arXiv subjects

Ewine F. van Dishoeck

Publications and source records attributed to Ewine F. van Dishoeck.

At least 307 records · Page 17Linked to original sources

arXiv2006

The Spitzer c2d Survey of Large, Nearby, Interstellar Clouds. III. Perseus Observed with IRAC

We present observations of 3.86 sq. deg. of the Perseus molecular cloud complex with the Spitzer Space Telescope Infrared Array Camera (IRAC). The maps show strong extended emission arising from shocked H2 in outflows in the region and from polycyclic aromatic hydrocarbon features. More than 120,000 sources are extracted toward the cloud. Based on their IRAC colors and comparison to off-cloud and extragalactic fields, we identify 400 candidate young stellar objects. About two thirds of these are associated with the young clusters IC348 and NGC1333, while the last third is distributed over the remaining cloud. We classify the young stellar objects according to the traditional scheme based on the slope of their spectral energy distributions. Significant differences are found for the numbers of embedded Class I objects relative to more evolved Class II objects in IC348, NGC1333 and the remaining cloud with the embedded Class I and "flat spectrum" YSOs constituting 14%, 36% and 47% of the total number of YSOs identified in each of these regions. The high number of Class I objects in the extended cloud (61% of the Class I objects in the entire cloud) suggests that a significant fraction of the current star formation is occuring outside the two main clusters. Finally we discuss a number of outflows and identify their driving sources, including the known deeply embedded Class 0 sources outside the two major clusters. The Class 0 objects are found to be detected by Spitzer and have very red [3.6]-[4.5] colors but do not show similarly red [5.8]-[8.0] colors. The Class 0 objects are easily identifiable in color-color diagrams plotting these two colors but are problematic to extract automatically due to the extended emission from shocked gas or scattered light in cavities related to the associated outflows.

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arXiv2005

Molecular dynamics study of photodissociation of water in crystalline and amorphous ice

We present results of classical dynamics calculations, performed to study the photodissociation of water in crystalline and amorphous ice surfaces at a surface temperature of 10 K. Dissociation in the top six monolayers is considered. Desorption of H2O has a low probability (less than 0.5% yield per absorbed photon) for both types of ice. The final outcome strongly depends on the original position of the photodissociated molecule. For molecules in the first bilayer of crystalline ice and the corresponding layers in amorphous ice, desorption of H atoms dominates. In the second bilayer H atom desorption, trapping of the H and OH fragments in the ice, and recombination of H and OH are of roughly equal importance. Deeper into the ice H atom desorption becomes less important and trapping and recombination dominate. The distribution of distances traveled by H atoms in the ice peaks at 6 - 7 Angstroms with a tail going to about 60 Angstroms for both types of ice. The mobility of OH radicals is low within the ice with most probable distances traveled of 2 and 1 Angstroms for crystalline and amorphous ice, respectively. OH is however quite mobile on top of the surface, where it has been found to travel more than 80 Angstroms. Simulated absorption spectra of crystalline ice, amorphous ice, and liquid water are found to be in very good agreement with experiments.

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arXiv2005

The effect of a strong external radiation field on protostellar envelopes in Orion

We discuss the effects of an enhanced interstellar radiation field (ISRF) on the observables of protostellar cores in the Orion cloud region. Dust radiative transfer is used to constrain the envelope physical structure by reproducing SCUBA 850 micron emission. Previously reported 13CO, C17O and H2CO line observations are reproduced through detailed Monte Carlo line radiative transfer models. It is found that the 13CO line emission is marginally optically thick and sensitive to the physical conditions in the outer envelope. An increased temperature in this region is needed in order to reproduce the 13CO line strengths and it is suggested to be caused by a strong heating from the exterior, corresponding to an ISRF in Orion 10^3 times stronger than the "standard" ISRF. The typical temperatures in the outer envelope are higher than the desorption temperature for CO. The C17O emission is less sensitive to this increased temperature but rather traces the bulk envelope material. The data are only fit by a model where CO is depleted, except in the inner and outermost regions where the temperature increases above 30-40 K. The fact that the temperatures do not drop below approximately 25 K in any of the envelopes whereas a significant fraction of CO is frozen-out suggest that the interstellar radiation field has changed through the evolution of the cores. The H2CO lines are successfully reproduced in the model of an increased ISRF with constant abundances of 3-5x10^{-10}.

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arXiv2005

Photodissociation of water in crystalline ice: a molecular dynamics study

Ultraviolet irradiation of ice is of great interest for understanding the chemistry in both atmospheric and astrophysical environments. In interstellar space, photodissociation of H2O molecules can be a driving force behind the chemistry on icy dust grains in dense, cold molecular clouds even though the flux of UV photons is extremely low. The mechanisms of such photoinduced processes are poorly understood, however. In this work the photodissociation dynamics of a water molecule in crystalline ice at 10 K is studied computationally using classical molecular dynamics. Photodissociation in the first bilayer leads mainly to H atoms desorbing (65%), while in the third bilayer trapping of H and OH dominates (51%). The kinetic energy distribution of the desorbing H atoms is much broader than that for the corresponding gas-phase photodissociation. The H atoms on average move 11 Angstroms before becoming trapped, while OH radicals typically move 2 Angstroms. In accordance with experiments a blueshift of the absorption spectrum is obtained relative to gas-phase water.

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arXiv2004

Ices in the edge-on disk CRBR 2422.8-3423: Spitzer spectroscopy and Monte Carlo radiative transfer modeling

We present 5.2-37.2 micron spectroscopy of the edge-on circumstellar disk CRBR 2422.8-3423 obtained using the InfraRed Spectrograph (IRS) of the Spitzer Space Telescope. The IRS spectrum is combined with ground-based 3-5 micron spectroscopy to obtain a complete inventory of solid state material present along the line of sight toward the source. We model the object with a 2D axisymmetric (effectively 3D) Monte Carlo radiative transfer code. It is found that the model disk, assuming a standard flaring structure, is too warm to contain the very large observed column density of pure CO ice, but is possibly responsible for up to 50% of the water, CO2 and minor ice species. In particular the 6.85 micron band, tentatively due to NH4+, exhibits a prominent red wing, indicating a significant contribution from warm ice in the disk. It is argued that the pure CO ice is located in the dense core Oph-F in front of the source seen in the submillimeter imaging, with the CO gas in the core highly depleted. The model is used to predict which circumstances are most favourable for direct observations of ices in edge-on circumstellar disks. Ice bands will in general be deepest for inclinations similar to the disk opening angle, i.e. ~70 degrees. Due to the high optical depths of typical disk mid-planes, ice absorption bands will often probe warmer ice located in the upper layers of nearly edge-on disks. The ratios between different ice bands are found to vary by up to an order of magnitude depending on disk inclination due to radiative transfer effects caused by the 2D structure of the disk. Ratios between ice bands of the same species can therefore be used to constrain the location of the ices in a circumstellar disk. [Abstract abridged]

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arXiv2004

Probing the Surfaces of Interstellar Dust Grains: The Adsorption of CO at Bare Grain Surfaces

A solid-state feature was detected at around 2175 cm-1 towards 30 embedded young stellar objects in spectra obtained using the ESO VLT-ISAAC. We present results from laboratory studies of CO adsorbed at the surface of Zeolite wafers, where absorption bands were detected at 2177 and 2168 cm-1 (corresponding to CO chemisorbed at the Zeolite surface), and 2130 cm-1 (corresponding to CO physisorbed at the Zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas-surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be ~ 4 x 10-19 cm molecule-1. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H2O ice, which is, at most, half of the abundance (relative to H2O ice) of CO residing in H2O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically-active) surface area, providing a refuge for interstellar species. Consequently the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas-grain models of the interstellar medium.

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arXiv2004

Organic molecules in protoplanetary disks around TTauri and HerbigAe stars

The results of single-dish observations of low- and high-J transitions of selected molecules from protoplanetary disks around two TTauri stars (LkCa15 and TWHya) and two HerbigAe stars (HD163296 and MWC480) are reported. Simple molecules such as CO, 13CO, HCO+, CN and HCN are detected. Several lines of H2CO are found toward the TTauri star LkCa15 but not in other objects. No CH3OH has been detected down to abundances of 10E-9 - 10E-8 with respect to H2. SO and CS lines have been searched for without success. Line ratios indicate that the molecular emission arises from dense 10E6 - 10E8 cm-3 and moderately warm (T ~ 20-40K) intermediate height regions of the disk atmosphere, in accordance with predictions from models of the chemistry in disks. The abundances of most species are lower than in the envelope around the solar-mass protostar IRAS 16293-2422. Freeze-out and photodissociation are likely causes of the depletion. DCO+ is detected toward TWHya, but not in other objects. The high inferred DCO+/HCO+ ratio of ~0.035 is consistent with models of the deuterium fractionation in disks which include strong depletion of CO. The inferred ionization fraction in the intermediate height regions as deduced from HCO+ is at least 10E-11 - 10E-10, comparable to that derived for the midplane from recent H2D+ observations. (abridged abstract)

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arXiv2004

ISO spectroscopy of gas and dust: from molecular clouds to protoplanetary disks

Observations of interstellar gas-phase and solid-state species in the 2.4-200 micron range obtained with the spectrometers on board the Infrared Space Observatory are reviewed. Lines and bands due to ices, polycyclic aromatic hydrocarbons, silicates and gas-phase atoms and molecules (in particular H2, CO, H2O, OH and CO2) are summarized and their diagnostic capabilities illustrated. The results are discussed in the context of the physical and chemical evolution of star-forming regions, including photon-dominated regions, shocks, protostellar envelopes and disks around young stars.

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arXiv2004

Probing the Early Stages of Low-Mass Star Formation in LDN 1689N: Dust and Water in IRAS 16293-2422A, B, and E

We present deep images of dust continuum emission at 450, 800, and 850 micron of the dark cloud LDN 1689N which harbors the low-mass young stellar objects (YSOs) IRAS 16293-2422A and B (I16293A and I16293B) and the cold prestellar object I16293E. Toward the positions of I16293A and E we also obtained spectra of CO-isotopomers and deep submillimeter observations of chemically related molecules with high critical densities. To I16293A we report the detection of the HDO 1_01 - 0_00 and H2O 1_10 - 1_01 ground-state transitions as broad self-reversed emission profiles with narrow absorption, and a tentative detection of H2D+ 1_10 - 1_11. To I16293E we detect weak emission of subthermally excited HDO 1_01 - 0_00. Based on this set of submillimeter continuum and line data we model the envelopes around I16293A and E. The density and velocity structure of I16293A is fit by an inside-out collapse model, yielding a sound speed of a=0.7 km/s, an age of t=(0.6--2.5)e4 yr, and a mass of 6.1 Msun. The density in the envelope of I16293E is fit by a radial power law with index -1.0+/-0.2, a mass of 4.4 Msun, and a constant temperature of 16K. These respective models are used to study the chemistry of the envelopes of these pre- and protostellar objects. The [HDO]/[H2O] abundance ratio in the warm inner envelope of I16293A of a few times 1e-4 is comparable to that measured in comets. This supports the idea that the [HDO]/[H2O] ratio is determined in the cold prestellar core phase and conserved throughout the formation process of low-mass stars and planets.

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arXiv2003

Astrochemistry of Sub-Millimeter Sources in Orion: Studying the Variations of Molecular Tracers with Changing Physical Conditions

Cornerstone molecules (CO, H_2CO, CH_3OH, HCN, HNC, CN, CS, SO) were observed toward seven sub-millimeter bright sources in the Orion molecular cloud in order to quantify the range of conditions for which individual molecular line tracers provide physical and chemical information. Five of the sources observed were protostellar, ranging in energetics from 1 - 500L_sun, while the other two sources were located at a shock front and within a photodissociation region (PDR). Statistical equilibrium calculations were used to deduce from the measured line strengths the physical conditions within each source and the abundance of each molecule. In all cases except the shock and the PDR, the abundance of CO with respect to H_2 appears significantly below (factor of ten) the general molecular cloud value of 10^-4. {Formaldehyde measurements were used to estimate a mean temperature and density for the gas in each source. Evidence was found for trends between the derived abundance of CO, H_2CO, CH_3OH, and CS and the energetics of the source, with hotter sources having higher abundances.} Determining whether this is due to a linear progression of abundance with temperature or sharp jumps at particular temperatures will require more detailed modeling. The observed methanol transitions require high temperatures (T>50 K), and thus energetic sources, within all but one of the observed protostellar sources. The same conclusion is obtained from observations of the CS 7-6 transition. Analysis of the HCN and HNC 4-3 transitions provides further support for high densities n> 10^7 cm^-3 in all the protostellar sources.

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arXiv2003

Further Evidence for Chemical Fractionation from Ultraviolet Observations of Carbon Monoxide

Ultraviolet absorption from interstellar 12CO and 13CO was detected toward rho Oph A and chi Oph. The measurements were obtained at medium resolution with the Goddard High Resolution Spectrograph on the Hubble Space Telescope. Column density ratios, N(12CO)/N(13CO), of 125 \pm 23 and 117 \pm 35 were derived for the sight lines toward rho Oph A and chi Oph, respectively. A value of 1100 \pm 600 for the ratio N(12C16O)/N(12C18O) toward rho Oph A was also obtained. Absorption from vibrationally excited H_2 (v" = 3) was clearly seen toward this star as well. The ratios are larger than the isotopic ratios for carbon and oxygen appropriate for ambient interstellar material. Since for both carbon and oxygen the more abundant isotopomer is enhanced, selective isotopic photodissociation plays the key role in the fractionation process for these directions. The enhancement arises because the more abundant isotopomer has lines that are more optically thick, resulting in more self shielding from dissociating radiation. A simple argument involving the amount of self shielding [from N(12CO)] and the strength of the ultraviolet radiation field premeating the gas (from the amount of vibrationally excited H_2) shows that selective isotopic photodissociation controls the fractionation seen in these two sight lines, as well as the sight line to zeta Oph.

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arXiv2003

Chemical changes during star formation: high- versus low-mass YSOs

Recent observational studies of high- and low-mass YSOs at (sub)millimeter and infrared wavelengths are reviewed, and chemical diagnostics of the different physical components are summarized. Methods for determining the temperature, density and abundance profiles in the envelopes are outlined, and are illustrated for one high-mass and one low-mass YSO. The combination of (sub)millimeter and infrared data gives a nearly complete chemical inventory of the gas and solid state material. In both high- and low-mass YSOs, the chemical characteristics are dominated by freeze-out in the cold outer part of the envelope and evaporation of ices in the warm inner part. Abundance jumps of factors of ~100 in selected molecules are found in the warm gas for both types of objects. Potential differences include (i) the complex hot core chemistry, which has been observed so far only for high-mass YSOs; (ii) the high level of deuterium fractionation seen only in low-mass YSOs; (iii) the effects of internal or external UV and X-rays; (iv) the relative importance of shocks versus thermal heating of the envelope; and (v) the importance of geometrical effects.

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arXiv2003

Interferometric Observations of Formaldehyde in the Protoplanetary Disk around LkCa15

Emission from the $2_{12}-1_{11}$ line of H$_2$CO has been detected and marginally resolved toward LkCa15 by the Nobeyama Millimeter Array. The column density of H$_2$CO is higher than that observed in DM Tau and than predicted by theoretical models of disk chemistry; also the line-intensity profile is less centrally peaked than that for CO. A similar behavior is observed in other organic gaseous molecules in the LkCa 15 disk.

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arXiv2002

Molecular abundances in low-mass protostellar envelopes

A study of the chemical structure of the envelopes around a sample protostars is introduced. Physical models for the envelopes derived using 1D radiative transfer modeling of their dust continuum emission are used as input for Monte Carlo modeling of single-dish line observations in order to establish the chemical inventories for the different sources. CO and HCO+ abundances are found to be correlated with envelope mass: the sources with the most massive envelopes show the lowest abundances, supporting the idea that the depletion of these molecules is most efficient in the colder, denser environments. Other molecules like CS and HCN do not show a similar trend. Deuterated species like DCO+ and DCN also show signs of correlations with envelope mass and temperature: the deuterium fractionation of HCO+ is most prominent for the coldest and most massive envelopes in the sample and at the same time anti-correlated with the fractionation of HCN. This puts constraints on the low temperature gas-phase deuterium chemistry.

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arXiv2002

Axi-symmetric models of ultraviolet radiative transfer with applications to circumstellar disk chemistry

A new two-dimensional axi-symmetric ultraviolet radiative transfer code is presented, which is used to calculate photodissociation and ionization rates for use in chemistry models of flaring circumstellar disks. Scattering and absorption of photons from the central star and from the interstellar radiation field are taken into account. The molecules are effectively photodissociated in the surface layer of the disk, but can exist in the intermediate, moderately warm layers. A comparison has been made with an approximate 2D ray-tracing method and it was found that the latter underestimates the ultraviolet field and thus the molecular photodissociation rates below the disk surface. The full 2D results show significantly higher abundances of radicals such as CN and C2H than previous work, partly due to the fact that CO is dissociated to greater depths. Results for different stellar radiation fields are also presented. The CN/HCN ratio shows a strong dependence on the stellar spectrum, whereas other ratios such as HCO+/CO show only little variation.

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arXiv2002

Physical structure and CO abundance of low-mass protostellar envelopes

We present 1D radiative transfer modelling of the envelopes of a sample of 18 low-mass protostars and pre-stellar cores with the aim of setting up realistic physical models, for use in a chemical description of the sources. The density and temperature profiles of the envelopes are constrained from their radial profiles obtained from SCUBA maps at 450 and 850 micron and from measurements of the source fluxes ranging from 60 micron to 1.3 mm. The densities of the envelopes within ~10000 AU can be described by single power-laws r^{-p} for the class 0 and I sources with p ranging from 1.3 to 1.9, with typical uncertainties of +/- 0.2. Four sources have flatter profiles, either due to asymmetries or to the presence of an outer constant density region. No significant difference is found between class 0 and I sources. The power-law fits fail for the pre-stellar cores, supporting recent results that such cores do not have a central source of heating. The derived physical models are used as input for Monte Carlo modelling of submillimeter C18O and C17O emission. It is found that class I objects typically show CO abundances close to those found in local molecular clouds, but that class 0 sources and pre-stellar cores show lower abundances by almost an order of magnitude implying that significant depletion occurs for the early phases of star formation. While the 2-1 and 3-2 isotopic lines can be fitted using a constant fractional CO abundance throughout the envelope, the 1-0 lines are significantly underestimated, possibly due to contribution of ambient molecular cloud material to the observed emission. The difference between the class 0 and I objects may be related to the properties of the CO ices.

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arXiv2001

Photon Dominated Regions in Low UV Fields: A Study of The Peripheral Region of L1204/S140

We have carried out an in-depth study of the peripheral region of the molecular cloud L1204/S140, where the far ultraviolet radiation and the density are relatively low. Our observations test theories of photon-dominated regions (PDRs) in a regime that has been little explored. CII 158 micron and OI 63 micron lines are detected by ISO at all 16 positions along a 1-dimensional cut in right ascension. Emission from molecular hydrogen rotational transitions, at 28 and 17 micron, was also detected at several positions. The CII, OI, and molecular hydrogen intensities along the cut show much less spatial variation than do the rotational lines of CO and other CO isotopes. The average CII and OI intensities and their ratio are consistent with models of PDRs with low FUV radiation (Go) and density. The best-fitting model has Go about 15 and density, n about 1000 per cubic cm. Standard PDR models underpredict the intensity in the H2 rotational lines by up to an order of magnitude. This problem has also been seen in bright PDRs and attributed to factors, such as geometry and gas-grain drift, that should be much less important in the regime studied here. The fact that we see the same problem in our data suggests that more fundamental solutions, such as higher H2 formation rates, are needed. Also, in this regime of low density and small line width, the OI line is sensitive to the radiative transfer and geometry. Using the ionization structure of the models, a quantitative analysis of timescales for ambipolar diffusion in the peripheral regions of the S140 cloud is consistent with a theory of photoionization-regulated star formation. Observations of CII in other galaxies differ both from those of high Go PDRs in our galaxy and from the low Go regions we have studied. ~

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arXiv2001

Submillimeter lines from circumstellar disks around pre-main sequence stars

Observations of submillimeter lines of CO (up to J=6-5), HCO+, HCN (up to J=4-3) and their isotopes from circumstellar disks around low mass pre-main sequence stars are presented. The different line ratios and optical depths indicate that most of the observed line emission arises from an intermediate disk layer with high densities of 1E6-1E8 cm-3 and moderately warm temperatures in the outer regions. The data are compared with three disk models from the literature using a full 2D Monte Carlo radiative transfer code. The abundances of the molecules are constrained from the more optically thin 13C species and indicate depletions of 1-30 for LkCa 15 and very high depletions of > 100 for TW Hya with respect to dark cloud abundances. Evidence for significant freeze-out (factors 10 or larger) of CO and HCO+ onto grain surfaces at temperatures below 22 K is found, but the abundances of these molecules must also be low in the warmer upper layer, most likely as a result of photodissociation. A warm upper layer near the surface of a flaring disk heated by stellar and interstellar radiation is an appropriate description of the observations of TW Hya. LkCa 15 seems to be cooler at the surface, perhaps due to dust settling.

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