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Ewine F. van Dishoeck

Publications and source records attributed to Ewine F. van Dishoeck.

At least 163 records · Page 9Linked to original sources

The chemical connection between 67P/C-G and IRAS 16293-2422

The chemical evolution of a star- and planet-forming system begins in the prestellar phase and proceeds across the subsequent evolutionary phases. The chemical trail from cores to protoplanetary disks to planetary embryos can be studied by comparing distant young protostars and comets in our Solar System. One particularly chemically rich system that is thought to be analogous to our own is the low-mass IRAS 16293-2422. ALMA-PILS observations have made the study of chemistry on the disk scales (< 100 AU) of this system possible. Under the assumption that comets are pristine tracers of the outer parts of the innate protosolar disk, it is possible to compare the composition of our infant Solar System to that of IRAS 16293-2422. The Rosetta mission has yielded a wealth of unique in situ measurements on comet 67P/C-G, making it the best probe to date. Herein, the initial comparisons in terms of the chemical composition and isotopic ratios are summarized. Much work is still to be carried out in the future as the analysis of both of these data sets is still ongoing.

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New insights into the nature of transition disks from a complete disk survey of the Lupus star forming region

Transition disks with large dust cavities around young stars are promising targets for studying planet formation. Previous studies have revealed the presence of gas cavities inside the dust cavities hinting at recently formed, giant planets. However, many of these studies are biased towards the brightest disks in the nearby star forming regions, and it is not possible to derive reliable statistics that can be compared with exoplanet populations. We present the analysis of 11 transition disks with large cavities (>20 AU radius) from a complete disk survey of the Lupus star forming region, using ALMA Band 7 observations at 0.3" (22-30 AU radius) resolution of the 345 GHz continuum, 13CO and C18O 3-2 observations and the Spectral Energy Distribution of each source. Gas and dust surface density profiles are derived using the physical-chemical modeling code DALI. This is the first study of transition disks of large cavities within a complete disk survey within a star forming region. The dust cavity sizes range from 20-90 AU radius and in three cases, a gas cavity is resolved as well. The deep drops in gas density and large dust cavity sizes are consistent with clearing by giant planets. The fraction of transition disks with large cavities in Lupus is ~11%, which is inconsistent with exoplanet population studies of giant planets at wide orbits. Furthermore, we present a hypothesis of an evolutionary path for large massive disks evolving into transition disks with large cavities.

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Probing Episodic Accretion in Very Low Luminosity Objects

Episodic accretion has been proposed as a solution to the long-standing luminosity problem in star formation; however, the process remains poorly understood. We present observations of line emission from N2H+ and CO isotopologues using the Atacama Large Millimeter/submillimeter Array (ALMA) in the envelopes of eight Very Low Luminosity Objects (VeLLOs). In five of the sources the spatial distribution of emission from N2H+ and CO isotopologues shows a clear anti-correlation. It is proposed that this is tracing the CO snow line in the envelopes: N2H+ emission is depleted toward the center of these sources in contrast to the CO isotopologue emission which exhibits a peak. The positions of the CO snow lines traced by the N2H+ emission are located at much larger radii than those calculated using the current luminosities of the central sources. This implies that these five sources have experienced a recent accretion burst because the CO snow line would have been pushed outwards during the burst due to the increased luminosity of the central star. The N2H+ and CO isotopologue emission from DCE161, one of the other three sources, is most likely tracing a transition disk at a later evolutionary stage. Excluding DCE161, five out of seven sources (i.e., ~70%) show signatures of a recent accretion burst. This fraction is larger than that of the Class 0/I sources studied by Jørgensen et al. (2015) and Frimann et al. (2016) suggesting that the interval between accretion episodes in VeLLOs is shorter than that in Class 0/I sources.

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Imaging the water snowline in a protostellar envelope with H$^{13}$CO$^+$

Snowlines are key ingredients for planet formation. Providing observational constraints on the locations of the major snowlines is therefore crucial for fully connecting planet compositions to their formation mechanism. Unfortunately, the most important snowline, that of water, is very difficult to observe directly in protoplanetary disks due to its close proximity to the central star. Based on chemical considerations, HCO$^+$ is predicted to be a good chemical tracer of the water snowline, because it is particularly abundant in dense clouds when water is frozen out. This work maps the optically thin isotopologue H$^{13}$CO$^+$ ($J=3-2$) toward the envelope of the low-mass protostar NGC1333-IRAS2A (observed with NOEMA at ~0.9" resolution), where the snowline is at larger distance from the star than in disks. The H$^{13}$CO$^+$ emission peaks ~2" northeast of the continuum peak, whereas the previously observed H$_2^{18}$O shows compact emission on source. Quantitative modeling shows that a decrease in H$^{13}$CO$^+$ abundance by at least a factor of six is needed in the inner ~360 AU to reproduce the observed emission profile. Chemical modeling predicts indeed a steep increase in HCO$^+$ just outside the water snowline; the 50% decrease in gaseous H$_2$O at the snowline is not enough to allow HCO$^+$ to be abundant. This places the water snowline at 225 AU, further away from the star than expected based on the 1D envelope temperature structure for NGC1333-IRAS2A. In contrast, DCO$^+$ observations show that the CO snowline is at the expected location, making an outburst scenario unlikely. The spatial anticorrelation of the H$^{13}$CO$^+$ and H$_2^{18}$O emission provide a proof of concept that H$^{13}$CO$^+$ can be used as a tracer of the water snowline.

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Inferring giant planets from ALMA millimeter continuum and line observations in (transition) disks

Potential signatures of proto-planets embedded in their natal protoplanetary disk are radial gaps or cavities in the continuum emission in the IR-mm wavelength range. ALMA observations are now probing spatially resolved rotational line emission of CO and other chemical species. These observations can provide complementary information on the mechanism carving the gaps in dust and additional constraints on the purported planet mass. We post-process 2D hydrodynamical simulations of planet-disk models, where the dust densities and grain size distributions are computed with a dust evolution code. The simulations explore different planet masses ($1\,M_{\rm J}\leq M_{\rm p}\leq15\,M_{\rm J}$) and turbulent parameters. The outputs are post-processed with the thermo-chemical code DALI, accounting for the radially and vertically varying dust properties as in Facchini et al. (2017). We obtain the gas and dust temperature structures, chemical abundances, and synthetic emission maps of both thermal continuum and CO rotational lines. This is the first study combining hydro simulations, dust evolution and chemistry to predict gas emission of disks hosting massive planets. All radial intensity profiles of the CO main isotopologues show a gap at the planet location. The ratio between the location of the gap as seen in CO and the peak in the mm continuum at the pressure maximum outside the orbit of the planet shows a clear dependence on planet mass. Due to the low dust density in the gaps, the dust and gas components can become thermally decoupled, with the gas being colder than the dust. The gaps seen in CO are due to a combination of gas temperature dropping at the location of the planet, and of the underlying surface density profile. In none of the models is a CO cavity observed, only CO gaps, indicating that one single massive planet is not able to explain the CO cavities observed in transition disks.

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Efficiency of radial transport of ices in protoplanetary disks probed with infrared observations: the case of CO$_2$

The efficiency of radial transport of icy solid material from outer disk to the inner disk is currently unconstrained. Efficient radial transport of icy dust grains could significantly alter the composition of the gas in the inner disk. Our aim is to model the gaseous CO$_2$ abundance in the inner disk and use this to probe the efficiency of icy dust transport in a viscous disk. Features in the simulated CO$_2$ spectra are investigated for their dust flux tracing potential. We have developed a 1D viscous disk model that includes gas and grain motions as well as dust growth, sublimation and freeze-out and a parametrisation of the CO$_2$ chemistry. The thermo-chemical code DALI was used to model the mid-infrared spectrum of CO$_2$, as can be observed with JWST-MIRI. CO$_2$ ice sublimating at the iceline increases the gaseous CO$_2$ abundance to levels equal to the CO$_2$ ice abundance of $\sim 10^{-5}$, which is three orders of magnitude more than the gaseous CO$_2$ abundances of $\sim 10^{-8}$ observed by Spitzer. Grain growth and radial drift further increase the gaseous CO$_2$ abundance. A CO$_2$ destruction rate of at least $10^{-11}$ s$^{-1}$ is needed to reconcile model prediction with observations. This rate is at least two orders of magnitude higher than the fastest known chemical destruction rate. A range of potential physical mechanisms to explain the low observed CO$_2$ abundances are discussed. Transport processes in disks can have profound effects on the abundances of species in the inner disk. The discrepancy between our model and observations either suggests frequent shocks in the inner 10 AU that destroy CO$_2$, or that the abundant midplane CO$_2$ is hidden from our view by an optically thick column of low abundance CO$_2$ in to the disk surface XDR/PDR. Other molecules, such as CH$_4$ or NH$_3$, can give further handles on the rate of mass transport.

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Shocks and UV radiation around low-mass protostars: the Herschel-PACS legacy

Far-infrared spectroscopy reveals gas cooling and its underlying heating due to physical processes taking place in the surroundings of protostars. These processes are reflected in both the chemistry and excitation of abundant molecular species. Here, we present the Herschel-PACS far-IR spectroscopy of 90 embedded low-mass protostars from the WISH (van Dishoeck et al. 2011), DIGIT (Green et al. 2013), and WILL surveys (Mottram et al. 2017). The $5\times5$ spectra covering the $\sim50''\times50''$ field-of-view include rotational transitions of CO, H$_2$O, and OH lines, as well as fine-structure [O I] and [C II] in the $\sim$50-200 $μ$m range. The CO rotational temperatures (for $J_\mathrm{u}\geq14)$ are typically $\sim$300 K, with some sources showing additional components with temperatures as high as $\sim$1000 K. The H$_2$O / CO and H$_2$O / OH flux ratios are low compared to stationary shock models, suggesting that UV photons may dissociate some H$_2$O and decrease its abundance. Comparison to C shock models illuminated by UV photons shows good agreement between the line emission and the models for pre-shock densities of $10^5$ cm$^{-3}$ and UV fields 0.1-10 times the interstellar value. The far-infrared molecular and atomic lines are the unique diagnostic of shocks and UV fields in deeply-embedded sources.

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On the origin of O$_2$ and other volatile species in comets

Molecular oxygen, O$_2$, was recently detected in comet 67P by the ROSINA instrument on board the Rosetta spacecraft with a surprisingly high abundance of 4 % relative to H$_2$O, making O$_2$ the fourth most abundant in comet 67P. Other volatile species with similar volatility, such as molecular nitrogen N$_2$, were also detected by Rosetta, but with much lower abundances and much weaker correlations with water. Here, we investigate the chemical and physical origin of O$_2$ and other volatile species using the new constraints provided by Rosetta. We follow the chemical evolution during star formation with state-of-the-art astrochemical models applied to dynamical physical models by considering three origins: i) in dark clouds, ii) during forming protostellar disks, and iii) during luminosity outbursts in disks. The models presented here favour a dark cloud (or "primordial") grain surface chemistry origin for volatile species in comets, albeit for dark clouds which are slightly warmer and denser than those usually considered as solar system progenitors.

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Chemical and kinematic complexity of the very young star-forming region Serpens Main observed with ALMA

The youngest low-mass protostars are known to be chemically rich, accreting matter most vigorously, and producing the most powerful outflows. Molecules are unique tracers of these phenomena. We use ALMA to study several outflow sources in the Serpens Main region. The most luminous source, Ser-SMM1, shows the richest chemical composition, but some complex molecules are also present in S68N. No emission from complex organics is detected toward Ser-emb 8N, which is the least luminous in the sample. We discuss whether these differences reflect an evolutionary effect or whether they are due to different physical structures. We also analyze the outflow structure from these young protostars by comparing emission of CO and SiO. EHV molecular jets originating from SMM1-a,b and Ser-emb 8N contrast with no such activity from S68N, which on the other hand presents a complex outflow structure.

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Astrochemistry: overview and challenges

This paper provides a brief overview of the journey of molecules through the Cosmos, from local diffuse interstellar clouds and PDRs to distant galaxies, and from cold dark clouds to hot star-forming cores, protoplanetary disks, planetesimals and exoplanets. Recent developments in each area are sketched and the importance of connecting astronomy with chemistry and other disciplines is emphasized. Fourteen challenges for the field of Astrochemistry in the coming decades are formulated.

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Unveiling the physical and chemical conditions in the young disk around L1527

Planets form in disks around young stars. The planet formation process may start when the protostar and disk are still deeply embedded within their infalling envelope. However, unlike more evolved protoplanetary disks, the physical and chemical structure of these young embedded disks are still poorly constrained. We have analyzed ALMA data for $^{13}$CO, C$^{18}$O and N$_2$D$^+$ to constrain the temperature structure, one of the critical unknowns, in the disk around L1527. The spatial distribution of $^{13}$CO and C$^{18}$O, together with the kinetic temperature derived from the optically thick $^{13}$CO emission and the non-detection of N$_2$D$^+$, suggest that this disk is warm enough ($\gtrsim$ 20 K) to prevent CO freeze-out.

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Different dust and gas radial extents in protoplanetary disks: consistent models of grain growth and CO emission

ALMA observations of protoplanetary disks confirm earlier indications that there is a clear difference between the dust and gas radial extents. The origin of this difference is still debated, with both radial drift of the dust and optical depth effects suggested in the literature. In this work, the feedback of realistic dust particle distributions onto the gas chemistry and molecular emissivity is investigated, with a particular focus on CO isotopologues. The radial dust grain size distribution is determined using dust evolution models that include growth, fragmentation and radial drift. A new version of the code DALI is used to take into account how dust surface area and density influence the disk thermal structure, molecular abundances and excitation. The difference of dust and gas radial sizes is largely due to differences in the optical depth of CO lines and millimeter continuum, without the need to invoke radial drift. The effect of radial drift is primarily visible in the sharp outer edge of the continuum intensity profile. The gas outer radius probed by $^{12}$CO emission can easily differ by a factor of $\sim 2$ between the models for a turbulent $α$ ranging between typical values. Grain growth and settling concur in thermally decoupling the gas and dust components, due to the low collision rate with large grains. As a result, the gas can be much colder than the dust at intermediate heights, reducing the CO excitation and emission, especially for low turbulence values. Also, due to disk mid-plane shadowing, a second CO thermal desorption (rather than photodesorption) front can occur in the warmer outer mid-plane disk. The models are compared to ALMA observations of HD 163296 as a test case. In order to reproduce the observed CO snowline of the system, a binding energy for CO typical of ice mixtures needs to be used rather than the lower pure CO value.

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Formation of Glycerol through Hydrogenation of CO ice under Prestellar Core Conditions

Observational studies reveal that complex organic molecules (COMs) can be found in various objects associated with different star formation stages. The identification of COMs in prestellar cores, i.e., cold environments in which thermally induced chemistry can be excluded and radiolysis is limited by cosmic rays and cosmic ray induced UV-photons, is particularly important as this stage sets up the initial chemical composition from which ultimately stars and planets evolve. Recent laboratory results demonstrate that molecules as complex as glycolaldehyde and ethylene glycol are efficiently formed on icy dust grains via non-energetic atom addition reactions between accreting H atoms and CO molecules, a process that dominates surface chemistry during the 'CO-freeze out stage' in dense cores. In the present study we demonstrate that a similar mechanism results in the formation of the biologically relevant molecule glycerol - HOCH2CH(OH)CH2OH - a three-carbon bearing sugar alcohol necessary for the formation of membranes of modern living cells and organelles. Our experimental results are fully consistent with a suggested reaction scheme in which glycerol is formed along a chain of radical-radical and radical-molecule interactions between various reactive intermediates produced upon hydrogenation of CO ice or its hydrogenation products. The tentative identification of the chemically related simple sugar glyceraldehyde - HOCH2CH(OH)CHO - is discussed as well. These new laboratory findings indicate that the proposed reaction mechanism holds much potential to form even more complex sugar alcohols and simple sugars.

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Simultaneous Hydrogenation and UV-photolysis Experiments of NO in CO-rich Interstellar Ice Analogues; linking HNCO, OCN-, NH2CHO and NH2OH

The laboratory work presented here, simulates the chemistry on icy dust grains as typical for the 'CO freeze-out stage' in dark molecular clouds. It differs from previous studies in that solid-state hydrogenation and vacuum UV-photoprocessing are applied simultaneously to co-depositing molecules. In parallel, the reactions at play are described for fully characterized laboratory conditions. The focus is on the formation of molecules containing both carbon and nitrogen atoms, starting with NO in CO-, H2CO-, and CH3OH-rich ices at 13 K. The experiments yield three important conclusions. 1. Without UV-processing hydroxylamine (NH2OH) is formed, as reported previously. 2. With UV-processing (energetic) NH2 is formed through photodissociation of NH2OH. This radical is key in the formation of species with an N-C bond. 3. The formation of three N-C bearing species, HNCO, OCN- and NH2CHO is observed. The experiments put a clear chemical link between these species; OCN- is found to be a direct derivative of HNCO and the latter is shown to have the same precursor as formamide (NH2CHO). Moreover, the addition of VUV competing channels decreases the amount of NO molecules converted into NH2OH by at least one order of magnitude. Consequently, this decrease in NH2OH formation yield directly influences the amount of NO molecules that can be converted into HNCO, OCN- and NH2CHO.

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ALMA Survey of Lupus Protoplanetary Disks I: Dust and Gas Masses

We present the first high-resolution sub-mm survey of both dust and gas for a large population of protoplanetary disks. Characterizing fundamental properties of protoplanetary disks on a statistical level is critical to understanding how disks evolve into the diverse exoplanet population. We use ALMA to survey 89 protoplanetary disks around stars with $M_{\ast}>0.1~M_{\odot}$ in the young (1--3~Myr), nearby (150--200~pc) Lupus complex. Our observations cover the 890~$μ$m continuum and the $^{13}$CO and C$^{18}$O 3--2 lines. We use the sub-mm continuum to constrain $M_{\rm dust}$ to a few Martian masses (0.2--0.4~$M_{\oplus}$) and the CO isotopologue lines to constrain $M_{\rm gas}$ to roughly a Jupiter mass (assuming ISM-like $\rm {[CO]/[H_2]}$ abundance). Of 89 sources, we detect 62 in continuum, 36 in $^{13}$CO, and 11 in C$^{18}$O at $>3σ$ significance. Stacking individually undetected sources limits their average dust mass to $\lesssim6$ Lunar masses (0.03~$M_{\oplus}$), indicating rapid evolution once disk clearing begins. We find a positive correlation between $M_{\rm dust}$ and $M_{\ast}$, and present the first evidence for a positive correlation between $M_{\rm gas}$ and $M_{\ast}$, which may explain the dependence of giant planet frequency on host star mass. The mean dust mass in Lupus is 3$\times$ higher than in Upper Sco, while the dust mass distributions in Lupus and Taurus are statistically indistinguishable. Most detected disks have $M_{\rm gas}\lesssim1~M_{\rm Jup}$ and gas-to-dust ratios $<100$, assuming ISM-like $\rm {[CO]/[H_2]}$ abundance; unless CO is very depleted, the inferred gas depletion indicates that planet formation is well underway by a few Myr and may explain the unexpected prevalence of super-Earths in the exoplanet population.

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HD far infrared emission as a measure of protoplanetary disk mass

Protoplanetary disks around young stars are the sites of planet formation. While the dust mass can be estimated using standard methods, determining the gas mass - and thus the amount of material available to form giant planets - has proven to be very difficult. Hydrogen deuteride (HD) is a promising alternative to the commonly-used gas mass tracer, CO. We aim to examine the robustness of HD as tracer of the disk gas mass, specifically the effect of gas mass on the HD FIR emission and its sensitivity to the vertical structure. Deuterium chemistry reactions relevant for HD were implemented in the thermochemical code DALI and models were run for a range of disk masses and vertical structures. The HD J=1-0 line intensity depends directly on the gas mass through a sublinear power law relation with a slope of ~0.8. Assuming no prior knowledge about the vertical structure of a disk and using only the HD 1-0 flux, gas masses can be estimated to within a factor of 2 for low mass disks (M$_{\rm disk} < 10^{-3}$ M$_\odot$). For more massive disks, this uncertainty increases to more than an order of magnitude. Adding the HD 2-1 line or independent information about the vertical structure can reduce this uncertainty to a factor of ~3 for all disk masses. For TW Hya, using the radial and vertical structure from Kama et al. 2016b the observations constrain the gas mass to $6\cdot10^{-3}$ M$_\odot$ < M$_{\rm disk} < 9\cdot10^{-3}$ M$_\odot$. Future observations require a 5$σ$ sensitivity of $1.8\cdot10^{-20}$ W m$^{-2}$ ($2.5\cdot10^{-20}$ W m$^{-2}$) and a spectral resolving power R > 300 (1000) to detect HD 1-0 (HD 2-1) for all disk masses above $10^{-5}$ M$_\odot$ with a line-to-continuum ratio > 0.01. These results show that HD can be used as an independent gas mass tracer with a relatively low uncertainty and should be considered as an important science goal for future FIR missions.

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An ALMA Survey of Protoplanetary Disks in the $σ$ Orionis Cluster

The $σ$ Orionis cluster is important for studying protoplanetary disk evolution, as its intermediate age ($\sim$3-5 Myr) is comparable to the median disk lifetime. We use ALMA to conduct a high-sensitivity survey of dust and gas in 92 protoplanetary disks around $σ$ Orionis members with $M_{\ast}\gtrsim0.1 M_{\odot}$. Our observations cover the 1.33 mm continuum and several CO $J=2-1$ lines: out of 92 sources, we detect 37 in the mm continuum and six in $^{12}$CO, three in $^{13}$CO, and none in C$^{18}$O. Using the continuum emission to estimate dust mass, we find only 11 disks with $M_{\rm dust}\gtrsim10 M_{\oplus}$, indicating that after only a few Myr of evolution most disks lack sufficient dust to form giant planet cores. Stacking the individually undetected continuum sources limits their average dust mass to 5$\times$ lower than that of the faintest detected disk, supporting theoretical models that indicate rapid dissipation once disk clearing begins. Comparing the protoplanetary disk population in $σ$ Orionis to those of other star-forming regions supports the steady decline in average dust mass and the steepening of the $M_{\rm dust}$-$M_{\ast}$ relation with age; studying these evolutionary trends can inform the relative importance of different disk processes during key eras of planet formation. External photoevaporation from the central O9 star is influencing disk evolution throughout the region: dust masses clearly decline with decreasing separation from the photoionizing source, and the handful of CO detections exist at projected separations $>1.5$ pc. Collectively, our findings indicate that giant planet formation is inherently rare and/or well underway by a few Myr of age.

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Survey of cold water lines in protoplanetary disks: indications of systematic volatile depletion

We performed very deep searches for 2 ground-state water transitions in 13 protoplanetary disks with the HIFI instrument on-board the Herschel Space Observatory, with integration times up to 12 hours per line. Two other water transitions that sample warmer gas were also searched for with shallower integrations. The detection rate is low, and the upper limits provided by the observations are generally much lower than predictions of thermo-chemical models with canonical inputs. One ground-state transition is newly detected in the stacked spectrum of AA Tau, DM Tau, LkCa 15, and MWC 480. We run a grid of models to show that the abundance of gas-phase oxygen needs to be reduced by a factor of at least ~100 to be consistent with the observational upper limits (and positive detections) if a dust-to-gas mass ratio of 0.01 were to be assumed. As a continuation of previous ideas, we propose that the underlying reason for the depletion of oxygen (hence the low detection rate) is the freeze-out of volatiles such as water and CO onto dust grains followed by grain growth and settling/migration, which permanently removes these gas-phase molecules from the emissive upper layers of the outer disk. Such depletion of volatiles is likely ubiquitous among different disks, though not necessarily to the same degree. The volatiles might be returned back to the gas phase in the inner disk (within about 15 AU), which is consistent with current constraints. Comparison with studies on disk dispersal due to photoevaporation indicates that the timescale for volatile depletion is shorter than that of photoevaporation.

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