arXiv subjects

Heinrich M. Jaeger

Publications and source records attributed to Heinrich M. Jaeger.

At least 55 records · Page 3Linked to original sources

arXiv2019

Dynamic jamming of dense suspensions under tilted impact

Dense particulate suspensions can not only increase their viscosity and shear thicken under external forcing, but also jam into a solid-like state that is fully reversible when the force is removed. An impact on the surface of a dense suspension can trigger this jamming process by generating a shear front that propagates into the bulk of the system. Tracking and visualizing such a front is difficult because suspensions are optically opaque and the front can propagate as fast as several meters per second. Recently, high-speed ultrasound imaging has been used to overcome this problem and extract two-dimensional sections of the flow field associated with jamming front propagation. Here we extend this method to reconstruct the three-dimensional flow field. This enables us to investigate the evolution of jamming fronts for which axisymmetry cannot be assumed, such as impact at angles tilted away from the normal to the free surface of the suspension. We find that sufficiently far from solid boundaries the resulting flow field is approximately identical to that generated by normal impact, but rotated and aligned with the angle of impact. However, once the front approaches the solid boundary at the bottom of the container, it generates a squeeze flow that deforms the front profile and causes jamming to proceed in a non-axisymmetric manner.

cond-mat.soft↗

arXiv2019

Tuning Interparticle Hydrogen Bonding in Shear-Jamming Suspensions: Kinetic Effects and Consequences for Tribology and Rheology

The shear-jamming of dense suspensions can be strongly affected by molecular-scale interactions between particles, e.g. by chemically controlling their propensity for hydrogen bonding. However, hydrogen bonding not only enhances interparticle friction, a critical parameter for shear jamming, but also introduces (reversible) adhesion, whose interplay with friction in shear-jamming systems has so far remained unclear. Here, we present atomic force microscopy studies to assess interparticle adhesion, its relationship to friction, and how these attributes are influenced by urea, a molecule that interferes with hydrogen bonding. We characterize the kinetics of this process with nuclear magnetic resonance, relating it to the time dependence of the macroscopic flow behavior with rheological measurements. We find that time-dependent urea sorption reduces friction and adhesion, causing a shift in the shear-jamming onset. These results extend our mechanistic understanding of chemical effects on the nature of shear jamming, promising new avenues for fundamental studies and applications alike.

cond-mat.soft↗

arXiv2019

Controlling Shear Jamming in Dense Suspensions via the Particle Aspect Ratio

Dense suspension of particles in a liquid exhibit rich, non-Newtonian behaviors such as shear thickening and shear jamming. Shear thickening is known to be enhanced by increasing the particles' frictional interactions and also by making their shape more anisotropic. For shear jamming, however, only the role of interparticle friction has been investigated, while the effect of changing particle shape has so far not been studied systematically. To address this we here synthesize smooth silica particles and design the particle surface chemistry to generate strong frictional interactions such that dense, aqueous suspensions of spheres exhibit pronounced shear jamming. We then vary particle aspect ratio from $Γ$=1 (spheres) to $Γ$=11 (slender rods), and perform rheological measurements to determine the effect of particle anisotropy on the onset of shear jamming and its precursor, discontinuous shear thickening. Keeping the frictional interactions fixed, we find that increasing aspect ratio significantly reduces $ϕ_m$, the minimum particle packing fraction at which shear jamming can be observed, to values as low $ϕ_m=33\%$ for $Γ$=11. The ability to independently control particle interactions due to friction and shape anisotropy yields fundamental insights about the thickening and jamming capabilities of suspensions and provides a framework to rationally design shear jamming characteristics.

cond-mat.soft↗

arXiv2018

Transforming mesoscale granular plasticity through particle shape

When an amorphous material is strained beyond the point of yielding it enters a state of continual reconfiguration via dissipative, avalanche-like slip events that relieve built-up local stress. However, how the statistics of such events depend on local interactions among the constituent units remains debated. To address this we perform experiments on granular material in which we use particle shape to vary the interactions systematically. Granular material, confined under constant pressure boundary conditions, is uniaxially compressed while stress is measured and internal rearrangements are imaged with x-rays. We introduce volatility, a quantity from economic theory, as a powerful new tool to quantify the magnitude of stress fluctuations, finding systematic, shape-dependent trends. For all 22 investigated shapes the magnitude $s$ of relaxation events is well-fit by a truncated power law distribution $P(s)\sim {s}^{-τ} exp(-s/s^*)$, as has been proposed within the context of plasticity models. The power law exponent $τ$ for all shapes tested clusters around $τ=$ 1.5, within experimental uncertainty covering the range 1.3 - 1.7. The shape independence of $τ$ and its compatibility with mean field models indicate that the granularity of the system, but not particle shape, modifies the stress redistribution after a slip event away from that of continuum elasticity. Meanwhile, the characteristic maximum event size $s^*$ changes by two orders of magnitude and tracks the shape dependence of volatility. Particle shape in granular materials is therefore a powerful new factor influencing the distance at which an amorphous system operates from scale-free criticality. These experimental results are not captured by current models and suggest a need to reexamine the mechanisms driving mesoscale plastic deformation in amorphous systems.

cond-mat.soft↗

arXiv2018

Stress controlled rheology of dense suspensions using transient flows

Dense suspensions of hard particles in a Newtonian liquid can be jammed by shear when the applied stress exceeds a certain threshold. However, this jamming transition from a fluid into a solidified state cannot be probed with conventional steady-state rheology because the stress distribution inside the material cannot be controlled with sufficient precision. Here we introduce and validate a method that overcomes this obstacle. Rapidly propagating shear fronts are generated and used to establish well-controlled local stress conditions that sweep across the material. Exploiting such transient flows, we are able to track how a dense suspension approaches its shear jammed state dynamically, and can quantitatively map out the onset stress for solidification in a state diagram.

cond-mat.soft↗

arXiv2018

Cluster formation via sonic depletion forces in levitated granular matter

The properties of small clusters can differ dramatically from the bulk phases of the same constituents. In equilibrium, cluster assembly has been recently explored, whereas out of equilibrium, the physical principles of clustering remain elusive. These principles underlie phenomena from molecular assembly to the formation of planets from granular matter. Here, we introduce acoustic levitation as a platform to experimentally probe the formation of nonequilibrium small structures in a controlled environment. We focus on the minimal models of cluster formation: six and seven millimetre-scale particles in two dimensions. Experiments and modelling reveal that, in contrast to thermal colloids, in non-equilibrium granular ensembles the magnitude of active fluctuations controls not only the assembly rates but also their assembly pathways and ground-state statistics. These results open up new possibilities for non-invasively manipulating macroscopic particles, tuning their interactions, and directing their assembly.

cond-mat.soft↗

arXiv2018

Evolutionary strategy for inverse charge measurements of dielectric particles

We report a computational strategy to obtain the charges of individual dielectric particles from experimental observation of their interactions as a function of time. This strategy uses evolutionary optimization to minimize the difference between trajectories extracted from experiment and simulated trajectories based on many-particle force fields. The force fields include both Coulombic interactions and dielectric polarization effects that arise due to particle-particle charge mismatch and particle-environment dielectric contrast. The strategy was applied to systems of free falling charged granular particles in vacuum, where electrostatic interactions are the only driving forces that influence the particles' motion. We show that when the particles' initial positions and velocities are known, the optimizer requires only an initial and final particle configuration of a short trajectory in order to accurately infer the particles' charges; when the initial velocities are unknown and only the initial positions are given, the optimizer can learn from multiple frames along the trajectory to determine the particles' initial velocities and charges. While the results presented here offer a proof-of-concept demonstration of the proposed ideas, the proposed strategy could be extended to more complex systems of electrostatically charged granular matter.

cond-mat.soft↗

arXiv2018

On modeling and measuring viscoelasticity with dynamic Atomic Force Microscopy

The interaction between a rapidly oscillating atomic force microscope tip and a soft material surface is described using both elastic and viscous forces with a moving surface model. We derive the simplest form of this model, motivating it as a way to capture the impact dynamics of the tip and sample with an interaction consisting of two components: interfacial or surface force, and bulk or volumetric force. Analytic solutions to the piece-wise linear model identify characteristic time constants, providing a physical explanation of the hysteresis observed in the measured dynamic force quadrature curves. Numerical simulation is used to fit the model to experimental data and excellent agreement is found with a variety of different samples. The model parameters form a dimensionless impact-rheology factor, giving a quantitative physical number to characterize a viscoelastic surface that does not depend on the tip shape or cantilever frequency.

physics.app-ph↗

arXiv2018

Collisional Charging of Individual Sub-Millimeter Particles: Using Ultrasonic Levitation to Initiate and Track Charge Transfer

Electrostatic charging of insulating fine particles can be responsible for numerous phenomena ranging from lightning in volcanic plumes to dust explosions. However, even basic aspects of how fine particles become charged are still unclear. Studying particle charging is challenging because it usually involves the complexities associated with many particle collisions. To address these issues we introduce a method based on acoustic levitation, which makes it possible to initiate sequences of repeated collisions of a single sub-millimeter particle with a flat plate, and to precisely measure the particle charge in-situ after each collision. We show that collisional charge transfer between insulators is dependent on the hydrophobicity of the contacting surfaces. We use glass, which we modify by attaching nonpolar molecules to the particle, the plate, or both. We find that hydrophilic surfaces develop significant positive charges after contacting hydrophobic surfaces. Moreover, we demonstrate that charging between a hydrophilic and a hydrophobic surface is suppressed in an acidic environment and enhanced in a basic one. Application of an electric field during each collision is found to modify the charge transfer, again depending on surface hydrophobicity. We discuss these results within the context of contact charging due to ion transfer and show that they lend strong support to OH- ions as the charge carriers.

cond-mat.mtrl-sci↗

arXiv2017

Constitutive relations for shear fronts in shear-thickening suspensions

We study the fronts that appear when a shear-thickening suspension is submitted to a sudden driving force at a boundary. Using a quasi-one-dimensional experimental geometry, we extract the front shape and the propagation speed from the suspension flow field and map out their dependence on applied shear. We find that the relation between stress and velocity is quadratic, as is generally true for inertial effects in liquids, but with a pre-factor that can be much larger than the material density. We show that these experimental findings can be explained by an extension of the Wyart-Cates model, which was originally developed to describe steady-state shear-thickening. This is achieved by introducing a sole additional parameter: the characteristic strain scale that controls the crossover from start-up response to steady-state behavior. The theoretical framework we obtain unifies both transient and steady-state properties of shear-thickening materials.

cond-mat.soft↗

arXiv2016

Dynamic shear jamming in dense granular suspensions under extension

Unlike dry granular materials, a dense granular suspension like cornstarch in water can strongly resist extensional flows. At low extension rates, such a suspension behaves like a viscous liquid, but rapid extension results in a response where stresses far exceed the predictions of lubrication hydrodynamics and capillarity. To understand this remarkable mechanical response, we experimentally measure the normal force imparted by a large bulk of the suspension on a plate moving vertically upward at a controlled velocity. We observe that above a velocity threshold, the peak force increases by orders of magnitude. Using fast ultrasound imaging we map out the local velocity profiles inside the suspension which reveal the formation of a growing jammed region under rapid extension. This region interacts with the rigid boundaries of the container through strong velocity gradients, suggesting a direct connection to the recently proposed shear-jamming mechanism.

cond-mat.soft↗

arXiv2016

From splashing to bouncing: the influence of viscosity on the impact of suspension droplets on a solid surface

We experimentally investigated the splashing of dense suspension droplets impacting a solid surface, extending prior work to the regime where the viscosity of the suspending liquid becomes a significant parameter. The overall behavior can be described by a combination of two trends. The first one is that the splashing becomes favored when the kinetic energy of individual particles at the surface of a droplet overcomes the confinement produced by surface tension. This is expressed by a particle-based Weber number $We_p$. The second is that splashing is suppressed by increasing the viscosity of the solvent. This is expressed by the Stokes number $St$, which influences the effective coefficient of restitution of colliding particles. We developed a phase diagram where the splashing onset is delineated as a function of both $We_p$ and $St$. A surprising result occurs at very small Stokes number, where not only splashing is suppressed but also plastic deformation of the droplet. This leads to a situation where droplets can bounce back after impact, an observation we are able to reproduce using discrete particle numerical simulations that take into account viscous interaction between particles and elastic energy.

cond-mat.soft↗

arXiv2016

High-speed ultrasound imaging in dense suspensions reveals impact-activated solidification due to dynamic shear jamming

A remarkable property of dense suspensions is that they can transform from liquid-like at rest to solid-like under sudden impact. Previous work showed that this impact-induced solidification involves rapidly moving jamming fronts; however, details of this process have remained unresolved. Here we use high-speed ultrasound imaging to probe non-invasively how the interior of a dense suspension responds to impact. Measuring the speed of sound we demonstrate that the solidification proceeds without a detectable increase in packing fraction, and imaging the evolving flow field we find that the shear intensity is maximized right at the jamming front. Taken together, this provides direct experimental evidence for jamming by shear, rather than densification, as driving the transformation to solid-like behavior. Based on these findings we propose a new model to explain the anisotropy in the propagation speed of the fronts and delineate the onset conditions for dynamic shear jamming in suspensions.

cond-mat.soft↗

arXiv2016

Non-affine bending mode of thin cylindrical tubes

We discuss the response of thin cylindrical tubes to small indentations. The stretching-free embedding of these surfaces is completely determined by the embedding of one edge curve, thus reducing their bending response to an effectively one dimensional problem. We obtain that in general thin cylindrical tubes will bend non-uniformly in response to an indentation normal to their surface. As a consequence, their local bending stiffness, as measured by indenting at various locations along their axis, is predicted to peak at the center and decrease by a universal factor of 4 at either end of the tube. This characteristic spatial profile of the bending stiffness variation allows a direct determination of the bending modulus of very thin tubes that are shorter than their pinch persistence length, $l_{p}\propto R^{3/2}/t^{1/2}$, where $R$ is the tube diameter and $t$ its wall thickness. We compare our results with experiments performed on rolled-up stainless steel sheets.

cond-mat.soft↗

arXiv2015

Freestanding loadbearing structures with Z-shaped particles

Architectural structures such as masonry walls or columns exhibit a slender verticality, in contrast to the squat, sloped forms obtained with typical unconfined granular materials. Here we demonstrate the ability to create freestanding, weight-bearing, similarly slender and vertical structures by the simple pouring of suitably shaped dry particles into a mold that is subsequently removed. Combining experiments and simulations we explore a family of particle types that can entangle through their non-convex, hooked shape. We show that Z-shaped particles produce granular aggregates which can either be fluid and pourable, or solid and rigid enough to maintain vertical interfaces and build freestanding columns of large aspect ratio (>10) that support compressive loads without external confinement. We investigate the stability of such columns with uniaxial compression, bending, and vibration tests and compare with other particle types including U-shaped particles and rods. We find a pronounced anisotropy in the internal stress propagation together with strong strain-stiffening, which stabilizes rather than destabilizes the structures under load.

cond-mat.soft↗

arXiv2015

Optimizing Packing Fraction in Granular Media Composed of Overlapping Spheres

What particle shape will generate the highest packing fraction when randomly poured into a container? In order to explore and navigate the enormous search space efficiently, we pair molecular dynamics simulations with artificial evolution. Arbitrary particle shape is represented by a set of overlapping spheres of varying diameter, enabling us to approximate smooth surfaces with a resolution proportional to the number of spheres included. We discover a family of planar triangular particles, whose packing fraction of $ϕ\sim$ 0.73 outpaces almost all reported experimental results for random packings of frictionless particles. We investigate how $ϕ$ depends on the arrangement of spheres comprising an individual particle and on the smoothness of the surface. We validate the simulations with experiments using 3D-printed copies of the simplest member of the family, a planar particle consisting of three overlapping spheres with identical radius. Direct experimental comparison with 3D-printed aspherical ellipsoids demonstrates that the triangular particles pack exceedingly well not only in the limit of large system size but also when confined to small containers.

cond-mat.soft↗

arXiv2015

Turning Statistical Physics Models Into Materials Design Engines

Despite the success statistical physics has enjoyed at predicting the properties of materials for given parameters, the inverse problem, identifying which material parameters produce given, desired properties, is only beginning to be addressed. Recently, several methods have emerged across disciplines that draw upon optimization and simulation to create computer programs that tailor material responses to specified behaviors. However, so far the methods developed either involve black-box techniques, in which the optimizer operates without explicit knowledge of the material's configuration space, or they require carefully tuned algorithms with applicability limited to a narrow subclass of materials. Here we introduce a formalism that can generate optimizers automatically by extending statistical mechanics into the realm of design. The strength of this new approach lies in its capability to transform statistical models that describe materials into optimizers to tailor them. By comparing against standard black-box optimization methods, we demonstrate how optimizers generated by this formalism can be faster and more effective, while remaining straightforward to implement. The scope of our approach includes new possibilities for solving a variety of complex optimization and design problems concerning materials both in and out of equilibrium.

cond-mat.stat-mech↗

arXiv2014

Quasi-2D dynamic jamming in cornstarch suspensions: visualization and force measurements

We report experiments investigating jamming fronts in a floating layer of cornstarch suspension. The suspension has a packing fraction close to jamming, which dynamically turns into a solid when impacted at a high speed. We show that the front propagates in both axial and transverse direction from the point of impact, with a constant ratio between the two directions of propagation of approximately 2. Inside the jammed solid, we observe an additional compression, which results from the increasing stress as the solid grows. During the initial growth of the jammed solid, we measure a force response that can be completely accounted for by added mass. Only once the jamming front reaches a boundary, the added mass cannot account for the measured force anymore. We do not, however, immediately see a strong force response as we would expect when compressing a jammed packing. Instead, we observe a delay in the force response on the pusher, which corresponds to the time it takes for the system to develop a close to uniform velocity gradient that spans the complete system.

cond-mat.soft↗