Design of model Boger fluids with systematically controlled viscoelastic properties
The subject of viscoelastic flow phenomena is crucial to many areas of engineering and the physical sciences. Although much of our understanding of viscoelastic flow features stems from carefully designed experiments, preparation of model viscoelastic fluids remains a challenge; for example, fabricating a series of fluids with different fluid shear moduli $G_0$, but with an identical relaxation time $τ$, is nontrivial. In this work, we harness the non-ideality of nearly constant-viscosity elastic fluids, commonly known as `Boger fluids', made with polyisobutylene, to develop an experimental methodology that produces a set of fluids with desired viscoelastic properties, specifically, $G_0$, $τ$, and the first normal stress difference coefficient $ψ_1$. Through a linear algebraic relation between the rheological properties of interest ($G_0$, $τ$, $ψ_1$) and the fluid compositions in terms of polymer concentration $c$, molecular weight $M_w$, and solvent viscosity $η_s$, we developed a `design equation' that takes $G_0$, $τ$, $ψ_1$ as inputs and calculates values for $c$, $M_w$, $η_s$ as outputs. Using this method, fabrication of dilute viscoelastic fluids whose rheological properties are \textit{a priori} known can be achieved.