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J. Cami

Publications and source records attributed to J. Cami.

At least 37 records · Page 2Linked to original sources

A high resolution study of near-IR diffuse interstellar bands, search for small scale structure, time variability and stellar features

Diffuse interstellar bands comprise hundreds of absorption features in the ISM. Most DIBs are observed in the optical, but some are in the IR. We observed 76 early-type stars at R=50,000 and S/N ratios of several hundreds using CRIRES. We measure DIBs around 1318, 1527, 1561, 1565, 1567, 1574 and/or 1624 nm. We detect a total of 6 DIB features and 17 likely stellar features assisted by a CMFGEN model. We also measured the DIBs at 1318 and 1527 nm using X-shooter towards ten Ceph. variables with 3.2 < E(B-V) < 6.5 and 4 stars at low values of water vapour. Correlation coeffs. of 0.73-0.96 are found comparing NIRDIB eq. width vs. E(B-V) and with r > 0.8 when comparing the NIR and optical DIBs 5705, 5780, 6203, 6283 and 6269 A. The 5797 A DIB is less well correlated with the NIDIBs. The "C60+" DIB at 9632 A is not well correlated with the 1318 nm DIB. Partial correlation coefficients using E(B-V) as the covariate were also determined. For stars earlier than B2, the 1318 nm DIB is affected by an emission line on its blue wing, likely stellar in nature, although we cannot rule out interstellar/circumstellar origin for example caused by by a DIB in emission. The 1318 nm DIB has a red wing and is reasonably well fitted by two gaussians. Neither the component ratios nor separation are correlated with 5780/5797 or E(B-V). EW(1318 nm) correlates with HI with EW(1318 nm)/E(B-V) decreasing with f(H2). Five pairs of stars within 1 am show similar 1318 nm DIB profiles. Variation in 1318 nm is seen in HD 145501/145502 and HD 168607/168625 pairs. CRIRES data for 17 stars separated by 6-14 months and 2 X-shooter sightlines separated by 9.9 yr were analysed. No time-variability is detected in the 5780, 5797 A, 1318 nm or 1527 nm DIBs. Tentative time variation is observed in the C60+ DIBs at 9577 and 9632 A towards HD 183143 although very close to the noise level with confirmation required.

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The Nearby Evolved Stars Survey II: Constructing a volume-limited sample and first results from the James Clerk Maxwell Telescope

The Nearby Evolved Stars Survey (NESS) is a volume-complete sample of $\sim$850 Galactic evolved stars within 3\,kpc at (sub-)mm wavelengths, observed in the CO $J = $ (2$-$1) and (3$-$2) rotational lines, and the sub-mm continuum, using the James Clark Maxwell Telescope and Atacama Pathfinder Experiment. NESS consists of five tiers, based on distances and dust-production rate (DPR). We define a new metric for estimating the distances to evolved stars and compare its results to \emph{Gaia} EDR3. Replicating other studies, the most-evolved, highly enshrouded objects in the Galactic Plane dominate the dust returned by our sources, and we initially estimate a total DPR of $4.7\times 10^{-5}$ M$_\odot$ yr$^{-1}$ from our sample. Our sub-mm fluxes are systematically higher and spectral indices are typically shallower than dust models typically predict. The 450/850 $μ$m spectral indices are consistent with the blackbody Rayleigh--Jeans regime, suggesting a large fraction of evolved stars have unexpectedly large envelopes of cold dust.

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Confirming interstellar C$_{60}^+$ using the Hubble Space Telescope

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60+) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60+ requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C60+ 9348, 9365, 9428 and 9577 Å absorption bands toward seven heavily-reddened stars. We focus in particular on searching for the weaker laboratory C60+ bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 Å and (strong) 9577 Å C60+ bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 Å band, and a conclusive confirmation of interstellar C60+.

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A remarkable change of the spectrum of the magnetic Of?p star HD 148937 reveals evidence of an eccentric, high-mass binary

We report new spectroscopic observations of the magnetic Of?p star HD 148937 obtained since 2015 that differ qualitatively from its extensive historical record of weak, periodic spectral variations. This remarkable behaviour represents clear evidence for an unprecedented change in the character of variability of the star. In this paper we describe the new spectral properties and compare them to the previous line profiles. Based on measurements of the radial velocities of the C iii/N iii} emission lines near 4640 Å and the C iv absorption lines near 5800 Å, we infer that HD 148937 is likely a high-mass, double-lined spectroscopic binary. Combining the spectroscopic orbit with an archival interferometric measurement of the apparent separation of the equal-brightness components, we tentatively conclude that HD 148937 consists of two O-type stars with masses of approximately 34 and $49~M_\odot$, orbiting in an eccentric ($e=0.75$), long-period ($P_{\rm orb}\sim 26$ y) orbit. We discuss the potential relationship of the binary system to the peculiar properties of HD 148937, and propose future observations to refine the orbital and stellar properties.

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The EDIBLES survey III. C2-DIBs and their profiles

The so-called C2-DIBs are a class of very weak bands that fall in the blue part of the optical spectrum and are associated with high column densities of the C2 molecule. DIB profile structures constrain potential molecular carriers, but their measurement requires high S/N and spectra and the use of sightlines without Doppler splitting, as typical for a single-cloud situation. Spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) conducted at the VLT (ESO/Paranal) were explored to identify single-cloud and high C2 column sightlines, extract the corresponding C2-DIBs and study their strengths and profiles, and to investigate in detail any sub-structures. The target selection was made based on profile-fitting of the Sodium doublets and the detection of C2 lines. The C2 (2-0) Phillips system was fitted using a physical model of the host cloud. C2 column densities, temperatures as well as gas densities were derived for each sightline. 18 known C2-DIBs and 8 strong non-C2 DIBs were extracted towards 8 targets, comprising 7 single-cloud and one multi-cloud line-of-sights. Correlational studies revealed a tight association of the former group with the C2 columns, whereas the non-C2 DIBs are primarily correlated with reddening. We report three new weak diffuse band candidates. We show for the first time that at least 14 C2-DIBs exhibit spectral sub-structures which are consistent with unresolved rotational branches of molecular carriers. The variability of their peak separations among the bands for a given sightline implies that their carriers are different molecules with quite different sizes. We also illustrate how profiles of the same DIB vary among targets and as a function of physical parameters and provide tables defining the sub-structures to be compared with future models and experimental results.

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EDIBLES II. On the detectability of C60+ bands

Gas phase spectroscopic laboratory experiments for the buckminsterfullerene cation C60+ resulted in accurate rest wavelengths for five C60+ transitions that have been compared with diffuse interstellar bands (DIBs) in the near infra-red. Detecting these in astronomical spectra is difficult due to the strong contamination of ground-based spectra by atmospheric water vapor, to the presence of weak and shallow stellar lines and/or blending with other weak DIBs. The detection of the two strong bands has been claimed by several teams, and the three additional and weaker bands have been detected in a few sources. Certain recent papers have argued against the identification of C60+ based on spectral analyses claiming (i) a large variation in the ratio between the equivalent widths of the 9632 and 9577Å\: bands, (ii) a large redshift of the 9632Å\: band for the Orion star HD 37022, and (iii) the non-detection of the weaker 9428Å~DIB. Here we address these three points. (i) We show that the model stellar line correction for the 9632Å~DIB overestimates the difference between the strengths of the lines in giant and dwarf star spectra, casting doubts on the conclusions about the ratio variability. (ii) Using high quality stellar spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES), recorded with the ESO/Paranal Ultraviolet Echelle Spectrograph (UVES) in about the same atmospheric conditions, we find no wavelength shift in the 9632Å band towards HD 37022. (iii) Using EDIBLES spectra and data from the Echelle SpectroPolarimetric Device for the Observation of Stars (ESPaDOnS) at CFHT we show that the presence of a weak 9428Å band cannot be ruled out, even in the same observations that a previous study claimed it was not present.

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Large Interstellar Polarisation Survey II. UV/optical study of cloud-to-cloud variations of dust in the diffuse ISM

It is well known that the dust properties of the diffuse interstellar medium exhibit variations towards different sight-lines on a large scale. We have investigated the variability of the dust characteristics on a small scale, and from cloud-to-cloud. We use low-resolution spectro-polarimetric data obtained in the context of the Large Interstellar Polarisation Survey (LIPS) towards 59 sight-lines in the Southern Hemisphere, and we fit these data using a dust model composed of silicate and carbon particles with sizes from the molecular to the sub-micrometre domain. Large (> 6 nm) silicates of prolate shape account for the observed polarisation. For 32 sight-lines we complement our data set with UVES archive high-resolution spectra, which enable us to establish the presence of single-cloud or multiple-clouds towards individual sight-lines. We find that the majority of these 35 sight-lines intersect two or more clouds, while eight of them are dominated by a single absorbing cloud. We confirm several correlations between extinction and parameters of the Serkowski law with dust parameters, but we also find previously undetected correlations between these parameters that are valid only in single-cloud sight-lines. We find that interstellar polarisation from multiple-clouds is smaller than from single-cloud sight-lines, showing that the presence of a second or more clouds depolarises the incoming radiation. We find large variations of the dust characteristics from cloud-to-cloud. However, when we average a sufficiently large number of clouds in single-cloud or multiple-cloud sight-lines, we always retrieve similar mean dust parameters. The typical dust abundances of the single-cloud cases are [C]/[H] = 92 ppm and [Si]/[H] = 20 ppm.

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Large Interstellar Polarisation Survey. LIPS I: FORS2 spectropolarimetry in the Southern Hemisphere

Polarimetric studies of light transmitted through interstellar clouds may give constraints on the properties of the interstellar dust grains. Traditionally, broadband linear polarisation (BBLP) measurements have been considered an important diagnostic tool for the study of the interstellar dust, while comparatively less attention has been paid to spectropolarimetric measurements. However, spectropolarimetry may offer stronger constraints than BBLP, for example by revealing narrowband features, and by allowing us to distinguish the contribution of dust from the contribution of interstellar gas. Therefore, we have decided to carry out a Large Interstellar Polarisation Survey (LIPS) using spectropolarimetric facilities in both hemispheres. Here we present the results obtained in the Southern Hemisphere with the FORS2 instrument of the ESO Very Large Telescope. Our spectra cover the wavelength range 380--950\,nm at a spectral resolving power of about 880. We have produced a publicly available catalogue of 127 linear polarisation spectra of 101 targets. We also provide the Serkowski-curve parameters, as well as the wavelength gradient of the polarisation position angle for the interstellar polarisation along 76 different lines of sight. In agreement with previous literature, we found that the best-fit parameters of the Serkowski-curve are not independent of each other. However, the relationships that we obtained are not always consistent with what was found in previous studies.

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Searching for interstellar C60+ using a new method for high signal-to-noise HST/STIS spectroscopy

Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): C60+ (ionized Buckminsterfullerene). Confirming the presence of this molecule would have significant implications regarding the carbon budget and chemical complexity of the ISM. Here we present results from a new method for ultra-high signal-to-noise (S/N) spectroscopy of background stars in the near infrared (at wavelengths 0.9-1 micron), using the Hubble Space Telescope Imaging Spectrograph (STIS) in a previously untested `STIS scan' mode. The use of HST provides the crucial benefit of eliminating the need for error-prone telluric correction methods in the part of the spectrum where the C60+ bands lie, and terrestrial water vapor contamination is severe. Our STIS spectrum of the heavily-reddened B0 star BD63\,1964 reaches an unprecedented S/N for this instrument ($\sim600-800$), allowing the detection of the diffuse interstellar band (DIB) at 9577 Å attributed to C60+ as well as new DIBs in the near-IR. Unfortunately, the presence of overlapping stellar lines, and the unexpected weakness of the C60+ bands in this sightline, prevents conclusive detection of the weaker C60+ bands. A probable correlation between the 9577 Å DIB strength and interstellar radiation field is identified, which suggests that more strongly-irradiated interstellar sightlines will provide the optimal targets for future C60+ searches.

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XSHOOTER spectroscopy of the enigmatic planetary nebula Lin49 in the Small Magellanic Cloud

We performed a detailed spectroscopic analysis of the fullerene C60-containing planetary nebula (PN) Lin49 in the Small Magellanic Cloud using XSHOOTER at the ESO VLT and the Spitzer/IRS instruments. We derived nebular abundances for nine elements. We used TLUSTY to derive photospheric parameters for the central star. Lin49 is C-rich and metal-deficient PN (Z~0.0006). The nebular abundances are in good agreement with Asymptotic Giant Branch nucleosynthesis models for stars with initial mass 1.25 Msun and metallicity Z = 0.001. Using the TLUSTY synthetic spectrum of the central star to define the heating and ionising source, we constructed the photoionisation model with CLOUDY that matches the observed spectral energy distribution (SED) and the line fluxes in the UV to far-IR wavelength ranges simultaneously. We could not fit the ~1-5 um SED using a model with 0.005-0.1 um-sized graphite grains and a constant hydrogen density shell owing to the prominent near-IR excess, while at other wavelengths the model fits the observed values reasonably well. We argue that the near-IR excess might indicate either (1) the presence of very small particles in the form of small carbon clusters, small graphite sheets, or fullerene precursors, or (2) the presence of a high-density structure surrounding the central star. We found that SMC C60 PNe show a near-IR excess component to lesser or greater degree. This suggests that these C60 PNe might maintain a structure nearby their central star.

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Herschel PACS and SPIRE spectroscopy of the Photodissociation Regions associated with S 106 and IRAS 23133+6050

Photodissociation regions (PDRs) contain a large fraction of all of the interstellar matter in galaxies. Classical examples include the boundaries between ionized regions and molecular clouds in regions of massive star formation, marking the point where all of the photons energetic enough to ionize hydrogen have been absorbed. In this paper we determine the physical properties of the PDRs associated with the star forming regions IRAS 23133+6050 and S 106 and present them in the context of other Galactic PDRs associated with massive star forming regions. We employ Herschel PACS and SPIRE spectroscopic observations to construct a full 55-650 μm spectrum of each object from which we measure the PDR cooling lines, other fine- structure lines, CO lines and the total far-infrared flux. These measurements are then compared to standard PDR models. Subsequently detailed numerical PDR models are compared to these predictions, yielding additional insights into the dominant thermal processes in the PDRs and their structures. We find that the PDRs of each object are very similar, and can be characterized by a two-phase PDR model with a very dense, highly UV irradiated phase (n $\sim$ 10^6 cm^(-3), G$_0$ $\sim$ 10^5) interspersed within a lower density, weaker radiation field phase (n $\sim$ 10^4 cm^(-3), G$_0$ $\sim$ 10^4). We employed two different numerical models to investigate the data, firstly we used RADEX models to fit the peak of the $^{12}$CO ladder, which in conjunction with the properties derived yielded a temperature of around 300 K. Subsequent numerical modeling with a full PDR model revealed that the dense phase has a filling factor of around 0.6 in both objects. The shape of the $^{12}$CO ladder was consistent with these components with heating dominated by grain photoelectric heating. An extra excitation component for the highest J lines (J > 20) is required for S 106.

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Characterizing the infrared spectra of small, neutral, fully dehydrogenated PAHs

We present the results of a computational study to investigate the infrared spectroscopic properties of a large number of polycyclic aromatic hydrocarbon (PAH) molecules and their fully dehydrogenated counterparts. We constructed a database of fully optimized geometries for PAHs that is complete for eight or fewer fused benzene rings, thus containing 1550 PAHs and 805 fully dehydrogenated aromatics. A large fraction of the species in our database have clearly non-planar or curved geometries. For each species, we determined the frequencies and intensities of their normal modes using density functional theory calculations. Whereas most PAH spectra are fairly similar, the spectra of fully dehydrogenated aromatics are much more diverse. Nevertheless, these fully dehydrogenated species show characteristic emission features at 5.2$μ$m, 5.5$μ$m and 10.6$μ$m; at longer wavelengths, there is a forest of emission features in the 16--30$μ$m range that appears as a structured continuum, but with a clear peak centered around 19$μ$m. We searched for these features in Spitzer-IRS spectra of various positions in the reflection nebula NGC 7023. We find a weak emission feature at 10.68$μ$m in all positions except that closest to the central star. We also find evidence for a weak 19$μ$m feature at all positions that is not likely due to C$_{60}$. We interpret these features as tentative evidence for the presence of a small population of fully dehydrogenated PAHs, and discuss our results in the framework of PAH photolysis and the formation of fullerenes.

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VLT/X-shooter survey of near-infrared diffuse interstellar bands

This paper presents a spectral survey of diffuse interstellar bands (DIBs) in the NIR range, from 0.9 to 2.5 micron. The observations were designed to detect new DIBs, confirm previously proposed NIR DIBs, and characterise their behaviour with respect to known line-of-sight properties (including the optical DIBs present in our spectra). X-shooter at the VLT was used to obtained medium-resolution spectra of eight known DIB targets and one telluric reference star. In addition to the known 9577, 9632, 10780, 11797, and 13175 Angstroms NIR DIBs, we confirm 9 out of the 13 NIR DIBs that were presented by Geballe and co-workers in 2011. Furthermore, we report 12 new NIR DIB candidates. The strengths of the strongest NIR DIBs show a general correlation with reddening, E(B-V), but with a large scatter. Several NIR DIBs are more strongly correlated with the 5780 Angstroms DIB strength than with E(B-V); this is especially the case for the 15268 Angstroms DIB. The NIR DIBs are strong: the summed equivalent widths of the five strongest NIR DIBs represent a few percent of the total equivalent width of the entire average DIB spectrum (per unit reddening). The NIR DIBs towards the translucent cloud HD 147889 are all weak with respect to the general trend. No direct match was found between observed NIR DIBs and laboratory matrix-isolation spectroscopic data of PAHs. The strong correlation between the 5780-15268 DIB pair implies that (Nf)_5780 / (Nf)_15268 = 14. However, the reduced strength of the 15268 Angstroms DIB in HD 147889 rules out a common carrier for these two DIBs. Since the ionisation fraction for small PAHs in this translucent cloud is known to be low compared to diffuse clouds, the weakness of the 15268 Angstrom DIB suggests that an ionised species could be the carrier of this NIR DIB. (abridged).

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Interstellar and circumstellar fullerenes

Fullerenes are a particularly stable class of carbon molecules in the shape of a hollow sphere or ellipsoid that might be formed in the outflows of carbon stars. Once injected into the interstellar medium (ISM), these stable species survive and are thus likely to be widespread in the Galaxy where they contribute to interstellar extinction, heating processes, and complex chemical reactions. In recent years, the fullerene species C60 (and to a lesser extent C70) have been detected in a wide variety of circumstellar and interstellar environments showing that when conditions are favourable, fullerenes are formed efficiently. Fullerenes are the first and only large aromatics firmly identified in space. The detection of fullerenes is thus crucial to provide clues as to the key chemical pathways leading to the formation of large complex organic molecules in space, and offers a great diagnostic tool to describe the environment in which they reside. Since fullerenes share many physical properties with PAHs, understanding how fullerenes form, evolve and respond to their physical environment will yield important insights into one of the largest reservoirs of organic material in space. In spite of all these detections, many questions remain about precisely which members of the fullerene family are present in space, how they form and evolve, and what their excitation mechanism is. We present here an overview of what we know from astronomical observations of fullerenes in these different environments, and discuss current thinking about the excitation process. We highlight the various formation mechanisms that have been proposed, discuss the physical conditions conducive to the formation and/or detection of fullerenes in carbon stars, and their possible connection to PAHs, HACs and other dust features.

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Carbon-rich dust past the asymptotic giant branch: aliphatics, aromatics, and fullerenes in the Magellanic Clouds

Infrared spectra of carbon-rich objects which have evolved off the asymptotic giant branch reveal a range of dust properties, including fullerenes, polycyclic aromatic hydrocarbons (PAHs), aliphatic hydrocarbons, and several unidentified features, including the 21 um emission feature. To test for the presence of fullerenes, we used the position and width of the feature at 18.7-18.9 um and examined other features at 17.4 and 6-9 um. This method adds three new fullerene sources to the known sample, but it also calls into question three previous identifications. We confirm that the strong 11 um features seen in some sources arise primarily from SiC, which may exist as a coating around carbonaceous cores and result from photo-processing. Spectra showing the 21 um feature usually show the newly defined Class D PAH profile at 7-9 um. These spectra exhibit unusual PAH profiles at 11-14 um, with weak contributions at 12.7 um, which we define as Class D1, or show features shifted to ~11.4, 12.4, and 13.2 um, which we define as Class D2. Alkyne hydrocarbons match the 15.8 um feature associated with 21 um emission. Sources showing fullerene emission but no PAHs have blue colors in the optical, suggesting a clear line of sight to the central source. Spectra with 21 um features and Class D2 PAH emission also show photometric evidence for a relatively clear line of sight to the central source. The multiple associations of the 21 um feature to aliphatic hydrocarbons suggest that the carrier is related to this material in some way.

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Physical Properties of Fullerene-containing Galactic Planetary Nebulae

We searched the Spitzer Space Telescope data archive for Galactic planetary nebulae (PNe), that show the characteristic 17.4 and um features due to C60, also known as buckminsterfullerene. Out of 338 objects with Spitzer/IRS data, we found eleven C60-containing PNe, six of which (Hen2-68, IC2501, K3-62, M1-6, M1-9, and SaSt2-3) are new detections. We analyzed the spectra, along with ancillary data, using the photo-ionization code CLOUDY to establish the atomic line fluxes, and determine the properties of the radiation field, as set by the effective temperature of the central star. In addition, we measured the infrared spectral features due to dust grains. We find that the Polycyclic Aromatic Hydrocarbon (PAH) profile over 6-9 um in these C60-bearing carbon-rich PNe is of the more chemically-processed class A. The intensity ratio of 3.3 um to 11.3 um PAH indicates that the number of C-atoms per PAH in C60-containing PNe is small compared to that in non-C60 PNe. The Spitzer spectra also show broad dust features around 11 and 30 um. Analysis of the 30-um feature shows that it is strongly correlated with the continuum, and we propose that a single carbon-based carrier is responsible for both the continuum and the feature. The strength of the 11-um feature is correlated to the temperature of the dust, suggesting that it is at least partially due to a solid-state carrier. The chemical abundances of C60-containing PNe can be explained by AGB nucleosynthesis models for initially 1.5-2.5 Msun stars with Z=0.004. We plotted the locations of C60-containing PNe on a face-on map of the Milky Way and we found that most of these PNe are outside the solar circle, consistent with low metallicity values. Their metallicity suggests that the progenitors are an older population.

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On the Excitation and Formation of Circumstellar Fullerenes

We compare and analyze the Spitzer mid-infrared spectrum of three fullerene-rich planetary nebulae in the Milky Way and the Magellanic Clouds; Tc1, SMP SMC16, and SMP LMC56. The three planetary nebulae share many spectroscopic similarities. The strongest circumstellar emission bands correspond to the infrared active vibrational modes of the fullerene species C60 and little or no emission is present from Polycyclic Aromatic Hydrocarbons (PAHs). The strength of the fullerene bands in the three planetary nebulae is very similar, while the ratio of the [NeIII]15.5um/[NeII]12.8um fine structure lines, an indicator of the strength of the radiation field, is markedly different. This raises questions about their excitation mechanism and we compare the fullerene emission to fluorescent and thermal models. In addition, the spectra show other interesting and common features, most notably in the 6-9um region, where a broad plateau with substructure dominates the emission. These features have previously been associated with mixtures of aromatic/aliphatic hydrocarbon solids. We hypothesize on the origin of this band, which is likely related to the fullerene formation mechanism, and compare it with modeled Hydrogenated Amorphous Carbon that present emission in this region.

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Discovery of a TiO emission band in the infrared spectrum of the S star NP Aurigae

We report on the discovery of an infrared emission band in the Spitzer spectrum of the S-type AGB star NP Aurigae that is caused by TiO molecules in the circumstellar environment. We modelled the observed emission to derive the temperature of the TiO molecules (\approx 600 K), an upper limit on the column density (\approx 10^17.25 cm^{-2}) and a lower limit on the spatial extent of the layer that contains these molecules. (\approx 4.6 stellar radii). This is the first time that this TiO emission band is observed. A search for similar emission features in the sample of S-type stars yielded two additional candidates. However, owing to the additional dust emission, the identification is less stringent. By comparing the stellar characteristics of NP Aur to those of the other stars in our sample, we find that all stars with TiO emission show large-amplitude pulsations, s-process enrichment, and a low C/O ratio. These characteristics might be necessary requirements for a star to show TiO in emission, but they are not sufficient.

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