2 line formation has been modelled using a two-dimensional disk model representative of T-Tauri disks. The CO2 gas that emits in the 15 $μ$m and 4.5 $μ$m regions of the spectrum is not in LTE and arises in the upper layers of disks, pumped by infrared radiation. The v$_2$ 15 $μ$m feature is dominated by optically thick emission for most of the models that fit the observations and increases linearly with source luminosity. Its narrowness compared with that of other molecules stems from a combination of the low rotational excitation temperature (~250 K) and the inherently narrower feature for CO2. The inferred CO2 abundances derived for observed disks are more than two orders of magnitude lower than those in interstellar ices (~10$^5$), similar to earlier LTE disk estimates. Line-to-continuum ratios are low, of order a few %, thus high signal-to-noise (S/N > 300) observations are needed for individual line detections. Prospects of accurate abundance retreival with JWST-MIRI and JWST-NIRSpec are discussed.

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Physical Properties of Molecular Clouds at 2 parsec Resolution in the Low-Metallicity Dwarf Galaxy NGC 6822 and the Milky Way

We present the ALMA survey of CO(2-1) emission from the 1/5 solar metallicity, Local Group dwarf galaxy NGC 6822. We achieve high (0.9 arcsec ~ 2 pc) spatial resolution while covering large area: four 250 pc x 250 pc regions that encompass ~2/3 of NGC 6822's star formation. In these regions, we resolve ~150 compact CO clumps that have small radii (~2-3 pc), narrow line width (~1 km/s), and low filling factor across the galaxy. This is consistent with other recent studies of low metallicity galaxies, but here shown with a 15 times larger sample. At parsec scales, CO emission correlates with 8 micron emission better than with 24 micron emission and anti-correlates with Halpha, so that PAH emission may be an effective tracer of molecular gas at low metallicity. The properties of the CO clumps resemble those of similar-size structures in Galactic clouds except of slightly lower surface brightness and CO-to-H2 ratio ~1-2 times the Galactic value. The clumps exist inside larger atomic-molecular complexes with masses typical for giant molecular cloud. Using dust to trace H2 for the entire complex, we find CO-to-H2 to be ~20-25 times the Galactic value, but with strong dependence on spatial scale and variations between complexes that may track their evolutionary state. The H2-to-HI ratio is low globally and only mildly above unity within the complexes. The SFR-to-H2 ratio is ~3-5 times higher in the complexes than in massive disk galaxies, but after accounting for the bias from targeting star-forming regions, we conclude that the global molecular gas depletion time may be as long as in massive disk galaxies.

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Lupus disks with faint CO isotopologues: low gas/dust or large carbon depletion?

An era has started in which gas and dust can be observed independently in protoplanetary disks, thanks to the recent surveys with ALMA. The first near-complete high-resolution disk survey in both dust and gas in a single star-forming region has been carried out in Lupus, finding surprisingly low gas/dust ratios. The goal of this work is to fully exploit CO isotopologues observations in Lupus, comparing them with physical-chemical model results, in order to obtain gas masses for a large number of disks. We have employed physical-chemical models to analyze continuum and CO isotopologues observations of Lupus disks, including isotope-selective processes and freeze-out. Employing also the ALMA 13CO-only detections, disk gas masses have been calculated for a total of 34 sources, expanding the sample of 10 disks studied by Ansdell et al. (2016), where also C18O was detected. We confirm that overall gas-masses are very low, often smaller than 1 $M_{\rm J}$, if volatile carbon is not depleted. Accordingly, global gas/dust ratios predominantly between 1 and 10. Low CO-based gas masses and gas/dust ratios may indicate rapid loss of gas, or alternatively chemical evolution, e.g. via sequestering of carbon from CO to more complex molecules, or carbon locked up in larger bodies. Current ALMA observations cannot distinguish between these two hypotheses. We have simulated both scenarios, but chemical model results do not allow us to rule out one of the two. Assuming that all Lupus disks have evolved mainly due to viscous processes over the past few Myr, the observed correlation between the current mass accretion rate and dust mass found by Manara et al. (2016) implies a constant gas-to-dust ratio, which is close to 100 based on the observed $M_{\rm disk}/\dot{M}_{\rm acc}$ ratio. This in turn points to a scenario in which carbon depletion is responsible for the low CO isotopologue line luminosities.

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Robustness of N2H+ as tracer of the CO snowline

[Abridged] Snowlines in protoplanetary disks play an important role in planet formation and composition. Since the CO snowline is difficult to observe directly with CO emission, its location has been inferred in several disks from spatially resolved ALMA observations of DCO+ and N2H+. N2H+ is considered to be a good tracer of the CO snowline based on astrochemical considerations predicting an anti-correlation between N2H+ and gas-phase CO. In this work, the robustness of N2H+ as a tracer of the CO snowline is investigated. A simple chemical network is used in combination with the radiative transfer code LIME to model the N2H+ distribution and corresponding emission in the disk around TW Hya. The assumed CO and N2 abundances, corresponding binding energies, cosmic ray ionization rate, and degree of large-grain settling are varied to determine the effects on the N2H+ emission and its relation to the CO snowline. For the adopted physical structure of the TW Hya disk and molecular binding energies for pure ices, the balance between freeze-out and thermal desorption predicts a CO snowline at 19 AU, corresponding to a CO midplane freeze-out temperature of 20 K. A model with a total, i.e. gas plus ice, CO abundance of 3e-6 with respect to H2 fits the position of the emission peak observed by Qi et al. 2013 for the TW Hya disk. However, the relationship between N2H+ and the CO snowline is more complicated than generally assumed: for the investigated parameters, the N2H+ column density peaks at least 5 AU outside the CO snowline. Moreover, the N2H+ emission can peak much further out, as far as ~50 AU beyond the snowline. Hence, chemical modeling, as done here, is necessary to derive a CO snowline location from N2H+ observations.

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A primordial origin for molecular oxygen in comets: A chemical kinetics study of the formation and survival of O$_2$ ice from clouds to disks

Molecular oxygen has been confirmed as the fourth most abundant molecule in cometary material O$_2$/H$_2$O $\sim 4$ %) and is thought to have a primordial nature, i.e., coming from the interstellar cloud from which our solar system was formed. However, interstellar O$_2$ gas is notoriously difficult to detect and has only been observed in one potential precursor of a solar-like system. Here, the chemical and physical origin of O$_2$ in comets is investigated using sophisticated astrochemical models. Three origins are considered: i) in dark clouds, ii) during forming protostellar disks, and iii) during luminosity outbursts in disks. The dark cloud models show that reproduction of the observed abundance of O$_2$ and related species in comet 67P/C-G requires a low H/O ratio facilitated by a high total density ($\geq 10^5$ cm$^{-3}$), and a moderate cosmic ray ionisation rate ($\leq 10^{-16}$ s$^{-1}$) while a temperature of 20 K, slightly higher than the typical temperatures found in dark clouds, also enhances the production of O$_2$. Disk models show that O$_2$ can only be formed in the gas phase in intermediate disk layers, and cannot explain the strong correlation between O$_2$ and H$_2$O in comet 67P/C-G together with the weak correlation between other volatiles and H$_2$O. However, primordial O$_2$ ice can survive transport into the comet-forming regions of disks. Taken together, these models favour a dark cloud (or "primordial") origin for O$_2$ in comets, albeit for dark clouds which are warmer and denser than those usually considered as solar system progenitors.

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Cometary ices in forming protoplanetary disc midplanes

Low-mass protostars are the extrasolar analogues of the natal Solar System. Sophisticated physicochemical models are used to simulate the formation of two protoplanetary discs from the initial prestellar phase, one dominated by viscous spreading and the other by pure infall. The results show that the volatile prestellar fingerprint is modified by the chemistry en route into the disc. This holds relatively independent of initial abundances and chemical parameters: physical conditions are more important. The amount of CO2 increases via the grain-surface reaction of OH with CO, which is enhanced by photodissociation of H2O ice. Complex organic molecules are produced during transport through the envelope at the expense of CH3OH ice. Their abundances can be comparable to that of methanol ice (few % of water ice) at large disc radii (R > 30 AU). Current Class II disc models may be underestimating the complex organic content. Planet population synthesis models may underestimate the amount of CO2 and overestimate CH3OH ices in planetesimals by disregarding chemical processing between the cloud and disc phases. The overall C/O and C/N ratios differ between the gas and solid phases. The two ice ratios show little variation beyond the inner 10 AU and both are nearly solar in the case of pure infall, but both are sub-solar when viscous spreading dominates. Chemistry in the protostellar envelope en route to the protoplanetary disc sets the initial volatile and prebiotically-significant content of icy planetesimals and cometary bodies. Comets are thus potentially reflecting the provenances of the midplane ices in the Solar Nebula.

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Setting the volatile composition of (exo)planet-building material. Does chemical evolution in disk midplanes matter?

[Abridged] Chemical evolution in the protoplanetary disk midplane can modify the composition of ices and gases. We have investigated if and how chemical evolution affects the abundances and distributions of key volatile species in the midplane of a protoplanetary disk in the 0.2-30 AU range. A full chemical network including gas-phase, gas-grain interactions and grain-surface chemistry is used to evolve chemistry in time, for 1 Myr. Great diversity is observed in the relative abundance ratios of the main considered species: H2O, CO, CO2, CH4, O2, NH3 and N2. The choice of ionisation level, the choice of initial abundances, as well as the extent of chemical reaction types included are all factors that affect the chemical evolution. The only exception is the inheritance scenario with a low ionisation level, which results in negligible changes compared with the initial abundances, regardless of whether grain-surface chemistry is included. The chemical processing changes the C/O ratios for gas and ice significantly with radius and with model assumptions. For high ionisation levels, chemical processing becomes significant after a few times $10^{5}$~yrs. It is concluded that chemical evolution in the disk midplane needs to be considered in the determination of the volatile composition of planetesimals.

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Determining protoplanetary disk gas masses from CO isotopologues line observations

Despite intensive studies of protoplanetary disks, there is still no reliable way to determine their total mass and their surface density distribution, quantities that are crucial for describing both the structure and the evolution of disks up to the formation of planets. The goal of this work is to use less abundant CO isotopologues, whose detection is routine for ALMA, to infer the gas mass of disks. Isotope-selective effects need to be taken into account in the analysis, because they can significantly modify CO isotopologues line intensities. CO isotope-selective photodissociation has been implemented in the physical-chemical code DALI and 800 disk models have been run for a range of disk and stellar parameters. Dust and gas temperature structures have been computed self-consistently, together with a chemical calculation of the main species. Both disk structure and stellar parameters have been investigated. Total fluxes have been ray-traced for different CO isotopologues and for various transitions for different inclinations. A combination of 13CO and C18O total intensities allows inference of the total disk mass, although with non-negligible uncertainties. These can be overcome by employing spatially resolved observations, i.e. the disk's radial extent and inclination. Comparison with parametric models shows differences at the factor of a few level, especially for extremely low and high disk masses. Finally, total line intensities for different CO isotopologue and for various low-J transitions are provided and are fitted to simple formulae. The effects of a lower gas-phase carbon abundance and different gas/dust ratios are investigated as well, and comparison with other tracers is made. Disk masses can be determined within a factor of a few by comparing CO isotopologue lines observations with the simulated line fluxes, modulo the uncertainties in the volatile elemental abundances.

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Do siblings always form and evolve simultaneously? Testing the coevality of multiple protostellar systems through SEDs

Multiplicity is common in field stars and among protostellar systems. Models suggest two paths of formation: turbulent fragmentation and protostellar disk fragmentation. We attempt to find whether or not the coevality frequency of multiple protostellar systems can help to better understand their formation mechanism. The coevality frequency is determined by constraining the relative evolutionary stages of the components in a multiple system. SEDs for known multiple protostars in Perseus were constructed from literature data. Herschel PACS photometric maps were used to sample the peak of the SED for systems with separations >7", a crucial aspect in determining the evolutionary stage of a protostellar system. Inclination effects and the surrounding envelope and outflows were considered to decouple source geometry from evolution. This together with the shape and derived properties from the SED was used to determine each system's coevality as accurately as possible. SED models were used to examine the frequency of non-coevality that is due to geometry. We find a non-coevality frequency of 33+/-10% from the comparison of SED shapes of resolved multiple systems. Other source parameters suggest a somewhat lower frequency of non-coevality. The frequency of apparent non-coevality that is due to random inclination angle pairings of model SEDs is 17+/-0.5%. Observations of the outflow of resolved multiple systems do not suggest significant misalignments within multiple systems. Effects of unresolved multiples on the SED shape are also investigated. We find that 1/3 of the multiple protostellar systems sampled here are non-coeval, which is more than expected from random geometric orientations. The other 2/3 are found to be coeval. Higher order multiples show a tendency to be non-coeval. The frequency of non-coevality found here is most likely due to formation and enhanced by dynamical evolution.

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First detection of gas-phase ammonia in a planet-forming disk

Nitrogen chemistry in protoplanetary disks and the freeze-out on dust particles is key to understand the formation of nitrogen bearing species in early solar system analogs. So far, ammonia has not been detected beyond the snowline in protoplanetary disks. We aim to find gas-phase ammonia in a protoplanetary disk and characterize its abundance with respect to water vapor. Using HIFI on the Herschel Space Observatory we detect, for the first time, the ground-state rotational emission of ortho-NH$_3$ in a protoplanetary disk, around TW Hya. We use detailed models of the disk's physical structure and the chemistry of ammonia and water to infer the amounts of gas-phase molecules of these species. We explore two radial distributions ( confined to $<$60 au like the millimeter-sized grains) and two vertical distributions (near the midplane where water is expected to photodesorb off icy grains) to describe the (unknown) location of the molecules. These distributions capture the effects of radial drift and vertical settling of ice-covered grains. We use physical-chemical models to reproduce the fluxes with assuming that water and ammonia are co-spatial. We infer ammonia gas-phase masses of 0.7-11.0 $\times$10$^{21}$ g. For water, we infer gas-phase masses of 0.2-16.0 $\times$10$^{22}$ g. This corresponds to NH$_3$/H$_2$O abundance ratios of 7\%-84\%, assuming that water and ammonia are co-located. Only in the most compact and settled adopted configuration is the inferred NH$_3$/H$_2$O consistent with interstellar ices and solar system bodies of $\sim$ 5\%-10\%. Volatile release in the midplane may occur via collisions between icy bodies if the available surface for subsequent freeze-out is significantly reduced, e.g., through growth of small grains into pebbles or larger.

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The Radial Distribution of H2 and CO in TW Hya as Revealed by Resolved ALMA Observations of CO Isotopologues

CO is widely used as a tracer of molecular gas. However, there is now mounting evidence that gas phase carbon is depleted in the disk around TW Hya. Previous efforts to quantify this depletion have been hampered by uncertainties regarding the radial thermal structure in the disk. Here we present resolved ALMA observations of 13CO 3-2, C18O 3-2, 13CO 6-5, and C18O 6-5 emission in TW Hya, which allow us to derive radial gas temperature and gas surface density profiles, as well as map the CO abundance as a function of radius. These observations provide a measurement of the surface CO snowline at ~30 AU and show evidence for an outer ring of CO emission centered at 53 AU, a feature previously seen only in less abundant species. Further, the derived CO gas temperature profile constrains the freeze-out temperature of CO in the warm molecular layer to < 21 K. Combined with the previous detection of HD 1-0, these data constrain the surface density of the warm H2 gas in the inner ~30 AU. We find that CO is depleted by two orders of magnitude from R=10-60 AU, with the small amount of CO returning to the gas phase inside the surface CO snowline insufficient to explain the overall depletion. Finally, this new data is used in conjunction with previous modeling of the TW Hya disk to constrain the midplane CO snowline to 17-23 AU.

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The (w)hole survey: an unbiased sample study of transition disk candidates based on Spitzer catalogs

Understanding disk evolution and dissipation is essential for studies of planet formation. Transition disks, i.e., disks with large dust cavities and gaps, are promising candidates of active evolution. About two dozen SED-selected candidates have been confirmed to have dust cavities through millimeter interferometric imaging, but this sample is biased towards the brightest disks. The Spitzer surveys of nearby low-mass star forming regions have resulted in more than 4000 Young Stellar Objects (YSOs). Using color criteria we have selected a sample of ~150 candidates, and an additional 40 candidates and known transition disks from the literature. The Spitzer data were complemented by new observations at longer wavelengths, including new JCMT and APEX submillimeter photometry, and WISE and Herschel-PACS mid and far-infrared photometry. Furthermore, optical spectroscopy was obtained and stellar types were derived for 85% of the sample, including information from the literature. The SEDs were fit to a grid of RADMC-3D disk models with a limited number of parameters: disk mass, inner disk mass, scale height and flaring, and disk cavity radius, where the latter is the main parameter of interest. A large fraction of the targets possibly have dust cavities based on the SED. The derived cavity sizes are consistent with imaging/modeling results in the literature, where available. Trends are found with Ldisk/Lstar and stellar mass and a possible connection with exoplanet orbital radii. A comparison with a previous study where color observables are used (Cieza et al. 2010) reveals large overlap between their category of planet-forming disks and our transition disks with cavities. A large number of the new transition disk candidates are suitable for follow-up observations with ALMA.

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The CDF Archive: Herschel PACS and SPIRE Spectroscopic Data Pipeline and Products for Protostars and Young Stellar Objects

We present the COPS-DIGIT-FOOSH (CDF) Herschel spectroscopy data product archive, and related ancillary data products, along with data fidelity assessments, and a user-created archive in collaboration with the Herschel-PACS and SPIRE ICC groups. Our products include datacubes, contour maps, automated line fitting results, and best 1-D spectra products for all protostellar and disk sources observed with PACS in RangeScan mode for two observing programs: the DIGIT Open Time Key Program (KPOT_nevans_1 and SDP_nevans_1; PI: N. Evans), and the FOOSH Open Time Program (OT1_jgreen02_2; PI: J. Green). In addition, we provide our best SPIRE-FTS spectroscopic products for the COPS Open Time Program (OT2_jgreen02_6; PI: J. Green) and FOOSH sources. We include details of data processing, descriptions of output products, and tests of their reliability for user applications. We identify the parts of the dataset to be used with caution. The resulting absolute flux calibration has improved in almost all cases. Compared to previous reductions, the resulting rotational temperatures and numbers of CO molecules have changed substantially in some sources. On average, however, the rotational temperatures have not changed substantially (< 2%), but the number of warm (Trot ~ 300 K) CO molecules has increased by about 18%.

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Molecular Oxygen in Oort Cloud Comet 1P/Halley

Recently the ROSINA mass spectrometer suite on board the European Space Agency's Rosetta spacecraft discovered an abundant amount of molecular oxygen, O2, in the coma of Jupiter family comet 67P/Churyumov-Gerasimenko of O2/H2O = 3.80+/-0.85%. It could be shown that O2 is indeed a parent species and that the derived abundances point to a primordial origin. One crucial question is whether the O2 abundance is peculiar to comet 67P/Churyumov-Gerasimenko or Jupiter family comets in general or whether also Oort cloud comets such as comet 1P/Halley contain similar amounts of molecular oxygen. We investigated mass spectra obtained by the Neutral Mass Spectrometer instrument obtained during the flyby by the European Space Agency's Giotto probe at comet 1P/Halley. Our investigation indicates that a production rate of O2 of 3.7+/-1.7% with respect to water is indeed compatible with the obtained Halley data and therefore that O2 might be a rather common and abundant parent species.

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Resolved gas cavities in transitional disks inferred from CO isotopologues with ALMA

Transitional disks around young stars are promising candidates to look for recently formed, embedded planets. Planet-disk interaction models predict that planets clear a gap in the gas while trapping dust at larger radii. Other physical mechanisms could be responsible for cavities as well. Previous observations have revealed that gas is still present inside these cavities, but the spatial distribution of this gas remains uncertain. We present high spatial resolution observations with the Atacama Large Millimeter/submillimeter Array (ALMA) of 13CO and C18O lines of four well-studied transitional disks. The observations are used to set constraints on the gas surface density, specifically cavity size and density drop inside the cavity. The physical-chemical model DALI is used to analyze the gas images of SR21, HD135344B, DoAr44 and IRS48. The main parameters of interest are the size, depth and shape of the gas cavity. CO isotope-selective photodissociation is included to properly constrain the surface density in the outer disk from C18O emission. The gas cavities are up to 3 times smaller than those of the dust in all four disks. Model fits indicate that the surface density inside the gas cavities decreases by a factor of 100-10000 compared with the surface density profile derived from the outer disk. A comparison with an analytical model of gap depths by planet-disk interaction shows that the disk viscosities are likely low, with a<1E-3 for planet masses <10 MJup. The resolved measurements of the gas and dust in transition disk cavities support the predictions of models that describe how planet-disk interactions sculpt gas disk structures and influence the evolution of dust grains. These observed structures strongly suggest the presence of giant planetary companions in transition disk cavities, although at smaller orbital radii than is typically indicated from the dust cavity radii alone.

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The molecular composition of the planet-forming regions of protoplanetary disks across the luminosity regime

(Abridged) Near- to mid-IR observations of protoplanetary disks show that the inner regions (<10AU) are rich in small organic volatiles (e.g., C2H2 and HCN). Trends in the data suggest that disks around cooler stars (~3000K) are potentially more carbon- and molecule-rich than their hotter counterparts. Our aims are to explore the composition of the planet-forming region of disks around stars from M dwarf to Herbig Ae and compare with the observed trends. Models of the disk physical structure are coupled with a gas-grain chemical network to map the abundances in the planet-forming zone. N2 self shielding, X-ray-induced chemistry, and initial abundances, are investigated. The composition in the 'observable' atmosphere is compared with that in the midplane where the planet-building reservoir resides. M dwarf disk atmospheres are relatively more molecule rich than those for T Tauri or Herbig Ae disks. The weak far-UV flux helps retain this complexity which is enhanced by X-ray-induced ion-molecule chemistry. N2 self shielding has only a small effect and does not explain the higher C2H2/HCN ratios observed towards cooler stars. The models underproduce the OH/H2O column density ratios constrained in Herbig Ae disks, despite reproducing the absolute value for OH: H2O self shielding only increases this discrepency. The disk midplane content is sensitive to the initial main elemental reservoirs. The gas in the inner disk is generally more carbon rich than the midplane ices and is most significant for disks around cooler stars. The atmospheric C/O ratio appears larger than it actually is when calculated using observable tracers only because gas-phase O2 is predicted to be a significant oxygen reservoir. The models suggest that the gas in the inner regions of disks around cooler stars is more carbon rich; however, calculations of the molecular emission are necessary to confirm the observed trends.

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