arXiv subjects

Guoqing Chang

Publications and source records attributed to Guoqing Chang.

At least 19 recordsLinked to original sources

arXiv2026

Anomalous vortex shape in a frustrated superconductor hosting chiral multicomponent order parameters

Multicomponent chiral superconductors can host spatially separated superconducting components within a single Abrikosov vortex, leading to unconventional, anisotropic vortex shapes forbidden in conventional single-component superconductors. Here, using spectroscopic scanning tunneling microscopy at 0.3 K, we investigate the mixed state of the spinel superconductor LiTi2O4 (Tc = 13 K). In the low-field regime, where vortex-vortex interactions are minimized and the intrinsic single-vortex shape is preserved, reasonably isolated triangular Abrikosov vortices are directly visualized with high statistical significance. Remarkably, the vortex orientation is locked to crystallographic domains rather than the magnetic-field direction, revealing a hidden chirality selectivity embedded in the zero-field electronic state.

cond-mat.supr-con↗

arXiv2026

Quantized Photocurrents in Gapless Topological Matter

The quantum Hall effect establishes that topology can fix a material response to integer multiples of fundamental constants when an energy gap isolates the relevant symmetry-protected electronic states. Whether such universal quantization can also emerge in gapless matter, where topological bands coexist with a continuum of metallic excitations, has remained a fundamental question in the field of quantum materials. Chiral topological semimetals provide a unique setting in which to explore this principle; when optical transitions are confined to a single chiral node, the resulting circular photogalvanic effect is predicted to be quantized by the topological charge of the node. In real materials, however, this nonlinear optical phenomenon has remained experimentally elusive, obscured by trivial band transitions, insufficient energy separation between node pairs, and their relative positions with respect to the Fermi level. Here we observe a quantized circular photogalvanic effect in the chiral topological semimetal Rh0.95Ni0.05Si. Band engineering via Ni substitution opens a photon-energy window dominated by interband optical transitions at the Γ-point multifold node. This allows circularly polarized near- to mid-infrared pulses to drive a helicity-odd terahertz response that manifests three hallmarks of quantization: a sharp onset, a photon-energy-independent plateau governed by the magnitude of the monopole charge, and an abrupt long-wavelength cutoff imposed by Pauli blocking. Our work thus establishes an all-optical analogue of the quantum Hall effect and a new paradigm to realize topological quantization in gapless matter.

cond-mat.mtrl-sci↗

arXiv2026

Electric-Switchable Chiral Magnons in PT-Symmetric Antiferromagnets

The magnons in antiferromagnetic insulators (AFIs) exhibit dual chirality, each carrying opposite spin angular momentum. However, in PT-symmetric AFIs, the magnon bands remain degenerate. In this work, we introduce a new class of PT-preserving AFIs in which the giant chiral splitting of magnons can be induced and controlled by an external electric field. Unlike conventional cases, such AFIs host a hidden dipole coupled to the antiferromagnetic order, which allows an external electric field to break the magnon sublattice symmetry and thereby largely lift the band degeneracy. Group theoretical analysis identifies the possible magnetic layer groups, while first-principles calculations and spin-wave theory reveal band splittings up to 20meV in Cr2CCl2 and Cr2CBr2 under the electric field of 0.2 V/Å, corresponding to an effective magnetic field of 200T. In addition, the electrically controlled magnon chiral splitting enables reversible switching of magnon-mediated spin currents. These findings open a new route toward nonvolatile spintronics based on magnons.

cond-mat.mtrl-sci↗

arXiv2026

Emergent Quantum-Geometric Equivalence of Injection and Shift Currents

Injection and shift currents are generally regarded as distinct nonlinear optical responses with separate microscopic origins. Here, we uncover a general hidden connection between them through interband Berry-curvature and quantum-metric dipoles. In systems with approximately linear electronic dispersion near the Fermi level and at low photon energies, this relation sharpens into an emergent equivalence, with injection and shift currents governed by the same interband quantum-geometric dipole. This regime is naturally realized in Dirac and Weyl semimetals, as well as in strained graphene, where measurements of injection and shift currents probe a unified geometric property of the electronic wavefunctions rather than distinct dynamical processes. Our results establish a new framework for interpreting nonlinear optical experiments and suggest that quantum geometry may provide a broader organizing principle linking seemingly distinct nonlinear optical responses in solids.

cond-mat.mes-hall↗

arXiv2026

Interlayer Charge-density-wave Vector Phase Induced Structural Chirality

Chiral charge density waves (CDWs) have attracted intense interest due to their exotic quantum properties, yet the microscopic origin of structural chirality emerging from correlated charge order remains elusive. Here, we reveal that the interlayer phases of CDW wave vectors, an overlooked degree of freedom, play a crucial role in driving chiral structural displacements in layered CDW materials. By explicitly incorporating the interlayer phases in first-principles calculations, we successfully obtained the chiral structure of the CDW phases of AV$_3$Sb$_5$ (A= K, Rb, and Cs) and 1T-TiSe$_2$. The electronic and optical properties of the predicted chiral structures are consistent with experimental measurements of these materials in their CDW phases. We further predict that 1T-NbSe$_2$ is a promising material candidate for realizing chiral CDW order. Beyond materials prediction, our theory reveals that the chiral CDW can be manipulated by electron filling. Our study opens new avenues for discovering, designing, and engineering chiral CDW materials.

cond-mat.mtrl-sci↗

arXiv2026

Discovery of Van Hove Singularities: Electronic Fingerprints of 3Q Magnetic Order in a van der Waals Quantum Magnet

Magnetically intercalated transition metal dichalcogenides are emerging as a rich platform for exploring exotic quantum states in van der Waals magnets. Among them, CoxTaS2 has attracted intense interest following the recent discovery of a distinctive 3Q magnetic ground state and a pronounced topological Hall effect below a critical doping of x=1/3, both intimately tied to cobalt concentration. To date, direct signatures of this enigmatic 3Q magnetic order in the electronic structure remain elusive. Here we report a comprehensive doping dependent angle resolved photoemission spectroscopy study that unveils these long-sought fingerprints. Our data reveal an unexpected "inverse Mexican hat" dispersion along the K-M-K direction, accompanied by two van Hove singularities. These features are consistent with theoretical predictions for a 3Q magnetic order near three-quarters band filling on a cobalt triangular lattice. These results provide evidence of 3Q magnetic order in the electronic structure, establishing TMD van der Waals magnets as tunable materials to explore the interplay between magnetism and topology.

cond-mat.mtrl-sci↗

arXiv2025

Complex Refractive Index Extraction for Spintronic Terahertz Emitter Analysis

Spintronic terahertz emitters (STEs) generate broadband terahertz (THz) radiation, which is essential for spectroscopy, imaging, and communication. The performances and the essential physical parameters of STE devices are linked to the dielectric properties of the constituent materials. Terahertz time-domain spectroscopy (THz-TDS) is an effective tool to measure these properties, but conventional analysis struggles with thin or complex multilayered systems due to simplifying approximations or complex transfer functions. In this work, we present a practical method to extract dielectric properties of STE multilayers using the Transfer Matrix Method (TMM). By comparing the THz pulse calculated using the Transfer Matrix Method (TMM) with the experimentally measured pulse transmitted through the sample, we can extract the dielectric properties of STEs, enhancing THz-TDS analysis and facilitating STE design and optimization. This method avoids constructing complex transfer functions, accommodates diverse sample geometries, and is designed to be accessible, with a publicly available codebase, making it a useful tool for STE research.

physics.optics↗

arXiv2025

Competitive Orders in Altermagnetic Chiral Magnons

The magnons in altermagnets exhibit chiral splitting even in the absence of spin-orbit coupling and external magnetic fields. Typically, this chiral splitting behavior can be well described by alternating isotropic spin exchanges (ISE) near the zero temperature. However, its finite-temperature dynamics, particularly when incorporating spin-orbit coupling effects, remains elusive. In this study, we reveal that, when including magnon-magnon interactions, long-range anisotropic spin exchange (ASE) can also induce chiral splitting of magnons at a finite temperature. Crucially, the chiral splitting induced by ASE competes with that arising from ISE, leading to a pronounced temperature-dependent modulation of the altermagnetic chiral splitting. Moreover, this competition is intimately connected to spin fluctuations, and can reverse the spin current driven by the band splitting as temperature increases. Our work uncovers the intrinsic competition governing collective spin excitations in altermagnets, providing new insights into their finite-temperature dynamical behavior.

cond-mat.str-el↗

arXiv2025

Wavefunction-Free Approach for Predicting Nonlinear Responses in Weyl Semimetals

By sidestepping the intractable calculations of many-body wavefunctions, density functional theory (DFT) has revolutionized the prediction of ground states of materials. However, predicting nonlinear responses--critical for next-generation quantum devices--still relies heavily on explicit wavefunctions, limiting computational efficiency. In this letter, using the circular photogalvanic effect (CPGE) in Weyl semimetals as a representative example, we realize a 1000-fold computational speedup by eliminating the explicit dependence on wavefunctions. Our approach leverages the one-to-one correspondence between free parameters of Weyl fermions and the associated responses to obtain precise wavefunction-free formulations. Applying our methodology, we systematically investigated known Weyl semimetals and revealed that Ta$_3$S$_2$ exhibits photocurrents an order of magnitude greater than those observed in TaAs, with potential for an additional order-of-magnitude enhancement under strain. To further demonstrate the generality of our approach, we obtained a wavefunction-free formula for the Berry-curvature dipole in Weyl semimetals. Our work paves the way for substantially more efficient screening and optimization of nonlinear electromagnetic properties in topological quantum materials.

cond-mat.mtrl-sci↗

arXiv2025

Defects Engineering of ZrTe5 for Stabilizing Ideal Topological States

ZrTe5 is a highly tunable, high-mobility topological material that hosts a rich variety of quantum phenomena, making it a promising platform for next-generation quantum technologies. Despite intensive research efforts, experimental studies have reported inconsistent and sometimes conflicting results for its electronic and topological states, largely due to variations in sample quality. Here, through systematic frst-principles investigations of all intrinsic point defects, we identify a practical route to achieving stable and ideal topological characteristics in ZrTe5. We show that the competition between two dominant charged defects, donor-like Zr interstitials and acceptor-like Te vacancies, governs the Fermi-level position. Furthermore, variations in defect density determine the topological phases of the samples. We theoretically propose and experimentally confrm that increasing the Te/Zr ratio during crystal growth effectively suppresses intrinsic defects and stabilizes ZrTe5 in a nearly ideal weak topological insulator state. These fndings provide clear guidance for defect control and sample optimization, paving the way toward robust and reproducible realization of topological quantum states in ZrTe5 for future quantum applications.

cond-mat.mtrl-sci↗

arXiv2025

Direct Visualization of a Disorder Driven Electronic Smectic Phase in Nonsymmorphic Square-Net Semimetal GdSbTe

Electronic liquid crystal (ELC) phases are spontaneous symmetry breaking states believed to arise from strong electron correlation in quantum materials such as cuprates and iron pnictides. Here, we report a direct observation of a smectic phase in a weakly correlated nonsymmorphic square-net semimetal GdSbxTe2-x. Incommensurate smectic charge modulation and intense local unidirectional nanostructure, which coexist with Dirac fermions across Fermi level, are visualized by using spectroscopic imaging - scanning tunneling microscopy. As materials with highly mobile carriers are mostly weakly correlated, the discovery of such an ELC phase are anomalous and raise questions on the origin of their emergence. Specifically, we demonstrate how chemical substitution generates these symmetry breaking phases before the system undergoes a charge density wave (CDW) - orthorhombic structural transition. Our results highlight the importance of impurities in realizing ELC phases and present a new material platform for exploring the interplay among quenched disorder, Dirac fermions and electron correlation.

cond-mat.str-el↗

arXiv2025

Visualizing higher-fold topology in chiral crystals

Novel topological phases of matter are fruitful platforms for the discovery of unconventional electromagnetic phenomena. Higher-fold topology is one example, where the low-energy description goes beyond Standard Model analogs. Despite intensive experimental studies, conclusive evidence remains elusive for the \textit{multi-gap topological nature of higher-fold chiral fermions}. In this Letter, we leverage a combination of fine-tuned chemical engineering and photoemission spectroscopy with photon energy contrast to discover the higher-fold topology of a chiral crystal. We identify all bulk branches of a higher-fold chiral fermion for the first time, critically important for allowing us to explore unique Fermi arc surface states in multiple inter-band gaps, which exhibit an emergent ladder structure. Through designer chemical gating of the samples in combination with our measurements, we uncover an unprecedented multi-gap bulk boundary correspondence. Our demonstration of multi-gap electronic topology will propel future research on unconventional topological responses.

cond-mat.mtrl-sci↗

arXiv2025

Magnon Nonlinear Hall Effect in 2D Antiferromagnetic Insulators

The efficient detection of the magnetism in 2D antiferromagnetic (AFM) insulators is crucial for the advancement of 2D AFM spintronics and remains a challenging problem. In this letter, we introduce the magnon nonlinear Hall current, a second-order Hall response of collective spin excitations in ordered magnets, as a novel probe for 2D layered AFM insulators. We theoretically demonstrate that the nonlinear Hall effect is intrinsically coupled to the underlying spin configuration. In particular, it exhibits a pronounced layer dependence in layered antiferromagnets, enabling direct characterization of the nature and strength of interlayer magnetic coupling in multilayer AFM insulators. Furthermore, we show that a a slight external field perturbation can induce and manipulate the magnon nonlinear Hall response. Our work establishes a novel approach for exploring 2D antiferromagnetism and holds great promise for AFM spintronic applications

cond-mat.mes-hall↗

arXiv2025

Weyl Semimetals: from Principles, Materials to Applications

Weyl semimetals have attracted significant interest in condensed matter physics and materials science, due to their unique electronic and topological properties. These characteristics not only deepen our understanding of fundamental quantum phenomena, but also make Weyl semimetals promising candidates for advanced applications in electronics, photonics, and spintronics. This review provides a systematic overview of the field, covering theoretical foundations, material synthesis, engineering strategies, and emerging device applications. We first outline the key theoretical principles and distinctive properties of Weyl semimetals, followed by an examination of recent advancements that enhance their functional versatility. Finally, we discuss the critical challenges hindering their practical implementation and explore future development directions, along with the potential for expanding and enhancing their existing range of applications. By integrating discussions of both opportunities and obstacles, this review offers a balanced perspective on current progress and future directions in Weyl semimetal research.

cond-mat.mtrl-sci↗

arXiv2025

Broken symmetries associated with a Kagome chiral charge order

Chirality or handedness manifests in all fields of science, ranging from cell biology, molecular interaction, and catalysis to different branches of physics. In condensed matter physics, chirality is intrinsic to enigmatic quantum phases, such as chiral charge density waves and chiral superconductivity. Here, the underlying chiral response is subtle and leads to broken symmetries in the ground state. Detection of subtle broken symmetries is the key to understand these quantum states but they are extremely challenging to expose leading to debate and controversy. Here, using second-order optical response, we uncover the broken symmetries of a chiral charge density wave in the Kagome lattice KV3Sb5, revealing the relevant broken symmetries of its charge order. KV3Sb5 undergoes a phase transition to a charge-ordered state at low temperatures. Our polarization-dependent mid-infrared photocurrent microscopy reveals an intrinsic, longitudinal helicity-dependent photocurrent associated with the charge order. Our measurements, supported by our theoretical analysis, provide direct evidence for broken inversion and mirror symmetries at the charge order transition, indicating a chiral charge ordered state. On the other hand, we do not observe a circular photogalvanic effect along the direction perpendicular to that of the incident light, imposing stringent constraints on the rotational and point group symmetries of the charge order. Our study not only visualizes the chiral nature of the Kagome charge order revealing its broken symmetries, but also highlights the nonlinear photogalvanic effect as a sensitive probe for detecting subtle symmetry breakings.

cond-mat.str-el↗

arXiv2025

Field induced density wave in a kagome superconductor

On the kagome lattice, electrons benefit from the simultaneous presence of band topology, flat electronic bands, and van Hove singularities, forming competing or cooperating orders. Understanding the interrelation between these distinct order parameters remains a significant challenge, leaving much of the associated physics unexplored. In the kagome superconductor KV3Sb5, which exhibits a charge density wave (CDW) state below T = 78 K, we uncover an unpredicted field-induced phase transition below 6 K. The observed transition is marked by a hysteretic anomaly in the resistivity, nonlinear electrical transport, and a change in the symmetry of the electronic response as probed via the angular dependence of the magnetoresistivity. These observations surprisingly suggest the emergence of an unanticipated broken symmetry state coexisting with the original CDW. To understand this experimental observation, we developed a theoretical minimal model for the normal state inside the high-temperature parent CDW phase where an incommensurate CDW order emerges as an instability sub-leading to superconductivity. The incommensurate CDW emerges when superconducting fluctuations become fully suppressed by large magnetic fields. Our results suggest that, in kagome superconductors, quantum states can either coexist or are nearly degenerate in energy, indicating that these are rich platforms to expose new correlated phenomena.

cond-mat.str-el↗

arXiv2024

This took us a Weyl: synthesis of a semimetallic Weyl ferromagnet with point Fermi surface

Quantum materials governed by emergent topological fermions have become a cornerstone of physics. Dirac fermions in graphene form the basis for moiré quantum matter, and Dirac fermions in magnetic topological insulators enabled the discovery of the quantum anomalous Hall effect. In contrast, there are few materials whose electromagnetic response is dominated by emergent Weyl fermions. Nearly all known Weyl materials are overwhelmingly metallic, and are largely governed by irrelevant, conventional electrons. Here we theoretically predict and experimentally observe a semimetallic Weyl ferromagnet in van der Waals (Cr,Bi)$_2$Te$_3$. In transport, we find a record bulk anomalous Hall angle $> 0.5$ along with non-metallic conductivity, a regime sharply distinct from conventional ferromagnets. Together with symmetry analysis, our data suggest a semimetallic Fermi surface composed of two Weyl points, with a giant separation $> 75\%$ of the linear dimension of the bulk Brillouin zone, and no other electronic states. Using state-of-the-art crystal synthesis techniques, we widely tune the electronic structure, allowing us to annihilate the Weyl state and visualize a unique topological phase diagram exhibiting broad Chern insulating, Weyl semimetallic and magnetic semiconducting regions. Our observation of a semimetallic Weyl ferromagnet offers an avenue toward novel correlated states and non-linear phenomena, as well as zero-magnetic-field Weyl spintronic and optical devices.

cond-mat.mes-hall↗

arXiv2024

Evidence chain for time-reversal symmetry-breaking kagome superconductivity

Superconductivity and magnetism are antagonistic quantum matter, while their intertwining has long been considered in frustrated-lattice systems1-3. In this work, we utilize scanning tunneling microscopy and muon spin resonance to discover time-reversal symmetry-breaking superconductivity in kagome metal Cs(V,Ta)3Sb5, where the Cooper pairing exhibits magnetism and is modulated by it. In the magnetic channel, we observe spontaneous internal magnetism in a full-gap superconducting state. Under perturbations of inverse magnetic fields, we detect a time-reversal asymmetrical interference of Bogoliubov quasi-particles at a circular vector. At this vector, the pairing gap spontaneously modulates, which is distinct from pair density waves occurring at a point vector and consistent with the theoretical proposal of unusual interference effect under time-reversal symmetry-breaking. The correlation between internal magnetism, Bogoliubov quasi-particles, and pairing modulation provides a chain of experimental clues for time-reversal symmetry-breaking kagome superconductivity.

cond-mat.supr-con↗