arXiv subjects

Francesco Piazza

Publications and source records attributed to Francesco Piazza.

At least 73 records · Page 4Linked to original sources

arXiv2017

Hopping in the crowd to unveil network topology

We introduce a nonlinear operator to model diffusion on a complex undirected network under crowded conditions. We show that the asymptotic distribution of diffusing agents is a nonlinear function of the nodes' degree and saturates to a constant value for sufficiently large connectivities, at variance with standard diffusion in the absence of excluded-volume effects. Building on this observation, we define and solve an inverse problem, aimed at reconstructing the a priori unknown connectivity distribution. The method gathers all the necessary information by repeating a limited number of independent measurements of the asymptotic density at a single node that can be chosen randomly. The technique is successfully tested against both synthetic and real data, and shown to estimate with great accuracy also the total number of nodes.

cond-mat.stat-mech↗

arXiv2017

Probing and characterizing the growth of a crystal of ultracold bosons and light

The non-linear coupled particle light dynamics of an ultracold gas in the field of two independent counter-propagating laser beams can lead to the dynamical formation of a self-ordered lattice structure as presented in Phys. Rev. X 6, 021026 (2016). Here we present new numerical studies on experimentally observable signatures to monitor the growth and properties of such a crystal in real time. While, at least theoretically, optimal non-destructive observation of the growth dynamics and the hallmarks of the crystalline phase can be performed by analyzing the scattered light, monitoring the evolution of the particle's momentum distribution via time-of-flight probing is an experimentally more accessible choice. In this work we show that both approaches allow to unambiguously distinguish the crystal from independent collective scattering as it occurs in matter wave super-radiance. As a clear crystallization signature we identify spatial locking between the two emerging standing laser waves together creating the crystal potential. For sufficiently large systems the system allows reversible adiabatic ramping into the crystalline phase as an alternative to a quench across the phase transition and growth from fluctuations.

quant-ph↗

arXiv2017

Disorder-Driven Density and Spin Self-Ordering of a Bose-Einstein Condensate in a Cavity

We study spatial spin and density self-ordering of a two-component Bose-Einstein condensate via collective Raman scattering into a linear cavity mode. The onset of the Dicke superradiance phase transition is marked by a simultaneous appearance of a crystalline density order and a spin-wave order. The latter spontaneously breaks the discrete $\mathbf{Z}_2$ symmetry between even and odd sites of the cavity optical potential. Moreover, in the superradiant state the continuous $U(1)$ symmetry of the relative phase of the two condensate wavefunctions is explicitly broken by the cavity-induced position-dependent Raman coupling with a zero spatial average. Thus, the spatially-averaged relative condensate phase is locked at either $π/2$ or $-π/2$. This continuous symmetry breaking and relative condensate phase locking by a zero-average Raman field can be considered as a generic order-by-disorder process similar to the random-field-induced order in the two-dimensional classical ferromagnetic $XY$ spin model. However, the seed of the random field in our model stems from quantum fluctuations in the cavity field and is a dynamical entity affected by self-ordering. The spectra of elementary excitations exhibit the typical mode softening at the superradiance threshold.

cond-mat.quant-gas↗

arXiv2017

Exciton transport in the PE545 complex: insight from atomistic QM/MM-based quantum master equations and elastic network models

In this paper we work out a parameterization of the environment noise within the Haken-Strobl-Reinenker (HSR) model for the PE545 light-harvesting complex based on atomic-level quantum mechanics/molecular mechanics (QM/MM) simulations. We use this approach to investigate the role of different auto- and cross-correlations in the HSR noise tensor, confirming that site-energy autocorrelations (pure dephasing) terms dominate the noise-induced exciton mobility enhancement, followed by site energy-coupling cross-correlations for specific triplets of pigments. Interestingly, several cross-correlations of the latter kind, together with coupling-coupling cross-correlations, display clear low-frequency signatures in their spectral densities in the region 30-70 inverse centimeters. These slow components lie at the limits of validity of the HSR approach, requiring that environmental fluctuations be faster than typical exciton transfer time scales. We show that a simple coarse-grained elastic-network-model (ENM) analysis of the PE545 protein naturally spotlights collective normal modes in this frequency range, that represent specific concerted motions of the subnetwork of cysteines that are covalenty linked to the pigments. This analysis strongly suggests that protein scaffolds in light-harvesting complexes are able to express specific collective, low-frequency normal modes providing a fold-rooted blueprint of exciton transport pathways. We speculate that ENM-based mixed quantum classical methods, such as Ehrenfest dynamics, might be promising tools to disentangle the fundamental designing principles of these dynamical processes in natural and artificial light-harvesting structures.

q-bio.BM↗

arXiv2016

Absence of thermalization for systems with long-range interactions coupled to a thermal bath

We investigate the dynamics of a small long-range interacting system, in contact with a large long-range thermal bath. Our analysis reveals the existence of striking anomalies in the energy flux between the bath and the system. In particular, we find that the evolution of the system is not influenced by the kinetic temperature of the bath, as opposed to what happens for short-range collisional systems. As a consequence, the system may get hotter also when its initial temperature is larger than the bath temperature. This observation is explained quantitatively in the framework of the collisionless Vlasov description of toy models with long-range interactions and shown to be valid whenever the Vlasov picture applies, from cosmology to plasma physics.

cond-mat.stat-mech↗

arXiv2016

Critical relaxation with overdamped quasiparticles in open quantum systems

We study the late-time relaxation following a quench in a driven-dissipative quantum many-body system. We consider the open Dicke model, describing the infinite-range interactions between $N$ atoms and a single, lossy electromagnetic mode. We show that the dynamical phase transition at a critical atom-light coupling is characterized by the interplay between reservoir-driven and intrinsic relaxation processes. Above the critical coupling, small fluctuations in the occupation of the dominant quasiparticle-mode start to grow in time while the quasiparticle lifetime remains finite due to losses. Near the critical interaction strength we observe a crossover between exponential and power-law $1/τ$ relaxation, the latter driven by collisions between quasiparticles. For a quench exactly to the critical coupling, the power-law relaxation extends to infinite times, but the finite lifetime of quasiparticles prevents ageing to appear. We predict our results to be accessible to quench experiments with ultracold bosons in optical resonators.

cond-mat.quant-gas↗

arXiv2016

Transport of quantum excitations coupled to spatially extended nonlinear many-body systems

The role of noise in the transport properties of quantum excitations is a topic of great importance in many fields, from organic semiconductors for technological applications to light-harvesting complexes in photosynthesis. In this paper we study a semi-classical model where a tight-binding Hamiltonian is fully coupled to an underlying spatially extended nonlinear chain of atoms. We show that the transport properties of a quantum excitation are subtly modulated by (i) the specific type (local vs non-local) of exciton-phonon coupling and by (ii) nonlinear effects of the underlying lattice. We report a non-monotonic dependence of the exciton diffusion coefficient on temperature, in agreement with earlier predictions, as a direct consequence of the lattice-induced fluctuations in the hopping rates due to long-wavelength vibrational modes. A standard measure of transport efficiency confirms that both nonlinearity in the underlying lattice and off-diagonal exciton-phonon coupling promote transport efficiency at high temperatures, preventing the Zeno-like quench observed in other models lacking an explicit noise-providing dynamical system.

quant-ph↗

arXiv2016

A Superradiant Topological Peierls Insulator inside an Optical Cavity

We consider a spinless ultracold Fermi gas tightly trapped along the axis of an optical resonator and transversely illuminated by a laser closely tuned to a resonator mode. At a certain threshold pump intensity the homogeneous gas density breaks a $\mathbf{Z}_2$ symmetry towards a spatially periodic order, which collectively scatters pump photons into the cavity. We show that this known self-ordering transition also occurs for low field seeking fermionic particles when the laser light is blue-detuned to an atomic transition. The emergent superradiant optical lattice in this case is homopolar and possesses two distinct dimerizations. Depending on the spontaneously chosen dimerization the resulting Bloch bands can have a non-trivial topological structure characterized by a non-vanishing Zak phase. In the case the Fermi momentum is close to half the cavity-mode wavenumber, a Peierls-like instability here creates a topoloical insulator with a gap at the Fermi surface, which hosts a pair of edge states. The topological features of the system can be non-destructively observed via the cavity output: the Zak phase of the bulk coincides with the relative phase between laser and cavity field, while the fingerprint of edge states can be observed as additional broadening in a well defined frequency window of the cavity spectrum.

cond-mat.quant-gas↗

arXiv2016

Breaking of Goldstone modes in two component Bose-Einstein condensate

We study the decay rate $Γ(k)$ of density excitations of two-component Bose-Einstein condensates at zero temperature. Those excitations, where the two components oscillate in phase, include the Goldstone mode resulting from condensation. While within Bogoliubov approximation the density sector and the spin (out-of-phase) sector are independent, they couple at the three-phonon level. For a Bose-Bose mixture we find that the Belyaev decay is slightly modified due to the coupling with the gapless spin mode. At the phase separation point the decay rate changes instead from the standard $k^5$ to a $k^{5/2}$ behaviour due to the parabolic nature of the spin mode. In presence of coherent coupling between the two components the spin sector is gapped and, away from the ferromagnetic-like phase transition point, the decay of density mode is not affected. On the other hand at the transition point, when the spin fluctuations become critical, the Goldstone mode is not well defined anymore since $Γ(k)\propto k$. As a consequence, we show that the friction induced by a moving impurity is enahnced -- a feature which could be experimentally tested. Our results apply to every non-linear 2-component quantum hydrodynamic Hamiltonian which is time-reversal invariant, and possesses an $U(1)\times {\mathbf Z}_2$ symmetry.

cond-mat.quant-gas↗

arXiv2016

Parity Symmetry Breaking and Topological Phases in a Superfluid Ring

We study analytically the superfluid flow of a Bose-Einstein condensate in a ring geometry in presence of a rotating barrier. We show that a phase transition breaking a parity symmetry among two topological phases occurs at a critical value of the height of the barrier. Furthermore, a discontinuous (accompanied by hysteresis) phase transition is observed in the ordered phase when changing the angular velocity of the barrier. At the critical point where the hysteresis area vanishes, chemical potential of the ground state develops a cusp (a discontinuity in the first derivative). Along this path, the jump between the two corresponding states having a different winding number shows strict analogies with a topological phase transition. We finally study the current-phase relation of the system and compare some of our calculations with published experimental results.

cond-mat.quant-gas↗

arXiv2016

Reaction rate of a composite core-shell nanoreactor with multiple, spatially distributed embedded nano-catalysts

We present a detailed theory for the total reaction rate constant of a composite core-shell nanoreactor, consisting of a central solid core surrounded by a hydrogel layer of variable thickness, where a given number of small catalytic nanoparticles are embedded at prescribed positions and are endowed with a prescribed surface reaction rate constant. Besides the precise geometry of the assembly, our theory accounts explicitly for the diffusion coefficients of the reactants in the hydrogel and in the bulk as well as for their transfer free energy jump upon entering the hydrogel shell. Moreover, we work out an approximate analytical formula for the overall rate constant, which is valid in the physically relevant range of geometrical and chemical parameters. We discuss in depth how the diffusion-controlled part of the rate depends on the essential variables, including the size of the central core. In particular, we derive some simple rules for estimating the number of nanocatalysts per nanoreactor for an efficient catalytic performance in the case of small to intermediate core sizes. Our theoretical treatment promises to provide a very useful and flexible tool for the design of superior performing nanoreactor geometries and with optimized nanoparticle load.

cond-mat.soft↗

arXiv2016

Spontaneous crystallization of light and ultracold atoms

Coherent scattering of light from ultracold atoms involves an exchange of energy and momentum introducing a wealth of non-linear dynamical phenomena. As a prominent example particles can spontaneously form stationary periodic configurations which simultaneously maximize the light scattering and minimize the atomic potential energy in the emerging optical lattice. Such self-ordering effects resulting in periodic lattices via bimodal symmetry breaking have been experimentally observed with cold gases and Bose-Einstein condensates (BECs) inside an optical resonator. Here we study a new regime of periodic pattern formation for an atomic BEC in free space, driven by far off-resonant counterpropagating and non-interfering lasers of orthogonal polarization. In contrast to previous works, no spatial light modes are preselected by any boundary conditions and the transition from homogeneous to periodic order amounts to a crystallization of both light and ultracold atoms breaking a continuous translational symmetry. In the crystallized state the BEC acquires a phase similar to a supersolid with an emergent intrinsic length scale whereas the light-field forms an optical lattice allowing phononic excitations via collective back scattering, which are gapped due to the infinte-range interactions. The studied system constitutes a novel configuration allowing the simulation of synthetic solid state systems with ultracold atoms including long-range phonon dynamics.

quant-ph↗

arXiv2016

FFLO strange metal and quantum criticality in two dimensions: theory and application to organic superconductors

Increasing the spin imbalance in superconductors can spatially modulate the gap by forming Cooper pairs with finite momentum. For large imbalances compared to the Fermi energy, the inhomogeneous FFLO superconductor ultimately becomes a normal metal. There is mounting experimental evidence for this scenario in 2D organic superconductors in large in-plane magnetic fields; this is complemented by ongoing efforts to realize this scenario in coupled tubes of atomic Fermi gases with spin imbalance. Yet, a theory for the phase transition from a metal to an FFLO superconductor has not been developed so far and the universality class has remained unknown. Here we propose and analyze a spin imbalance driven quantum critical point between a 2D metal and an FFLO phase in anisotropic electron systems. We derive the effective action for electrons and bosonic FFLO pairs at this quantum phase transition. Using this action, we predict non-Fermi liquid behavior and the absence of quasi-particles at a discrete set of hot spots on the Fermi surfaces. This results in strange power-laws in thermodynamics and response functions, which are testable with existing experimental set-ups on 2D organic superconductors and may also serve as signatures of the elusive FFLO phase itself. The proposed universality class is distinct from previously known quantum critical metals and, because its critical fluctuations appear already in the pairing channel, a promising candidate for naked metallic quantum criticality over extended temperature ranges.

cond-mat.str-el↗

arXiv2015

Theory of diffusion-influenced reactions in complex geometries

Chemical reactions involving diffusion of reactants and subsequent chemical fixation steps are generally termed "diffusion-influenced" (DI). Virtually all biochemical processes in living media can be counted among them, together with those occurring in an ever-growing number of emerging nano-technologies. The role of the environment's geometry (obstacles, compartmentalization) and distributed reactivity (competitive reactants, traps) is key in modulating the rate constants of DI reactions, and is therefore a prime design parameter. Yet, it is a formidable challenge to build a comprehensive theory able to describe the environment's "reactive geometry". Here we show that such a theory can be built by unfolding this many-body problem through addition theorems for special functions. Our method is powerful and general and allows one to study a given DI reaction occurring in arbitrary "reactive landscapes", made of multiple spherical boundaries of given size and reactivity. Importantly, ready-to-use analytical formulas can be derived easily in most cases.

physics.chem-ph↗

arXiv2015

Self-organised Limit-Cycles, Chaos and Phase-Slippage with a Superfluid inside an Optical Resonator

We study dynamical phases of a driven Bose-Einstein condensate coupled to the light field of a high-Q optical cavity. For high field seeking atoms at red detuning the system is known to show a transition from a spatially homogeneous steady-state to a self-organized regular lattice exhibiting super-radiant scattering into the cavity. For blue atom pump detuning the particles are repelled from the maxima of the light-induced optical potential suppressing scattering. We show that this generates a new dynamical instability of the self-ordered phase, leading to the appearance of self-ordered stable limit-cycles characterized by large amplitude self-sustained oscillations of both the condensate density and cavity field. The limit-cycles evolve into chaotic behavior by period doubling. Large amplitude oscillations of the condensate are accompanied by phase-slippage through soliton nucleation at a rate which increases by orders of magnitude in the chaotic regime. Different from a superfluid in a closed setup, this driven dissipative superfluid is not destroyed by the proliferation of solitons since kinetic energy is removed through cavity losses.

cond-mat.quant-gas↗

arXiv2015

Self-Ordered stationary states of driven quantum degenerate gases in optical resonators

We study the role of quantum statistics in the self-ordering of ultracold bosons and fermions moving inside an optical resonator with transverse coherent pumping. For few particles we numerically compute the nonequilibrium dynamics of the density matrix towards the self-ordered stationary state of the coupled atom-cavity system. We include quantum fluctuations of the particles and the cavity field. These fluctuations in conjunction with cavity cooling determine the stationary distribution of the particles, which exhibits a transition from a homogeneous to a spatially ordered phase with the appearance of a superradiant scattering peak in the cavity output spectrum. At the same time the cavity field $Q$-function changes from a single to a double peaked distribution. While the ordering threshold is generally lower for bosons, we confirm the recently predicted zero pump strength threshold for superradiant scattering for fermions when the cavity photon momentum coincides with twice the Fermi momentum.

quant-ph↗

arXiv2014

Diffusion-influenced reactions in a hollow nano-reactor with a circular hole

Hollow nanostructures are paid increasing attention in many nanotechnology-related communities in view of their numerous applications in chemistry and biotechnology, e.g. as smart nanoreactors or drug-delivery systems. In this paper we consider irreversible, diffusion-influenced reactions occurring within a hollow spherical cavity endowed with a circular hole on its surface. Importantly, our model is not limited to small sizes of the aperture. In our scheme, reactants can freely diffuse inside and outside the cavity through the hole, and react at a spherical boundary of given size encapsulated in the chamber and endowed with a given intrinsic rate constant. We work out the solution of the above problem, enabling one to compute the reaction rate constant to any desired accuracy. Remarkably, we show that, in the case of narrow holes, the rate constant is extremely well-approximated by a simple formula that can be derived on the basis of simple physical arguments and that can be readily employed to analyze experimental data.

cond-mat.other↗

arXiv2014

Phase-slips and vortex dynamics in Josephson oscillations between Bose-Einstein condensates

We study the relation between Josephson dynamics and topological excitations in a dilute Bose-Einstein condensate confined in a double-well trap. We show that the phase slips responsible for the self-trapping regime are created by vortex rings entering and annihilating inside the weak-link region or created at the center of the barrier and expanding outside the system. Large amplitude oscillations just before the onset of self-trapping are also strictly connected with the dynamics of vortex rings at the edges of the inter-well barrier. Our results extend and analyze the dynamics of the vortex-induced phase slippages suggested a few decades ago in relation to the "ac" Josephson effect of superconducting and superfluid helium systems.

cond-mat.quant-gas↗