arXiv subjects

Hiroshi Eisaki

Publications and source records attributed to Hiroshi Eisaki.

At least 109 records · Page 6Linked to original sources

arXiv2012

Disentangling a quantum antiferromagnet with resonant inelastic X-ray scattering

Low-dimensional copper oxide lattices naturally manifest electronic states with strong short range quantum entanglement, which are known to lead to remarkable emergent material properties. However the nanometer scale many-body wavefunction is challenging to measure or manipulate in a simple way. In this study, X-ray induced $dd$ electronic transitions are used to suppress spin entanglement across a single lattice site in the spin-1/2 antiferromagnetic chain compound SrCuO$_2$, revealing a class of cuprate magnetic excitations that result from breaking the spin chain. These measurements are the first to employ two closely spaced X-ray resonances of copper (M$_2$ and M$_3$) as a form of natural 2-slit interferometer to distinguish between different types of electronic transition and resolve how they influence the dynamics of nearby spin-entangled electrons.

cond-mat.str-el↗

arXiv2012

Disentangling the electronic and phononic glue in a high-Tc superconductor

Unveiling the nature of the bosonic excitations that mediate the formation of Cooper pairs is a key issue for understanding unconventional superconductivity. A fundamen- tal step toward this goal would be to identify the relative weight of the electronic and phononic contributions to the overall frequency (Ω) dependent bosonic function, Π(Ω). We perform optical spectroscopy on Bi2212 crystals with simultaneous time- and frequency-resolution; this technique allows us to disentangle the electronic and phononic contributions by their different temporal evolution. The strength of the interaction (λ~1.1) with the electronic excitations and their spectral distribution fully account for the high critical temperature of the superconducting phase transition.

cond-mat.supr-con↗

arXiv2012

Picometer Registration of Zinc Impurity States in Bi2Sr2CaCu2O8+d for Phase Determination in Intra-unit-cell Fourier Transform STM

Direct visualization of electronic-structure symmetry within each crystalline unit cell is a new technique for complex electronic matter research. By studying the Bragg peaks in Fourier transforms of electronic structure images, and particularly by resolving both the real and imaginary components of the Bragg amplitudes, distinct types of intra-unit cell symmetry breaking can be studied. However, establishing the precise symmetry point of each unit cell in real space is crucial in defining the phase for such Bragg-peak Fourier analysis. Exemplary of this challenge is the high temperature superconductor Bi2Sr2CaCu2O8+d for which the surface Bi atom locations are observable, while it is the invisible Cu atoms that define the relevant CuO2 unit-cell symmetry point. Here we demonstrate, by imaging with picometer precision the electronic impurity states at individual Zn atoms substituted at Cu sites, that the phase established using the Bi lattice produces a ~2% (2pi) error relative to the actual Cu lattice. Such a phase assignment error would not diminish reliability in the determination of intra-unit-cell rotational symmetry breaking at the CuO2 plane. Moreover, this type of impurity atom substitution at the relevant symmetry site can be of general utility in phase determination for Bragg-peak Fourier analysis of intra-unit-cell symmetry.

cond-mat.supr-con↗

arXiv2012

Potential antiferromagnetic fluctuations in hole-doped iron-pnictide superconductor Ba_{1-x}K_{x}Fe_{2}As_{2} studied by ^{75}As nuclear magnetic

We have performed ^{75}As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) on single crystalline Ba_{1-x}K_{x}Fe_{2}As_{2} for x = 0.27-1. ^{75}As nuclear quadruple resonance frequency (ν_{Q}) increases linearly with increasing x. The Knight shift K in normal state shows Pauli paramagnetic behavior with slight temperature T dependence. The value of K increases gradually with increasing x. By contrast, nuclear spin- lattice relaxation rate 1/T_{1} in normal state has a large T-dependence, which indicates existence of large antiferomagnetic (AF) spin fluctuations for all x. The T-dependence of 1/T_{1} shows a gap-like behavior below approximately 100 K for 0.6 < x < 0.9. These behaviors are well explained by the change of band structure with expansion of hole Fermi surfaces and shrink and disappearance of electron Fermi surfaces at Brillouin zone (BZ) with increasing x. The anisotropy of 1/T_{1}, represented by a ratio of 1/T_{1ab} to 1/T_{1c}, is always larger than 1 for all x, which indicates that the stripe-type AF fluctuations is dominant in this system. The K in superconducting (SC) state decreases, which corresponds to appearance of spin-singlet superconductivity. The T dependence of 1/T_{1} in SC state indicates multiple-SC-gap feature. A simple two gap model analysis shows that the larger superconducting gap gradually decreases with increasing x from 0.27 to 1 and smaller gap decreases rapidly and nearly vanishes for x > 0.6 where the electron pockets in BZ disappear.

cond-mat.supr-con↗

arXiv2011

Possibility of Horizontal Line Node in KFe$_2$As$_2$ Probed by Muon Spin Rotation

The anisotropy and temperature dependence of the magnetic field penetration depth in the iron-based superconductor KFe$_2$As$_2$ have been measured down to 20 mK by means of muon spin rotation. We have observed that the flux-line lattice forms triangular symmetry when we applied the field parallel to c-axis, suggesting the interaction between vortices should be isotropic. The temperature dependence of the penetration depth observd with an applied field parallel and perpendicular to c-axis are different. These results can be accounted for by a superconducting gap function with a horizontal line node in the basal plane.

cond-mat.supr-con↗

arXiv2011

Spectroscopic Imaging STM Studies of Electronic Structure in the Superconducting and Pseudogap Phases of Cuprate High-Tc Superconductors

One of the key motivations for the development of atomically resolved spectroscopic imaging STM (SI-STM) has been to probe the electronic structure of cuprate high temperature superconductors. In both the d-wave superconducting (dSC) and the pseudogap (PG) phases of underdoped cuprates, two distinct classes of electronic states are observed using SI-STM. The first class consists of the dispersive Bogoliubov quasiparticles of a homogeneous d-wave superconductor. These are detected below a lower energy scale |E|=Δ0 and only upon a momentum space (k-space) arc which terminates near the lines connecting k=\pm(π/a0,0) to k=\pm(0, π/a0). In both the dSC and PG phases, the only broken symmetries detected in the |E|\leq Δ0 states are those of a d-wave superconductor. The second class of states occurs at energies near the pseudogap energy scale |E| Δ1 which is associated conventionally with the 'antinodal' states near k=\pm(π/a0,0) and k=\pm(0, π/a0). We find that these states break the 90o-rotational (C4) symmetry of electronic structure within CuO2 unit cells, at least down to 180o rotational (C2) symmetry (nematic) but in a spatially disordered fashion. This intra-unit-cell C4 symmetry breaking coexists at |E| Δ1 with incommensurate conductance modulations locally breaking both rotational and translational symmetries (smectic). The properties of these two classes of |E| Δ1 states are indistinguishable in the dSC and PG phases. To explain this segregation of k-space into the two regimes distinguished by the symmetries of their electronic states and their energy scales |E| Δ1 and |E|\leqΔ0, and to understand how this impacts the electronic phase diagram and the mechanism of high-Tc superconductivity, represents one of a key challenges for cuprate studies.

cond-mat.supr-con↗

arXiv2011

Cyclotron resonance and mass enhancement by electron correlation in KFe$_2$As$_2$

Cyclotron resonance (CR) measurements for the Fe-based superconductor KFe$_2$As$_2$ are performed. One signal for CR is observed, and is attributed to the two-dimensional $α$ Fermi surface at the $Γ$ point. We found a large discrepancy in the effective masses of CR [(3.4$\pm$0.05)$m_e$ ($m_e$ is the free electron mass)] and de-Haas van Alphen (dHvA) results, a direct evidence of mass enhancement due to electronic correlation. A comparison of the CR and dHvA results shows that both intra- and interband electronic correlations contribute to the mass enhancement in KFe$_2$As$_2$.

cond-mat.mtrl-sci↗

arXiv2011

Structural quantum criticality and superconductivity in iron-based superconductor Ba(Fe1-xCox)2As2

We investigated the elastic properties of the iron-based superconductor Ba(Fe1-xCox)2As2 with eight Co concentrations. The elastic constant C66 shows large elastic softening associated with the structural phase transition. The C66 was analyzed base on localized and itinerant pictures of Fe-3d electrons, which shows the strong electron-lattice coupling and a possible mass enhancement in this system. The results resemble those of unconventional superconductors, where the properties of the system are governed by the quantum fluctuations associated with the zero-temperature critical point of the long-range order; namely, the quantum critical point (QCP). In this system, the inverse of C66 behaves just like the magnetic susceptibility in the magnetic QCP systems. While the QCPs of these existing superconductors are all ascribed to antiferromagnetism, our systematic studies on the canonical iron-based superconductor Ba(Fe1-xCox)2As2 have revealed that there is a signature of "structural quantum criticality" in this material, which is so far without precedent. The elastic constant anomaly is suggested to concern with the emergence of superconductivity. These results highlight the strong electron-lattice coupling and effect of the band in this system, thus challenging the prevailing scenarios that focus on the role of the iron 3d-orbitals.

cond-mat.supr-con↗

arXiv2011

Complete Fermi surface in BaFe$_2$As$_2$ observed via Shubnikov-de Haas oscillation measurements on detwinned single crystals

We show that the Fermi surface (FS) in the antiferromagnetic phase of BaFe$_2$As$_2$ is composed of one hole and two electron pockets, all of which are three dimensional and closed, in sharp contrast to the FS observed by angle-resolved photoemission spectroscopy. Considerations on the carrier compensation and Sommerfeld coefficient rule out existence of unobserved FS pockets of significant sizes. A standard band structure calculation reasonably accounts for the observed FS, despite the overestimated ordered moment. The mass enhancement, the ratio of the effective mass to the band mass, is 2--3.

cond-mat.supr-con↗

arXiv2011

Electric polarization induced by Neel order without magnetic superlattice: experimental study of Cu3Mo2O9 and numerical study of a small spin cluster

We clarify that the antiferromagnetic order in the distorted tetrahedral quasi-one dimensional spin system induces electric polarizations. In this system, the effects of the low dimensionality and the magnetic frustration are expected to appear simultaneously. We obtain the magnetic-field-temperature phase diagram in Cu3Mo2O9 by studying the dielectric constant and the spontaneous electric polarization. Around the tricritical point at 10 T and 8 K, the change of the direction in the electric polarization causes a colossal magnetocapacitance. We calculate the charge redistribution in the small spin cluster consisting of two magnetic tetrahedra to demonstrate the electric polarization induced by the antiferromagnetism.

cond-mat.str-el↗

arXiv2011

Revealing the high-energy electronic excitations underlying the onset of high-temperature superconductivity in cuprates

In strongly-correlated systems the electronic properties at the Fermi energy (EF) are intertwined with those at high energy scales. One of the pivotal challenges in the field of high-temperature superconductivity (HTSC) is to understand whether and how the high energy scale physics associated with Mott-like excitations (|E-E$_{F}$|>1 eV) is involved in the condensate formation. Here we show the interplay between the many-body high-energy CuO2 excitations at 1.5 and 2 eV and the onset of HTSC. This is revealed by a novel optical pump supercontinuum-probe technique, which provides access to the dynamics of the dielectric function in Bi$_2$Sr$_2$Ca$_{0.92}$Y$_{0.08}$Cu$_2$O$_{8+δ}$ over an extended energy range, after the photoinduced suppression of the superconducting pairing. These results unveil an unconventional mechanism at the base of HTSC both below and above the optimal hole concentration required to attain the maximum critical temperature (T$_c$).

cond-mat.str-el↗

arXiv2011

Reply to "Comment on 'Isotope effect in multi-band and multi-channel attractive systems and inverse isotope effect in iron-based superconductors'"

The Comment insists on the following: in our model it is assumed that the effective interactions have specific energy ranges within the single band with a cutoff at ω_1 for the phononic part and a range from ω_1 to ω_2 in the AF channel. Our reply is that we assume that V_i(k,k')\neq 0 if |ξ_k|<ω_i and |ξ_{k'}|<ω_i, and otherwise V_i(k,k')= 0 (i=1,2), as stated in our paper. This is the model of BCS type with two attractive interactions, and this assumption is the characteristic of the BCS approximation. The claim "the integration limits have been modified such that the AF channel mediated pairing sets in where the ph-channel pairing terminates and is limited at an energy given by ω_j=ω_{AF}" in the Comment is wrong. We describe the model and the method to solve the gap equation in more detail.

cond-mat.supr-con↗

arXiv2011

Structural Analysis on Iron-Based Superconductor Pr1111 System with Oxygen Deficiency and Flourine Substitution

We have performed structural analyses on iron-based superconductors, PrFeAsO$_{1-y}$ and PrFeAsO$_{1-x}$F$_x$, systematically, by means of Rietveld method on neutron powder diffraction data. The shifts of iron ion valence from +2, $δ$, are accurately determined from the occupancies of O and O$_{1-x}$F$_x$ sites obtained by the Rietveld analysis and F-concentration obtained by secondary ion-microprobe mass spectrometry. $T_\textrm{c}$-$δ$ curve of PrFeAsO$_{1-y}$ is different from the curve of PrFeAsO$_{1-x}$F$_x$, indicating that $δ$ is not a principal parameter for $T_\textrm{c}$ in so-called 1111 system. Structural parameters of the FeAs layers, for example, As-Fe-As bond angle and As-height from Fe layer, are different between both systems with similar $δ$-values. Their parent compounds are also found to have different structural parameters, possibly due to the different synthetic conditions. These results suggest that the difference of structural parameters of FeAs layer is the origin of the discrepancy of $T_\textrm{c}$-$δ$ curves of both systems and the $T_\textrm{c}$-value in the 1111 system is sensitive to the structural parameters. It may be attribute to an energy balance of the conducting bands contributing to the superconductivity.

cond-mat.supr-con↗

arXiv2010

Synthesis of ErFeAsO-based superconductors by hydrogen doping method

Here we demonstrate the technique to stabilize the ErFeAsO-based superconductor with the smallest lattice constants in LnFeAsO1-y (Ln = lanthanide) series using hydrogen doping method. Polycrystalline samples were synthesized by heating pellets with nominal compositions of ErFeAsO1-y (1-y = 0.75 ~ 0.95) sandwiched between pellets of LaFeAsO0.8H0.8 compositions at 1100 °C under a pressure of 5.0 - 5.5 GP. The sample with lattice constants of a = 3.8219 Å and c = 8.2807 Å shows the highest superconducting critical temperatures (Tc) of 44.5 K and 41.0 K determined by onset transitions of resistivity and susceptibility, respectively. We discuss phase diagram of Ln dependence of Tc in LnFeAsO-based superconductors.

cond-mat.supr-con↗

arXiv2010

Superconductivity at 28.3 and 17.1 K in (Ca4Al2O6-y)(Fe2Pn2) (Pn = As and P)

We have successfully synthesized (Ca4Al2O6-y)(Fe2Pn2) (Pn = As and P) (Al-42622(Pn)) using high-pressure synthesis technique. Al-42622(Pn) exhibit superconductivity for both Pn = As and P with the transition temperatures of 28.3 K and 17.1 K, respectively. The a-lattice parameters of Al-42622(Pn) (a = 3.713 Å and 3.692 Å for Pn = As and P, respectively) are smallest among the iron-pnictide superconductors. Correspondingly, Al-42622(As) has the smallest As-Fe-As bond angle (102.1 °) and the largest As distance from the Fe planes (1.500 Å).

cond-mat.supr-con↗

arXiv2010

Single Crystal Growth and Characterization of the Iron-Based Superconductor KFe2As2 Synthesized by KAs Flux Method

Centimeter sized platelet single crystals of KFe2As2 were grown using a self-flux method. An encapsulation technique using commercial stainless steel container allowed the stable crystal growth lasting for more than 2 weeks. Ternary K-Fe-As systems with various starting compositions were examined to determine the optimal growth conditions. Employment of KAs flux led to the growth of large single crystals with the typical size of as large as 15 mm x 10 mm x 0.4 mm. The grown crystals exhibit sharp superconducting transition at 3.4 K with the transition width 0.2 K, as well as the very large residual resistivity ratio exceeding 450, evidencing the good sample quality.

cond-mat.supr-con↗

arXiv2010

Absence of an appreciable iron isotope effect on the transition temperature of the optimally doped SmFeAsO_{1-y} superconductor

We report the iron (Fe) isotope effect on the transition temperature (Tc) in the oxygen-deficient SmFeAsO_{1-y}, a 50 K-class Fe-based superconductor. For the optimally-doped samples with Tc = 54 K, change of the Fe average atomic mass (MFe) causes a negligibly small shift in Tc, with the Fe isotope coefficient (alphaFe) as small as -0.024 \pm 0.015. This result contrasts with the finite, inverse isotope shift observed in optimally-doped (Ba,K)Fe2As2, indicating that the contribution of the electron-phonon interaction markedly differs between these two Fe-based high-Tc superconductors.

cond-mat.supr-con↗

arXiv2010

Comment on "Quantum Criticality and Nodal Superconductivity in the FeAs-Based Superconductor KFe$_2$As$_2$"

In a recent Letter [J. K. Dong et al., Phys. Rev. Lett. 104, 087005 (2010)], Dong \textit{et al}. have observed a $T^{1.5}$ dependence of resistivity $ρ$ in KFe$_2$As$_2$ at the upper critical field $B_{c2}$ = 5 T parallel to the c axis and have suggested the existence of a field-induced quantum critical point (QCP) at $B_{c2}$. In this comment, we argue that observation of a $T^{1.5}$ dependence of $ρ$ in a sample showing broad resistive transitions does not constitute evidence for a QCP and that recent dHvA results do not support the proposed QCP.

cond-mat.supr-con↗