arXiv subjects

J. Cami

Publications and source records attributed to J. Cami.

At least 19 recordsLinked to original sources

arXiv2026

Searching for the elusive CH2+ with the James Webb Space Telescope. Another carbocation to constrain astrochemical networks

Carbocations are key species in interstellar chemistry, providing entry points for building larger hydrocarbons. CH+, and more recently, CH3+, have been detected. Other carbocations await detection to provide a comprehensive view of the astrochemical network that is at work in the interstellar medium. We search for CH2+ in objects in which CH3+ was detected and evaluate the most favorable conditions for detecting the elusive CH2+ reactive cation. We calculated the CH2+ rotational and rovibrational transitions expected to contribute in the mid- to far-infrared, focusing on the lower-energy rovibrational levels. We then calculated CH2+ infrared emission spectra at different excitation temperatures and compared them to JWST spectra of the externally irradiated disk d203-506 in Orion, where CH+ and CH3+ have already been detected. We used thermochemical models to predict the abundance and spatial morphology of CH2+ to better understand its nondetection. The comparison to JWST spectra allowed us to provide excitation-temperature-dependent upper limits to the excited column density. These are several times lower than those detected for CH+ and CH3+ in their excited states. Based on model calculations for photodissociation regions and assuming similar excitation temperatures, the upper limit derived from observations and CH2+ model spectrum is either slightly above or below the column density expected from models of photodissociation regions. We provide a list of tabulated transitions to allow the community to search for this carbocation in future observations as CH2+ is key in providing observational constraints on astrochemical models.

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arXiv2026

MUSE Imaging Spectroscopy of the Fullerene Planetary Nebula Tc 1

The planetary nebula Tc 1 (PN G345.2 -08.8), one of the rare group of Galactic PNe showing fullerene emission in the infrared, was observed with MUSE wide field mode with adaptive optics, wavelength range 4750-9300A. Extinction, electron temperature (T_e) and density (N_e) images are presented from collisionally excited and recombination line ratios. The nebula has a high surface brightness 12 arcsec core, an elliptical ring of major axis 2.8 arcsec around the central star and some low ionization knots, and an extended halo 55 arcsec in size; between the core and halo is an annulus with intermediate properties, including higher T_e and lower N_e than in the core. The image of optical extinction from H Balmer line ratios is highly structured, and shows an annulus, adjacent to the core, of low extinction, lower than the line-of-sight interstellar extinction. Instrumental effects to account for this anomalously low extinction area are investigated and intrinsic effects from the scattering properties of nebular dust; neither can entirely explain the low-extinction region and the most likely cause is a local non-standard dust reddening law. This low extinction region also shows an anomalously high He I 7281/6678A line ratio, possibly caused by a contaminating line, but none were conclusively identified. The spectrum of the central star was extracted and fitted by a 31000K model atmosphere and is of type O7.5I(f). Over extended regions an enhancement of the detected continuum above the nebular continuum was found, as also seen in some other PNe observed with MUSE. The annulus of low extinction occurs outside the region of strongest fullerene emission, in the zone where N_e declines and T_e rises. A change in dust properties linked to conditions in this transition region between the higher density core nebula and lower density halo is deduced. (Abridged)

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arXiv2026

Mid-infrared JWST spectra of carbon stars in the Large Magellanic Cloud

Mid-infrared spectra from the Medium Resolution Spectrometer on the James Webb Space Telescope have revealed the molecular chemistry of carbon stars in the Large Magellanic Cloud with better resolution and sensitivity than previously possible. Our sample spans a range of dust-production rates and includes three relatively dust-free semiregular variables and six dustier Mira variables. All were observed 15-20 yr earlier with the Infrared Spectrograph on the Spitzer Space Telescope at lower spectral resolution. The new spectra show that the C3 molecule is responsible for a strong absorption band centered at 5.2 um. CS is clearly present in some of the sample, especially the stars with less dust. HCN also appears to be present. Some of the spectra have changed significantly between the Spitzer epoch and the MRS observations in 2023 and 2024, and in most cases these changes can be attributed to the stellar pulsation cycle. One exception is the disappearance of a dust emission feature at ~18 um in one of the Miras. The new spectra reveal a dip centered at ~10 um, which could arise either from an unknown carrier or from variable molecular emission to the red and blue. The presence of this spectral structure on the short-wavelength side of the SiC dust emission feature at ~11.3 um along with the broad C2H2 band centered at 14 um raise the possibility that some previously reported detections of weak SiC dust emission in other carbon stars may not be real.

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arXiv2026

JWST MIRI-MRS observations of the Red Rectangle: AIB class transformation in the outer nebula

Aims: We characterize the mid-infrared spectrum of the outer regions of the Red Rectangle nebula to probe the carbonaceous dust and molecular content beyond the circumbinary disk. Methods: We present JWST MIRI-MRS observations of the SW whisker, extracted from three distinct environments: the biconical outflow, the whisker itself, and the shadow region outside the outflow. We compare these with an archival ISO-SWS observation of the inner nebula. Results: The JWST spectra display only classical AIB emission on a weak dust continuum, with no signatures of the oxygen-rich circumbinary disk mineralogy nor of the rich molecular emission seen at optical wavelengths. The AIBs are predominantly Class A - in marked contrast to the exclusively Class B profiles previously reported for the inner regions - with systematic differences between the outflow and shadow regions pointing to environmentally driven PAH processing.

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arXiv2025

The Nearby Evolved Stars Survey III: First data release of JCMT CO-line observations

Low- to intermediate-mass ($\sim$0.8$-$8 M$_\odot$) evolved stars contribute significantly to the chemical enrichment of the interstellar medium in the local Universe, making accurate mass-return estimates in their final stages crucial. The Nearby Evolved Stars Survey (NESS) is a large multi-telescope project targeting a volume-limited sample of $\sim$850 stars within 3 kpc in order to derive the dust and gas return rates in the Solar Neighbourhood, and to constrain the physics underlying these processes. We present an initial analysis of the CO-line observations, including detection statistics, carbon isotopic ratios, initial mass-loss rates, and gas-to-dust ratios. We describe a new data reduction pipeline to analyse the available NESS CO data from the JCMT, measuring line parameters and calculating empirical gas mass-loss rates. We present the first release of the available data on 485 sources, one of the largest homogeneous samples of CO data to date. Comparison with a large literature sample finds that high mass-loss rate and especially carbon-rich sources are over-represented in literature, while NESS is probing significantly more sources at low mass-loss rates, detecting 59 sources in CO for the first time and providing useful upper limits. CO line detection rates are 81% for the CO (2--1) line and 75% for CO (3--2). The majority (82%) of detected lines conform to the expected soft parabola shape, while eleven sources show a double wind. Calculated mass-loss rates show power-law relations with both the dust-production rates and expansion velocities up to $\sim 5 \times 10^{-6}$~\msunyr. Median gas-to-dust ratios of 250 and 680 are found for oxygen-rich and carbon-rich sources, respectively. Our analysis of CO observations in this first data release highlights the importance of our volume-limited approach in characterizing the local AGB population as a whole.

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arXiv2025

Nickel- and iron-rich clumps in planetary nebulae: New discoveries and emission-line diagnostics

Integral field spectroscopy (IFS) offers a distinct advantage for studying extended sources by enabling spatially resolved emission maps for several emission lines without the need for specific filters. This study conducts a detailed analysis of iron and nickel emission lines in 12 planetary nebulae (PNe) using integral field unit (IFU) data from MUSE to provide insights into their formation and evolution mechanisms. New diagnostic line ratios, combined with machine-learning algorithms, were used to distinguish excitation mechanisms such as shock and photoionization. Electron densities and elemental abundances were estimated using different atomic data through the PyNeb package. The contribution of fluorescent excitation of nickel lines was also examined. A total of 16 iron- and nickel-rich clumps are detected in seven out of 12 PNe. New clumps are discovered in NGC 3132 and IC 4406. The most prominent lines are [Fe II] 8617 Angstrom and [Ni II] 7378 Angstrom. Both emission lines are observed emanating directly from the low-ionization structures (LIS) of NGC 3242, NGC 7009, and NGC 6153, as well as from clumps in NGC 6369 and Tc 1. Their abundances are found to be below solar values, indicating that a fraction of Fe and Ni remains depleted in dust grains. The depletion factors exhibit a strong correlation over a wide range. A machine-learning approach allows us to classify ten out of 16 clumps as shock-excited and to establish a new shock/photoionization selection criterion: log([Ni II] 7378 Angstrom / H-alpha) and log([Fe II] 8617 Angstrom / H-alpha) greater than -2.20.

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arXiv2025

The Nearby Evolved Stars Survey (NESS) V: properties of volume-limited samples of Galactic evolved stars

We provide a meta-study of the statistical and individual properties of two volume-complete sets of evolved stars in the Solar Neighbourhood: (1) 852 stars from the Nearby Evolved Stars Survey (NESS), and (2) a partially overlapping set of 507 evolved stars within 300 pc. We also investigate distance determinations to these stars, their luminosity functions and their spatial distribution. Gaia APSIS GSP-Phot AENEAS temperatures of bright giant stars often appear to be underestimated. Existing literature on AGB stars under-samples both the most and least extreme nearby dust-producing stars. We reproduce the literature star-formation history of the solar neighbourhood, though stellar-evolution models over-predict the number of AGB stars of ages around 500 Myr. The distribution of AGB stars broadly matches the known 300 pc scale height of the Galactic disc and shows concentration in the direction of the Galactic centre. Most dust-producing carbon stars belong to the Galactic thick-disc population.

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arXiv2025

PDRs4All XV: CH radical and H$_3^+$ molecular ion in the irradiated protoplanetary disk d203-506

Most protoplanetary disks experience a phase in which they are subjected to strong ultraviolet radiation from nearby massive stars. This UV radiation can substantially alter their chemistry by producing numerous radicals and molecular ions. In this Letter we present detailed analysis of the JWST-NIRSpec spectrum of the d203-506 obtained as part of the PDRs4All Early Release Science program. Using state-of-the-art spectroscopic data, we searched for species using a multi-molecule fitting tool, PAHTATmol, that we developed for this purpose. Based on this analysis, we report the clear detection of ro-vibrational emission of the CH radical and likely detection of the H$_3^+$ molecular ion, with estimated abundances of a few times 10$^{-7}$ and approximately 10$^{-8}$, respectively. The presence of CH is predicted by gas-phase models and well explained by hydrocarbon photochemistry. H$_3^+$ is usually formed through reactions of H$_2$ with H$_2^+$ originating from cosmic ray ionization of H$_2$. However, recent theoretical studies suggest that H$_3^+$ also forms through UV-driven chemistry in strongly irradiated ($G_0>$10$^3$), dense ($n_{\rm H} >10^{6}$ cm$^{-3}$) gas. The latter is favored as an explanation for the presence of ``hot'' H$_3^+$ ($T_{\rm ex}\gtrsim$1000 K) in the outer disk layers of d203-506, coinciding with the emission of FUV-pumped H$_2$ and other ``PDR species'', such as CH$^+$, CH$_3^+$, and OH. Our detection of infrared emission from vibrationally excited H$_3^+$ and CH raises questions about their excitation mechanisms and, underscore that UV radiation can have a profound impact on the chemistry of planet forming disks. They also demonstrate the power of JWST pushing the limit for the detection of elusive species in protoplanetary disks.

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arXiv2025

PDRs4All. XII. FUV-driven formation of hydrocarbon radicals and their relation with PAHs

We present subarcsecond-resolution ALMA mosaics of the Orion Bar PDR in [CI] 609um, C2H (4-3), and C18O (3-2) emission lines complemented by JWST images of H2 and aromatic infrared band (AIB) emission. The rim of the Bar shows very corrugated structures made of small-scale H2 dissociation fronts (DFs). The [CI] 609 um emission peaks very close (~0.002 pc) to the main H2-emitting DFs, suggesting the presence of gas density gradients. These DFs are also bright and remarkably similar in C2H emission, which traces "hydrocarbon radical peaks" characterized by very high C2H abundances, reaching up to several x10^-7. The high abundance of C2H and of related hydrocarbon radicals, such as CH3, CH2, and CH, can be attributed to gas-phase reactions driven by elevated temperatures, the presence of C+ and C, and the reactivity of FUV-pumped H2. The hydrocarbon radical peaks roughly coincide with maxima of the 3.4/3.3 um AIB intensity ratio, a proxy for the aliphatic-to-aromatic content of PAHs. This implies that the conditions triggering the formation of simple hydrocarbons also favor the formation (and survival) of PAHs with aliphatic side groups, potentially via the contribution of bottom-up processes in which abundant hydrocarbon radicals react in situ with PAHs. Ahead of the DFs, in the atomic PDR zone (where [H]>>[H2]), the AIB emission is the brightest, but small PAHs and carbonaceous grains undergo photo-processing due to the stronger FUV field. Our detection of trace amounts of C2H in this zone may result from the photoerosion of these species. This study provides a spatially resolved view of the chemical stratification of key carbon carriers in a PDR. Overall, both bottom-up and top-down processes appear to link simple hydrocarbon molecules with PAHs in molecular clouds; however, the exact chemical pathways and their relative contributions remain to be quantified.

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arXiv2025

The EDIBLES survey. X. The 6196 {\AA} diffuse interstellar band: Identification of side DIBs as an indication of a small carrier molecule

Context: Numerous studies of diffuse interstellar band (DIB) profiles have detected substructures, which in turn suggests that large molecules are acting as their carriers. However, some of the narrowest DIBs generally do not show such substructures, suggesting the possibility of very small carriers. Aims: Based on the previously found tight correlation of the three narrow DIBs at 6196, 6440 and 6623 A and the present detection of weaker side DIBs to each of them in the extensive data set from the ESO Diffuse Interstellar Bands Large Exploration Survey, we investigated whether they may stem from small linear carrier molecules. This approach can lead to concrete DIB carrier suggestions, which can be tested in laboratory measurements in future studies. Methods: We suggest that the DIBs we studied here represent individual rotational transitions of a small molecule. We determined the molecular constants from observations and compared them with data from a large set of quantum-chemical calculations to constrain possible carrier candidates. Furthermore, we determined the rotational temperatures by fitting line ratios using the fitted molecular models. Results: We determined molecular constants for three DIB systems and the corresponding transition types. The fitted rotational temperatures lie within the range of known interstellar diatomic molecules. We identified several DIB carrier candidates, almost all of them molecular ions. Some of them are metastable species, indicating the possibility of collision complexes as DIB carriers. Conclusions: If our hypothesis holds, this would be a major step towards the identification of a carrier molecule of the 6196 A DIB, the strongest among the narrow DIBs.

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arXiv2024

Temporal Changes in the Infrared Spectra of Magellanic Carbon Stars

The Medium-Resolution Spectrometer on the Mid-Infrared Instrument on JWST obtained spectra of three carbon stars in the Large Magellanic Cloud. Two of the spectra differ significantly from spectra obtained ~16-19 years earlier with the Infrared Spectrograph on the Spitzer Space Telescope. The one semi-regular variable among the three has changed little. The long-period Mira variable in the sample shows changes consistent with its pulsation cycle. The short-period Mira shows dramatic changes in the strength of its molecular absorption bands, with some bands growing weaker and some stronger. Whether these variations result from its pulsation cycle or its evolution is not clear.

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arXiv2024

The EDIBLES Survey. VIII. Band profile alignment of diffuse interstellar bands

Context: There have been many attempts to identify families of diffuse interstellar bands (DIBs) with perfectly correlating band strengths. Although major efforts have been made to classify broadly based DIB families and important insights have been gained, no family has been identified with sufficient accuracy or statistical significance to prove that a series of selected DIBs originates from the same carrier. This can be attributed in part to the exclusive use of equivalent widths to establish DIB families. Aims: In a change of strategy, we search for DIBs that are highly correlated in both band strength and profile shape. This approach increases the chance of correlating DIBs being members of one family and originating from the same carrier molecule. We also search for correlations between DIB profile families and atomic interstellar lines, with the goal of further chemically constraining possible DIB carriers. Methods: We adapted the well-known method of time-series alignment to perform a spectral alignment; that is, DIB alignment. In a second step, we analysed the alignment results using a clustering analysis. This method required a statistically significant data set of DIB sight lines. The ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) data were perfectly suited for this application. Results: We report eight DIB families with correlating strengths and profiles, as well as four previously unreported DIBs in the visual range, found using DIB alignment. All profile family members show Pearson correlation coefficients in band strength higher than 0.9. In particular, we report the 6614 - 6521 AA DIB pair, in which both DIBs show the same triple-peak substructure and an unprecedented band strength Pearson correlation coefficient of 0.9935. The presented approach opens up new perspectives that can guide the laboratory search for DIB carriers.

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arXiv2024

PDRs4All. V. Modelling the dust evolution across the illuminated edge of the Orion Bar

We study the emission of dust grains within the Orion Bar - a well-known, highly far-UV (FUV)-irradiated PDR. The Orion Bar because of its edge-on geometry provides an exceptional benchmark for characterizing dust evolution and the associated driving processes under varying physical conditions. Our goal is to constrain the local properties of dust by comparing its emission to models. Taking advantage of the recent JWST PDRs4All data, we follow the dust emission as traced by JWST NIRCam (at 3.35 and 4.8 micron) and MIRI (at 7.7, 11.3, 15.0, and 25.5 micron), along with NIRSpec and MRS spectroscopic observations. First, we constrain the minimum size and hydrogen content of carbon nano-grains from a comparison between the observed dust emission spectra and the predictions of the THEMIS dust model coupled to the numerical code DustEM. Using this dust model, we then perform 3D radiative transfer simulations of dust emission with the SOC code and compare to data obtained along well chosen profiles across the Orion Bar. The JWST data allows us, for the first time, to spatially resolve the steep variation of dust emission at the illuminated edge of the Orion Bar PDR. By considering a dust model with carbonaceous nano-grains and submicronic coated silicate grains, we derive unprecedented constraints on the properties of across the Orion Bar. To explain the observed emission profiles with our simulations, we find that the nano-grains must be strongly depleted with an abundance (relative to the gas) 15 times less than in the diffuse ISM. The NIRSpec and MRS spectroscopic observations reveal variations in the hydrogenation of the carbon nano-grains. The lowest hydrogenation levels are found in the vicinity of the illuminating stars suggesting photo-processing while more hydrogenated nano-grains are found in the cold and dense molecular region, potentially indicative of larger grains.

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arXiv2023

PDRs4All VI: Probing the Photochemical Evolution of PAHs in the Orion Bar Using Machine Learning Techniques

[Abridged] JWST observations of the Orion Bar have shown the incredible richness of PAH bands and their variation on small scales. We aim to probe the photochemical evolution of PAHs across the key zones of the photodissociation region (PDR) that is the Orion Bar using unsupervised machine learning. We use NIRSpec and MIRI IFU data from the JWST ERS Program PDRs4All. We lever bisecting k-means clustering to generate detailed spatial maps of the spectral variability in several wavelength regions. We discuss the variations in the cluster profiles and connect them to the local physical conditions. We interpret these variations with respect to the key zones: the HII region, the atomic PDR zone, and the three dissociation fronts. The PAH emission exhibits spectral variation that depends strongly on spatial position in the PDR. We find the 8.6um band to behave differently than all other bands which vary systematically with one another. We find uniform variation in the 3.4-3.6um bands and 3.4/3.3 intensity ratio. We attribute the carrier of the 3.4-3.6um bands to a single side group attached to very similarly sized PAHs. Cluster profiles reveal a transition between characteristic profiles classes of the 11.2um feature from the atomic to the molecular PDR zone. We find the carriers of each of the profile classes to be independent, and reason the latter to be PAH clusters existing solely deep in the molecular PDR. Clustering also reveals a connection between the 11.2 and 6.2um bands; and that clusters generated from variation in the 10.9-11.63um region can be used to recover those in the 5.95-6.6um region. Clustering is a powerful tool for characterizing PAH variability on both spatial and spectral scales. For individual bands as well as global spectral behaviours, we find UV-processing to be the most important driver of the evolution of PAHs and their spectral signatures in the Orion Bar.

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arXiv2022

A high resolution study of near-IR diffuse interstellar bands, search for small scale structure, time variability and stellar features

Diffuse interstellar bands comprise hundreds of absorption features in the ISM. Most DIBs are observed in the optical, but some are in the IR. We observed 76 early-type stars at R=50,000 and S/N ratios of several hundreds using CRIRES. We measure DIBs around 1318, 1527, 1561, 1565, 1567, 1574 and/or 1624 nm. We detect a total of 6 DIB features and 17 likely stellar features assisted by a CMFGEN model. We also measured the DIBs at 1318 and 1527 nm using X-shooter towards ten Ceph. variables with 3.2 < E(B-V) < 6.5 and 4 stars at low values of water vapour. Correlation coeffs. of 0.73-0.96 are found comparing NIRDIB eq. width vs. E(B-V) and with r > 0.8 when comparing the NIR and optical DIBs 5705, 5780, 6203, 6283 and 6269 A. The 5797 A DIB is less well correlated with the NIDIBs. The "C60+" DIB at 9632 A is not well correlated with the 1318 nm DIB. Partial correlation coefficients using E(B-V) as the covariate were also determined. For stars earlier than B2, the 1318 nm DIB is affected by an emission line on its blue wing, likely stellar in nature, although we cannot rule out interstellar/circumstellar origin for example caused by by a DIB in emission. The 1318 nm DIB has a red wing and is reasonably well fitted by two gaussians. Neither the component ratios nor separation are correlated with 5780/5797 or E(B-V). EW(1318 nm) correlates with HI with EW(1318 nm)/E(B-V) decreasing with f(H2). Five pairs of stars within 1 am show similar 1318 nm DIB profiles. Variation in 1318 nm is seen in HD 145501/145502 and HD 168607/168625 pairs. CRIRES data for 17 stars separated by 6-14 months and 2 X-shooter sightlines separated by 9.9 yr were analysed. No time-variability is detected in the 5780, 5797 A, 1318 nm or 1527 nm DIBs. Tentative time variation is observed in the C60+ DIBs at 9577 and 9632 A towards HD 183143 although very close to the noise level with confirmation required.

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arXiv2021

The Nearby Evolved Stars Survey II: Constructing a volume-limited sample and first results from the James Clerk Maxwell Telescope

The Nearby Evolved Stars Survey (NESS) is a volume-complete sample of $\sim$850 Galactic evolved stars within 3\,kpc at (sub-)mm wavelengths, observed in the CO $J = $ (2$-$1) and (3$-$2) rotational lines, and the sub-mm continuum, using the James Clark Maxwell Telescope and Atacama Pathfinder Experiment. NESS consists of five tiers, based on distances and dust-production rate (DPR). We define a new metric for estimating the distances to evolved stars and compare its results to \emph{Gaia} EDR3. Replicating other studies, the most-evolved, highly enshrouded objects in the Galactic Plane dominate the dust returned by our sources, and we initially estimate a total DPR of $4.7\times 10^{-5}$ M$_\odot$ yr$^{-1}$ from our sample. Our sub-mm fluxes are systematically higher and spectral indices are typically shallower than dust models typically predict. The 450/850 $\mu$m spectral indices are consistent with the blackbody Rayleigh--Jeans regime, suggesting a large fraction of evolved stars have unexpectedly large envelopes of cold dust.

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arXiv2019

Confirming interstellar C$_{60}^+$ using the Hubble Space Telescope

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60+) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60+ requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C60+ 9348, 9365, 9428 and 9577 {\AA} absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C60+ bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 {\AA} and (strong) 9577 {\AA} C60+ bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 {\AA} band, and a conclusive confirmation of interstellar C60+.

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arXiv2018

A remarkable change of the spectrum of the magnetic Of?p star HD 148937 reveals evidence of an eccentric, high-mass binary

We report new spectroscopic observations of the magnetic Of?p star HD 148937 obtained since 2015 that differ qualitatively from its extensive historical record of weak, periodic spectral variations. This remarkable behaviour represents clear evidence for an unprecedented change in the character of variability of the star. In this paper we describe the new spectral properties and compare them to the previous line profiles. Based on measurements of the radial velocities of the C iii/N iii} emission lines near 4640 \AA\ and the C iv absorption lines near 5800 \AA, we infer that HD 148937 is likely a high-mass, double-lined spectroscopic binary. Combining the spectroscopic orbit with an archival interferometric measurement of the apparent separation of the equal-brightness components, we tentatively conclude that HD 148937 consists of two O-type stars with masses of approximately 34 and $49~M_\odot$, orbiting in an eccentric ($e=0.75$), long-period ($P_{\rm orb}\sim 26$ y) orbit. We discuss the potential relationship of the binary system to the peculiar properties of HD 148937, and propose future observations to refine the orbital and stellar properties.

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