arXiv subjects

Francesco Piazza

Publications and source records attributed to Francesco Piazza.

At least 55 records · Page 3Linked to original sources

arXiv2019

Hierarchy of relaxation timescales in local random Liouvillians

To characterize the generic behavior of open quantum systems, we consider random, purely dissipative Liouvillians with a notion of locality. We find that the positivity of the map implies a sharp separation of the relaxation timescales according to the locality of observables. Specifically, we analyze a spin-1/2 system of size $\ell$ with up to $n$-body Lindblad operators, which are $n$-local in the complexity-theory sense. Without locality ($n=\ell$), the complex Liouvillian spectrum densely covers a "lemon"-shaped support, in agreement with recent findings [Phys. Rev. Lett. 123, 140403;arXiv:1905.02155]. However, for local Liouvillians ($n<\ell$), we find that the spectrum is composed of several dense clusters with random matrix spacing statistics, each featuring a lemon-shaped support wherein all eigenvectors correspond to $n$-body decay modes. This implies a hierarchy of relaxation timescales of $n$-body observables, which we verify to be robust in the thermodynamic limit.

cond-mat.str-el↗

arXiv2019

Diffusion-influenced reactions on non-spherical partially absorbing axisymmetric surfaces

The calculation of the diffusion-controlled reaction rate for partially absorbing, non-spherical boundaries presents a formidable problem of broad relevance. In this paper we take the reference case of a spherical boundary and work out a perturbative approach to get a simple analytical formula for the first-order correction to the diffusive flux onto a non-spherical partially absorbing surface of revolution. To assess the range of validity of this formula, we derive exact and approximate expressions for the reaction rate in the case of partially absorbing prolate and oblate spheroids. We also present numerical solutions by a finite-element method that extend the validity analysis beyond spheroidal shapes. Our perturbative solution provides a handy way to quantify the effect of non-sphericity on the rate of capture in the general case of partial surface reactivity.

cond-mat.stat-mech↗

arXiv2019

Emergent Quasicrystalline Symmetry in Light-Induced Quantum Phase Transitions

The discovery of quasicrystals with crystallographically forbidden rotational symmetries has changed the notion of the ordering in materials, yet little is known about the dynamical emergence of such exotic forms of order. Here we theoretically study a nonequilibrium cavity-QED setup realizing a zero-temperature quantum phase transition from a homogeneous Bose-Einstein condensate to a quasicrystalline phase via collective superradiant light scattering. Across the superradiant phase transition, collective light scattering creates a dynamical, quasicrystalline optical potential for the atoms. Remarkably, the quasicrystalline potential is "emergent" as its eight-fold rotational symmetry is not present in the Hamiltonian of the system, rather appears solely in the low-energy states. For sufficiently strong two-body contact interactions between atoms, a quasicrystalline order is stabilized in the system, while for weakly interacting atoms the condensate is localized in one or few of the deepest minima of the quasicrystalline potential.

cond-mat.quant-gas↗

arXiv2019

Mesoscale computational protocols for the design of highly cooperative bivalent macromolecules

The last decade has witnessed a swiftly increasing interest in the design and production of novel multivalent molecules as powerful alternatives for conventional antibodies in the fight against cancer and infectious diseases. However, while it is widely accepted that large-scale flexibility ($10-100$ nm) and free/constrained dynamics (100 ns $- μ$s) control the activity of such novel molecules, computational strategies at the mesoscale still lag behind experiments in optimizing the design of crucial features, such as the binding cooperativity (a.k.a. avidity). In this study, we introduced different coarse-grained models of a polymer-linked, two-nanobody composite molecule, with the aim of laying down the physical bases of a thorough computational drug design protocol at the mesoscale. We show that the calculation of suitable potentials of mean force allows one to apprehend the nature, range and strength of the thermodynamic forces that govern the motion of free and wall-tethered molecules. Furthermore, we develop a simple computational strategy to quantify the encounter/dissociation dynamics between the free end of a wall-tethered molecule and the surface, at the roots of binding cooperativity. This procedure allows one to pinpoint the role of internal flexibility and weak non-specific interactions on the kinetic constants of the NB-wall encounter and dissociation. Finally, we quantify the role and weight of rare events, which are expected to play a major role in real-life situations, such as in the immune synapse, where the binding kinetics is likely dominated by fluctuations.

cond-mat.soft↗

arXiv2019

Exceptional points and the topology of quantum many-body spectra

We show that in a generic, ergodic quantum many-body system the interactions induce a non-trivial topology for an arbitrarily small non-hermitean component of the Hamiltonian. This is due to an exponential-in-system-size proliferation of exceptional points which have the hermitian limit as an accumulation (hyper-)surface. The nearest-neighbour level repulsion characterizing hermitian ergodic many-body sytems is thus shown to be a projection of a richer phenomenology where actually all the exponentially many pairs of eigenvalues interact. The proliferation and accumulation of exceptional points also implies an exponential difficulty in isolating a local ergodic quantum many-body system from a bath, as a robust topological signature remains in the form of exceptional points arbitrarily close to the hermitian limit.

quant-ph↗

arXiv2019

Topological soliton-polaritons in 1D systems of light and fermionic matter

Quantum nonlinear optics is a quickly growing field with large technological promise, at the same time involving complex and novel many-body phenomena. In the usual scenario, optical nonlinearities originate from the interactions between polaritons, which are hybrid quasi-particles mixing matter and light degrees of freedom. Here we introduce a type of polariton which is intrinsically nonlinear and emerges as the natural quasi-particle in presence quantum degenerate fermionic matter. It is a composite object made of a fermion trapped inside an optical soliton forming a topological defect in a spontaneously formed crystalline structure. Each of these soliton-polaritons carries a $\textbf{Z}_2$ topological quantum number, as they create a domain wall between two crystalline regions with opposite dimerization so that the fermion is trapped in an interphase state. These composite objects are formally equivalent to those appearing in the Su-Schrieffer-Heeger (SSH) model for electrons coupled to lattice phonons.

cond-mat.quant-gas↗

arXiv2019

On time crystallinity in dissipative Floquet systems

We investigate the conditions under which periodically driven quantum systems subject to dissipation exhibit a stable subharmonic response. Noting that coupling to a bath introduces not only cooling but also noise, we point out that a system subject to the latter for the entire cycle tends to lose coherence of the subharmonic oscillations, and thereby the long-time temporal symmetry breaking. We provide an example of a short-ranged two-dimensional system which does not suffer from this and therefore displays persistent subharmonic oscillations stabilised by the dissipation. We also show that this is fundamentally different from the disordered DTC previously found in closed systems, both conceptually and in its phenomenology. The framework we develop here clarifies how fully connected models constitute a special case where subharmonic oscillations are stable in the thermodynamic limit.

cond-mat.stat-mech↗

arXiv2019

Cavity-quantum-electrodynamical toolbox for quantum magnetism

The recent experimental observation of spinor self-ordering of ultracold atoms in optical resonators has set the stage for the exploration of emergent magnetic orders in quantum-gas--cavity systems. Based on this platform, we introduce a generic scheme for the implementation of long-range quantum spin Hamiltonians composed of various types of couplings, including Heisenberg and Dzyaloshinskii-Moriya interactions. Our model is comprised of an effective two-component Bose-Einstein condensate, driven by two classical pump lasers and coupled to a single dynamic mode of a linear cavity in a double $Λ$ scheme. Cavity photons mediate the long-range spin-spin interactions with spatially modulated coupling coefficients, where the latter ones can be tuned by modifying spatial profiles of the pump lasers. As experimentally relevant examples, we demonstrate that by properly choosing the spatial profiles of the pump lasers achiral domain-wall antiferromagnetic and chiral spin-spiral orders emerge beyond critical laser strengths. The transition between these two phases can be observed in a single experimental setup by tuning the reflectivity of a mirror. We also discuss extensions of our scheme for the implementation of other classes of spin Hamiltonians.

cond-mat.quant-gas↗

arXiv2019

Universality of fold-encoded localized vibrations in enzymes

Enzymes speed up biochemical reactions at the core of life by as much as 15 orders of magnitude. Yet, despite considerable advances, the fine dynamical determinants at the microscopic level of their catalytic proficiency are still elusive. In this work, we use a powerful mathematical approach to show that rate-promoting vibrations in the picosecond range, specifically encoded in the 3D protein structure, are localized vibrations optimally coupled to the chemical reaction coordinates at the active site. The universality of these features is demonstrated on a pool of more than 900 enzyme structures, comprising a total of more than 10,000 experimentally annotated catalytic sites. Our theory provides a natural microscopic rationale for the known subtle structural compactness of active sites in enzymes.

physics.bio-ph↗

arXiv2019

Wavelet imaging of transient energy localization in nonlinear systems at thermal equilibrium: the case study of NaI crystals at high temperature

In this paper we introduce a method to resolve transient excitations in time-frequency space from molecular dynamics simulations. Our technique is based on continuous wavelet transform of velocity time series coupled to a threshold-dependent filtering procedure to isolate excitation events from background noise in a given spectral region. By following in time the center of mass of the reference frequency interval, the data can be easily exploited to investigate the statistics of the burst excitation dynamics, by computing, for instance, the distribution of the burst lifetimes, excitation times, amplitudes and energies. As an illustration of our method, we investigate transient excitations in the gap of NaI crystals at thermal equilibrium at different temperatures. Our results reveal complex ensembles of transient nonlinear bursts in the gap, whose lifetime and excitation rate increase with temperature. The method described in this paper is a powerful tool to investigate transient excitations in many-body systems at thermal equilibrium. Our procedure gives access to both the equilibrium and the kinetics of transient excitation processes, allowing one in principle to reconstruct the full picture of the dynamical process under examination.

cond-mat.other↗

arXiv2018

Multipartite-Entanglement Dynamics in Regular-to-Ergodic Transition: a Quantum-Fisher-Information approach

The characterization of entanglement is a central problem for the study of quantum many-body dynamics. Here, we propose the quantum Fisher information as a useful tool for the study of multipartite-entanglement dynamics in many-body systems. We illustrate this by considering the regular-to-ergodic transition in the Dicke model---a fully-connected spin model showing quantum thermalization above a critical interaction strength. We show that the QFI has a rich dynamical behavior which drastically changes across the transition. In particular, the asymptotic value of the QFI, as well as its characteristic timescales, witness the transition both through their dependence on the interaction strength and through the scaling with the system size. Since the QFI also sets the ultimate bound for the precision of parameter estimation, it provides a metrological perspective on the characterization of entanglement dynamics in many-body systems. Here we show that quantum ergodic dynamics allows for a much faster production of metrologically useful states.

cond-mat.stat-mech↗

arXiv2018

Interaction-induced transparency for strong-coupling polaritons

The propagation of light in strongly coupled atomic media takes place through the formation of polaritons - hybrid quasi-particles resulting from a superposition of an atomic and a photonic excitation. Here we consider the propagation under the condition of electromagnetically-induced transparency and show that a novel many-body phenomenon can appear due to strong, dissipative interactions between the polaritons. Upon increasing the photon-pump strength, we find a first-order transition between an opaque phase with strongly broadened polaritons and a transparent phase where a long-lived polariton branch with highly tunable occupation emerges. Across this non-equilibrium phase transition, the transparency window is reconstructed via nonlinear interference effects induced by the dissipative polariton interactions. Our predictions are based on a systematic diagrammatic expansion of the non-equilibrium Dyson equations which is quantitatively valid, even in the non-perturbative regime of large single-atom cooperativities, provided the polariton interactions are sufficiently long ranged. Such a regime can be reached in photonic crystal waveguides thanks to the tunability of interactions, allowing to observe the interaction-induced-transparency transition even at low polariton densities.

cond-mat.quant-gas↗

arXiv2018

Non-Fermi liquid at the FFLO quantum critical point

When a 2D superconductor is subjected to a strong in-plane magnetic field, Zeeman polarization of the Fermi surface can give rise to inhomogeneous FFLO order with a spatially modulated gap. Further increase of the magnetic field eventually drives the system into a normal metal state. Here, we perform a renormalization group analysis of this quantum phase transition, starting from an appropriate low-energy theory recently introduced by Piazza et al. (Ref.1). We compute one-loop flow equations within the controlled dimensional regularization scheme with fixed dimension of Fermi surface, expanding in $ε= 5/2 - d$. We find a new stable non-Fermi liquid fixed point and discuss its critical properties. One of the most interesting aspects of the FFLO non-Fermi liquid scenario is that the quantum critical point is potentially naked, with the scaling regime observable down to arbitrary low temperatures. In order to study this possibility, we perform a general analysis of competing instabilities, which suggests that only charge density wave order is enhanced in the vicinity of the quantum critical point.

cond-mat.str-el↗

arXiv2018

Diffusion to capture and the concept of diffusive interactions

Diffusion to capture is an ubiquitous phenomenon in many fields in biology and physical chemistry, with implications as diverse as ligand-receptor binding on eukaryotic and bacterial cells, nutrient uptake by colonies of unicellular organisms and the functioning of complex core-shell nanoreactors. Whenever many boundaries compete for the same diffusing molecules, they inevitably shield a variable part of the molecular flux from each other. This gives rise to the so-called diffusive interactions (DI), which can reduce substantially the influx to a collection of reactive boundaries depending chiefly on their geometrical configuration. In this review we provide a pedagogical discussion of the main mathematical aspects underlying a rigorous account of DIs. Starting from a striking and deep result on the mean-field description of ligand binding to a receptor-covered cell, we develop little by little a rigorous mathematical description of DIs in the stationary case through the use of translational addition theorems for spherical harmonics. We provide several enlightening illustrations of this powerful mathematical theory, including diffusion to capture to ensembles of reactive boundaries within a spherical cavity.

cond-mat.soft↗

arXiv2018

Aging dynamics in quenched noisy long-range quantum Ising models

We consider the $d$-dimensional transverse-field Ising model with power-law interactions $J/r^{d+σ}$ in the presence of a noisy longitudinal field with zero average. We study the longitudinal-magnetization dynamics of an initial paramagnetic state after a sudden switch-on of both the interactions and the noisy field. While the system eventually relaxes to an infinite-temperature state with vanishing magnetization correlations, we find that two-time correlation functions show aging at intermediate times. Moreover, for times shorter than the inverse noise strength $κ$ and distances longer than $a(J/κ)^{2/σ}$ with $a$ being the lattice spacing, we find a critical scaling regime of correlation and response functions consistent with the model A dynamical universality class with an initial-slip exponent $θ=1$ and dynamical critical exponent $z=σ/2$. We obtain our results analytically by deriving an effective action for the magnetization field including the noise in a non-perturbative way. The above scaling regime is governed by a non-equilibrium fixed point dominated by the noise fluctuations.

cond-mat.str-el↗

arXiv2018

Collective excitations and supersolid behavior of bosonic atoms inside two crossed optical cavities

We discuss the nature of symmetry breaking and the associated collective excitations for a system of bosons coupled to the electromagnetic field of two optical cavities. For the specific configuration realized in a recent experiment at ETH, we show that, in absence of direct intercavity scattering and for parameters chosen such that the atoms couple symmetrically to both cavities, the system possesses an approximate $U(1)$ symmetry which holds asymptotically for vanishing cavity field intensity. It corresponds to the invariance with respect to redistributing the total intensity $I=I_1+I_2$ between the two cavities. The spontaneous breaking of this symmetry gives rise to a broken continuous translation-invariance for the atoms, creating a supersolid-like order in the presence of a Bose-Einstein condensate. In particular, we show that atom-mediated scattering between the two cavities, which favors the state with equal light intensities $I_1=I_2$ and reduces the symmetry to $\mathbf{Z}_2\otimes \mathbf{Z}_2$, gives rise to a finite value $\sim \sqrt{I}$ of the effective Goldstone mass. For strong atom driving, this low energy mode is clearly separated from an effective Higgs excitation associated with changes of the total intensity $I$. In addition, we compute the spectral distribution of the cavity light field and show that both the Higgs and Goldstone mode acquire a finite lifetime due to Landau damping at non-zero temperature.

cond-mat.quant-gas↗

arXiv2018

Driven-Dissipative Supersolid in a Ring Cavity

Supersolids are characterized by the counter-intuitive coexistence of superfluid and crystalline order. Here we study a supersolid phase emerging in the steady state of a driven-dissipative system. We consider a transversely pumped Bose-Einstein condensate trapped along the axis of a ring cavity and coherently coupled to a pair of degenerate counter-propagating cavity modes. Above a threshold pump strength the interference of photons scattered into the two cavity modes results in an emergent superradiant lattice, which spontaneously breaks the continuous translational symmetry towards a periodic atomic pattern. The crystalline steady state inherits the superfluidity of the Bose-Einstein condensate, thus exhibiting genuine properties of a supersolid. A gapless collective Goldstone mode correspondingly appears in the superradiant phase, which can be non-destructively monitored via the relative phase of the two cavity modes on the cavity output. Despite cavity-photon losses the Goldstone mode remains undamped, indicating the robustness of the supersolid phase.

cond-mat.quant-gas↗

arXiv2018

Catalysis by metallic nanoparticles in solution: Thermosensitive microgels as nanoreactors

Metallic nanoparticles have been used as catalysts for various reactions, and the huge literature on the subject is hard to overlook. In many applications, the nanoparticles must be affixed to a colloidal carrier for easy handling during catalysis. These "passive carriers" (e.g., dendrimers) serve for a controlled synthesis of the nanoparticles and prevent coagulation during catalysis. Recently, hybrids from nanoparticles and polymers have been developed that allow us to change the catalytic activity of the nanoparticles by external triggers. In particular, single nanoparticles embedded in a thermosensitive network made from poly(N-isopropylacrylamide) (PNIPAM) have become the most-studied examples of such hybrids: Immersed in cold water, the PNIPAM network is hydrophilic and fully swollen. In this state, hydrophilic substrates can diffuse easily through the network, and react at the surface of the nanoparticles. Above the volume transition located at 32°C, the network becomes hydrophobic and shrinks. Now hydrophobic substrates will preferably diffuse through the network and react with other substrates in the reaction catalyzed by the enclosed nanoparticle. Such "active carriers", may thus be viewed as true nanoreactors that open new ways for the use of nanoparticles in catalysis.

physics.chem-ph↗