arXiv subjects

Ilane Schroetter

Publications and source records attributed to Ilane Schroetter.

At least 19 recordsLinked to original sources

arXiv2026

PDRs4All: XVIII. The evolution of the PAH ionisation and PAH size distribution across the Orion Bar

We investigate the evolution of the PAH population's charge state and size across key physical zones in the Orion Bar, which include the HII region, the atomic PDR (APDR), and three HI/H2 dissociation fronts (DF1, DF2, and DF3). Utilising the NASA Ames PAH Infrared Spectroscopic Database (PAHdb) and the pyPAHdb spectral modelling tool, we analysed the MIRI-MRS observations of the Orion Bar from the "PDRs4All" ERS Program. pyPAHdb modelling reveals the fractional contribution of the different PAH charge states and sizes to the total PAH emission across the Orion Bar. Cationic PAH emission peaks in the APDR region, where neutral PAHs have minimal contribution. Emission from neutral PAHs peaks in the HII region that consists of emission from a face-on PDR associated to the background OMC-1 molecular cloud, and in the molecular cloud regions past DF2. PAH anions are observed deep within the DF2 and DF3 zones. The average PAH size ranges between ~$60-74$ Nc. The modelling reveals regions of top-down PAH formation at the ionisation front, and bottom-up PAH formation within the molecular cloud region. The PAH ionisation parameter $γ$ ranges between ~$2-9 x 10^4$. Intensity ratios tracing PAH ionisation scale well with $γ$ in regions encompassing edge-on or face-on PDR emission, but their correlation weakens within the molecular cloud zone. Modelling of the $5-15$ $μ$m PAH spectrum with pyPAHdb achieves comprehensive characterization of the net contribution of neutral and cationic PAHs across different environments, whereas empirical PAH proxy intensity ratio tracers can be highly variable and unreliable outside regions dominated by PDR emission. The derived average PAH size in the different physical zones is consistent with a view of PAHs being more extensively subjected to ultraviolet processing closer to the ionisation front, and less affected within the molecular cloud.

astro-ph.GA↗

arXiv2026

Observation of an Accreting Planetary-Mass Companion with Signs of Disk-Disk Interaction in Orion

Young ($\lesssim 10$ Myr) planetary-mass companions (PMCs) provide valuable insights into the formation and early evolution of planetary systems. To date, only a dozen such objects have been identified through direct imaging. Using JWST/NIRCam observations towards the Orion Nebula, obtained as part of the \textit{PDRs4All} Early Release Science program, we have identified a faint point source near the M-type star V2376 Ori. Follow-up spectroscopic observations with the MUSE instrument on the VLT confirm that the source, V2376 Ori b, is indeed a young planetary-mass companion. It is a member of Orion D, around 80\,pc in the foreground of the Trapezium cluster of Orion and with an age of approximately $7 \pm 3$ Myr. We fit the SED of V2376 Ori b to infer a mass of $ \sim 20~M_{\rm Jup}$. The MUSE spectrum reveals several accretion tracers. Based on the H$α$ line intensity, we estimate an accretion rate of $\sim$10$^{-6.5 \pm 0.7}~\rm M_{Jup}\,yr^{-1}$, which is comparable to that of young PMCs such as PDS~70b. In addition, the MUSE data cube reveals extended emission in the [O\,\textsc{ii}] doublet at 7320 and 7330~Å, which is interpreted as evidence of a dynamical interaction between the two sources that, potentially, involves mass transfer between their individual accretion disks. These results demonstrate that JWST/NIRCam imaging surveys of young stellar associations can uncover new PMCs, which can then be confirmed and characterized through ground-based spectroscopic follow-up.

astro-ph.EP↗

arXiv2025

Using simultaneous mass accretion and external photoevaporation rates for d203-504 to constrain disc evolution processes

We cannot understand planet formation without understanding disc evolutionary processes. However, there is currently ambiguity about how protoplanetary discs transport angular momentum (e.g. via viscosity or winds) and the relative contributions and interplay of different dispersal mechanisms. A key difficulty is that for any given system only a handful of disc parameters are usually available to constrain theoretical models. Recent observations of the d203-504 disc in Orion, have yielded values of the stellar accretion rate, external photoevaporative mass loss rate, stellar mass and the disc size and mass. In particular, having the combination of accretion rate and external photoevaporative rate is new. Using this unique combination of observables, we run a suite of disc evolution simulations to constrain which scenarios can match the observed values. We explore both viscous and MHD wind-driven discs, finding that they best match observations when the angular momentum transport $α$ parameter is $3\times10^{-4}\leqα_ν\leq2\times10^{-3}$ for viscous discs, and $2\times10^{-3}\leqα_{\rm DW}\leq10^{-2}$ for MHD wind-driven discs, consistent with other estimates in the literature. As well constraining the disc properties and evolution, the d203-504 disc allows us to define a new irradiation age, since in order to match observations, it was required that the disc had only just appeared in the extreme UV environment it is currently exposed to (a known issue for proplyds referred to as the proplyd lifetime problem). This indicates that it is either very young, i.e. <0.1 Myr, or it has been shielded until recently, which would have protected the planet forming reservoir and helped facilitate planet growth despite it now residing in a harsh UV environment.

astro-ph.EP↗

arXiv2025

H3+ in irradiated protoplanetary disks: Linking far-ultraviolet radiation and water vapor

The likely JWST detection of vibrationally excited H3+ emission in Orion's irradiated disk system d203-506 raises the important question of whether cosmic-ray ionization is enhanced in disks within clustered star-forming regions, or whether alternative mechanisms contribute to H3+ formation and excitation. We present a detailed model of the photodissociation region (PDR) component of a protoplanetary disk -comprising the outer disk surface and the photoevaporative wind - exposed to strong external far-ultraviolet (FUV) radiation. We investigate key gas-phase reactions involving excited H2 that lead to the formation of H3+ in the PDR, including detailed state-to-state dynamical calculations of reactions H2(v>=0) + HOC+ -> H3+ + CO and H2(v>=0) + H+ -> H2+ + H. We also consider the effects of photoionization of vibrationally excited H2(v>=4), a process not previously included in PDR or disk models. We find that these FUV-driven reactions dominate the formation of H3+ in the PDR of strongly irradiated disks, largely independently of cosmic-ray ionization. The predicted H3+ abundance in the disk PDR peaks at x(H3+)~1E-8, coinciding with regions of enhanced HOC+ and water vapor abundances, and is linked to the strength of the external FUV field (G0). The predicted H3+ column density (~1E13 cm^-2) agrees with the presence of H3+ in the PDR of d203-506. We also find that formation pumping, resulting from exoergic reactions between excited H2 and HOC+, drives the vibrational excitation of H3+ in these regions. We expect this photochemistry to be highly active in disks where G_0 > 1E3. The H3+ formation pathways studied here may also be relevant in the inner disk region (near the host star), in exoplanetary ionospheres, and in the early Universe.

astro-ph.GA↗

arXiv2025

PDRs4All XIX. The 6 to 9 $μ$m region as a probe of PAH charge and size in the Orion Bar

Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of molecular clouds. We aim to investigate the distribution and sizes of charged PAHs across the key zones of the Orion Bar PDR. We employ JWST MIRI-MRS observations of the Orion Bar from the Early Release Science program ''PDRs4All'' and synthetic images in the JWST MIRI filters. We investigate the spatial morphology of the AIBs at 6.2, 7.7, 8.6, and 11.0 $μ$m that commonly trace PAH cations, and the neutral PAH-tracing 11.2 $μ$m AIB, their (relative) correlations, and the relationship with existing empirical prescriptions for AIBs. The 6.2. 7.7, 8.6, 11.0, and 11.2 $μ$m AIBs are similar in spatial morphology, on larger scales. Analyzing three-feature intensity correlations, two distinct groups emerge: the 8.6 and 11.0 $μ$m vs. the 6.2 and 7.7 $μ$m AIBs. We attribute these correlations to PAH size. The 6.2 and 7.7 $μ$m AIBs trace cationic, medium-sized PAHs. Quantum chemical calculations reveal that the 8.6 $μ$m AIB is carried by large, compact, cationic PAHs, and the 11.0 $μ$m AIB's correlation to it implies, so is this band. The 6.2/8.6 and 7.7/8.6 PAH band ratios thus probe PAH size. We conclude that the 6.2/11.2 AIB ratio is the most reliable proxy for charged PAHs, within the cohort. We outline JWST MIRI imaging prescriptions that serve as effective tracers of the PAH ionization fraction as traced. This study showcases the efficacy of the 6-9 $μ$m AIBs to probe the charge state and size distribution of the emitting PAHs, offering insights into the physical conditions of their host environments. JWST MIRI photometry offers a viable alternative to IFU spectroscopy for characterizing this emission in extended objects.

astro-ph.GA↗

arXiv2025

High-resolution Ultraviolet-to-nearinfrared Characterization of Exoplanet Atmospheres

The Habitable Worlds Observatory (HWO) offers a unique opportunity to revolutionize our understanding of planetary formation and evolution. The goal of this Science Case Development Document (SCDD) is to investigate the physical and chemical processes that shape the composition and atmospheric mass loss in exoplanets. We review the key observables currently known as diagnostics of mass loss via transit observations, i.e., absorption lines of escaping hydrogen (Lyman-alpha), helium, and metals (Fe, Mg, C, O). We also explore the challenges to infer planetary formation processes based on atmospheric composition characterization. HWO could enable a broad, continuous coverage from far-ultraviolet to near-infrared spectroscopy (~100--1600 nm) at high resolution (R > 60, 000), which is essential to make these measurements, disentangle their planetary origin from stellar activity, and ultimately, contextualize the escape rates by simultaneously characterizing the composition, cloud predominance, and thermal structure of exoplanet atmospheres.

astro-ph.IM↗

arXiv2025

Solar C/O ratio in planet-forming gas at 1 au in a highly irradiated disk

The chemical composition of exoplanets is thought to be influenced by the composition of the disks in which they form. JWST observations have unveiled a variety of species in numerous nearby disks, showing significant variations in the C/O abundance ratio. However, little is known about the composition and C/O ratio of disks around young stars in clusters exposed to strong ultraviolet (UV) radiation from nearby massive stars, which are representative of the environments where most planetary systems form, including ours. We present JWST spectroscopy of d203-504, a young 0.7 $\rm M_{\odot}$ star in the Orion Nebula with a 30 au disk irradiated by nearby massive stars. These observations reveal spectroscopic signatures of CO, H$_2$O, CH$_3^+$, and PAHs. Water and CO are detected in absorption in the inner disk ($r\lesssim 1$ au), where the estimated gas-phase C/O ratio is 0.48, consistent with the Solar value and that of the Orion Nebula. In contrast, \ch{CH3+} and PAHs are found in the extended surface layers of the disk. These results suggest that gas in the inner disk is chemically shielded from UV radiation while the surface layers of the disk experience UV-induced chemistry, potentially depleting their carbon content.

astro-ph.GA↗

arXiv2025

The past, present and future of observations of externally irradiated disks

Recent years have seen a surge of interest in the community studying the effect of ultraviolet radiation environment, predominantly set by OB stars, on protoplanetary disc evolution and planet formation. This is important because a significant fraction of planetary systems, potentially including our own, formed in close proximity to OB stars. This is a rapidly developing field, with a broad range of observations across many regions recently obtained or recently scheduled. In this paper, stimulated by a series of workshops on the topic, we take stock of the current and upcoming observations. We discuss how the community can build on this recent success with future observations to make progress in answering the big questions of the field, with the broad goal of disentangling how external photoevaporation contributes to shaping the observed (exo)planet population. Both existing and future instruments offer numerous opportunities to make progress towards this goal.

astro-ph.SR↗

arXiv2025

PDRs4All XIII. Empirical prescriptions for the interpretation of JWST imaging observations of star-forming regions

(Abridged) JWST continues to deliver incredibly detailed infrared (IR) images of star forming regions in the Milky Way and beyond. IR emission from star-forming regions is very spectrally rich due to emission from gas-phase atoms, ions, and polycyclic aromatic hydrocarbons (PAHs). Physically interpreting IR images of these regions relies on assumptions about the underlying spectral energy distribution in the imaging bandpasses. We aim to provide empirical prescriptions linking line, PAH, and continuum intensities from JWST images, to facilitate the interpretation of JWST images in a wide variety of contexts. We use JWST PDRs4All Near-Infrared Camera (NIRCam) and Mid-Infrared Instrument (MIRI) imaging and Near-Infrared Spectrograph (NIRSpec) integral field unit (IFU) and MIRI Medium Resolution Spectrograph (MRS) spectroscopic observations of the Orion Bar photodissociation region (PDR), to directly compare and cross-calibrate imaging and IFU data at ~100 AU resolution over a region where the radiation field and ISM environment evolves from the hot ionized gas to the cold molecular gas. We measure the relative contributions of line, PAH, and continuum emission to the NIRCam and MIRI filters as functions of local physical conditions. We provide empirical prescriptions based on NIRCam and MIRI images to derive intensities of emission lines and PAH features. Within the range of the environments probed in this study, these prescriptions accurately predict Pa-$α$, Br-$α$, PAH 3.3 $μ$m and 11.2 $μ$m intensities, while those for FeII 1.644 $μ$m, H$_2$ 1--0 S(1) 2.12 $μ$m and 1--0 S(9) 4.96 $μ$m, and PAH 7.7 $μ$m show more complicated environmental dependencies. Linear combinations of JWST NIRCam and MIRI images provide effective tracers of ionized gas, H$_2$, and PAH emission in PDRs. We expect these recipes to be useful for both the Galactic and extragalactic communities.

astro-ph.GA↗

arXiv2025

PDRs4All XI. Detection of infrared CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and disk d203-506: evidence of chemical pumping

The methylidyne cation (CH$^+$) and the methyl cation (CH$_3^+$) are building blocks of organic molecules, yet their coupled formation and excitation mechanisms remain mainly unprobed. The James Webb Space Telescope (JWST), with its high spatial resolution and good spectral resolution, provides unique access to the detection of these molecules. Our goal is to use the first detection of CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and in the protoplanetary disk d203-506, irradiated by the Trapezium cluster, to probe their formation and excitation mechanisms and constrain the physico-chemical conditions. We use spectro-imaging acquired using both the NIRSpec and MIRI-MRS instruments to study the CH$^+$ and CH$_3^+$ spatial distribution at very small scales, and compare it to excited H$_2$ emission. CH$^+$ and CH$_3^+$ emissions originate from the same region as highly excited H$_2$. Our comparison between the Bar and d203-506 reveals that both CH$^+$ and CH$_3^+$ excitation and/or formation are highly dependent on gas density. The excitation temperature of the observed CH$^+$ and CH$_3^+$ rovibrational lines is around $T$ ~ 1500 K in the Bar and $T$ ~ 800 K in d203-506. Moreover, the column densities derived from the rovibrational emission are less than 0.1 % of the total known (CH$^+$) and expected (CH$_3^+$) column densities. These results show that CH$^+$ and CH$_3^+$ level populations strongly deviate from ETL. CH$^+$ rovibrational emission can be explained by chemical formation pumping with excited H$_2$ via C$^+$ + H$_2^*$ = CH$^+$ + H. These results support a gas phase formation pathway of CH$^+$ and CH$_3^+$ via successive hydrogen abstraction reactions. However, we do not find any evidence of CH$_2^+$ emission in the JWST spectrum. Finally, observed CH$^+$ intensities coupled with chemical formation pumping model provide a diagnostic tool to trace the local density.

astro-ph.GA↗

arXiv2024

MusE GAs FLOw and Wind (MEGAFLOW) XIII. Cool gas traced by MgII around isolated galaxies

The circumgalactic medium (CGM) is a key component needed to understand the physical processes governing the flows of gas around galaxies. Quantifying its evolution and its dependence on galaxy properties is particularly important for our understanding of accretion and feedback mechanisms. We select a volume-selected sample of 66 {\it isolated} star-forming galaxies (SFGs) at $0.4< z <1.5$ with $\log(M_\star/M_{\odot})> 9$ from the MusE GAs FLOw and Wind (MEGAFLOW) survey. Using MgII 2796,2803 absorptions in background quasars, we measure the covering fraction $f_c$ and quantify how the cool gas profile depends on galaxy properties (such as star-formation rate (SFR), stellar mass ($M_\star$) or azimuthal angle relative to the line of sight) and how these dependencies evolve with redshift. The MgII covering fraction of isolated galaxies is a strong function of impact parameter, and is steeper than previously reported. The impact parameter $b_{50}$ at which $f_c = $50\% is $b_{50}=50\pm7$kpc ($65\pm7$ kpc) for $W_r^{2796}>$0.5 Å($W_r^{2796}>0.1$ Å), respectively. It is weakly correlated with SFR ($\propto$ SFR$^{0.08\pm0.09}$) and decreases with cosmic time ($\propto (1+z)^{0.8 \pm 0.7}$), contrary to the expectation of increasingly larger halos with time. The covering fraction is also higher along the minor axis than along the major axis at the $\approx 2 σ$ level. The CGM traced by \MgII{} is similar across the isolated galaxy population. Indeed, among the isolated galaxies with an impact parameter below 55 kpc, all have associated MgII absorption with $W_r^{2796}>$0.3Å, resulting in a steep covering fraction $f_c(b)$.

astro-ph.GA↗

arXiv2024

PDRs4All IX. Sulfur elemental abundance in the Orion Bar

One of the main problems in astrochemistry is determining the amount of sulfur in volatiles and refractories in the interstellar medium. The detection of the main sulfur reservoirs (icy H$_2$S and atomic gas) has been challenging, and estimates are based on the reliability of models to account for the abundances of species containing less than 1% of the total sulfur. The high sensitivity of the James Webb Space Telescope provides an unprecedented opportunity to estimate the sulfur abundance through the observation of the [S I] 25.249 $μ$m line. We used the [S III] 18.7 $μ$m, [S IV] 10.5 $μ$m, and [S l] 25.249 $μ$m lines to estimate the amount of sulfur in the ionized and molecular gas along the Orion Bar. For the theoretical part, we used an upgraded version of the Meudon photodissociation region (PDR) code to model the observations. New inelastic collision rates of neutral atomic sulfur with ortho- and para- molecular hydrogen were calculated to predict the line intensities. The [S III] 18.7 $μ$m and [S IV] 10.5 $μ$m lines are detected over the imaged region with a shallow increase (by a factor of 4) toward the HII region. We estimate a moderate sulfur depletion, by a factor of $\sim$2, in the ionized gas. The corrugated interface between the molecular and atomic phases gives rise to several edge-on dissociation fronts we refer to as DF1, DF2, and DF3. The [S l] 25.249 $μ$m line is only detected toward DF2 and DF3, the dissociation fronts located farthest from the HII region. The detailed modeling of DF3 using the Meudon PDR code shows that the emission of the [S l] 25.249 $μ$m line is coming from warm ($>$ 40 K) molecular gas located at A$_{\rm V}$ $\sim$ 1$-$5 mag from the ionization front. Moreover, the intensity of the [S l] 25.249 $μ$m line is only accounted for if we assume the presence of undepleted sulfur.

astro-ph.GA↗

arXiv2024

On the origin of infrared bands attributed to tryptophan in Spitzer observations of IC 348

Infrared emission features toward interstellar gas of the IC 348 star cluster in Perseus have been recently proposed to originate from the amino acid tryptophan. The assignment was based on laboratory infrared spectra of tryptophan pressed into pellets, a method which is known to cause large frequency shifts compared to the gas phase. We assess the validity of the assignment based on the original Spitzer data as well as new data from JWST. In addition, we report new spectra of tryptophan condensed in para-hydrogen matrices to compare with the observed spectra. The JWST MIRI data do not show evidence for tryptophan, despite deeper integration toward IC 348. In addition, we show that several of the lines attributed to tryptophan are likely due to instrumental artifacts. This, combined with the new laboratory data, allows us to conclude that there is no compelling evidence for the tryptophan assignment.

astro-ph.GA↗

arXiv2024

MusE GAs FLOw and Wind (MEGAFLOW) XI. Scaling relations between outflows and host galaxy properties

Absorption line spectroscopy using background quasars can provide strong constraints on galactic outflows. In this paper, we investigate possible scaling relations between outflow properties, namely outflow velocity \Vout, the mass ejection rate $\dot M_{\rm out}$, and the mass loading factor $η$ and the host galaxy properties, such as star formation rate (SFR), SFR surface density, redshift, and stellar mass using galactic outflows probed by background quasars from MEGAFLOW and other surveys. We find that $V_{\rm out}$ ($η$) is (anti-)correlated with SFR and SFR surface density. We extend the formalism of momentum-driven outflows of Heckman et al. to show that it applies not only to down the barrel studies but also to winds probed by background quasars, suggesting a possible universal wind formalism. Under this formalism, we find a clear distinction between ``strong'' and ``weak'' outflows where ``strong'' outflows seem to have tighter correlations with galaxy properties (SFR or galaxy stellar mass) than ``weak'' outflows.

astro-ph.GA↗

arXiv2024

PDRs4All VIII: Mid-IR emission line inventory of the Orion Bar

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations.

astro-ph.GA↗

arXiv2024

A far-ultraviolet-driven photoevaporation flow observed in a protoplanetary disk

Most low-mass stars form in stellar clusters that also contain massive stars, which are sources of far-ultraviolet (FUV) radiation. Theoretical models predict that this FUV radiation produces photo-dissociation regions (PDRs) on the surfaces of protoplanetary disks around low-mass stars, impacting planet formation within the disks. We report JWST and Atacama Large Millimetere Array observations of a FUV-irradiated protoplanetary disk in the Orion Nebula. Emission lines are detected from the PDR; modelling their kinematics and excitation allows us to constrain the physical conditions within the gas. We quantify the mass-loss rate induced by the FUV irradiation, finding it is sufficient to remove gas from the disk in less than a million years. This is rapid enough to affect giant planet formation in the disk.

astro-ph.GA↗

arXiv2024

PDRs4All VII. The 3.3 $μ$m aromatic infrared band as a tracer of physical properties of the ISM in galaxies

Aromatic infrared bands (AIBs) are a set of broad emission bands at 3.3, 6.2, 7.7, 8.6, 11.2, and 12.7 $μ$m, seen in the infrared spectra of most galaxies. With JWST, the 3.3 $μ$m AIB can in principle be detected up to a redshift of $\sim$ 7. Relating the evolution of the 3.3 $μ$m AIB to local physical properties of the ISM is thus of paramount importance. By applying a dedicated machine learning algorithm to JWST NIRSpec observations of the Orion Bar photodissociation region obtained as part of the PDRs4All Early Release Science (ERS) program, we extracted two template spectra capturing the evolution of the AIB-related emission in the 3.2-3.6 $μ$m range, which includes the AIB at 3.3 $μ$m and its main satellite band at 3.4 $μ$m. In the Orion Bar, we analyze the spatial distribution of the templates and their relationship with the fluorescent emission of H$_2$ in the near infrared. We find that one template ("AIB$_{\rm Irrad}$") traces regions of neutral atomic gas with strong far-UV fields, while the other template ("AIB$_{\rm Shielded}$") corresponds to shielded regions with lower FUV fields and a higher molecular gas fraction. We then show that these two templates can be used to fit the NIRSpec AIB-related spectra of nearby galaxies. The relative weight of the two templates (AIB$_{\rm Irrad/Shielded}$) is a tracer of the radiative feedback from massive stars on the ISM. We derive an estimate of AIB$_{\rm Irrad/Shielded}$ in a $z$ = 4.22 lensed galaxy, and find that it has a lower value than for local galaxies. This pilot study illustrates how a detailed analysis of AIB emission in nearby regions can be used to probe the physical conditions of the extragalactic ISM.

astro-ph.GA↗

arXiv2024

Formation of the Methyl Cation by Photochemistry in a Protoplanetary Disk

Forty years ago it was proposed that gas phase organic chemistry in the interstellar medium was initiated by the methyl cation CH3+, but hitherto it has not been observed outside the Solar System. Alternative routes involving processes on grain surfaces have been invoked. Here we report JWST observations of CH3+ in a protoplanetary disk in the Orion star forming region. We find that gas-phase organic chemistry is activated by UV irradiation.

astro-ph.GA↗