arXiv subjects

F. Martelli

Publications and source records attributed to F. Martelli.

11 recordsLinked to original sources

arXiv2025

Effect of FABr Over-Stoichiometry on the Morphology and Optoelectronic Properties of Wide-Bandgap FAPbBr_3 Films

In this study, we investigate the impact of formamidinium bromide (FABr) over-stoichiometry in the precursor solution on the optoelectronic properties and morphology of the resulting films of formamidinium lead bromide (FAPbBr_3). Optical characterization, including steady-state absorption, photoluminescence (PL), and femtosecond transient absorption spectroscopy, reveals a systematic blueshift in emission energy with increasing FABr content, attributed to the passivation of bromine vacancies and to the reduction of defect-assisted recombination. Power-dependent PL confirms this interpretation: the stoichiometric film exhibits a PL band due to donor-acceptor pair (DAP) recombination as identified by the typical excitation-dependent blueshift, whereas FABr-enriched samples show no evidence of DAP emission, indicating effective defect passivation. Additionally, morphological characterization shows a reduction in grain size with increasing FABr excess, indicating a trade-off between improved electronic quality and enhanced structural disorder. The film synthesized with a 5% excess of FABr provides the optimal balance, yielding the highest power conversion efficiency (6.26%), average visible transmittance (61.6%), and light utilization efficiency (3.85%). These results demonstrate that fine-tuning the precursor stoichiometry through controlled FABr addition represents a simple yet effective strategy to enhance the optoelectronic quality and performance of semitransparent perovskite solar cells.

cond-mat.mtrl-sci↗

arXiv2025

Hole Transfer Dynamics in Thin Films of Mixed-Dimensional Quasi-2D Perovskites

The understanding of charge transfer processes in mixed-dimensional quasi-2D perovskites is crucial for their application in high-performance photovoltaic devices. In this work, we investigate the link between charge transport dynamics and morphology in a thin film of quasi-2D perovskites (PEA2MAn-1PbnI3n+1), grown with a distinct dimensionality gradient, where the n=1 phase is concentrated near the substrate and phases with higher dimensionality progressively increase in concentration toward the surface. By selectively exciting the n=4 phase, we observe efficient hole transfer to the n=2 and n=3 phases occurring within few tens of picoseconds after excitation. In contrast, the n=1 phase acts as a hole-blocking layer, limiting the overall charge transport efficiency. These results emphasize the critical importance of minimizing or eliminating the n=1 layer to enhance charge carrier separation and transport, offering valuable insights into the optimization of quasi-2D perovskite-based solar cells.

cond-mat.mes-hall↗

arXiv2022

Characterization of ion-beam-sputtered AlF$_3$ thin films for gravitational-wave interferometers

Thermal noise in amorphous coatings is a limitation for a wide range of precision experiments such as gravitational-wave detectors (GWDs). Mirrors for GWDs are composed of multiple thin layers of dielectric materials deposited on a substrate: the stack is made of layers with a high refractive index interleaved with layers of a low refractive index. The goal is to obtain high reflectivity and low thermal noise. In this paper we report on the optical and mechanical properties of ion-beam-sputtered aluminium fluoride (AlF$_3$) thin films which have one of the lowest refractive index among the known coating materials and we discuss their application in current and future GWDs.

physics.ins-det↗

arXiv2021

Optical and mechanical properties of ion-beam-sputtered MgF$_2$ thin films for gravitational-wave interferometers

Brownian thermal noise associated with highly reflective coatings is a fundamental limit for several precision experiments, including gravitational-wave detectors. Research is currently ongoing to find coatings with low thermal noise that also fulfill strict optical requirements such as low absorption and scatter. We report on the optical and mechanical properties of ion-beam-sputtered magnesium fluoride thin films, and we discuss the application of such coatings in current and future gravitational-wave detectors.

physics.ins-det↗

arXiv2014

Evaluation of the surface strength of glass plates shaped by hot slumping process

The Hot Slumping Technology is under development by several research groups in the world for the realization of grazing-incidence segmented mirrors for X-ray astronomy, based on thin glass plates shaped over a mould at temperatures above the transformation point. The performed thermal cycle and related operations might have effects on the strength characteristics of the glass, with consequences on the structural design of the elemental optical modules and consecutively on the entire X-ray optic for large astronomical missions like IXO and ATHENA. The mechanical strength of glass plates after they underwent the slumping process was tested through destructive double-ring tests in the context of a study performed by the Astronomical Observatory of Brera with the collaboration of Stazione Sperimentale del Vetro and BCV Progetti. The entire study has been realized on more than 200 D263 Schott borosilicate glass specimens of dimension 100 mm x 100 mm and thickness 0.4 mm, either flat or bent at a Radius of Curvature of 1000 mm through the particular pressure assisted hot slumping process developed by INAF-OAB. The collected experimental data have been compared to non-linear FEM analyses and treated with Weibull statistic to assess the current IXO glass X-ray telescope design, in terms of survival probability, when subject to static and acoustic loads characteristic of the launch phase. The paper describes the activities performed and presents the obtained results.

astro-ph.IM↗

arXiv2012

The Mn site in Mn-doped Ga-As nanowires: an EXAFS study

We present an EXAFS study of the Mn atomic environment in Mn-doped GaAs nanowires. Mn doping has been obtained either via the diffusion of the Mn used as seed for the nanowire growth or by providing Mn during the growth of Au-induced wires. As a general finding, we observe that Mn forms chemical bonds with As but is not incorporated in a substitutional site. In Mn-induced GaAs wires, Mn is mostly found bonded to As in a rather disordered environment and with a stretched bond length, reminiscent of that exhibited by MnAs phases. In Au-seeded nanowires, along with stretched Mn-As coordination we have found the presence of Mn in a Mn-Au intermetallic compound.

cond-mat.mtrl-sci↗

arXiv2003

Testing the performance of a blind burst statistic

In this work we estimate the performance of a method for the detection of burst events in the data produced by interferometric gravitational wave detectors. We compute the receiver operating characteristics in the specific case of a simulated noise having the spectral density expected for Virgo, using test signals taken from a library of possible waveforms emitted during the collapse of the core of Type II Supernovae.

gr-qc↗

arXiv1998

Solar models and neutrino deficit

The existing measurements of the solar neutrino flux are compared with the predictions of all models capable of reproducing the other solar observables. These predictions are supplemented by the hypothesis of neutrino oscillations with mass differences large enough to render energy-independent the depletion of the solar nu(e) flux. It is concluded that the data are consistent with this hypothesis and that an energy-dependence of the solar neutrino deficit must be regarded as an attractive possibility but not as a compelling reality.

hep-ph↗

arXiv1997

Is the solar neutrino deficit energy-dependent?

All existing measurements of the solar neutrino flux are compared with the predictions of the most recent solar model by Bahcall and Pinsonneault, modified by introducing the hypothesis of neutrino oscillations with mass differences large enough to render energy-independent any quantity observable on earth. It is concluded that the data are consistent with this hypothesis and that, at least for the time being, any energy-dependence of the solar neutrino deficit must be regarded as just an attractive theoretical possibility, but not as a compelling reality.

hep-ph↗

arXiv1996

Stokes shift in quantum wells: trapping versus thermalization

Low temperature photoluminescence and photoluminescence excitation measurements have been performed in a set of InGaAs/GaAs samples with different indium molar fraction, well width, growth conditions and post-growth treatment. This has allowed to change in a controlled way the degree and source of disorder in the samples, thus resulting in an excitonic absorption linewidth varying between 1 and 18 meV, and an ensueing Stokes shift changing between zero and 8 meV. The conditions of validity of two different models relating the Stokes shift to the linewidth broadening have been established in terms of different regimes of disorder and temperature. A continuous transition between those regimes has been demonstrated.

cond-mat↗

arXiv1996

A complete solution to neutrino mixing

Deviations from expectations have been claimed for solar, atmospheric and high energy prompt neutrinos from charm decay. This information, supplemented only by the existing very good upper limits for oscillations of the $ν_μ$ at accelerator energies, is used as input to a phenomenological three-flavour analysis of neutrino mixing. The solution found is unique and completely determines the mass eigenstates as well as the mixing matrix relating mass and flavour eigenstates. Assuming the mass eigenstates to follow the hierarchy $m_{1} \ll m_{2} \ll m_{3}$, their values are found to be $m_{1} \ll 10^{-2}$ eV, $m_{2} = (0.18 \pm 0.06)$ eV, $m_{3} = (19.4 \pm 0.7)$ eV. These masses are in agreement with the leptonic quadratic hierarchy of the see-saw model and large enough to render energy-independent any oscillation-induced phenomenon in solar neutrino physics observable on Earth. This possibility is not excluded by the present knowledge of solar neutrino physics. The mixing angles are determined to be $θ_{12} = 0.55 \pm 0.08$, $θ_{13} = 0.38 \pm 0.06$, $θ_{23} < 0.03$. Small values of $θ_{23}$ are typical of any solution in which $m_{3}$ lies in the cosmological interesting region. The solution found is not in serious contradiction with any of the present limits to the existence of neutrino oscillations. The most relevant implications in particle physics, astrophysics and cosmology are discussed.

hep-ph↗