arXiv subjects

G. Cuniberti

Publications and source records attributed to G. Cuniberti.

53 records · Page 3Linked to original sources

arXiv2002

The role of contacts in molecular electronics

Molecular electronic devices are the upmost destiny of the miniaturization trend of electronic components. Although not yet reproducible on large scale, molecular devices are since recently subject of intense studies both experimentally and theoretically, which agree in pointing out the extreme sensitivity of such devices on the nature and quality of the contacts. This chapter intends to provide a general theoretical framework for modelling electronic transport at the molecular scale by describing the implementation of a hybrid method based on Green function theory and density functional algorithms. In order to show the presence of contact-dependent features in the molecular conductance, we discuss three archetypal molecular devices, which are intended to focus on the importance of the different sub-parts of a molecular two-terminal setup.

cond-mat.mes-hall↗

arXiv2002

A pure-carbon ring transistor: The role of topology and structure

We report results on the rectification properties of a carbon nanotube (CNT) ring transistor, contacted by CNT leads, whose novel features have been recently communicated by Watanabe et al. [Appl. Phys. Lett. 78, 2928 (2001)]. This paper contains results which are validated by the experimental observations. Moreover, we report on additional features of the transmission of this ring device which are associated with the possibility of breaking the lead inversion symmetry. The linear conductance displays a "chessboard"-like behavior alternated with anomalous zero-lines which should be directly observable in experiments. We are also able to discriminate in our results structural properties (quasi-onedimensional confinement) from pure topological effects (ring configuration), thus helping to gain physical intuition on the rich ring phenomenology.

cond-mat.mes-hall↗

arXiv2002

Fingerprints of mesoscopic leads in the conductance of a molecular wire

The influence of contacts on linear transport through a molecular wire attached to mesoscopic tubule leads is studied. It is shown that low dimensional leads, such as carbon nanotubes, in contrast to bulky electrodes, strongly affect transport properties. By focusing on the specificity of the lead-wire contact, we show, in a fully analytical treatment, that the geometry of this hybrid system supports a mechanism of channel selection and a sum rule, which is a distinctive hallmark of the mesoscopic nature of the electrodes.

cond-mat.mes-hall↗

arXiv2002

Backbone-induced semiconducting behavior in short DNA wires

We propose a model Hamiltonian for describing charge transport through short homogeneous double stranded DNA molecules. We show that the hybridization of the overlapping pi orbitals in the base-pair stack coupled to the backbone is sufficient to predict the existence of a gap in the nonequilibrium current-voltage characteristics with a minimal number of parameters. Our results are in a good agreement with the recent finding of semiconducting behavior in short poly(G)-poly(C) DNA oligomers. In particular, our model provides a correct description of the molecular resonances which determine the quasi-linear part of the current out of the gap region.

cond-mat.soft↗

arXiv2002

A molecular wire sandwiched between nanotube leads: analytic results for the conductance

Analytic results for the conductance of a molecular wire attached to mesoscopic tubule leads are obtained. They permit to study linear transport in presence of low dimensional leads in the whole range of parameters. In particular contact effects can be addressed in detail. By focusing on the specificity of the lead-wire contact, we show that the geometry of this hybrid system supports a mechanism of channel selection, which is a distinctive hallmark of the mesoscopic nature of the electrodes.

cond-mat.mes-hall↗

arXiv2002

Molecular wire-nanotube interfacial effects on electron transport

We discuss the conductance of a molecular bridge between mesoscopic electrodes supporting low-dimensional transport and bearing an internal structure. As an example for such nanoelectrodes we assume semi-infinite (carbon) nanotubes. In the Landauer scattering matrix approach, we show that the conductance of this hybrid is very sensitive to the geometry of the contact unlike the usual behaviour in the presence of bulk electrodes.

cond-mat.mes-hall↗

arXiv2001

Transport through a one-dimensional quantum dot

We examine the effects of long-range interactions in a quantum wire with two impurities. We employ the bosonization technique and derive an effective action for the system. The effect of the long-range interaction on the charging energy and spectral properties of the island formed by the impurities and the linear transport is discussed.

cond-mat.mes-hall↗

arXiv2001

Reconstructing the thermal Green functions at real times from those at imaginary times

By exploiting the analyticity and boundary value properties of the thermal Green functions that result from the KMS condition in both time and energy complex variables, we treat the general (non-perturbative) problem of recovering the thermal functions at real times from the corresponding functions at imaginary times, introduced as primary objects in the Matsubara formalism. The key property on which we rely is the fact that the Fourier transforms of the retarded and advanced functions in the energy variable have to be the `unique Carlsonian analytic interpolations' of the Fourier coefficients of the imaginary-time correlator, the latter being taken at the discrete Matsubara imaginary energies, respectively in the upper and lower half-planes. Starting from the Fourier coefficients regarded as `data set', we then develop a method based on the Pollaczek polynomials for constructing explicitly their analytic interpolations.

cond-mat.str-el↗

arXiv2001

Asset-asset interactions and clustering in financial markets

The collective phenomena of a liquid market is characterized in terms of a particle system scenario. This physical analogy enables us to disentangle intrinsic features from purely stochastic ones. The latter are the result of environmental changes due to a `heat bath' acting on the many-asset system, quantitatively described in terms of a time dependent effective temperature. The remaining intrinsic properties can be widely investigated by applying standard methods of classical many body systems. As an example, we consider a large set of stocks traded at the NYSE and determine the corresponding asset--asset `interaction' potential. In order to investigate in more detail the cluster structure suggested by the short distance behavior of the interaction potential, we perform a connectivity analysis of the spatial distribution of the particle system. In this way, we are able to draw conclusions on the intrinsic cluster persistency independently of the specific market conditions.

cond-mat.dis-nn↗

arXiv2001

Effects of regulation on a self-organized market

Adapting a simple biological model, we study the effects of control on the market. Companies are depicted as sites on a lattice and labelled by a fitness parameter (some `company-size' indicator). The chance of survival of a company on the market at any given time is related to its fitness, its position on the lattice and on some particular external influence, which may be considered to represent regulation from governments or central banks. The latter is rendered as a penalty for companies which show a very fast betterment in fitness space. As a result, we find that the introduction of regulation on the market contributes to lower the average fitness of companies.

cond-mat.stat-mech↗

arXiv2001

Fullerene based devices for molecular electronics

We have investigated the electronic properties of a C_60 molecule in between carbon nanotube leads. This problem has been tackled within a quantum chemical treatment utilizing a density functional theory-based LCAO approach combined with the Landauer formalism. Owing to low-dimensionality, electron transport is very sensitive to the strength and geometry of interfacial bonds. Molecular contact between interfacial atoms and electrodes gives rise to a complex conductance dependence on the electron energy exhibiting spectral features of both the molecule and electrodes. These are attributed to the electronic structure of the C_60 molecule and to the local density of states of the leads, respectively.

cond-mat.mes-hall↗

arXiv2001

An `all-carbon' molecular device

We have performed parameter-free calculations of electron transport across a carbon molecular junction consisting of a C$_{60}$ molecule sandwiched between two semi-infinite metallic carbon nanotubes. It is shown that the Landauer conductance of this carbon hybrid system can be tuned within orders of magnitude not only by varying the tube-C$_{60}$ distance, but more importantly at fixed distances by i) changing the orientation of the Buckminsterfullerene or ii) rotating one of the tubes around its cylinder axis. Furthermore, it is explicitely shown that structural relaxation determines qualitatively the transmission spectrum of such devices.

cond-mat.mes-hall↗

arXiv2001

Conductance of a molecular wire attached to mesoscopic leads: contact effects

We study linear electron transport through a molecular wire sandwiched between nanotube leads. We show that the presence of such electrodes strongly influences the calculated conductance. We find that depending on the quality and geometry of the contacts between the molecule and the tubular reservoirs, linear transport can be tuned between an effective Newns spectral behavior and a more structured one. The latter strongly depends on the topology of the leads. We also provide analytical evidence for an anomalous behavior of the conductance as a function of the contact strength.

cond-mat.mes-hall↗

arXiv2001

Liquid markets and market liquids: collective and single-asset dynamics in financial markets

We characterize the collective phenomena of a liquid market. By interpreting the behavior of a no-arbitrage N asset market in terms of a particle system scenario, (thermo)dynamical-like properties can be extracted from the asset kinetics. In this scheme the mechanisms of the particle interaction can be widely investigated. We test the verisimilitude of our construction on two-decade stock market daily data (DAX30) and show the result obtained for the interaction potential among asset pairs.

cond-mat.dis-nn↗

arXiv2000

Electron transport in nanotube--molecular wire hybrids

We study contact effects on electron transport across a molecular wire sandwiched between two semi-infinite (carbon) nanotube leads as a model for nanoelectrodes. Employing the Landauer scattering matrix approach we find that the conductance is very sensitive to parameters such as the coupling strength and geometry of the contact. The conductance exhibits markedly different behavior in the two limiting scenarios of single contact and multiple contacts between the molecular wire and the nanotube interfacial atoms. In contrast to a single contact the multiple-contact configuration acts as a filter selecting single transport channels. It exhibits a scaling law for the conductance as a function of coupling strength and tube diameter. We also observe an unusual narrow-to-broad-to-narrow behavior of conductance resonances upon decreasing the coupling.

cond-mat.mes-hall↗

arXiv2000

Learning short-option valuation in the presence of rare events

We present a neural-network valuation of financial derivatives in the case of fat-tailed underlying asset returns. A two-layer perceptron is trained on simulated prices taking into account the well-known effect of volatility smile. The prices of the underlier are generated using fractional calculus algorithms, and option prices are computed by means of the Bouchaud-Potters formula. This learning scheme is tested on market data; the results show a very good agreement between perceptron option prices and real market ones.

cond-mat.stat-mech↗

arXiv1998

Fermi liquids and Luttinger liquids

In these lecture notes, the basic physics of Fermi liquids and Luttinger liquids is presented. Fermi liquids are discussed both from a phenomenological viewpoint, in relation to microscopic approaches, and as renormalization group fixed points. Luttinger liquids are introduced using the bosonization formalism, and their essential differences with Fermi liquids are pointed out. Applications to transport effects, the effect of disorder, quantum spin chains, and spin ladders, both insulating and metallic, are given.

cond-mat.str-el↗