arXiv subjects

J. Akimitsu

Publications and source records attributed to J. Akimitsu.

At least 19 recordsLinked to original sources

arXiv2025

Cooper-Pair Localization in the Magnetic Dynamics of a Cuprate Ladder

We investigate the spin dynamics of the cuprate ladder Sr$_{2.5}$Ca$_{11.5}$Cu$_{24}$O$_{41}$ to elucidate the behavior of its intrinsically doped holes. Combining high-resolution neutron spectroscopy and density matrix renormalization group calculations enables a comprehensive analysis of the collective magnetic dynamics. We find a general absence of magnetic signatures from unpaired charges, indicating holes within the system form strongly bound localized Cooper pairs. A one-band Hubbard model fails to match the spectral features but a straightforward extension to a large attractive nearest-neighbor interaction quantitatively explains our results. Our finding shows the significance of additional interactions beyond the long-predicted quantum spin pairing in the ($d$-wave) charge pairing process. Considering the parallels between ladders and two-dimensional cuprates, these results are potentially relevant for square lattices as well.

cond-mat.str-el↗

arXiv2024

Layer buckling and absence of superconductivity in LaNiO2

The recent observation of unconventional superconductivity in thin films of LaNiO2 (critical temperature, Tc~10 K) and in bulk single crystals of La3Ni2O7 (327) under pressure (Tc~80 K), has brought to light a long sought-after class of superconducting nickelates. Through structural measurements in the 327-system, it was shown that the absence of superconductivity is related to bending of the O-Ni-O bonds. Similarly, the bond bending may be linked to the absence of superconductivity in bulk LaNiO2. Neutron diffraction was used on bulk non-superconducting La(1-x)Sr(x)NiO(2) samples to show that the layers are naturally buckled, creating a Ni-O-Ni bond angle of 177 at 2 K and ambient pressure. The buckling angle increases to 170 on warming to room temperature. Furthermore, a broad paramagnetic continuum is observed that decreases in intensity on cooling from room temperature signaling a possible transition to a coherent state. However, no antiferromagnetic (AFM) peaks are detected, although enhancement of ferromagnetic (FM) correlations cannot be excluded.

cond-mat.supr-con↗

arXiv2022

An emergence of chiral helimagnetism or ferromagnetism governed by Cr intercalation in a dichalcogenide CrNb$_{3}$S$_{6}$

A synthesis of single crystals of chiral dichalcogenides $TM_{3}X_{6}$ ($T$: 3$d$ transition metal, $M$: Nb or Ta, $X$: S or Se) remains an intriguing issue for the investigation of emergent quantum properties such as chiral helimagnetism. In this study, we investigated a correlation between the quantity of Cr intercalation $x$ and magnetic property in single crystals of a chromium (Cr) intercalated chiral disulfide Cr$_x$Nb$_3$S$_6$ in order to optimize the synthesis condition for the intercalation-controlled single crystals. The magnetic properties including a magnetic transition temperature $T_{c}$ take different values depending on the samples. We systematically grew single crystals of Cr$_{x}$Nb$_{3}$S$_{6}$ with $x$ ranged from 0.89 to 1.03 and found that the amount of the Cr intercalation $x$ is an essential factor in controlling the magnetic properties of the grown crystals. The magnetization anomaly, which appears in the temperature dependence as evidence of the formation of chiral magnetic soliton lattice (CSL), was observed only in a narrow region of $x$ from 0.98 to 1.03. The single crystals with $x$ being 0.98 and 0.99 showed the CSL behavior with the highest $T_{c}$ of 133 K. These results indicate that small amount of defects on the sites for $T$ ions dramatically affects the quality of the single crystals in the synthesis of $TM_{3}$S$_{6}$. We also discuss an importance of synthesizing enantiopure single crystals of chiral dichalgogenides in order to observe chiral physical properties unique to chiral compounds such as magneto-chiral effect and chiral-induced spin selectivity.

cond-mat.mtrl-sci↗

arXiv2021

Nodeless superconductivity in Lu$_{5-x}$Rh$_6$Sn$_{18+x}$ with broken time reversal symmetry

Evidence for broken time reversal symmetry (TRS) has been found in the superconducting states of the $R_5$Rh$_6$Sn$_{18}$ (R = Sc, Y, Lu) compounds with a centrosymmetric caged crystal structure, but the origin of this phenomenon is unresolved. Here we report neutron diffraction measurements of single crystals with $R$=Lu, as well as measurements of the temperature dependence of the magnetic penetration depth using a self-induced tunnel diode-oscillator (TDO) based technique, together with band structure calculations using density functional theory. Neutron diffraction measurements reveal that the system crystallizes in a tetragonal caged structure, and that one of nominal Lu sites in the Lu$_5$Rh$_6$Sn$_{18}$ structure is occupied by Sn, yielding a composition Lu$_{5-x}$Rh$_6$Sn$_{18+x}$ ($x=1$). The low temperature penetration depth shift $\Delta\lambda(T)$ exhibits an exponential temperature dependence below around $0.3T_c$, giving clear evidence for fully gapped superconductivity. The derived superfluid density is reasonably well accounted for by a single gap $s$-wave model, whereas agreement cannot be found for models of TRS breaking states with two-component order parameters. Moreover, band structure calculations reveal multiple bands crossing the Fermi level, and indicate that the aforementioned TRS breaking states would be expected to have nodes on the Fermi surface, in constrast to the observations.

cond-mat.supr-con↗

arXiv2019

Unconventional superconductivity in the cage type compound Sc$_5$Rh$_6$Sn$_{18}$

We have examined the superconducting ground state properties of the caged type compound Sc$_5$Rh$_6$Sn$_{18}$ using magnetization, heat capacity, and muon-spin relaxation or rotation ($\mu$SR) measurements. Magnetization measurements indicate type-II superconductivity with an upper critical field $\mu_0H_{c2}(0)$ = 7.24 T. The zero-field cooled and field cooled susceptibility measurements unveil an onset of diamagnetic signal below $T_{\bf c}$ = 4.4 K. The interpretation of the heat capacity results below $T_{\bf c}$ using the $\alpha-$BCS model unveils the value of $\alpha$ = 2.65, which gives the dimensionless ratio 2$\Delta(0)/k_B T_{\bf c}$ = 5.3, intimating that Sc$_5$Rh$_6$Sn$_{18}$ is a strong-coupling BCS superconductor. The zero-field $\mu$SR measurements in the longitudinal geometry exhibit a signature of a spontaneous appearance of the internal magnetic field below the superconducting transition temperature, indicating that the superconducting state is characterized by the broken time-reversal symmetry (TRS). We have compared the results of broken TRS in Sc$_5$Rh$_6$Sn$_{18}$ with that observed in R$_5$Rh$_6$Sn$_{18}$ (R = Lu and Y).

cond-mat.supr-con↗

arXiv2018

Determination of the local structure of Sr$_{2-x}$M$_x$IrO$_4$ (M = K, La) as a function of doping and temperature

The local structure of correlated spin-orbit insulator Sr$_{2-x}$M$_x$IrO$_4$ (M = K, La) has been investigated by Ir L$_3$-edge extended x-ray absorption fine structure measurements. The measurements were performed as a function of temperature for different dopings induced by substitution of Sr with La or K. It is found that Ir-O bonds have strong covalency and they hardly show any change across the N\'eel temperature. In the studied doping range, neither Ir-O bonds nor their dynamics, measured by their mean square relative displacements, show any appreciable change upon carrier doping, indicating possibility of a nanoscale phase separation in the doped system. On the other hand, there is a large increase of the static disorder in Ir-Sr correlation, larger for K doping than La doping. Similarities and differences with respect to the local lattice displacements in cuprates are briefly discussed.

cond-mat.str-el↗

arXiv2017

Evolution of remnant Fermi surface state in lightly-doped correlated spin-orbit insulator Sr$_{2-x}$La$_x$IrO$_4$

Electronic structure has been studied in lightly electron doped correlated spin-orbit insulator Sr$_2$IrO$_4$ by angle-resolved photoelectron spectroscopy. We have observed coexistence of the lower Hubbard band and the in-gap band, the momentum dependence of the latter traces that of the band calculations without on-site Coulomb repulsion. The in-gap state remained anisotropically gapped in all observed momentum area, forming a remnant Fermi surface state, evolving towards the Fermi energy by carrier doping. These experimental results show a striking similarity with those observed in deeply underdoped cuprates, suggesting the common nature of the nodal liquid states observed in both compounds.

cond-mat.str-el↗

arXiv2016

Spin excitations in hole-overdoped iron-based superconductors

Understanding the overall features of magnetic excitation is essential for clarifying the mechanism of Cooper pair formation in iron-based superconductors. In particular, clarifying the relationship between magnetism and superconductivity is a central challenge because magnetism may play a key role in their exotic superconductivity. BaFe2As2 is one of ideal systems for such investigation because its superconductivity can be induced in several ways, allowing a comparative examination. Here we report a study on the spin fluctuations of the hole-overdoped iron-based superconductors Ba1-xKxFe2As2 (x = 0.5 and 1.0; Tc = 36 K and 3.4 K, respectively) over the entire Brillouin zone using inelastic neutron scattering. We find that their spin spectra consist of spin wave and chimney-like dispersions. The chimney-like dispersion can be attributed to the itinerant character of magnetism. The band width of the spin wave-like dispersion is almost constant from the non-doped to optimum-doped region, which is followed by a large reduction in the overdoped region. This suggests that the superconductivity is suppressed by the reduction of magnetic exchange couplings, indicating a strong relationship between magnetism and superconductivity in iron-based superconductors.

cond-mat.supr-con↗

arXiv2016

Suppression of spin-exciton state in hole overdoped iron-based superconductors

The mechanism of Cooper pair formation in iron-based superconductors remains a controversial topic. The main question is whether spin or orbital fluctuations are responsible for the pairing mechanism. To solve this problem, a crucial clue can be obtained by examining the remarkable enhancement of magnetic neutron scattering signals appearing in a superconducting phase. The enhancement is called spin resonance for a spin fluctuation model, in which their energy is restricted below twice the superconducting gap value (2Ds), whereas larger energies are possible in other models such as an orbital fluctuation model. Here we report the doping dependence of low-energy magnetic excitation spectra in Ba1-xKxFe2As2 for 0.5<x<0.84 studied by inelastic neutron scattering. We find that the behavior of the spin resonance dramatically changes from optimum to overdoped regions. Strong resonance peaks are observed clearly below 2Ds in the optimum doping region, while they are absent in the overdoped region. Instead, there is a transfer of spectral weight from energies below 2Ds to higher energies, peaking at values of 3Ds for x = 0.84. These results suggest a reduced impact of magnetism on Cooper pair formation in the overdoped region.

cond-mat.supr-con↗

arXiv2015

Chiral surface twists and skyrmion stability in nanolayers of cubic helimagnets

Lorentz transmission electron microscopy (LTEM) investigations of modulated states in a FeGe wedge and detailed calculations demonstrate that chiral twists arising near the surfaces of noncentrosymmetric ferromagnets (Meynell et al. Phys. Rev. B, 90, 014406 (2014)) provide a stabilization mechanism for skyrmion lattices and helicoids in cubic helimagnet nanolayers. The calculated magnetic phase diagram for free standing cubic helimagnet nanolayers shows that magnetization processes in these compounds fundamentally differ from those in bulk cubic helimagnets and are characterized by the first-order transitions between modulated phases and the formation of specific multidomain states. The paper reports LTEM observations of multidomain patterns in FeGe free-standing nanolayers.

cond-mat.mes-hall↗

arXiv2015

Broken time-reversal symmetry probed by muon spin relaxation in the caged type superconductor Lu$_5$Rh$_6$Sn$_{18}$

The superconducting state of the caged type compound Lu$_5$Rh$_6$Sn$_{18}$ has been investigated by using magnetization, heat capacity, and muon-spin relaxation or rotation ($μ$SR) measurements and the results interpreted on the basis of the group theoretical classifications of the possible pairing symmetries and a simple model of the resulting quasiparticle spectra. Our zero-field $μ$SR measurements clearly reveal the spontaneous appearance of an internal magnetic field below the transition temperature, which indicates that the superconducting state in this material is characterized by the broken time-reversal symmetry. Further the analysis of temperature dependence of the magnetic penetration depth measured using the transverse field $μ$SR measurements suggest an isotropic $s$-wave character for the superconducting gap. This is in agreement with the heat capacity behavior and we show that it can be interpreted in terms of a non unitary triplet state with point nodes and an open Fermi surface.

cond-mat.supr-con↗

arXiv2014

Bulk Nature of Layered Perovskite Iridates beyond the Mott Scenario : An Approach from Bulk Sensitive Photoemission Study

We present genuine bulk Ir 5d jeff states of layered perovskite iridates obtained by hard-x-ray photoemission spectroscopy (HAXPES) with s- and p-polarized lights. HAXPES spectra of Sr2IrO4 and Ba2IrO4 are well reproduced by the quasi-particle densities of states calculated by the local density approximation with dynamical mean-field theory (LDA+DMFT). It is demonstrated that the insulating nature of the iridates is triggered by antiferromagnetic correlation (Slater type) combined with electron correlation (Mott type). The extremely-low-energy bulk-sensitive photoemission spectroscopy reveals "bad metallic" states in the paramagnetic phase of the iridates, suggesting strongly renormalized metallic states above the Neel temperature as predicted by the LDA+DMFT.

cond-mat.str-el↗

arXiv2013

Orbital occupancies and the putative jeff = 1/2 groundstate in Ba2IrO4: a combined oxygen K edge XAS and RIXS study

The nature of the electronic groundstate of Ba2IrO4 has been addressed using soft X-ray absorption and inelastic scattering techniques in the vicinity of the oxygen K edge. From the polarization and angular dependence of XAS we deduce an approximately equal superposition of xy, yz and zx Ir4+ 5d orbitals. By combining the measured orbital occupancies, with the value of the spin-orbit coupling provided by RIXS, we estimate the crystal field splitting associated with the tetragonal distortion of the IrO6 octahedra to be small, Δ=50(50) meV. We thus conclude definitively that Ba2IrO4 is a close realization of a spin-orbit Mott insulator with a jeff = 1/2 groundstate, thereby overcoming ambiguities in this assignment associated with the interpretation of X-ray resonant scattering experiments.

cond-mat.str-el↗

arXiv2013

The electronic structure of the high-symmetry perovskite iridate Ba2IrO4

We report angle-resolved photoemission (ARPES) measurements, density functional and model tight-binding calculations on Ba$_2$IrO$_4$ (Ba-214), an antiferromagnetic ($T_N=230$ K) insulator. Ba-214 does not exhibit the rotational distortion of the IrO$_6$ octahedra that is present in its sister compound Sr$_2$IrO$_4$ (Sr-214), and is therefore an attractive reference material to study the electronic structure of layered iridates. We find that the band structures of Ba-214 and Sr-214 are qualitatively similar, hinting at the predominant role of the spin-orbit interaction in these materials. Temperature-dependent ARPES data show that the energy gap persists well above $T_N$, and favour a Mott over a Slater scenario for this compound.

cond-mat.str-el↗

arXiv2012

Emergence of highly degenerate excited states in frustrated magnet MgCr$_2$O$_4$

High degeneracy in ground states leads to the generation of exotic zero-energy modes, a representative example of which is the formation of molecular spin liquid-like fluctuations in a frustrated magnet. Here we present single-crystal inelastic neutron scattering results for the frustrated magnet MgCr$_2$O$_4$, which show that a common set of finite-energy molecular spin excitation modes is sustained in both the liquid-like paramagnetic phase and a magnetically ordered phase with an extremely complex structure. Based on this finding, we propose the concept of high degeneracy in excited states, which promotes local resonant elementary excitations. This concept is expected to have ramifications on our understanding of excitations in many complex systems, including not only spin but also atomic liquids, complex order systems, and amorphous systems.

cond-mat.str-el↗

arXiv2011

Hole-depletion of ladders in Sr$_{14}$Cu$_{24}$O$_{41}$ induced by correlation effects

The hole distribution in Sr$_{14}$Cu$_{24}$O$_{41}$ is studied by low temperature polarization dependent O K Near-Edge X-ray Absorption Fine Structure measurements and state of the art electronic structure calculations that include core-hole and correlation effects in a mean-field approach. Contrary to all previous analysis, based on semi-empirical models, we show that correlations and antiferromagnetic ordering favor the strong chain hole-attraction. For the remaining small number of holes accommodated on ladders, leg-sites are preferred to rung-sites. The small hole affinity of rung-sites explains naturally the 1D - 2D cross-over in the phase diagram of (La,Y,Sr,Ca)$_{14}$Cu$_{24}$O$_{41}$

cond-mat.str-el↗

arXiv2011

Evidence of nodal gap structure in the non-centrosymmetric superconductor Y2C3

The magnetic penetration depth $λ(T)$ and the upper critical field $% μ_{0}H_{c2}(T_{c})$ of the non-centrosymmetric (NCS) superconductor Y$_{2} $C$_{3}$ have been measured using a tunnel-diode (TDO) based resonant oscillation technique. We found that the penetration depth $λ(T)$ and its corresponding superfluid density $ρ_{s}(T)$ show linear temperature dependence at very low temperatures ($T\ll T_{c}$), indicating the existence of line nodes in the superconducting energy gap. Moreover, the upper critical field $μ_{0}H_{c2}(T_{c})$ presents an upturn at low temperatures with a rather high value of $μ_{0}H_{c2}(0)$ $\simeq 29$T, which slightly exceeds the weak-coupling Pauli limit. We discuss the possible origins for these nontrivial superconducting properties, and argue that the nodal gap structure in Y$_{2}$C$_{3}$ is likely attributed to the absence of inversion symmetry, which allows the admixture of spin-singlet and spin-triplet pairing states.

cond-mat.supr-con↗

arXiv2011

Large upper critical field in non-centrosymmetric superconductor Y2C3

We determine the upper critical field $μ_0 H_{c2}(T_c)$ of non-centrosymmetric superconductor $Y_2 C_3$ using two distinct methods: the bulk magnetization M(T) and the tunnel-diode oscillator (TDO) based impedance measurements. It is found that the upper critical field reaches a value of 30T at zero temperature which is above the weak-coupling Pauli paramagnetic limit. We argue that the observation of such a large $μ_0 H_{c2}(0)$ in $Y_2 C_3$ could be attributed to the admixture of spin-singlet and spin-triplet pairing states as a result of broken inversion symmetry.

cond-mat.supr-con↗