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Ewine F. van Dishoeck

Publications and source records attributed to Ewine F. van Dishoeck.

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Abundance profiles of CH3OH and H2CO toward massive young stars as evolutionary tracers

The chemical evolution of thirteen regions of massive star formation is studied through single-dish and interferometer line observations at submillimeter wavelengths. The wealth of CH3OH and H2CO lines covering a large range of excitation conditions allows us to calculate radial abundance profiles, using the physical structures of the sources derived earlier from submillimeter continuum and CS lines. The data indicate three types of abundance profiles: flat profiles at CH3OH/H2 ~10^-9 for the coldest sources, profiles with a jump in its abundance from ~10^-9 to ~10^-7 for the warmer sources, and flat profiles at CH3OH/H2 ~few 10^-8 for the hot cores. The location of the jump at T~100 K suggests that it is due to evaporation of grain mantles, followed by destruction in gas-phase reactions in the hot core stage. In contrast, the H2CO data can be well fit with a constant abundance of a few x 10^-9 throughout the envelope, providing limits on its grain surface formation. These results indicate that T_rot(CH3OH) can be used as evolutionary indicator during the embedded phase of massive star formation, independent of source optical depth or orientation.

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Limits on the cosmic-ray ionization rate toward massive young stars

Recent models of the envelopes of seven massive protostars are used to analyze observations of H3+ infrared absorption and H13CO+ submillimeter emission lines toward these stars, and to constrain the cosmic-ray ionization rate zeta. The H13CO+ gives best-fit values of zeta=(2.6+/- 1.8) x 10^-17 s^-1, in good agreement with diffuse cloud models and with recent Voyager/Pioneer data but factors of up to 7 lower than found from the H3+ data. No relation of zeta with luminosity or total column density is found, so that local (X-ray) ionization and shielding against cosmic rays appear unimportant for these sources. The difference between the H3+ and H13CO+ results and the correlation of N(H3+) with heliocentric distance suggest that intervening clouds contribute significantly to the H3+ absorptions in the more distant regions. The most likely absorbers are low-density (<~10^4 cm^-3) clouds with most carbon in neutral form or in CO.

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Chemistry in the Envelopes around Massive Young Stars

Recent observational studies of intermediate- and high-mass star-forming regions at submillimeter and infrared wavelengths are reviewed, and chemical diagnostics of the different physical components associated with young stellar objects are summarized. Procedures for determining the temperature, density and abundance profiles in the envelopes are outlined. A detailed study of a set of infrared-bright massive young stars reveals systematic increases in the gas/solid ratios, the abundances of evaporated molecules, and the fraction of heated ices with increasing temperature. Since these diverse phenomena involve a range of temperatures from < 100 K to 1000 K, the enhanced temperatures must be communicated to both the inner and outer parts of the envelopes. This `global heating' plausibly results from the gradual dispersion of the envelopes with time. Similarities and differences with low-mass YSOs are discussed. The availability of accurate physical models will allow chemical models of ice evaporation followed by `hot core' chemistry to be tested in detail.

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Structure and Evolution of the Envelopes of Deeply Embedded Massive Young Stars

The physical structure of the envelopes around a sample of fourteen massive (1000-100,000 solar L) young stars is investigated on 100- 100,000 AU scales using maps and spectra in submillimeter continuum and lines of C17O, CS and H2CO. The total column densities and the temperature profiles are obtained by fitting self-consistent dust models to submillimeter photometry. Both the molecular line and dust emission data indicate density gradients ~r^{-alpha}, with alpha=1.0-1.5, significantly flatter than the alpha=2.0 generally found for low-mass objects. This flattening may indicate that in massive young stellar objects, nonthermal pressure is more important for the support against gravitational collapse, while thermal pressure dominates for low-mass sources. We find alpha=2 for two hot core-type sources, but regard this as an upper limit since in these objects, the CS abundance may be enhanced in the warm gas close to the star.

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Detection of H2 pure rotational line emission from the GG~Tau binary system

We present the first detection of the low-lying pure rotational emission lines of H2 from circumstellar disks around T~Tauri stars, using the Short Wavelength Spectrometer on the Infrared Space Observatory. These lines provide a direct measure of the total amount of warm molecular gas in disks. The J=2->0 S(0) line at 28.218 mum and the J=3->1 S(1) line at 17.035 mum have been observed toward the double binary system GG Tau. Together with limits on the J=5->3 S(3) and J=7->5 S(5) lines, the data suggest the presence of gas at T_kin=110+-10 K with a mass of (3.6+-2.0)x10^-3 M_sol (3sigma). This amounts to ~3% of the total gas + dust mass of the circumbinary disk as imaged by millimeter interferometry, but is larger than the estimated mass of the circumstellar disk(s). Possible origins for the warm gas seen in H2 are discussed in terms of photon and wind-shock heating mechanisms of the circumbinary material, and comparisons with model calculations are made.

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Detection of interstellar H_2D^+ emission

We report the detection of the 1_{10}-1_{11} ground state transition of ortho-H_2D^+ at 372.421 GHz in emission from the young stellar object NGC 1333 IRAS 4A. Detailed excitation models with a power-law temperature and density structure yield a beam-averaged H_2D^+ abundance of 3 x 10^{-12} with an uncertainty of a factor of two. The line was not detected toward W 33A, GL 2591, and NGC 2264 IRS, in the latter source at a level which is 3-8 times lower than previous observations. The H_2D^+ data provide direct evidence in support of low-temperature chemical models in which H_2D^+ is enhanced by the reaction of H_3^+ and HD. The H_2D^+ enhancement toward NGC 1333 IRAS 4A is also reflected in the high DCO^+/HCO^+ abundance ratio. Simultaneous observations of the N_2H^+ 4-3 line show that its abundance is about 50-100 times lower in NGC 1333 IRAS 4A than in the other sources, suggesting significant depletion of N_2. The N_2H^+ data provide independent lower limits on the H_3^+ abundance which are consistent with the abundances derived from H_2D^+. The corresponding limits on the H_3^+$ column density agree with recent near-infrared absorption measurements of H_3^+ toward W 33A and GL 2591.

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Models and Observations of the Chemistry near Young Stellar Objects

The study of the chemical evolution of gas and dust from pre-stellar dense cores to circumstellar disks around young stars forms an essential part of understanding star- and planet formation. Throughout the collapse- and protostellar phases, simple and complex molecules are formed, many of which deplete onto cold grains and are eventually incorporated into the icy planetesimals of new solar systems. Tracing this chemical evolution provides a wealth of information, not only about the chemical processing in primitive solar nebulae, but also about physical processes which occur in the immediate surroundings of young stellar objects (YSOs). Here we review the chemical processes which occur in the protostellar environment, and models and observations of the chemical structure of the various stages of star formation. We briefly discuss the way in which molecular abundances are derived from observations, and conclude with two examples: the low- to intermediate mass YSOs in Serpens, and the massive YSOs in W3.

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The Impact of the Massive Young Star GL 2591 on its Circumstellar Material: Temperature, Density and Velocity Structure

The temperature, density and kinematics of the gas and dust surrounding the luminous young stellar object GL~2591 are investigated on scales as small as 100 AU, probed by 4.7 micron absorption spectroscopy, to over 60,000 AU, probed by single-dish submillimeter spectroscopy. These two scales are connected by interferometric 86-226 GHz images of size 60,000 AU and resolution 2000 AU in continuum and molecular lines. The data are used to constrain the physical structure of the envelope and investigate the influence of the young star on its immediate surroundings.

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ISO-LWS detection of the 112 micron HD J=1-0 line toward the Orion Bar

We report the first detection outside of the solar system of the lowest pure rotational J=1-0 transition of the HD molecule at 112 microns. The detection was made toward the Orion Bar using the Fabry-Perot of the Long Wavelength Spectrometer (LWS) on board the Infrared Space Observatory (ISO). The line appears in emission with an integrated flux of (0.93+/-0.17)e-19 Watts per cm squared in the LWS beam, implying a beam-averaged column density in the v=0, J=1 state of (1.2+/-0.2)e17 molecules per cm squared. Assuming LTE excitation, the total HD column density is (2.9+/-0.8)e17 molecules per cm squared for temperatures between 85 and 300 K. Combined with the total warm molecular hydrogen (H2) column density of about (1.5-3.0)e22 molecules per cm squared derived from either the H2 pure rotational lines, C18O observations or dust continuum emission, the implied HD abundance, HD/H2, ranges from 0.7e-5 to 2.6e-5, with a preferred value of (2.0+/-0.6)e-5. The corresponding deuterium abundance of [D]/[H]=(1.0+/-0.3)e-5 is compared with recent values derived from ultraviolet absorption line observations of atomic HI and DI in interstellar clouds in the solar neighborhood and in Orion.

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Far-Infrared and Sub-Millimeter Observations and Physical Models of the Reflection Nebula Ced 201

ISO [C II] 158 micron, [O I] 63 micron, and H_2 9 and 17 micron observations are presented of the reflection nebula Ced 201, which is a photon-dominated region illuminated by a B9.5 star with a color temperature of 10,000 K (a cool PDR). In combination with ground based [C I] 609 micron, CO, 13CO, CS and HCO+ data, the carbon budget and physical structure of the reflection nebula are constrained. The obtained data set is the first one to contain all important cooling lines of a cool PDR, and allows a comparison to be made with classical PDRs. To this effect one- and three-dimensional PDR models are presented which incorporate the physical characteristics of the source, and are aimed at understanding the dominant heating processes of the cloud. The contribution of very small grains to the photo-electric heating rate is estimated from these models and used to constrain the total abundance of PAHs and small grains. Observations of the pure rotational H_2 lines with ISO, in particular the S(3) line, indicate the presence of a small amount of very warm, approximately 330 K, molecular gas. This gas cannot be accommodated by the presented models.

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Molecular Cloud Structure in the Magellanic Clouds: Effect of Metallicity

The chemical structure of neutral clouds in low metallicity environments is examined with particular emphasis on the H to H_2 and C+ to CO transitions. We observed near-IR H_2 lines and the CO J=1-0 line from 30 Doradus and N159/N160 in the Large Magellanic Cloud and from DEM S 16, DEM S 37, and LI-SMC 36 in the Small Magellanic Cloud. We find that the H_2 emission is UV-excited and that (weak) CO emission always exists (in our surveyed regions) toward positions where H_2 and [CII] emission have been detected. Using a PDR code and a radiative transfer code, we simulate the emission of line radiation from spherical clouds and from large planar clouds. Because the [CII] emission and H_2 emission arise on the surface of the cloud and the lines are optically thin, these lines are not affected by changes in the relative sizes of the neutral cloud and the CO bearing core, while the optically thick CO emission can be strongly affected. The sizes of clouds are estimated by measuring the deviation of CO emission strength from that predicted by a planar cloud model of a given size. The average cloud column density and therefore size increases as the metallicity decreases. Our result agrees with the photoionization regulated star formation theory by Mc Kee (1989).

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Tracing the envelopes around embedded low-mass young stellar objects with HCO+ and millimeter-continuum observations

Interferometer observations of millimeter-continuum (OVRO) and single-dish observations of HCO+ and H13CO+ J=1-0, 3-2, and 4-3 (JCMT, IRAM 30m) are presented of nine embedded low-mass young stellar objects (YSOs) in Taurus. All nine objects are detected at 3.4 and 2.7 mm, with fluxes of 4-200 mJy, and consist of unresolved (<3 arcsec) point sources, plus, toward about half of the objects, an extended envelope. The point sources likely are circumstellar disks, showing that these are established early in the embedded phase. Literature values of 1.1 mm continuum emission are used to trace the envelopes, carrying 0.001-0.26 M(sol). In HCO+, the 1-0 lines trace the surrounding clouds, while the 3-2 and 4-3 are concentrated toward the sources with intensities well correlated with the envelope flux. An HCO+/H2 abundance of 1.2e-8 is derived. The HCO+ line strengths and envelope fluxes can be fit simultaneously with the simple collapse model of Shu (1977), and related density power laws with slopes p=1-3. As an indicator of the relative evolutionary phase of a YSO, the ratio of HCO+ 3-2 line intensity over bolometric luminosity is proposed, which is roughly proportional to the current ratio of envelope over stellar mass. It is concluded that HCO+ 3-2 and 4-3 are excellent tracers of the early embedded phase of star formation.

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Circumstellar C2, CN, and CH+ in the optical spectra of post-AGB stars

We present optical high-resolution spectra of a sample of sixteen post-AGB stars and IRC +10216. Of the post-AGB stars, ten show C2 Phillips and Swan and CN Red System absorption, one CH+ emission, one CH+ absorption, and four without any molecules. We find typically Trot=43-399, 155-202, and 18-50 K, log N = 14.90-15.57, 14.35, and 15.03-16.47 cm-2 for C2, CH+, and CN respectively, and 0.6 20. The presence of C2 and CN absorption is correlated with cold dust (Tdust<300K) and the presence of CH+ with hot dust (Tdust>300K). All objects with the unidentified 21mum emission feature exhibit C2 and CN absorption, but not all objects with C2 and CN detections exhibit a 21mum feature. The derived expansion velocity, ranging from 5 to 44 km/s, is the same as that derived from CO millimeter line emission. This unambiguously proves that these lines are of circumstellar origin and are formed in the AGB ejecta (circumstellar shell expelled during the preceding AGB phase). Furthermore there seems to be a relation between the C2 molecular column density and the expansion velocity, which is attributed to the fact that a higher carbon abundance of the dust leads to a more efficient acceleration of the AGB wind. Using simple assumptions for the location of the molecular lines and molecular abundances, mass-loss rates have been derived from the molecular absorption lines and are comparable to those obtained from CO emission lines and the infrared excess.

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Lines of Circumstellar C2, CN, and CH+ in the Optical Spectra of Post-Agb Stars

Recent optical spectra of post-AGB stars show the presence of C2, CN, and CH+ originating in the circumstellar shell. We present here new, higher resolution spectra which provide constraints on the physical parameters and information on the line profiles. An empirical curve of growth for the C2 Phillips and CN Red system lines in the spectrum of HD 56126 yields b = 0.50 (+0.59, -0.23) km/s. CH+ (0,0) emission lines in the spectrum of the Red Rectangle have been resolved with a FWHM approx 8.5 pm 0.8 km/s. The circumstellar CN lines of IRAS 08005--2356 are resolved into two separate components with a velocity separation of Delta v = 5.7 pm 2.0 km/s. The line profiles of CN of HD 235858 have not been resolved.

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The Infrared Band Strengths of H2o, Co and Co2 in Laboratory Simulations of Astrophysical Ice Mixtures

Infrared spectroscopic observations toward objects obscured by dense cloud material show that H$_2$O, CO and, likely, CO$_2$ are important constituents of interstellar ice mantles. In order to accurately calculate the column densities of these molecules, it is important to have good measurements of their infrared band strengths in astrophysical ice analogs. We present the results of laboratory experiments to determine these band strengths. Improved experimental methods, relying on simultaneous independent depositions of the molecule to be studied and of the dominating ice component, have led to accuracies better than a few percent. Furthermore, the temperature behavior of the infrared band strengths of CO and H$_2$O are studied. In contrast with previous work, the strengths of the CO, CO$_2$, and H$_2$O infrared features are found to depend only weakly on the composition of the ice matrix, and the reversible temperature dependence of the CO band is found to be weaker than previously measured for a mixture of CO in H$_2$O.

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Evidence for Hco+ Infall toward T Tauri?

High spectral and spatial resolution observations of the HCO+ molecule toward the T Tau binary system obtained with the Owens Valley Millimeter Array reveal a broad emission line profile (V_LSR = 7.2 km/s, width = 2.0 km/s) upon which a narrow, redshifted absorption feature (V_LSR = 8.5 km/s, width +/- 0.5 km/s) is superposed. One possible interpretation of the absorption is that it arises from infall of molecular cloud envelope material onto the immediate circumbinary region, which would imply that large scale dynamic accretion processes are still active well into the optically visible stages of star formation. Provided the mass is deposited at radii sufficiently close to the young stars, estimates of the accretion rates indicate that infall may add enough material to the system to account for the FU~Orionis type flares recently observed in T~Tau in =< 100 yr.

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