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Isabelle Cantat

Publications and source records attributed to Isabelle Cantat.

At least 19 recordsLinked to original sources

Long distance attraction between particles in a soap film

Millimeter-sized particles trapped at the surface of a liquid bath attract each other through the deformation of the liquid-air interface, a phenomenon known as "the Cheerios effect". We consider here a situation similar at first sight: the interaction between two millimeter-sized particles trapped in an horizontal soap film. In this geometry, the deformation of the film due to the weight of one particle extends over the entire system size, which induces an extremely long-ranged attraction. Combined with the low viscous friction in the film, this leads to intricate particle orbits, lasting up to ten seconds before the two particles eventually collide. By tracking the particles dynamics, we measure the force exerted by each particle on the other, and we develop a theoretical model. Because the interface deformation induced by a particle depends on its position in the soap film, the attractive force has two features that fundamentally depart from classical interaction forces. The force exerted by one particle on the other differs both in direction and magnitude from the reverse interaction, with an asymmetry reaching 150% when one particle is close to the center and the other one close to the frame. Reciprocity is recovered when both particles are close to the film center. These results are a original example of non-reciprocal effective interactions due to boundary conditions.

cond-mat.soft↗

Flowing menisci: coupled dynamics and liquid exchange with soap films

Liquid foams exhibit menisci whose lengths range from hundreds of microns in microfoams to several centimeters in macroscopic bubble arrangements. These menisci thin under gravity until reaching a steady thickness profile, where hydrostatic and capillary pressures are balanced. While these menisci are in contact with soap films, dynamical liquid exchanges between them are neglected in current drainage models, which assume thin films provide a negligible liquid reservoir. Using controlled experiments, we systematically measure the shape of an isolated meniscus placed in a vertical soap film. By increasing the film thickness, we identify a flowing regime in which the flux from the adjacent film significantly enlarges the meniscus. We present an analytical model that extends the drainage equation to incorporate this film flux and introduce a gravito-exchange length, which sets the minimum meniscus thickness. The model is in quantitative agreement with experiments, capturing the transition between hydrostatic and flowing menisci. This study has implications for flowing or rearranging foams, where thick films are commonly observed.

cond-mat.soft↗

Sliding dynamics of a particle in a soap film

We investigate the sliding dynamics of a millimeter-sized particle trapped in a horizontal soap film. Once released, the particle moves toward the center of the film in damped oscillations. We study experimentally and model the forces acting on the particle, and evidence the key role of the mass of the film on its shape and particle dynamics. Not only is the gravitational distortion of the film measurable, it completely determines the force responsible for the motion of the particle - the catenoid-like deformation induced by the particle has negligible effect on the dynamics. Surprisingly, this is expected for all film sizes as long as the particle radius remains much smaller than the film width. We also measure the friction force, and show that ambient air and the film contribute almost equally to the friction. The theoretical model that we propose predicts exactly the friction coefficient as long as inertial effects can be neglected in air (for the smallest and slowest particles). The fit between theory and experiments sets an upper boundary of 0.01 μPa s m for the surface viscosity, in excellent agreement with recent interfacial microrheology measurements.

cond-mat.soft↗

Hydrodynamic thinning of a coating film induced by a small solid defect: evidence of a time-minimum thickness

During coating processes, dust deposition can lead to an uneven thickness in the resulting film, posing significant problems in industrial processes. Our study explores the effects of solid defects using a vertical cylindrical fiber deposited on a silicone oil film coating a horizontal solid substrate. We use a hyperspectral camera to measure the film thickness by interferometry in the vicinity of the defect. As predicted and observed in many studies in various geometries, a circular groove appears around the fiber because of the capillary suction induced by the meniscus that grows at the bottom of the fiber. We measure the evolution of the thickness of the film at the groove over time. The thickness decreases before increasing again leading to the healing of the perturbation at long time. We propose that healing is due to the arrest of the suction when the meniscus reaches its equilibrium shape. By combining geometric analysis with the thin film equation, we have developed scaling laws that predict both the minimum thickness of the groove, that we call the time-minimum thickness, and the time required to reach this minimum. If the time-minimum thickness reaches the thickness at which intermolecular forces begin to play a role prior to healing, the thickness of the groove will stop decreasing and saturate due to the competition between drainage and repulsive intermolecular forces. Based on the previous scaling law, we developed a scaling law accounting for the critical initial thickness of the film below which the intermolecular repulsion will start to have an effect, which is in good agreement with our experiments. These results thus offer valuable insights into predicting and preventing defects in coating processes, thereby improving the quality and reliability of coated products in various industries.

cond-mat.soft↗

Line tension in a thick soap film

The thickness of freshly made soap films is usually in the micron range, and interference colors make thickness fluctuations easily visible. Circular patterns of constant thickness are commonly observed, either a thin film disc in a thicker film or the reverse. In this Letter, we evidence the line tension at the origin of these circular patterns. Using a well controlled soap film preparation, we produce a piece of thin film surrounded by a thicker film. The thickness profile, measured with a spectral camera, leads to a line tension of the order of 0.1 nN which drives the relaxation of the thin film shape, initially very elongated, toward a circular shape.A balance between line tension and air friction leads to a quantitative prediction of the relaxation process. Such a line tension is expected to play a role in the production of marginal regeneration patches, involved in soap film drainage and stability.

cond-mat.soft↗

Thickness profiles of giant soap films

Production, drainage and stability of foams films, i.e. films in contact with their menisci, are fascinating problems that remain still unsolved. In this article, we propose to explore the regime of large velocities and large film sizes. This one is not accessible in experiments classically conducted in the literature, and allows us to study the regime of large extension and large extension rates. With our setup, we make soap films up to two meters high by pulling a horizontal fishing line driven by belts out of a soapy solution at velocities ranging from 20~cm/s to 250~cm/s. We characterize the thickness profile of the central part of the film that behaves like a rubber band under tension. We show that its thickness profile is well described by a static model in which a homogeneous elastic film is stretched by its own weight. This leads to an exponential thickness profile with a characteristic length given by a competition between gravity and surface elasticity. The prefactor is fixed by the shape and area of the film, governed by the fishing line motion but also by a continuous extraction of foam film from the lateral menisci, thicker than the central part, and that progressively invades the film from its lateral boundaries. The model we propose captures the subtle interplay between gravity, film elasticity and film extraction and leads to predictions in good agreement with our experimental data.

cond-mat.soft↗

Local origin of the visco-elasticity of a millimetric elementary foam

Liquid foam exhibits surprisingly high viscosity, higher than each of its phases. This dissipation enhancement has been rationalized by invoking either a geometrical confinement of the shear in the liquid phase, or the influence of the interface viscosity. However, a precise localization of the dissipation, and its mechanism, at the bubble scale is still lacking. To this aim, we simultaneously monitored the evolution of the local flow velocity, film thickness and surface tension of a five films assembly, induced by different controlled deformations. These measurements allow us to build local constitutive relations for this foam elementary brick. We first show that, for our millimetric foam films, the main part of the film has a purely elastic, reversible behavior, thus ruling out the interface viscosity to explain the observed dissipation. We then highlight a generic frustration at the menisci, controlling the interface transfer between neighbor films and resulting in the localization of a bulk shear flow close to the menisci. A model accounting for surfactant transport in these small sheared regions is developed. It is in good agreement with the experiment, and demonstrate that most of the dissipation is localized in these domains. The length of these sheared regions, determined by the physico-chemical properties of the solution, sets a transition between a large bubble regime in which the films are mainly stretched and compressed, and a small bubble regime in which they are sheared. Finally, we discuss the parameter range where a model of foam viscosity could be built on the basis of these local results.

cond-mat.soft↗

Dynamical coupling between connected foam films by interface transfer across the menisci

The highly confined flow of the liquid phase, trapped between the gas bubbles, is at the origin of the large effective viscosity of the liquid foams. Despite the industrial relevance of this complex fluid, the foam viscosity remains difficult to predict, because of the lack of flow characterization at the bubble scale. Using an original deformable frame, we provide the first experimental evidence of the interface transfer between a compressed film (resp. a stretched film) and its first neighbour, across their common meniscus. We measure this transfer velocity, which is a key boundary condition for local flows in foams. We also show the dramatic film thickness variation induced by this interface transfer, which may play an important role in the film thickness distribution of a 3D foam sample.

cond-mat.soft↗

The Marangoni flow of soluble amphiphiles

Surfactant distribution heterogeneities at a fluid/fluid interface trigger the Marangoni effect, i.e. a bulk flow due to a surface tension gradient. The influence of surfactant solubility in the bulk on these flows remains incompletely characterized. Here we study Marangoni flows sustained by injection of hydrosoluble surfactants at the air/water interface. We show that the flow extent increases with a decrease of the critical micelle concentration, i.e. the concentration at which these surfactants self-assemble in water. We document the universality of the surface velocity field and predict scaling laws based on hydrodynamics and surfactant physicochemistry that capture the flow features.

physics.flu-dyn↗

Structure-dependent mobility of a dry aqueous foam flowing along two parallel channels

The velocity of a two-dimensional aqueous foam has been measured as it flows through two parallel channels, at a constant overall volumetric flow rate. The flux distribution between the two channels is studied as a function of the ratio of their widths. A peculiar dependence of the velocity ratio on the width ratio is observed when the foam structure in the narrower channel is either single staircase or bamboo. In particular, discontinuities in the velocity ratios are observed at the transitions between double and single staircase and between single staircase and bamboo. A theoretical model accounting for the viscous dissipation at the solid wall and the capillary pressure across a film pinned at the channel outlet predicts the observed non-monotonic evolution of the velocity ratio as a function of the width ratio. It also predicts quantitatively the intermittent temporal evolution of the velocity in the narrower channel when it is so narrow that film pinning at its outlet repeatedly brings the flow to a near stop.

physics.flu-dyn↗

Extension of a suspended soap film: A homogeneous dilatation followed by new film extraction

Liquid foams are widely used in industry for their high effective viscosity, whose local origin is still unclear. This Letter presents new results on the extension of a suspended soap film, in a configuration mimicking the elementary deformation occurring during foam shearing. We evidence a surprising two-step evolution: the film first extends homogeneously, then its extension stops, and a new thicker film is extracted from the meniscus. The second step is independent of the nature of the surfactant solution, whereas the initial extension is only observed for surfactant solutions with negligible dilatational moduli. We predict this complex behavior using a model based on Frankel's theory and on interface rigidification induced by confinement.

cond-mat.soft↗

Liquid meniscus friction on a wet plate: Bubbles, lamellae and foams

Many microfluidics devices, coating processes or diphasic flows involve the motion of a liquid meniscus on a wet wall. This motion induces a specific viscous force, that exhibits a non-linear dependency in the meniscus velocity. We propose a review of the theoretical and experimental work made on this viscous force, for simple interfacial properties. The interface is indeed assumed either perfectly compressible (mobile interface) or perfectly incompressible (rigid interface). We show that, in the second case, the viscous force exerted by the wall on the meniscus is a combination of two power laws, scaling like $Ca^{1/3}$ and $Ca^{2/3}$, with $Ca$ the capillary number. We provide a prediction for the stress exerted on a foam sliding on a wet solid and compare it with experimental data, for the incompressible case.

cond-mat.soft↗

Liquid films with high surface modulus moving in tubes: dynamic wetting film and jumpy motion

We investigate the motion through a wet tube of transverse soap films, or lamellae, of high surface dilatationnal modulus. Combining local thickness and velocity measurements in the wetting film, we reveal a zone of several centimeters in length, the dynamic wetting film, which is significantly influenced by a moving lamella. The dependence of this influence length on lamella velocity and wetting film thickness provides a discrimination among several possible surfactant minimal models. A spectacular jumpy mode of unsteady motion of a lamella is also evidenced.

cond-mat.soft↗

Experimental growth law for bubbles in a "wet" 3D liquid foam

We used X-ray tomography to characterize the geometry of all bubbles in a liquid foam of average liquid fraction $ϕ_l\approx 17 %$ and to follow their evolution, measuring the normalized growth rate $\mathcal{G}=V^{-{1/3}}\frac{dV} {dt}$ for 7000 bubbles. While $\mathcal{G}$ does not depend only on the number of faces of a bubble, its average over $f-$faced bubbles scales as $G_f\sim f-f_0$ for large $f$s at all times. We discuss the dispersion of $\mathcal{G}$ and the influence of $V$ on $\mathcal{G}$.

cond-mat.soft↗

Stokes experiment in a liquid foam

The paper reports on the quasi-static steady flow of a dry liquid foam around a fixed spherical bead, few times larger than the typical bubble size. The force exerted on the bead is recorded with a precision and a time resolution large enough to show the succession of elastic loading of the foam, separated by sudden force drops. The foam structure is observed by direct light transmission, synchronized with the force measurement, thus allowing to correlate the plastic events with the force variations. Scaling laws for the force signal as a function of the bubble size are detailed and interpreted with a simple elasto-plastic model. The spatial distribution of the plasticity is strongly localized in the first bubbles layers around the bead and the average size of bubble rearrangements increases with the corresponding force jump amplitude.

cond-mat.soft↗

Mechanical probing of liquid foam aging

We present experimental results on the Stokes experiment performed in a 3D dry liquid foam. The system is used as a rheometric tool : from the force exerted on a 1cm glass bead, plunged at controlled velocity in the foam in a quasi static regime, local foam properties are probed around the sphere. With this original and simple technique, we show the possibility of measuring the foam shear modulus, the gravity drainage rate and the evolution of the bubble size during coarsening.

cond-mat.soft↗

Viscous force exerted on a foam at a solid boundary : influence of the liquid fraction and of the bubble size

We study experimentally the pressure drop needed to push a bubble train in a millimetric channel, as a function of the velocity. For dry liquid foams, the influence of the amount of liquid and of the bubble size is pointed out and we predict theoretically that this influence is closely related to the power law obtained for the force/velocity relation. This model is in fair agreement with our experimental data and provides a new interpretation of previous results.

cond-mat.soft↗

Experimental evidence of flow destabilization in a 2D bidisperse foam

Liquid foam flows in a Hele-Shaw cell were investigated. The plug flow obtained for a monodisperse foam is strongly perturbed in the presence of bubbles whose size is larger than the average bubble size by an order of magnitude at least. The large bubbles migrate faster than the mean flow above a velocity threshold which depends on its size. We evidence experimentally this new instability and, in case of a single large bubble, we compare the large bubble velocity with the prediction deduced from scaling arguments. In case of a bidisperse foam, an attractive interaction between large bubbles induces segregation and the large bubbles organize themselves in columns oriented along the flow. These results allow to identify the main ingredients governing 2D polydisperse foam flows.

cond-mat.soft↗