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Gilles Tarjus

Publications and source records attributed to Gilles Tarjus.

At least 19 recordsLinked to original sources

On the anomalous elasticity in the mechanical response of amorphous solids

The response of amorphous solids to a mechanical perturbation consists in an elastic and a plastic deformation. The latter is mediated by localized irreversible rearrangements associated with Eshelby-like quadrupolar singularities in the displacement field. It has recently been argued that a density of such singularities leads to an anomalous elastic behavior taking the form of screening effects, which goes beyond classical elastic predictions. Here, we reexamine this scenario using general theoretical arguments and a description in terms of an elasto-plastic model, which we compare with atomistic simulations of the canonical Eshelby inclusion geometry. We discuss the conditions under which a finite, i.e., nonvanishing, density of quadrupolar events is created by an imposed perturbation. We argue that, except when the perturbation is macroscopic, there are many situations in which the density of quadrupolar defects is zero in the thermodynamic limit. In these cases, we find that plastically active quadrupoles emerge in a region whose size generically scales as the spatial extent $\ell$ of the mechanical perturbation. This mechanism leads to anomalous elasticity on a scale $\ell$ close to the perturbation and to conventional elasticity beyond. The simulations of the elasto-plastic model reproduce the emergence of plastic quadrupoles in a region set by $\ell$ and the associated renormalization of the effective shear modulus, but they do not exhibit the dipole-screening signatures reported in atomistic and experimental studies. Our analysis delineates the scale-dependent breakdown of long-wavelength elasticity in amorphous materials and suggests directions for incorporating anomalous screening into mesoscopic modeling frameworks.

cond-mat.soft

On the breakdown of dimensional reduction and supersymmetry in random-field models

We discuss the breakdown of the Parisi-Sourlas supersymmetry (SUSY) and of the dimensional-reduction (DR) property in the random field Ising and O($N$) models as a function of space dimension $d$ and/or number of components $N$. The functional renormalization group (FRG) predicts that this takes place below a critical line $d_{\rm DR}(N)$. We revisit the perturbative FRG results for the RFO($N$)M in $d=4+ε$ and carry out a more comprehensive investigation of the nonperturbative FRG approximation for the RFIM. In light of this FRG description, we discuss the perturbative results in $ε=6-d$ recently derived for the RFIM by Kaviraj, Rychkov, and Trevisani. We stress in particular that the disappearance of the SUSY/DR fixed point below $d_{\rm DR}$ arises as a consequence of the nonlinearity of the FRG equations and cannot be found via the perturbative expansion in $ε=6-d$ (nor in $1/N$). We also provide an error bar on the value of the critical dimension $d_{\rm DR}$ for the RFIM, which we find around $5.11\pm0.09$, by studying several successive orders of the nonperturbative FRG approximation scheme.

cond-mat.dis-nn

Ductile-to-brittle transition and yielding in soft amorphous materials: perspectives and open questions

Soft amorphous materials are viscoelastic solids ubiquitously found around us, from clays and cementitious pastes to emulsions and physical gels encountered in food or biomedical engineering. Under an external deformation, these materials undergo a noteworthy transition from a solid to a liquid state that reshapes the material microstructure. This yielding transition was the main theme of a workshop held from January 9 to 13, 2023 at the Lorentz Center in Leiden. The manuscript presented here offers a critical perspective on the subject, synthesizing insights from the various brainstorming sessions and informal discussions that unfolded during this week of vibrant exchange of ideas. The result of these exchanges takes the form of a series of open questions that represent outstanding experimental, numerical, and theoretical challenges to be tackled in the near future.

cond-mat.soft

Shear-Induced Phase Behavior and Topological Defects in Two-Dimensional Crystals

We investigate through numerical simulations how a two-dimensional crystal yields and flows under an applied shear. We focus over a range that allows us to both address the response in the limit of an infinitesimal shear rate and describe the phase behavior of the system at a finite shear rate. In doing so, we carefully discuss the role of the topological defects and of the finite-size effects. We map out the whole phase diagram of the flowing steady state in the plane formed by temperature and shear rate. Shear-induced melting of the two-dimensional crystal is found to proceed in two steps: first, the solid loses long-range bond-orientational order and flows, even for an infinitesimal shear rate (in the thermodynamic limit). The resulting flowing hexatic phase then melts to a flowing, rather isotropic, liquid at a finite shear rate that depends on temperature. Finally, at a high shear rate, a third regime corresponding to a strongly anisotropic string-like flowing phase appears.

cond-mat.soft

Far-from-equilibrium criticality in the Random Field Ising Model with Eshelby Interactions

We study a quasi-statically driven random field Ising model (RFIM) at zero temperature with interactions mediated by the long-range anisotropic Eshelby kernel. Analogously to amorphous solids at their yielding transition, and differently from ferromagnetic and dipolar RFIMs, the model shows a discontinuous magnetization jump associated with the appearance of a band-like structure for weak disorder and a continuous magnetization growth, yet punctuated by avalanches, for strong disorder. Through a finite-size scaling analysis in 2 and 3 dimensions we find that the two regimes are separated by a finite-disorder critical point which we characterize. We discuss similarities and differences between the present model and models of sheared amorphous solids.

cond-mat.dis-nn

Approach to the lower critical dimension of the $φ^4$ theory in the derivative expansion of the Functional Renormalization Group

We revisit the approach to the lower critical dimension $d_{\rm lc}$ in the Ising-like $φ^4$ theory within the functional renormalization group by studying the lowest approximation levels in the derivative expansion of the effective average action. Our goal is to assess how the latter, which provides a generic approximation scheme valid across dimensions and found to be accurate in $d\geq 2$, is able to capture the long-distance physics associated with the expected proliferation of localized excitations near $d_{\rm lc}$. We show that the convergence of the fixed-point effective potential is nonuniform when $d\to d_{\rm lc}$ with the emergence of a boundary layer around the minimum of the potential. This allows us to make analytical predictions for the value of the lower critical dimension $d_{\rm lc}$ and for the behavior of the critical temperature as $d\to d_{\rm lc}$, which are both found in fair agreement with the known results. This confirms the versatility of the theoretical approach.

cond-mat.stat-mech

Finite-disorder critical point in the yielding transition of elasto-plastic models

Upon loading, amorphous solids can exhibit brittle yielding, with the abrupt formation of macroscopic shear bands leading to fracture, or ductile yielding, with a multitude of plastic events leading to homogeneous flow. It has been recently proposed, and subsequently questioned, that the two regimes are separated by a sharp critical point, as a function of some control parameter characterizing the intrinsic disorder strength and the degree of stability of the solid. In order to resolve this issue, we have performed extensive numerical simulations of athermally driven elasto-plastic models with long-range and anisotropic realistic interaction kernels in two and three dimensions. Our results provide clear evidence for a finite-disorder critical point separating brittle and ductile yielding, and we provide an estimate of the critical exponents in 2D and 3D.

cond-mat.soft

Emergence of a random field at the yielding transition of a mean-field Elasto-Plastic model

We study the mean-field limit of an elasto-plastic model introduced to describe the yielding transition of athermally and quasi-statically sheared amorphous solids. We focus on the sample-to-sample fluctuations, which we characterize analytically, and investigate in detail the analogy with the athermally driven random-field Ising model. We stress that the random field at the yielding transition is an emerging disorder and we investigate the various factors that determine its strength.

cond-mat.dis-nn

The Kauzmann Transition to an Ideal Glass Phase

The idea that a thermodynamic glass transition of some sort underlies the observed glass formation has been highly debated since Kauzmann first stressed the hypothetical entropy crisis that could take place if one were able to equilibrate supercooled liquids below the experimental glass transition temperature $T_g$. This a priori unreachable transition at some $T_K<T_g$ has since received a firm theoretical basis as a key feature predicted by the mean-field theory of the glass transition. In this chapter, we assess whether, and in which form, such a transition can survive in finite dimensions, and we review some of the recent computer simulation work addressing the issue in $2$- and $3$-dimensional glass-forming liquid models. We also discuss theoretical reasons to focus on an apparently inaccessible singularity.

cond-mat.dis-nn

Is glass a state of matter?

Glass is everywhere. We use and are surrounded by glass objects which make tangible the reality of glass as a distinct state of matter. Yet, glass as we know it is usually obtained by cooling a liquid sufficiently rapidly below its melting point to avoid crystallisation. The viscosity of this supercooled liquid increases by many orders of magnitude upon cooling, until the liquid becomes essentially arrested on experimental timescales below the ``glass transition'' temperature. From a structural viewpoint, the obtained glass still very much resembles the disordered liquid, but from a mechanical viewpoint, it is as rigid as an ordered crystal. Does glass qualify as a separate state of matter? We provide a pedagogical perspective on this question using basic statistical mechanical concepts. We recall the definitions of states of matter and of phase transitions between them. We review recent theoretical results suggesting why and how an ``ideal glass'' can indeed be defined as a separate equilibrium state of matter. We discuss recent success of computer simulations trying to analyse this glass state. We close with some experimental perspectives.

cond-mat.stat-mech

A perspective on the fragility of glass-forming liquids

We discuss possible extraneous effects entering in the conventional measures of "fragility" at atmospheric pressure that may obscure a characterization of the genuine super-Arrhenius slowdown of relaxation. We first consider the role of density, which increases with decreasing temperature at constant pressure, and then the potential influence of the high-temperature dynamical behavior and of the associated activation energy scale. These two effects involve both thermodynamic parameters and the strength of the "bare" activation energy reflecting the specific bonding between neighboring molecules. They vary from system to system with, most likely, little connection with any putative collective behavior associated with glass formation. We show how to scale these effects out by refining the definition of fragility and modifying the celebrated Angell plot. We dedicate this note to our great and so inspiring friend, Austen Angell, and associate in this tribute another dear colleague who died too soon, Daniel Kivelson.

cond-mat.soft

Rare events and disorder control the brittle yielding of well-annealed amorphous solids

We use atomistic computer simulations to provide a microscopic description of the brittle failure of amorphous materials, and we assess the role of rare events and quenched disorder. We argue that brittle yielding originates at rare soft regions, similarly to Griffiths effects in disordered systems. We numerically demonstrate how localized plastic events in such soft regions trigger macroscopic failure via the propagation of a shear band. This physical picture, which no longer holds in poorly annealed ductile materials, allows us to discuss the role of finite size effects in brittle yielding and reinforces the similarities between yielding and other disorder-controlled nonequilibrium phase transitions.

cond-mat.soft

Static self-induced heterogeneity in glass-forming liquids: Overlap as a microscope

We propose and numerically implement a local probe of the static self-induced heterogeneity characterizing glass-forming liquids. The method relies on the equilibrium statistics of the overlap between pairs of configurations measured in mesoscopic cavities with unconstrained boundaries. By systematically changing the location of the probed cavity, we directly detect spatial variations of the overlap fluctuations. We provide a detailed analysis of the statistics of a local estimate of the configurational entropy and we infer an estimate of the surface tension between amorphous states, ingredients that are both at the basis of the random first-order transition theory of glass formation. Our results represent the first direct attempt to visualize and quantify the self-induced heterogeneity underpinning the thermodynamics of glass formation. They pave the way for the development of coarse-grained effective theories and for a direct assessment of the role of thermodynamics in the activated dynamics of deeply supercooled liquids.

cond-mat.soft

Dense polar active fluids in a disordered environment

We examine the influence of quenched disorder on the flocking transition of dense polar active matter. We consider incompressible systems of active particles with aligning interactions under the effect of either quenched random forces or random dilution. The system displays a continuous disorder-order (flocking) transition, and the associated scaling behavior is described by a new universality class which is controlled by a quenched Navier-Stokes fixed point. We determine the critical exponents through a perturbative renormalization group analysis. We show that the two forms of quenched disorder, random force and random mass (dilution), belong to the same universality class, in contrast with the situation at equilibrium.

cond-mat.stat-mech

Statistical mechanics of coupled supercooled liquids in finite dimensions

We study the statistical mechanics of supercooled liquids when the system evolves at a temperature $T$ with a field $ε$ linearly coupled to its overlap with a reference configuration of the same liquid sampled at a temperature $T_0$. We use mean-field theory to fully characterize the influence of the reference temperature $T_0$, and we mainly study the case of a fixed, low-$T_0$ value in computer simulations. We numerically investigate the extended phase diagram in the $(ε,T)$ plane of model glass-forming liquids in spatial dimensions $d=2$ and $d=3$, relying on umbrella sampling and reweighting techniques. For both $2d$ and $3d$ cases, a similar phenomenology with nontrivial thermodynamic fluctuations of the overlap is observed at low temperatures, but a detailed finite-size analysis reveals qualitatively distinct behaviors. We establish the existence of a first-order transition line for nonzero $ε$ ending in a critical point in the universality class of the random-field Ising model (RFIM) in $d=3$. In $d=2$ instead, no phase transition is found in large enough systems at least down to temperatures below the extrapolated calorimetric glass transition temperature $T_g$. Our results confirm that glass-forming liquid samples of limited size display the thermodynamic fluctuations expected for finite systems undergoing a random first-order transition. They also support the relevance of the physics of the RFIM for supercooled liquids, which may then explain the qualitative difference between $2d$ and $3d$ glass-formers.

cond-mat.stat-mech

Interplay of vitrification and ice formation in a cryoprotectant aqueous solution at low temperature

The proneness of water to crystallize is a major obstacle to understanding its putative exotic behavior in the supercooled state. It also represents a strong practical limitation to cryopreservation of biological systems. Adding some concentration of glycerol, which has a cryoprotective effect preventing to some degree water crystallization, has been proposed as a possible way out, provided the concentration is small enough for water to retain some of its bulk character and/or for limiting the damage caused by glycerol on living organisms. Contrary to previous expectations, we show that in the ``marginal'' glycerol molar concentration $\approx18\%$, at which vitrification is possible with no crystallization on rapid cooling, water crystallizes upon isothermal annealing even below the calorimetric glass transition of the solution. Through a time-resolved polarized neutron scattering investigation, we extract key parameters, size and shape of the ice crystallites, fraction of water that crystallizes, crystallization time, which are important for cryoprotection, as a function of the annealing temperature. We also characterize the nature of the out-of-equilibrium liquid phases that are present at low temperature, providing more arguments against the presence of an iso-compositional liquid-liquid transition. Finally, we propose a rule-of-thumb to estimate the lower temperature limit below which water crystallization does not occur in aqueous solutions.

cond-mat.soft

On the overlap between configurations in glassy liquids

The overlap, or similarity, between liquid configurations is at the core of the mean-field description of the glass transition, and remains a useful concept when studying three-dimensional glass-forming liquids. In liquids, however, the overlap involves a tolerance, typically of a fraction $a/σ$ of the inter-particle distance, associated with how precisely similar two configurations must be for belonging to the same physically relevant "state". Here, we systematically investigate the dependence of the overlap fluctuations and of the resulting phase diagram when the tolerance is varied over a large range. We show that while the location of the dynamical and thermodynamic glass transitions (if present) is independent of $a/σ$, that of the critical point associated with a transition between a low- and a high-overlap phases in the presence of an applied source nontrivially depends on the value of $a/σ$. We rationalize our findings by using liquid-state theory and the hypernetted chain (HNC) approximation for correlation functions. In addition, we confirm the theoretical trends by studying a three-dimensional glass-former by computer simulations. We show in particular that \rev{a range of $a/σ$ below what is commonly considered maximizes the temperature of the critical point, pushing it up in a liquid region where viscosity is low and computer investigations are easier due to a significantly faster equilibration.

cond-mat.stat-mech

Random-field Ising model criticality in a glass-forming liquid

We use computer simulations to investigate the extended phase diagram of a supercooled liquid linearly coupled to a quenched reference configuration. An extensive finite-size scaling analysis demonstrates the existence of a random-field Ising model (RFIM) critical point and of a first-order transition line, in agreement with recent field-theoretical approaches. The dynamics in the vicinity of this critical point resembles the peculiar activated scaling of RFIM-like systems, and the overlap autocorrelation displays a logarithmic stretching. Our study demonstrates RFIM criticality in the thermodynamic limit for a three-dimensional supercooled liquids at equilibrium.

cond-mat.stat-mech