Searcharxiv⌕ Search

arXiv subjects

J. Cami

Publications and source records attributed to J. Cami.

At least 19 recordsLinked to original sources
arXiv2026

An extended red wing of the 5797 Å diffuse interstellar band in the Red Rectangle nebula

Diffuse interstellar bands (DIBs) are interstellar molecular absorption features that are ubiquitous in the interstellar medium (ISM). So far, there was only one known sight line where DIBs show an extend tail towards the red (ETR), namely Herschel 36. Such sight lines are essential to illuminate the DIB problem, namely the identification of their carriers, because they show more DIB variation than standard ISM sight lines. To report a new detection of the 5797 Å DIB in the Red Rectangle nebula with an ETR, which adds a new observational constraint for the DIB carrier. We analysed archival GIRAFFE/FLAMES integral field spectroscopy to extract all spectral features between 5776 and 5810 Å at different spatial positions. We used time series spectra to identify stellar and circumstellar features, and data from different instruments to exclude instrumental effects. We report the firm detection of the 5797 Å DIB that is localised in the Red Rectangle nebula, or in the ISM in the sight line towards it. Curiously, while the 5797 Å DIB shows an ETR in the Red Rectangle, the 5780 Å DIB does not. Further, we report an exceptionally high equivalent ratio of EW(5797)/EW(5780) = 1.79 higher than any other literature value.

astro-ph.GA↗
arXiv2026

H2 emission in the Orion Bar, NGC7023 and the Horsehead Nebula observed with the James Webb Space Telescope

Molecular hydrogen (H2), the most abundant molecule in the interstellar medium, is a handy tool to study Photodissociation Regions. The JWST, with its high spatial resolution, sensitivity, and wavelength coverage, provides unique access to the detection and spatial morphology of the H2 rotational and rovibrational lines. Our goal is to analyze H2 line emission detected with JWST in several PDRs (the Orion Bar, NGC7023, and the Horsehead Nebula) to constrain the physical structure of dissociation front, and compare the impact of the ultraviolet field and the gas density across different regions. The analysis of H2 spatial morphology reveals similar filamentary structures across all regions. Spatial shifts between H2 lines (0.5") are observed and linked to differences in excitation mechanisms (thermalized vs FUV-pumped lines) and the temperature gradient. Despite differences in incident irradiation conditions, analysis of H2 rotational excitation yields high gas temperatures that are similar across the three PDRs. This is expected for a certain regime of excited PDRs (such as Orion and NGC7023), where the G0 at the DFs and the density are similar. However, it is surprising for less excited PDRs like the Horsehead Nebula. OPRs in the rotational and rovibrational levels differ across the three PDRs. We also used H2 rovibrational lines and the 0-0 S(3) line to estimate the visual extinction across the field of view, yielding markedly different results that constrain both the geometry and the grain composition. Due to the complex 3D geometry, H2 emission is observed throughout the FOV and is dominated by the thin UV illuminated layer, making H2 an unreliable tracer of gas temperature in deeper and coolers molecular layers of the PDR. Therefore, H2 emission is not sufficient to trace the possible temperature and density gradient across PDRs and must therefore be associated with other tracers.

astro-ph.GA↗
arXiv2026

The JWST Proto-PAH project. Computational modeling of the emission carriers

The infrared spectra of many carbon-rich post-asymptotic giant branch stars are dominated by emission features from aromatic and aliphatic hydrocarbons, but the chemical structure of the carriers remains unidentified. Class D sources show unusual emission profiles with strong aliphatic emission, providing a stringent test of carrier candidates. Here we investigate whether hydrogenated carbonaceous molecular particles can be the carriers of these features. Rather than assuming candidate geometries we generate the initial structures using ab initio molecular dynamics simulations and optimize them using density functional theory. We then compare the computed emission spectra to JWST NIRSpec and MIRI/MRS observations of Class D sources. The structures providing the best agreements contain sizeable domains with defect-bearing aromatics and hydrogenated-aromatics connected by aliphatic bridges, in contrast to the "arophatic" cluster model of isolated two- to three-ring aromatics connected by aliphatic and olefinic bridges. As a representative example, we discuss in detail the molecular particle C130H96 (radius of 5.5 A) and compare its computed spectrum to the JWST spectra of IRAS 05110-6616, a Class D2 source with apparent shifts of the aromatic C-H out-of-plane bands. The calculated spectra are in qualitative agreement with the observed 3 micron profile, the aliphatic C-H bending bands, the broad 8 micron feature, the 11-14 micron C-H out-of-plane region, and the bands at 16 and 21 microns. We hypothesize that UV photo-driven fragmentation of such molecular particles releases aromatics linked by aliphatics, followed by the formation of polycyclic aromatic hydrocarbons and fullerenes as these objects evolve into planetary nebulae.

astro-ph.GA↗
arXiv2026

The JWST Proto-PAH project: Aromatic backbones with extensive aliphatic substitution account for both the aromatic and aliphatic emission

We find that the aromatic and aliphatic emission bands in four carbon-rich post-asymptotic giant branch stars with class D emission arise from a single carrier population: extensive aliphatic decoration of an aromatic skeleton, i.e. molecules with a coherent aromatic backbone and an unusually high aliphatic content. This conclusion is based on JWST NIRSpec and MIRI/MRS spectroscopy, covering 2.88-28.7um. The aliphatic 3.4um feature is stronger than the aromatic 3.3um feature, reversing the ratio seen in sources with typical polycyclic aromatic hydrocarbon (PAH) emission. If the aromatic emission arose from nominal PAHs, the 3.3um feature - unavailable in previous observations - together with the mid-infrared aromatic features, would constrain them to be large (greater than about carbon atoms), compact, and at least partially ionized. These properties predict a strong 8.6um feature. However, the 8.6um feature is weak or absent in all four sources, ruling out PAHs as the source of the aromatic emission. Instead, the emission must arise from the same carriers as the aliphatic emission. The position of the 6.9um feature and the broadened 11-14um out-of-plane emission independently support this. The CH2 and CH3 feature strengths vary across the sample, with the class D2 sources showing higher CH3 content. These carriers are far more aliphatic than the PAHs of planetary nebulae and the interstellar medium. However, they retain the aromatic skeleton that produces their aromatic features.

astro-ph.GA↗
arXiv2026

The JWST Proto-PAH Project: Detection of the methyl radical CH$_{3}$ in the highly evolved C-rich object SMP LMC 011

We report the first detection of the neutral methyl radical CH$_3$ in a highly evolved C-rich object, SMP LMC 011, using JWST MIRI/MRS. CH$_3$ is well fitted by an excitation temperature of $T_{\rm ex} \simeq$~190\,K and a column density of $N_{\rm tot}(\mathrm{CH_3}) \simeq 5.6\times10^{17}$ cm$^{-2}$. We also report the non-detection of ethane (C$_2$H$_6$), consistent with CH$_3$ reacting preferentially with unsaturated radicals rather than self-recombination, which may be inefficient in SMP LMC 011. Combined with the exceptionally large benzene column density of SMP LMC 011, this supports a methyl-addition route from benzene towards alkyl-substituted aromatics. We propose that the high CH$_3$ abundance is driven by the erosion of hydrogenated amorphous carbon (HAC) dust grains in the dense warm torus by UV photons from the central star and/or by shocks, which release CH$_3$ directly into the gas phase. These results establish CH$_3$ as a key reactive intermediate in the formation of complex hydrocarbons in C-rich circumstellar environments. Chemical models that incorporate methyl-addition reactions are needed for a better understanding of PAH formation pathways in evolved stars. The potential detection of alkyl-substituted aromatics such as toluene (C$_7$H$_8$) and ethylbenzene (C$_8$H$_{10}$) in C-rich evolved stars would provide direct confirmation of CH$_3$-driven aromatic growth in circumstellar environments.

astro-ph.SR↗
arXiv2026

Searching for the elusive CH2+ with the James Webb Space Telescope. Another carbocation to constrain astrochemical networks

Carbocations are key species in interstellar chemistry, providing entry points for building larger hydrocarbons. CH+, and more recently, CH3+, have been detected. Other carbocations await detection to provide a comprehensive view of the astrochemical network that is at work in the interstellar medium. We search for CH2+ in objects in which CH3+ was detected and evaluate the most favorable conditions for detecting the elusive CH2+ reactive cation. We calculated the CH2+ rotational and rovibrational transitions expected to contribute in the mid- to far-infrared, focusing on the lower-energy rovibrational levels. We then calculated CH2+ infrared emission spectra at different excitation temperatures and compared them to JWST spectra of the externally irradiated disk d203-506 in Orion, where CH+ and CH3+ have already been detected. We used thermochemical models to predict the abundance and spatial morphology of CH2+ to better understand its nondetection. The comparison to JWST spectra allowed us to provide excitation-temperature-dependent upper limits to the excited column density. These are several times lower than those detected for CH+ and CH3+ in their excited states. Based on model calculations for photodissociation regions and assuming similar excitation temperatures, the upper limit derived from observations and CH2+ model spectrum is either slightly above or below the column density expected from models of photodissociation regions. We provide a list of tabulated transitions to allow the community to search for this carbocation in future observations as CH2+ is key in providing observational constraints on astrochemical models.

astro-ph.GA↗
arXiv2026

MUSE Imaging Spectroscopy of the Fullerene Planetary Nebula Tc 1

The planetary nebula Tc 1 (PN G345.2 -08.8), one of the rare group of Galactic PNe showing fullerene emission in the infrared, was observed with MUSE wide field mode with adaptive optics, wavelength range 4750-9300A. Extinction, electron temperature (T_e) and density (N_e) images are presented from collisionally excited and recombination line ratios. The nebula has a high surface brightness 12 arcsec core, an elliptical ring of major axis 2.8 arcsec around the central star and some low ionization knots, and an extended halo 55 arcsec in size; between the core and halo is an annulus with intermediate properties, including higher T_e and lower N_e than in the core. The image of optical extinction from H Balmer line ratios is highly structured, and shows an annulus, adjacent to the core, of low extinction, lower than the line-of-sight interstellar extinction. Instrumental effects to account for this anomalously low extinction area are investigated and intrinsic effects from the scattering properties of nebular dust; neither can entirely explain the low-extinction region and the most likely cause is a local non-standard dust reddening law. This low extinction region also shows an anomalously high He I 7281/6678A line ratio, possibly caused by a contaminating line, but none were conclusively identified. The spectrum of the central star was extracted and fitted by a 31000K model atmosphere and is of type O7.5I(f). Over extended regions an enhancement of the detected continuum above the nebular continuum was found, as also seen in some other PNe observed with MUSE. The annulus of low extinction occurs outside the region of strongest fullerene emission, in the zone where N_e declines and T_e rises. A change in dust properties linked to conditions in this transition region between the higher density core nebula and lower density halo is deduced. (Abridged)

astro-ph.SR↗
arXiv2026

Mid-infrared JWST spectra of carbon stars in the Large Magellanic Cloud

Mid-infrared spectra from the Medium Resolution Spectrometer on the James Webb Space Telescope have revealed the molecular chemistry of carbon stars in the Large Magellanic Cloud with better resolution and sensitivity than previously possible. Our sample spans a range of dust-production rates and includes three relatively dust-free semiregular variables and six dustier Mira variables. All were observed 15-20 yr earlier with the Infrared Spectrograph on the Spitzer Space Telescope at lower spectral resolution. The new spectra show that the C3 molecule is responsible for a strong absorption band centered at 5.2 um. CS is clearly present in some of the sample, especially the stars with less dust. HCN also appears to be present. Some of the spectra have changed significantly between the Spitzer epoch and the MRS observations in 2023 and 2024, and in most cases these changes can be attributed to the stellar pulsation cycle. One exception is the disappearance of a dust emission feature at ~18 um in one of the Miras. The new spectra reveal a dip centered at ~10 um, which could arise either from an unknown carrier or from variable molecular emission to the red and blue. The presence of this spectral structure on the short-wavelength side of the SiC dust emission feature at ~11.3 um along with the broad C2H2 band centered at 14 um raise the possibility that some previously reported detections of weak SiC dust emission in other carbon stars may not be real.

astro-ph.SR↗
arXiv2026

JWST MIRI-MRS observations of the Red Rectangle: AIB class transformation in the outer nebula

Aims: We characterize the mid-infrared spectrum of the outer regions of the Red Rectangle nebula to probe the carbonaceous dust and molecular content beyond the circumbinary disk. Methods: We present JWST MIRI-MRS observations of the SW whisker, extracted from three distinct environments: the biconical outflow, the whisker itself, and the shadow region outside the outflow. We compare these with an archival ISO-SWS observation of the inner nebula. Results: The JWST spectra display only classical AIB emission on a weak dust continuum, with no signatures of the oxygen-rich circumbinary disk mineralogy nor of the rich molecular emission seen at optical wavelengths. The AIBs are predominantly Class A - in marked contrast to the exclusively Class B profiles previously reported for the inner regions - with systematic differences between the outflow and shadow regions pointing to environmentally driven PAH processing.

astro-ph.GA↗
arXiv2025

The Nearby Evolved Stars Survey III: First data release of JCMT CO-line observations

Low- to intermediate-mass ($\sim$0.8$-$8 M$_\odot$) evolved stars contribute significantly to the chemical enrichment of the interstellar medium in the local Universe, making accurate mass-return estimates in their final stages crucial. The Nearby Evolved Stars Survey (NESS) is a large multi-telescope project targeting a volume-limited sample of $\sim$850 stars within 3 kpc in order to derive the dust and gas return rates in the Solar Neighbourhood, and to constrain the physics underlying these processes. We present an initial analysis of the CO-line observations, including detection statistics, carbon isotopic ratios, initial mass-loss rates, and gas-to-dust ratios. We describe a new data reduction pipeline to analyse the available NESS CO data from the JCMT, measuring line parameters and calculating empirical gas mass-loss rates. We present the first release of the available data on 485 sources, one of the largest homogeneous samples of CO data to date. Comparison with a large literature sample finds that high mass-loss rate and especially carbon-rich sources are over-represented in literature, while NESS is probing significantly more sources at low mass-loss rates, detecting 59 sources in CO for the first time and providing useful upper limits. CO line detection rates are 81% for the CO (2--1) line and 75% for CO (3--2). The majority (82%) of detected lines conform to the expected soft parabola shape, while eleven sources show a double wind. Calculated mass-loss rates show power-law relations with both the dust-production rates and expansion velocities up to $\sim 5 \times 10^{-6}$~\msunyr. Median gas-to-dust ratios of 250 and 680 are found for oxygen-rich and carbon-rich sources, respectively. Our analysis of CO observations in this first data release highlights the importance of our volume-limited approach in characterizing the local AGB population as a whole.

astro-ph.GA↗
arXiv2025

PDRs4All XV: CH radical and H$_3^+$ molecular ion in the irradiated protoplanetary disk d203-506

Most protoplanetary disks experience a phase in which they are subjected to strong ultraviolet radiation from nearby massive stars. This UV radiation can substantially alter their chemistry by producing numerous radicals and molecular ions. In this Letter we present detailed analysis of the JWST-NIRSpec spectrum of the d203-506 obtained as part of the PDRs4All Early Release Science program. Using state-of-the-art spectroscopic data, we searched for species using a multi-molecule fitting tool, PAHTATmol, that we developed for this purpose. Based on this analysis, we report the clear detection of ro-vibrational emission of the CH radical and likely detection of the H$_3^+$ molecular ion, with estimated abundances of a few times 10$^{-7}$ and approximately 10$^{-8}$, respectively. The presence of CH is predicted by gas-phase models and well explained by hydrocarbon photochemistry. H$_3^+$ is usually formed through reactions of H$_2$ with H$_2^+$ originating from cosmic ray ionization of H$_2$. However, recent theoretical studies suggest that H$_3^+$ also forms through UV-driven chemistry in strongly irradiated ($G_0>$10$^3$), dense ($n_{\rm H} >10^{6}$ cm$^{-3}$) gas. The latter is favored as an explanation for the presence of ``hot'' H$_3^+$ ($T_{\rm ex}\gtrsim$1000 K) in the outer disk layers of d203-506, coinciding with the emission of FUV-pumped H$_2$ and other ``PDR species'', such as CH$^+$, CH$_3^+$, and OH. Our detection of infrared emission from vibrationally excited H$_3^+$ and CH raises questions about their excitation mechanisms and, underscore that UV radiation can have a profound impact on the chemistry of planet forming disks. They also demonstrate the power of JWST pushing the limit for the detection of elusive species in protoplanetary disks.

astro-ph.GA↗
arXiv2025

Nickel- and iron-rich clumps in planetary nebulae: New discoveries and emission-line diagnostics

Integral field spectroscopy (IFS) offers a distinct advantage for studying extended sources by enabling spatially resolved emission maps for several emission lines without the need for specific filters. This study conducts a detailed analysis of iron and nickel emission lines in 12 planetary nebulae (PNe) using integral field unit (IFU) data from MUSE to provide insights into their formation and evolution mechanisms. New diagnostic line ratios, combined with machine-learning algorithms, were used to distinguish excitation mechanisms such as shock and photoionization. Electron densities and elemental abundances were estimated using different atomic data through the PyNeb package. The contribution of fluorescent excitation of nickel lines was also examined. A total of 16 iron- and nickel-rich clumps are detected in seven out of 12 PNe. New clumps are discovered in NGC 3132 and IC 4406. The most prominent lines are [Fe II] 8617 Angstrom and [Ni II] 7378 Angstrom. Both emission lines are observed emanating directly from the low-ionization structures (LIS) of NGC 3242, NGC 7009, and NGC 6153, as well as from clumps in NGC 6369 and Tc 1. Their abundances are found to be below solar values, indicating that a fraction of Fe and Ni remains depleted in dust grains. The depletion factors exhibit a strong correlation over a wide range. A machine-learning approach allows us to classify ten out of 16 clumps as shock-excited and to establish a new shock/photoionization selection criterion: log([Ni II] 7378 Angstrom / H-alpha) and log([Fe II] 8617 Angstrom / H-alpha) greater than -2.20.

astro-ph.SR↗
arXiv2025

The Nearby Evolved Stars Survey (NESS) V: properties of volume-limited samples of Galactic evolved stars

We provide a meta-study of the statistical and individual properties of two volume-complete sets of evolved stars in the Solar Neighbourhood: (1) 852 stars from the Nearby Evolved Stars Survey (NESS), and (2) a partially overlapping set of 507 evolved stars within 300 pc. We also investigate distance determinations to these stars, their luminosity functions and their spatial distribution. Gaia APSIS GSP-Phot AENEAS temperatures of bright giant stars often appear to be underestimated. Existing literature on AGB stars under-samples both the most and least extreme nearby dust-producing stars. We reproduce the literature star-formation history of the solar neighbourhood, though stellar-evolution models over-predict the number of AGB stars of ages around 500 Myr. The distribution of AGB stars broadly matches the known 300 pc scale height of the Galactic disc and shows concentration in the direction of the Galactic centre. Most dust-producing carbon stars belong to the Galactic thick-disc population.

astro-ph.SR↗
arXiv2025

The EDIBLES survey. X. The 6196 Å diffuse interstellar band: Identification of side DIBs as an indication of a small carrier molecule

Context: Numerous studies of diffuse interstellar band (DIB) profiles have detected substructures, which in turn suggests that large molecules are acting as their carriers. However, some of the narrowest DIBs generally do not show such substructures, suggesting the possibility of very small carriers. Aims: Based on the previously found tight correlation of the three narrow DIBs at 6196, 6440 and 6623 A and the present detection of weaker side DIBs to each of them in the extensive data set from the ESO Diffuse Interstellar Bands Large Exploration Survey, we investigated whether they may stem from small linear carrier molecules. This approach can lead to concrete DIB carrier suggestions, which can be tested in laboratory measurements in future studies. Methods: We suggest that the DIBs we studied here represent individual rotational transitions of a small molecule. We determined the molecular constants from observations and compared them with data from a large set of quantum-chemical calculations to constrain possible carrier candidates. Furthermore, we determined the rotational temperatures by fitting line ratios using the fitted molecular models. Results: We determined molecular constants for three DIB systems and the corresponding transition types. The fitted rotational temperatures lie within the range of known interstellar diatomic molecules. We identified several DIB carrier candidates, almost all of them molecular ions. Some of them are metastable species, indicating the possibility of collision complexes as DIB carriers. Conclusions: If our hypothesis holds, this would be a major step towards the identification of a carrier molecule of the 6196 A DIB, the strongest among the narrow DIBs.

astro-ph.GA↗
arXiv2025

PDRs4All. XII. FUV-driven formation of hydrocarbon radicals and their relation with PAHs

We present subarcsecond-resolution ALMA mosaics of the Orion Bar PDR in [CI] 609um, C2H (4-3), and C18O (3-2) emission lines complemented by JWST images of H2 and aromatic infrared band (AIB) emission. The rim of the Bar shows very corrugated structures made of small-scale H2 dissociation fronts (DFs). The [CI] 609 um emission peaks very close (~0.002 pc) to the main H2-emitting DFs, suggesting the presence of gas density gradients. These DFs are also bright and remarkably similar in C2H emission, which traces "hydrocarbon radical peaks" characterized by very high C2H abundances, reaching up to several x10^-7. The high abundance of C2H and of related hydrocarbon radicals, such as CH3, CH2, and CH, can be attributed to gas-phase reactions driven by elevated temperatures, the presence of C+ and C, and the reactivity of FUV-pumped H2. The hydrocarbon radical peaks roughly coincide with maxima of the 3.4/3.3 um AIB intensity ratio, a proxy for the aliphatic-to-aromatic content of PAHs. This implies that the conditions triggering the formation of simple hydrocarbons also favor the formation (and survival) of PAHs with aliphatic side groups, potentially via the contribution of bottom-up processes in which abundant hydrocarbon radicals react in situ with PAHs. Ahead of the DFs, in the atomic PDR zone (where [H]>>[H2]), the AIB emission is the brightest, but small PAHs and carbonaceous grains undergo photo-processing due to the stronger FUV field. Our detection of trace amounts of C2H in this zone may result from the photoerosion of these species. This study provides a spatially resolved view of the chemical stratification of key carbon carriers in a PDR. Overall, both bottom-up and top-down processes appear to link simple hydrocarbon molecules with PAHs in molecular clouds; however, the exact chemical pathways and their relative contributions remain to be quantified.

astro-ph.GA↗
arXiv2024

Temporal Changes in the Infrared Spectra of Magellanic Carbon Stars

The Medium-Resolution Spectrometer on the Mid-Infrared Instrument on JWST obtained spectra of three carbon stars in the Large Magellanic Cloud. Two of the spectra differ significantly from spectra obtained ~16-19 years earlier with the Infrared Spectrograph on the Spitzer Space Telescope. The one semi-regular variable among the three has changed little. The long-period Mira variable in the sample shows changes consistent with its pulsation cycle. The short-period Mira shows dramatic changes in the strength of its molecular absorption bands, with some bands growing weaker and some stronger. Whether these variations result from its pulsation cycle or its evolution is not clear.

astro-ph.SR↗
arXiv2024

The EDIBLES Survey. VIII. Band profile alignment of diffuse interstellar bands

Context: There have been many attempts to identify families of diffuse interstellar bands (DIBs) with perfectly correlating band strengths. Although major efforts have been made to classify broadly based DIB families and important insights have been gained, no family has been identified with sufficient accuracy or statistical significance to prove that a series of selected DIBs originates from the same carrier. This can be attributed in part to the exclusive use of equivalent widths to establish DIB families. Aims: In a change of strategy, we search for DIBs that are highly correlated in both band strength and profile shape. This approach increases the chance of correlating DIBs being members of one family and originating from the same carrier molecule. We also search for correlations between DIB profile families and atomic interstellar lines, with the goal of further chemically constraining possible DIB carriers. Methods: We adapted the well-known method of time-series alignment to perform a spectral alignment; that is, DIB alignment. In a second step, we analysed the alignment results using a clustering analysis. This method required a statistically significant data set of DIB sight lines. The ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) data were perfectly suited for this application. Results: We report eight DIB families with correlating strengths and profiles, as well as four previously unreported DIBs in the visual range, found using DIB alignment. All profile family members show Pearson correlation coefficients in band strength higher than 0.9. In particular, we report the 6614 - 6521 AA DIB pair, in which both DIBs show the same triple-peak substructure and an unprecedented band strength Pearson correlation coefficient of 0.9935. The presented approach opens up new perspectives that can guide the laboratory search for DIB carriers.

astro-ph.GA↗
arXiv2024

PDRs4All. V. Modelling the dust evolution across the illuminated edge of the Orion Bar

We study the emission of dust grains within the Orion Bar - a well-known, highly far-UV (FUV)-irradiated PDR. The Orion Bar because of its edge-on geometry provides an exceptional benchmark for characterizing dust evolution and the associated driving processes under varying physical conditions. Our goal is to constrain the local properties of dust by comparing its emission to models. Taking advantage of the recent JWST PDRs4All data, we follow the dust emission as traced by JWST NIRCam (at 3.35 and 4.8 micron) and MIRI (at 7.7, 11.3, 15.0, and 25.5 micron), along with NIRSpec and MRS spectroscopic observations. First, we constrain the minimum size and hydrogen content of carbon nano-grains from a comparison between the observed dust emission spectra and the predictions of the THEMIS dust model coupled to the numerical code DustEM. Using this dust model, we then perform 3D radiative transfer simulations of dust emission with the SOC code and compare to data obtained along well chosen profiles across the Orion Bar. The JWST data allows us, for the first time, to spatially resolve the steep variation of dust emission at the illuminated edge of the Orion Bar PDR. By considering a dust model with carbonaceous nano-grains and submicronic coated silicate grains, we derive unprecedented constraints on the properties of across the Orion Bar. To explain the observed emission profiles with our simulations, we find that the nano-grains must be strongly depleted with an abundance (relative to the gas) 15 times less than in the diffuse ISM. The NIRSpec and MRS spectroscopic observations reveal variations in the hydrogenation of the carbon nano-grains. The lowest hydrogenation levels are found in the vicinity of the illuminating stars suggesting photo-processing while more hydrogenated nano-grains are found in the cold and dense molecular region, potentially indicative of larger grains.

astro-ph.GA↗