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Giuseppe Pellicane

Publications and source records attributed to Giuseppe Pellicane.

8 recordsLinked to original sources

Layering and superfluidity of soft-core bosons in shallow spherical traps

Fundamental theories and models of many-body physics can be probed in experiments on ultracold atoms held in place by electromagnetic fields. In particular, of considerable interest are systems under curved confinement, since they can yield exotic states of matter which would be impossible to obtain in flat space. In this study we focus on relatively small samples, where curvature effects are stronger, and analyze by Monte Carlo simulations the peculiar structure arising in an assembly of soft-core bosons subject to a weak trapping potential with spherical symmetry. Upon suitable tuning of the parameters, a hundred particles or so group together in clusters arranged in a shell with icosahedral symmetry. As the number of particles increases, a second shell gradually develops, concentric to (and partly overlapping with) the original one, where clusters are in perfect registry with the first shell, thus forming a dodecahedral pattern. Cluster arrangements with the symmetry of other polyhedra are seen for different sets of parameters. At low temperature the superfluid density is non-uniform in the radial direction; heating the system progressively, superfluidity eventually vanishes while still clusters are present, a behavior resembling the transition from supersolid to normal solid on a plane. Two shells of clusters are also observed in systems of classical or distinguishable quantum particles, but in those cases the shells are more fragile to thermal fluctuations. All these behaviors can in principle be tested in systems of Rydberg-dressed atoms loaded into a bubble trap.

cond-mat.quant-gas

Dynamical Networking of Polymer Networks with Dedicated Cross-linker Particles

This paper extends a field-theoretical dynamical networking formalism for mesoscopic polymer dynamics to explicitly include dedicated cross-linker particles. Cross-linkers are represented within a Martin-Siggia-Rose generating functional and reversibly coupled to polymers through Gaussian networking fields, enabling an approximation scheme that reduces their degrees of freedom while remaining compatible with polymer dynamics. The framework is applied to a two-species polymer system in which intra- and inter-species cross-linking are assigned different statistical advantages. Effective networking potentials are derived and used to calculate correlation functions and dynamic structure factors. To validate these results, molecular dynamics simulations of semi-flexible polymers with reversible intra- and inter-species cross-linking are performed. Simulations show that cross-linking decreases polymer persistence lengths and local alignment, and the resulting trajectories yield dynamic structure factors consistent with theoretical predictions. In both approaches, cross-linking broadens the diffusive peaks and enhances the high-frequency tails of the structure factors. Together, theory and simulation provide complementary insights into the dynamics of cross-linked polymers, establishing a tractable framework that captures essential features observed in experiments and offering a basis for exploring more complex synthetic and biological networks.

cond-mat.soft

Effects of gravity on supersolid order in bubble-trapped bosons

Unveiling the principles behind self-organization in quantum systems is of paramount importance, both intrinsically and practically, in view of foreseeable technological applications. Recently, increasing attention is being paid to atomic systems in curved geometries, which are a promising platform for the discovery of new emergent phenomena. A notable example is that of a gas of ultracold atoms loaded into a thin spherical shell, according to a protocol introduced by Zobay and Garraway more than twenty years ago. However, gravity prevents a dilute assembly of atoms from uniformly spreading throughout the shell, which explains why experiments on the condensation and superfluidity of bubble-trapped gases are usually conducted in space under microgravity conditions. In this paper, we focus instead on strongly-interacting quantum particles in a bubble trap, choosing the cluster supersolid of soft-core bosons as testbed. To study the impact of gravity on supersolid order, we consider a gedanken experiment in which the strength of gravity relative to the core repulsion is gradually enhanced. Using path integral Monte Carlo simulations, we trace the parallel evolution of system structure and superfluidity at low temperature, finding that the latter is sizeable only when gravity is a small perturbation or, at the other extreme, so strong that particles are all gathered in one cluster at the bottom of the trap. Finally, we assess the relevance of gravity for the equilibrium behavior of ultracold Rydberg-dressed atoms in a bubble trap, concluding that in some cases clues of the supersolid phase in the absence of gravity could be found even in a laboratory on Earth.

cond-mat.quant-gas

Liquid-liquid transition in a Bose fluid near collapse

Discovering novel emergent behavior in quantum many-body systems is a main objective of contemporary research. In this paper, we explore the effects on phases and phase transitions of the proximity to a Ruelle-Fisher instability, marking the transition to a collapsed state. To accomplish this, we study by quantum Monte Carlo simulations a two-dimensional system of soft-core bosons interacting through an isotropic finite-ranged attraction, with a parameter $η$ describing its strength. If $η$ exceeds a characteristic value $η_c$, the thermodynamic limit is lost, as the system becomes unstable against collapse. We investigate the phase diagram of the model for $η\lesssimη_c$, finding -- in addition to a liquid-vapor transition -- a first-order transition between two liquid phases. Upon cooling, the high-density liquid turns superfluid, possibly above the vapor-liquid-liquid triple temperature. As $η$ approaches $η_c$, the stability region of the high-density liquid is shifted to increasingly higher densities, a behavior at variance with distinguishable quantum or classical particles. Finally, for $η$ larger than $η_c$ our simulations yield evidence of collapse of the low-temperature fluid for any density; the collapsed system forms a circular cluster whose radius is insensitive to the number of particles.

cond-mat.stat-mech

Supersolid phases of bosonic particles in a bubble trap

Confinement can have a considerable effect on the behavior of particle systems, and is therefore an effective way to discover new phenomena. A notable example is a system of identical bosons at low temperature under an external field mimicking an isotropic bubble trap, which constrains the particles to a portion of space close to a spherical surface. Using Path Integral Monte Carlo simulations, we examine the spatial structure and superfluid fraction in two emblematic cases. First, we look at soft-core bosons, finding the existence of supersolid cluster arrangements with polyhedral symmetry; we show how different numbers of clusters are stabilized depending on the trap radius and the particle mass, and we characterize the temperature behavior of the cluster phases. A detailed comparison with the behavior of classical soft-core particles is provided too. Then, we examine the case, of more immediate experimental interest, of a dipolar condensate on the sphere, demonstrating how a quasi-one-dimensional supersolid of clusters is formed on a great circle for realistic values of density and interaction parameters. Crucially, this supersolid phase is only slightly disturbed by gravity. We argue that the predicted phases can be revealed in magnetic traps with spherical-shell geometry, possibly even in a lab on Earth. Our results pave the way for future simulation studies of correlated quantum systems in curved geometries.

cond-mat.quant-gas

Self-assembled structures of colloidal dimers and disks on a spherical surface

We study the self-assembly on a spherical surface of a model for a binary mixture of amphiphilic dimers in the presence of guest particles via Monte Carlo (MC) computer simulation. All particles have a hard core, but one monomer of the dimer also interacts with the guest particle by means of a short-range attractive potential. We observe the formation of aggregates of various shape as a function of the composition of the mixture and of the size of guest particles. Our MC simulations are a further step towards a microscopic understanding of experiments on colloidal aggregation over curved surfaces, such as oil droplets.

cond-mat.soft

Virial coefficients, equation of state, and demixing of binary asymmetric nonadditive hard-disk mixtures

Values of the fifth virial coefficient, compressibility factors, and fluid-fluid coexistence curves of binary asymmetric nonadditive mixtures of hard disks are reported. The former correspond to a wide range of size ratios and positive nonadditivities and have been obtained through a standard Monte Carlo method for the computation of the corresponding cluster integrals. The compressibility factors as functions of density, derived from canonical Monte Carlo simulations, have been obtained for two values of the size ratio ($q=0.4$ and $q=0.5$), a value of the nonadditivity parameter $Δ=0.3$), and five values of the mole fraction of the species with the biggest diameter ($x_1=0.1$, $0.3$, $0.5$, $0.7$, and $0.9$). Some points of the coexistence line relative to the fluid-fluid phase transition for the same values of the size ratios and nonadditivity parameter have been obtained from Gibbs Ensemble Monte Carlo simulations. A comparison is made between the numerical results and those that follow from some theoretical equations of state.

cond-mat.soft

Fluids in porous media: The case of neutral walls

The bulk phase behavior of a fluid is typically altered when the fluid is brought into confinement by the walls of a random porous medium. Inside the porous medium, phase transition points are shifted, or may disappear altogether. A crucial determinant is how the walls interact with the fluid particles. In this work, we consider the situation whereby the walls are neutral with respect to the liquid and vapor phase. In order to realize the condition of strict neutrality, we use a symmetric binary mixture inside a porous medium that interacts identically with both of the mixture species. Monte Carlo simulations are then used to obtain the phase behavior. Our main finding is that, in the presence of the porous medium, a liquid-vapor type transition still occurs, but with critical exponents that deviate from bulk Ising values. In addition, we observe clear violations of self-averaging. These findings provide further evidence that random confinement by neutral walls induces critical behavior of the random Ising model (i.e. Ising models with dilution type disorder, where the disorder couples to the energy).

cond-mat.stat-mech