arXiv subjects
Publications and source records attributed to Francesco Cappelli.
Feature importance methods using unrestricted permutations are flawed due to extrapolation errors; such errors appear in all non-trivial variable importance approaches. We propose three new approaches: conditional model reliance and Knockoffs with Gaussian transformation, and restricted ALE plot designs. Theoretical and numerical results show our strategies reduce/eliminate extrapolation.
Quantum cascade lasers (QCLs) are unipolar semiconductor lasers first demonstrated in 1994. Since then, they have played a central role in advancing mid-infrared and terahertz photonics, becoming among the most reliable light sources in these regions of the electromagnetic spectrum. Their importance is further reinforced by their ability to generate self-starting optical frequency combs, whose investigation is motivated both by fundamental physics and by a wide range of applications, including molecular spectroscopy and free-space optical communications. This Roadmap provides a unified overview of current advances and emerging directions in QCL research. The chapters are organized into three main sections: device design and technology; frequency combs and pulse formation; and applications of QCLs. Each chapter reviews the relevant background, summarizes the current state of the art, and identifies key challenges and future directions within its specific research area.
Noise characteristics of state-of-the art light sources are crucial parameters in understanding their limitations towards quantum applications. This work describes a method to study the electrical noise transfer of current driver sources to the intensity noise of mid-infrared emission by commercial quantum and interband cascade lasers (QCLs and ICLs, respectively). A current driver with sub-shot electrical noise in a specific frequency range (up to 10 dB below the shot noise level) was developed for this purpose. This enables testing the performance of mid-infrared lasers when driven via such a quiet pump source. By using this novel current driver, we identify the fundamental noise of a QCL and an ICL, that is the laser intensity noise resulting solely from the internal dynamics of the laser under test. The proposed methodology allows us to retrieve the noise transfer function from current to light, showing that the main limitations in observing the quantum properties of the emitted photons come from laser excess noise and poor matching between laser and detection system in terms of bandwidth and optical power. From the analysis of the measured parameters, we highlight current technological limitations and suggest which key features should be optimized in mid-infrared systems for matching the performance required by quantum applications.
Quantum cascade lasers (QCLs) are semiconductor-heterostructure devices known for their emission in the mid-infrared and THz spectral regions. Due to their operating regime, their intrinsic linewidth is significantly narrower compared to bipolar semiconductor lasers. Here, we demonstrate that by implementing an external-cavity (EC) configuration based on a commercial diffraction grating, we have successfully induced a Fabry-Perot QCL to emit on a single mode with a broadly-tunable wavelength in the range 4.29-4.44 {\mu}m. This very simple setup enhances the laser's performance in terms of threshold current and emitted power. We further prove that the EC configuration positively impacts the laser's noise properties. In particular, the intrinsic linewidth is substantially reduced, the full linewidth is also decreased (depending on the integration timescale), and the relative intensity noise is slightly reduced. These characteristics, which hold within the whole tuning range, make the EC-QCL a good candidate for spectroscopy applications where broad tunability and narrow linewidth are highly demanded.
Versatile, ultracompact, easy-to-handle, high-sensitivity sensors are compelling tools for in situ pivotal applications, such as medical diagnostics, security and safety assessments, and environmental control. In this work, we combine photoacoustic spectroscopy and feedback interferometry, proposing a novel trace-gas sensor equipped with a self-mixing readout. This scheme demonstrates a readout sensitivity comparable to that of bulkier state-of-the-art balanced Michelson-interferometric schemes, achieving the same spectroscopic performance in terms of signal-to-noise ratio (SNR) and minimum detection limit (MDL). At the same time, the self-mixing readout benefits from a reduced size and a lower baseline, paving the way for future system downsizing and integration while offering a higher detectability for lower gas concentrations. Moreover, the intrinsic wavelength independence of both self-mixing and photoacoustic techniques allows the applicability and tailorability of the sensor to any desired spectral range.
This work describes a self-mixing-assisted optomechanical platform for transferring information between near- and mid-infrared radiation. In particular, the self-mixing signal of a mid-infrared quantum cascade laser is used to detect the oscillation of a membrane driven by light-induced forces exerted by a near-infrared excitation beam, which is amplitude-modulated at the membrane resonance frequency. This technique benefits from spectral broadness and, therefore, can link different spectral regions from both the excitation and probe sides. This versatility can pave the way for future applications of this self-mixing-assisted optomechanical platform in communication and advanced sensing systems.
Quantum technologies play a central role in establishing new ways of quantum-secured communication. We investigate Free-Space Quantum Communication and explore the advantage of implementing Quantum Key Distribution (QKD) with weak coherent states produced by a light source in the Mid-Infrared (>3$\mu$m). We simulate time-bin encoded quantum key distribution and demonstrate that a free-space QKD link operating in the Mid-infrared outperforms configurations based on conventional near-infrared wavelengths under various weather scenarios, with a particular significance in adverse meteorological conditions.
Single photon detection is the underpinning technology for quantum communication and quantum sensing applications. At visible and near-infrared wavelengths, single-photon-detectors (SPDs) underwent a significant development in the past two decades, with the commercialization of SPADs and superconducting detectors. At longer wavelengths, in the mid-infrared range (4-11$\mu$um), given the reduced scattering and favourable transparent atmospheric windows, there is an interest in developing quantum earth-satellites-links and quantum imaging for noisy environments or large-distance telescopes. Still, SPD-level mid-infrared devices have been rarely reported in the state-of-the-art (superconductors, single-electron-transistors or avalanche-photodiodes) and, crucially, all operating at cryogenic temperatures. Here, we demonstrate a room-temperature detection system operating at 4.6$\mu$m-wavelength with a sensitivity-level of atto-watt optical power, corresponding to few tens of mid-infrared photons. This result was obtained by exploiting a pair of commercially available photodetectors within two balanced-heterodyne-detection setups: one involving a quantum-cascade-laser (QCL) and an acousto-optic-modulator (AOM) and the other one including two QCLs with mutual coherence ensured by a phase-lock-loop (PLL). Our work not only validates a viable method to detect ultra-low-intensity signals, but is also potentially scalable to the entire wavelength range already accessible by mature QCL technology, unfolding - for the first time - quantum applications at mid- and long-wave-infrared-radiation.
The intensity noise of a laser source represents one of the key factors limiting the ultimate sensitivity in laser-based systems for sensing and telecommunication. For advanced applications based on interferometry, the availability of a shot-noise-limited local oscillator is even more important for the effective feasibility of high-precision measurements. This is particularly crucial in quantum optics applications based on homodyne detection schemes to measure non-classical light states, such as squeezed states. This work deeply investigates and analyzes the intensity noise features of the most widely used mid-infrared semiconductor heterostructured lasers: quantum cascade and interband cascade lasers. For this purpose, a comprehensive comparison of three different continuous-wave lasers operating at room temperature around 4.5 {\mu}m wavelength is presented. First, a thorough electro-optical characterization is given, highlighting the differences and the shared common characteristics of the tested devices. Then, a detailed intensity noise analysis is reported, identifying their different noise operations with a particular reference to shot-noise-limited operations. Finally, some perspectives towards advanced applications are discussed.
Many precision applications in the mid-infrared spectral range have strong constraints based on quantum effects that are expressed in particular noise characteristics. They limit, e.g., sensitivity and resolution of mid-infrared imaging and spectroscopic systems as well as the bit-error rate in optical free-space communication. Interband cascade lasers (ICLs) are a class of mid-infrared laser exploiting interband transitions in type-II band alignment geometry. They are currently gaining significant importance for mid-infrared applications from <3 {\mu}m to >6 {\mu}m wavelength, enabled by novel types of high-performance ICLs such as ring-cavity devices. Their noise-behavior is an important feature that still needs to be thoroughly analyzed, including its potential reduction with respect to the shot noise limit. In this work, we provide a comprehensive characterization of {\lambda} = 3.8 {\mu}m-emitting, continuous-wave ring-ICLs operating at room temperature. It is based on an in-depth study of their main physical intensity noise features, such as their bias-dependent intensity noise power spectral density (INPSD) and relative intensity noise (RIN). We obtain shot-noise-limited statistics for Fourier frequencies above 100 kHz. This is an important result for precision applications, e.g. interferometry or advanced spectroscopy, which benefit from exploiting the advantage of using such a shot-noise limited source, enhancing the setup sensitivity. Moreover, it is an important feature for novel quantum optics schemes including testing specific light states below the shot noise level, such as squeezed states.
The recent development of Quantum Cascade Lasers (QCLs) represents one of the biggest opportunities for the deployment of a new class of Free Space Optical (FSO) communication systems working in the mid-infrared (Mid-IR) wavelength range. As compared to more common FSO systems exploiting the telecom range, the larger wavelength employed in Mid-IR systems delivers exceptional benefits in case of adverse atmospheric conditions, as the reduced scattering rate strongly suppresses detrimental effects on the FSO link length given by the presence of rain, dust, fog and haze. In this work, we use a novel FSO testbed operating at \SI{4.7}{\micro m}, to provide a detailed experimental analysis of noise regimes that could occur in realistic FSO Mid-IR systems based on QCLs. Our analysis reveals the existence of two distinct noise regions, corresponding to different realistic channel attenuation conditions, which are precisely controlled in our setup. To relate our results with real outdoor configurations, we combine experimental data with predictions of an atmospheric channel loss model, finding that error-free communication could be attained for effective distances up to 8~km in low visibility conditions of 1 km. Our analysis of noise regimes may have a key relevance for the development of novel, long-range FSO communication systems based on Mid-IR QCL sources
A novel study on harmonic frequency combs emitted by Quantum Cascade Lasers (QCLs) is here presented, demonstrating the presence of intensity correlations between twin modes characterising the emission spectra. These originate from a Four-Wave Mixing (FWM) process driven by the active medium's third-order non-linearity. The study of such correlations is essential for the engineering of a new generation of semiconductor devices with the potential of becoming integrated emitters of light with quantum properties, such as squeezing and entanglement. Starting from experimental results, the limits of state-of-the-art technology are discussed as well as the possible methodologies that could lead to the detection of non-classical phenomena, or alternatively improve the design of QCLs, in the compelling perspective of generating quantum correlations in mid-infrared light.
Quantum cascade laser frequency combs are nowadays well-appreciated sources for infrared spectroscopy. Here their applicability for free-space optical communication is demonstrated. The spontaneously-generated intermodal beat note of the frequency comb is used as carrier for transferring the analog signal via frequency modulation. Exploiting the atmospheric transparency window at 4 $μ$m, an optical communication with a signal-to-noise ratio up to 65 dB is realized, with a modulation bandwidth of 300 kHz. The system tolerates a maximum optical attenuation exceeding 35 dB. The possibility of parallel transmission of an independent digital signal via amplitude modulation at 5 MS/s is also demonstrated.
We propose to use ultracold fermionic atoms in one-dimensional optical lattices to quantum simulate the electronic transport in quantum cascade laser (QCL) structures. The competition between the coherent tunneling among (and within) the wells and the dissipative decay at the basis of lasing is discussed. In order to validate the proposed simulation scheme, we quantitatively address such competition in a simplified one-dimensional model. We show the existence of optimal relationships between the model parameters, maximizing the particle current, the population inversion (or their product), and the stimulated emission rate. This substantiates the concept of emulating the QCL operation mechanisms in cold-atom optical lattice simulators, laying the groundwork for addressing open questions, such as the impact of electron-electron scattering and the origin of transport-induced noise, in the design of new-generation QCLs.
Terahertz quantum cascade laser sources based on intra-cavity difference frequency generation from mid-IR devices are an important asset for applications in rotational molecular spectroscopy and sensing, beingthe only electrically pumped device able to operate in the 0.6-6 THz range without the need of bulky andexpensive liquid helium cooling. Here we present comb operation obtained by intra-cavity mixing of adistributed feedback laser at λ = 6.5 μm and a Fabry-Pérot device at around λ = 6.9 μm. The resultingultra-broadband THz emission extends from 1.8 to 3.3 THz, with a total output power of 8 μW at 78K.The THz emission has been characterized by multi-heterodyne detection with a primary frequencystandard referenced THz comb, obtained by optical rectification of near infrared pulses. The down-converted beatnotes, simultaneously acquired, confirm an equally spaced THz emission down to 1 MHzaccuracy. In the next future this setup can be used for Fourier transform based evaluation of the phaserelation among the emitted THz modes, paving the way to room-temperature, compact and field-deployable metrological grade THz frequency combs.
We present the characterization of a novel balanced homodyne detector operating in the mid-infrared. The challenging task of revealing non-classicality in mid-infrared light, e.~g. in quantum cascade lasers emission, requires a high-performance detection system. Through the intensity noise power spectral density analysis of the differential signal coming from the incident radiation, we show that our setup is shot-noise limited. We discuss the experimental results with a view to possible applications to quantum technologies, such as free-space quantum communication.
Four-wave-mixing-based quantum cascade laser frequency combs (QCL-FC) are a powerful photonic tool, driving a recent revolution in major molecular fingerprint regions, i.e. mid- and far-infrared domains. Their compact and frequency-agile design, together with their high optical power and spectral purity, promise to deliver an all-in-one source for the most challenging spectroscopic applications. Here, we demonstrate a metrological-grade hybrid dual comb spectrometer, combining the advantages of a THz QCL-FC with the accuracy and absolute frequency referencing provided by a free-standing, optically-rectified THz frequency comb. A proof-of-principle application to methanol molecular transitions is presented. The multi-heterodyne molecular spectra retrieved provide state-of-the-art results in line-center determination, achieving the same precision as currently available molecular databases. The devised setup provides a solid platform for a new generation of THz spectrometers, paving the way to more refined and sophisticated systems exploiting full phase control of QCL-FCs, or Doppler-free spectroscopic schemes.
The road towards the realization of quantum cascade laser (QCL) frequency combs (QCL-combs) has undoubtedly attracted ubiquitous attention from the scientific community, as these devices promise to deliver all-in-one (i.e. a single, miniature, active devices) frequency comb (FC) synthesizers in a range as wide as QCL spectral coverage itself (from about 4 microns to the THz range), with the unique possibility to tailor their spectral emission by band structure engineering. For these reasons, vigorous efforts have been spent to characterize the emission of four-wave-mixing multi-frequency devices, aiming to seize their functioning mechanisms. However, up to now, all the reported studies focused on free-running QCL-combs, eluding the fundamental ingredient that turns a FC into a useful metrological tool. For the first time we have combined mode-locked multi-frequency QCL emitters with full phase stabilization and independent control of the two FC degrees of freedom. At the same time, we have introduced the Fourier transform analysis of comb emission (FACE) technique, used for measuring and simultaneously monitoring the Fourier phases of the QCL-comb modes. The demonstration of tailored-emission, miniaturized, electrically-driven, mid-infrared/THz coverage, fully-stabilized and fully-controlled QCL-combs finally enables this technology for metrological-grade applications triggering a new scientific leap affecting several fields ranging from everyday life to frontier-research.