arXiv subjects

Gregory B. Rieker

Publications and source records attributed to Gregory B. Rieker.

At least 19 recordsLinked to original sources

arXiv2025

High-Speed Thermal Imaging of Disk-shaped Firebrands in a Wind Tunnel

The transport and temperature-time history of disk-shaped firebrands was studied with high-speed thermal imaging in a wind tunnel. One millimeter diameter wooden disks were ignited using a novel firebrand generator. The firebrands dropped vertically into a wind tunnel crossflow. Optical images of the firebrands were recorded at 960 frames/second during their transport in the wind tunnel test section at three different wind speeds. The resulting high speed color videos were processed using a particle tracking algorithm and a two color pyrometry technique to determine temperature, position, and velocity time histories of individual firebrands. The firebrand temperatures were observed to oscillate at distinct frequencies that ranged between 50Hz and 480Hz (the Nyquist frequency of the imaging system). A positive correlation was observed between the temperature fluctuation frequency and the relative speed of the firebrand compared to the wind speed. The observed high speed temperature fluctuations suggest that rapid transitions between glowing and flaming combustion may be an important aspect in firebrand transport phenomena and should be considered within the context of model development.

physics.flu-dyn↗

arXiv2024

Dual-Comb Photothermal Microscopy

We introduce a new parallelized approach to photothermal microscopy that utilizes mid-infrared dual-comb lasers, enabling simultaneous measurements at hundreds of wavelengths. This technology allows for high-speed, label-free chemical identification with super-resolution infrared imaging, overcoming the limitations of slow, single-wavelength-laser methods.

physics.optics↗

arXiv2024

Mid-Infrared Hyperspectral Microscopy with Broadband 1-GHz Dual Frequency Combs

Mid-infrared microscopy is an important tool for biological analyses, allowing a direct probe of molecular bonds in their low energy landscape. In addition to the label-free extraction of spectroscopic information, the application of broadband sources can provide a third dimension of chemical specificity. However, to enable widespread deployment, mid-infrared microscopy platforms need to be compact and robust while offering high speed, broad bandwidth and high signal-to-noise ratio (SNR). In this study, we experimentally showcase the integration of a broadband, high-repetition-rate dual-comb spectrometer (DCS) in the mid-infrared range with a scanning microscope. We employ a set of 1-GHz mid-infrared frequency combs, demonstrating their capability for high-speed and broadband hyperspectral imaging of polymers and ovarian tissue. The system covers 1000 $\mathrm{cm^{-1}}$ at $\mathrm{ν_c=2941 \; cm^{-1}}$ with 12.86 kHz spectra acquisition rate and 5 $\mathrm{μm}$ spatial resolution. Taken together, our experiments and analysis elucidate the trade-off between bandwidth and speed in DCS as it relates to microscopy. This provides a roadmap for the future advancement and application of high-repetition-rate DCS hyperspectral imaging.

physics.optics↗

arXiv2024

Single-Beam Velocimetry with Dual Frequency Comb Absorption Spectroscopy

Laser absorption Doppler velocimeters use a crossed-beam configuration to cancel error due to laser frequency drift and absorption model uncertainty. This configuration complicates the spatial interpretation of the measurement since the two beams sample different volumes of gas. Here, we achieve single-beam velocimetry with a portable dual comb spectrometer (DCS) with high frequency accuracy and stability enabled by GPS-referencing, and a new high-temperature water vapor absorption database. We measure the inlet flow in a supersonic ramjet engine and demonstrate single-beam measurements that are on average within 19 m/s of concurrent crossed-beam measurements. We estimate that the DCS and the new database contribute 1.6 and 13 m/s to this difference respectively.

physics.optics↗

arXiv2024

Temperature, Pressure, Velocity, and Water Vapor Mole Fraction Profiles in a Ramjet Combustor using Dual Frequency Comb Spectroscopy and a High Temperature Absorption Database

Accurate diagnostics of the combustor region of ramjet engines can improve engine design and create benchmarks for computational fluid dynamics models. Previous works demonstrate that dual frequency comb spectroscopy can provide low uncertainty diagnostics of multiple flow parameters in the non-combusting regions of ramjets. However, the high temperatures present in the combustor present a challenge for broadband spectroscopic absorption models that are used to interpret measurements in these regions. Here, we utilize a new water vapor absorption database created for high temperature water-air mixtures to fit spectra measured in a ground-test ramjet engine with a broadband near-infrared dual comb absorption spectrometer. We extract 2D profiles of pressure, temperature, water mole fraction, and velocity using this new database. We demonstrate that the new database provides the lowest fit residuals compared to other water vapor absorption databases. We compare computational fluid dynamics simulations of the combustor with the measured data to demonstrate that the simulations overpredict heat release and water vapor production.

physics.flu-dyn↗

arXiv2024

Water-Vapor Absorption Database using Dual Comb Spectroscopy from 300-1300 K Part II: Air-Broadened H$_2$O, 6600 to 7650 cm$^{-1}$

We present broadband dual frequency comb laser absorption measurements of 2% H$_2$O (natural isotopic abundance of 99.7% H$_2^{16}$O) in air from 6600-7650 cm$^{-1}$ (1307-1515 nm) with a spectral point spacing of 0.0068 cm$^{-1}$. Twenty-nine datasets were collected at temperatures between 300 and 1300 K ($\pm$0.82% average uncertainty) and pressures ranging from 20 to 600 Torr ($\pm$0.25%) with an average residual absorbance noise of 8.0E-4 across the spectrum for all measurements. We fit measurements using a quadratic speed-dependent Voigt profile to determine 7088 absorption parameters for 3366 individual transitions found in HITRAN2020. These measurements build on the line strength, line center, self-broadening, and self-shift parameters determined in the Part I companion of this work. Here we measure air-broadened width (with temperature- and speed-dependence) and air pressure shift (with temperature dependence) parameters. Various trends are explored for extrapolation to weak transitions that were not covered in this work. Improvements made in this work are predominantly due to the inclusion of air pressure shift temperature dependence values. In aggregate, these updates improved RMS absorbance error by a factor of 4.2 on average, and the remaining residual is predominantly spectral noise. This updated database improves high temperature spectroscopic knowledge across the 6600 7650 cm$^{-1}$ region of H$_2$O absorption.

physics.ao-ph↗

arXiv2023

WindCline: Sloping Wind Tunnel for Characterizing Flame Behavior Under Variable Inclines and Wind Conditions

Developing accurate computational models of wildfire dynamics is increasingly important due to the substantial and expanding negative impacts of wildfire events on human health, infrastructure, and the environment. Wildfire spread and emissions depend on a number of factors, including fuel type, environmental conditions (moisture, wind speed, etc.) and terrain/location. However, there currently exist only a few experimental facilities that enable testing of the interplay of these factors at length scales <1 m with carefully controlled and characterized boundary conditions and advanced diagnostics. Experiments performed at such facilities are required for informing and validating computational models. Here we present the design and characterization of a novel tilting wind tunnel (the 'WindCline') for studying wildfire dynamics. The WindCline is unique in that the entire tunnel platform is constructed to pivot around a central axis, which enables sloping of the entire system without compromising the quality of the flow properties. In addition, this facility has a configurable design for the test section and diffuser to accommodate a suite of advanced diagnostics to aid in the characterization of 1) the parameters needed to establish boundary conditions and 2) flame properties and dynamics. The WindCline thus allows for measurement and control of several critical wildfire variables and boundary conditions, especially at the small length scales important to the development of high fidelity computational simulations (10 - 100 cm). Computational modeling frameworks developed and validated under these controlled conditions can expand understanding of fundamental combustion processes, promoting greater confidence when leveraging these processes in complex combustion environments.

physics.flu-dyn↗

arXiv2023

Nanosecond time-resolved dual-comb absorption spectroscopy

Frequency combs have revolutionized the field of optical spectroscopy, enabling researchers to probe molecular systems with a multitude of accurate and precise optical frequencies. While there have been tremendous strides in direct frequency comb spectroscopy, these approaches have been unable to record high resolution spectra on the nanosecond timescale characteristic of many physiochemical processes. Here we demonstrate a new approach to optical frequency comb generation in which a pair of electro-optic combs is produced in the near-infrared and subsequently transferred with high mutual coherence and efficiency into the mid-infrared within a single optical parametric oscillator. The high power, mutual coherence, and agile repetition rates of these combs as well as the large mid-infrared absorption of many molecular species enable fully resolved spectral transitions to be recorded in timescales as short as 20 ns. We have applied this approach to study the rapid dynamics occurring within a supersonic pulsed jet, however we note that this method is widely applicable to fields such as chemical and quantum physics, atmospheric chemistry, combustion science, and biology.

physics.optics↗

arXiv2023

Complete reactants-to-products observation of a gas-phase chemical reaction with broad, fast mid-infrared frequency combs

Molecular diagnostics are a primary tool of modern chemistry, enabling researchers to map chemical reaction pathways and rates to better design and control chemical systems. Many chemical reactions are complex and fast, and existing diagnostic approaches provide incomplete information. For example, mass spectrometry is optimized to gather snapshots of the presence of many chemical species, while conventional laser spectroscopy can quantify a single chemical species through time. Here we optimize for multiple objectives by introducing a high-speed and broadband, mid-infrared dual frequency comb absorption spectrometer. The optical bandwidth of >1000 cm-1 covers absorption fingerprints of many species with spectral resolution <0.03 cm-1 to accurately discern their absolute quantities. Key to this advance are 1 GHz pulse repetition rate frequency combs covering the 3-5 um region that enable microsecond tracking of fast chemical process dynamics. We demonstrate this system to quantify the abundances and temperatures of each species in the complete reactants-to-products breakdown of 1,3,5-trioxane, which exhibits a formaldehyde decomposition pathway that is critical to modern low temperature combustion systems. By maximizing the number of observed species and improving the accuracy of temperature and concentration measurements, this spectrometer advances understanding of chemical reaction pathways and rates and opens the door for novel developments such as combining high-speed chemistry with machine learning.

physics.chem-ph↗

arXiv2022

Spatially resolved mass flux measurements with dual comb spectroscopy

Providing an accurate, representative sample of mass flux across large open areas for atmospheric studies or the extreme conditions of a hypersonic engine is challenging for traditional intrusive or point-based sensors. Here, we demonstrate that laser absorption spectroscopy with mode-locked frequency combs can simultaneously measure all of the components of mass flux (velocity, temperature, pressure, and species mole fraction) with low uncertainty, spatial resolution corresponding to the laser line of sight, and no supplemental sensor readings. The low uncertainty is provided by the broad spectral bandwidth, high resolution, and extremely well-known and controlled frequency axis of stabilized, mode-locked frequency combs. We demonstrate these capabilities using dual frequency comb spectroscopy (DCS) in the isolator of a ground-test supersonic propulsion engine at Wright-Patterson Air Force Base. The mass flux measurements are consistent within 3.6% of the facility-level engine air supply values. A vertical scan of the laser beams in the isolator measures the spatially resolved mass flux, which is compared with computational fluid dynamics simulations. A rigorous uncertainty analysis demonstrates a instrument uncertainty of ~0.4%, and total uncertainty (including non-instrument sources) of ~7% for mass flux measurements. These measurements demonstrate DCS with mode-locked frequency combs as a low-uncertainty mass flux sensor for a variety of applications.

physics.app-ph↗

arXiv2022

Supersonic Combustion Diagnostics with Dual Comb Spectroscopy

Supersonic engine development requires accurate and detailed measurements of fluidic and thermodynamic parameters to optimize engine designs and benchmark computational fluid dynamic (CFD) simulations. Here, we demonstrate that dual frequency comb spectroscopy (DCS) with mode-locked frequency combs can provide simultaneous absolute measurements of several flow parameters with low uncertainty across a range of conditions owing to the broadband and ultrastable optical frequency output of the lasers. We perform DCS measurements across a 6800-7200 cm-1 bandwidth covering hundreds of H2O absorption features resolved with a spectral point spacing of 0.0067 cm-1 and point spacing precision of 1.68 x 10-10 cm-1. We demonstrate 2D profiles of velocity, temperature, pressure, water mole fraction, and air mass flux in a ground-test dual-mode ramjet at Wright-Patterson Air Force Base. The narrow angles of the measurement beams offer sufficient spatial resolution to resolve properties across an oblique shock train in the isolator and the thermal throat of the combustor. We determine that the total measurement uncertainties for the various parameters range from 1% for temperature to 9% for water vapor mole fraction, with the absorption database/model that is used to interpret the data typically contributing the most uncertainty (leaving the door open for even lower uncertainty in the future). CFD at the various measurement locations show good agreement, largely falling within the DCS measurement uncertainty for most profiles and parameters.

physics.app-ph↗

arXiv2021

Demonstration of a uniform, high-pressure, high-temperature gas cell with a dual frequency comb absorption spectrometer

Accurate absorption models for gases at high pressure and temperature support advanced optical combustion diagnostics and aid in the study of harsh planetary atmospheres. Developing and validating absorption models for these applications requires recreating the extreme temperature and pressure conditions of these environments in static, uniform, well-known conditions in the laboratory. Here, we present the design of a new gas cell to enable reference-quality absorption spectroscopy at high pressure and temperature. The design centers on a carefully controlled quartz sample cell housed at the core of a pressurized ceramic furnace. The half-meter sample cell is relatively long compared to past high- pressure and temperature absorption cells, and is surrounded by a molybdenum heat spreader that enables high temperature uniformity over the full length of the absorbing gas. We measure the temperature distribution of the sample gas using in situ thermocouples, and fully characterize the temperature uniformity across a full matrix of conditions up to 1000 K and 50 bar. The results demonstrate that the new design enables highly uniform and precisely known conditions across the full absorbing path length. Uniquely, we test the new gas cell with a broadband, high-resolution dual frequency comb spectrometer that enables highly resolved absorption spectroscopy across a wide range of temperature and pressure conditions. With this system, we measure the spectrum of CO$_2$ between 6800 and 7000 cm$^{-1}$ at pressures between 0.2 and 20 bar, and temperatures up to 1000 K. The measurements reveal discrepancies from spectra predicted by the HITRAN2016 database with a Voigt line shape at both low- and high-pressure conditions. These results motivate future work to expand absorption models and databases to accurately model high-pressure and -temperature spectra in combustion and planetary science research.

physics.ins-det↗

arXiv2021

Efficient Simulations of Propagating Flames Using Adaptive Mesh Refinement

Wildland fires are complex multi-physics problems that span wide spatial scale ranges. Capturing this complexity in computationally affordable numerical simulations for process studies and "outer-loop" techniques (e.g., optimization and uncertainty quantification) is a fundamental challenge in reacting flow research. Further complications arise for propagating fires where a priori knowledge of the fire spread rate and direction is typically not available. In such cases, static mesh refinement at all possible fire locations is a computationally inefficient approach to bridging the wide range of spatial scales relevant to wildland fire behavior. In the present study, we address this challenge by incorporating adaptive mesh refinement (AMR) in fireFoam, an OpenFOAM solver for simulations of complex fire phenomena. The AMR functionality in the extended solver, called wildFireFoam, allows us to dynamically track regions of interest and to avoid inefficient over-resolution of areas far from a propagating flame. We demonstrate the AMR capability for fire spread on vertical panels and for large-scale fire propagation on a variable-slope surface that is representative of real topography. We show that the AMR solver reproduces results obtained using much larger statically refined meshes, at a substantially reduced computational cost.

physics.flu-dyn↗

arXiv2020

Long Distance Continuous Methane Emissions Monitoring with Dual Frequency Comb Spectroscopy: deployment and blind testing in complex emissions scenarios

Continuous monitoring of oil and gas infrastructure is of interest for improving emissions and safety by enabling rapid identification and repair of emission sources, especially large sources that are responsible for the bulk of total emissions. We have previously demonstrated dual frequency comb spectroscopy (DCS) coupled with atmospheric modeling and inversion techniques (the DCS Observing System) as a viable and accurate approach for detection, attribution and quantification of methane emissions at distances of more than 1 km under controlled, steady emissions scenarios. Here, we present the results of validation testing designed to mimic the complexity of operational well pad emissions from oil and gas production, and the first field measurements at an active oil and gas facility. The validation tests are performed single-blind (the measurement and data analysis team are not given information about the emissions) at the Methane Emissions Technology Evaluation Center (METEC) test facility. They consist of a series of scenarios ranging from a single, steady-rate emission point to multiple emission points that include intermittent releases (the METEC "R2" tests). Additionally, we present field measurements at an active natural gas storage facility demonstrating that the system can remotely and autonomously monitor methane emissions in a true industrial setting. This field verification is in a configuration designed for continuous and long-term characterization of operational and fugitive emissions. These demonstrations confirm that the DCS Observing System can provide high-confidence continuous monitoring of emissions from complex, operational facilities among natural gas infrastructure.

physics.ao-ph↗

arXiv2020

Cepstral Analysis for Baseline-Insensitive Absorption Spectroscopy Using Light Sources with Pronounced Intensity Variations

This manuscript presents a data-processing technique which improves the accuracy and precision of absorption-spectroscopy measurements by isolating the molecular absorbance signal from errors in the baseline light intensity (Io) using cepstral analysis. Recently, cepstral analysis has been used with traditional absorption spectrometers to create a modified form of the time-domain molecular free-induction decay (m-FID) signal which can be analyzed independently from Io. However, independent analysis of the molecular signature is not possible when the baseline intensity and molecular response do not separate well in the time domain, which is typical when using injection-current-tuned lasers (e.g., quantum cascade lasers) and other light sources with pronounced intensity tuning. In contrast, the method presented here is applicable to all light sources since it determines gas properties by least-squares fitting a simulated m-FID signal to the measured m-FID signal in the time domain. This method is insensitive to errors in the estimated Io which vary slowly with optical frequency and, therefore, decay rapidly in the time domain. The benefits provided by this method are demonstrated via scanned-wavelength direct-absorption measurements acquired with a distributed-feedback (DFB) quantum-cascade laser (QCL). The wavelength of a DFB QCL was scanned across CO's P(0,20) and P(1,14) absorption transitions at 1 kHz to measure the gas temperature and concentration of CO. Measurements were acquired in a gas cell and in an ethylene-air flame at 1 atm. The measured spectra were processed using the new m-FID-based method and two traditional methods which rely on inferring the baseline error within the spectral-fitting routine. The m-FID-based method demonstrated superior accuracy in all cases and a measurement precision that was 1.5 to 10 times smaller than that provided using traditional methods.

physics.ins-det↗

arXiv2020

Fully phase-stabilized 1 GHz turnkey frequency comb at 1.56 $μ$m

Low noise and high repetition rate optical frequency combs are desirable for many applications from timekeeping to precision spectroscopy. For example, gigahertz repetition rate sources greatly increase the acquisition speed of spectra in a dual-comb modality when compared to lower repetition rate sources, while still maintaining sufficient instantaneous resolution to resolve ro-vibrational signatures from molecules in a variety of conditions. In this paper, we present the stabilization and characterization of a turnkey commercial 1~GHz mode-locked laser that operates at telecom wavelengths (1.56 $μ$m). Fiber amplification and spectral broadening result in the high signal-to-noise ratio detection and stabilization of $\textit{f}_{\textit{ceo}}$ with 438 mrad of residual phase noise (integrated from 10$^2$ to 10$^7$ Hz). Simultaneously, we stabilize the beatnote between the nearest comb mode and a cavity stabilized continuous-wave laser at 1.55 $μ$m with 41 mrad of residual phase noise (integrated from 10$^2$ to 10$^7$ Hz). This robust, self-referenced comb system is built with off-the-shelf polarization-maintaining fiber components and will be useful for a wide range of low noise frequency comb applications that benefit from the increased repetition rate.

physics.optics↗

arXiv2020

11-μs Time-resolved, Continuous Dual-Comb Spectroscopy with Spectrally Filtered Mode-locked Frequency Combs

Broadband dual-comb spectroscopy (DCS) based on portable mode-locked fiber frequency combs is a powerful tool for in situ, calibration free, multi-species spectroscopy. While the acquisition of a single spectrum with mode-locked DCS typically takes microseconds to milliseconds, the applications of these spectrometers have generally been limited to systems and processes with time changes on the order of seconds or minutes due to the need to average many spectra to reach a high signal-to-noise ratio (SNR). Here, we demonstrate high-speed, continuous, fiber mode-locked laser DCS with down to 11 $μ$s time resolution. We achieve this by filtering the comb spectra using portable Fabry-Perot cavities to generate filtered combs with 1 GHz tooth spacing. The 1 GHz spacing increases the DCS acquisition speed and SNR for a given optical bandwidth while retaining a sufficient spacing to resolve absorption features over a wide range of conditions. We measure spectra of methane inside a rapid compression machine throughout the 16 ms compression cycle with 133 cm$^{-1}$ bandwidth (4000 comb teeth) and 1.4 ms time resolution by spectrally filtering one of the combs. By filtering both combs, we measured a single-shot, 25 cm$^{-1}$ (750 comb teeth) spectrum of CO around 6330 cm$^{-1}$ in 11 $μ$s. The technique enables simultaneously high-speed and high-resolution DCS measurements, and can be applied anywhere within the octave-spanning spectrum of robust and portable fiber mode-locked frequency combs.

physics.optics↗

arXiv2019

Baseline-free Quantitative Absorption Spectroscopy Based on Cepstral Analysis

The accuracy of quantitative absorption spectroscopy depends on correctly distinguishing molecular absorption signatures in a measured transmission spectrum from the varying intensity or "baseline" of the light source. Baseline correction becomes particularly difficult when the measurement involves complex, broadly absorbing molecules or non-ideal transmission effects such as etalons. We demonstrate a technique that eliminates the need to account for the laser intensity in absorption spectroscopy by converting the measured transmission spectrum of a gas sample to a modified form of the time-domain molecular free induction decay (m-FID) using a cepstral analysis technique developed for audio signal processing. Much of the m-FID signal is temporally separated from and independent of the source intensity, and this portion can be fit directly with a model to determine sample gas properties without correcting for the light source intensity. We validate the new approach in several complex absorption spectroscopy scenarios and discuss its limitations. The technique is applicable to spectra obtained with any absorption spectrometer and provides a fast and accurate approach for analyzing complex spectra.

physics.ins-det↗