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J. Casanova

Publications and source records attributed to J. Casanova.

At least 19 recordsLinked to original sources

Reducing Sensing Time through Offline Experimental Design for Nuclear Spin Detection

The characterization of nuclear spin environments in solid-state devices plays an important role in advancing quantum technologies, yet traditional methods often demand long measurement times. To address this challenge, we integrate surrogate information gain (SIG) into our deep learning model based on the SALI architecture. By using SIG for data point selection, we achieve a significant reduction in experimental time while maintaining high precision in nuclear spin detection. SIG is a figure of merit based on the expected variance of the signal, which is more straightforward to compute than the expected information gain (EIG) rooted in Bayesian estimation, and, crucially, it selects experiments that are more robust to experimental imperfections. We demonstrate our approach on a nitrogen-vacancy (NV) center in diamond coupled to $^{13}$C nuclei. In the high-field regime, our variance-based optimization is validated with experimental data, resulting in an 85$\%$ reduction in measurement time for a modest reduction in performance. In the low-field regime, we explore the model's performance on simulated data, predicting a 60$\%$ reduction in the total experimental time by improving the temporal resolution of the measurements and applying SIG. This demonstrates the potential of integrating deep learning with optimized signal selection to enhance the efficiency of quantum sensing and nuclear spin characterization, paving the way for scaling these techniques to larger nuclear spin systems.

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Nanoscale Sensing of Solid-State Samples with High Frequency Resolution

To meet the growing demand for nanoscale surface analysis, nitrogen-vacancy (NV) centers offer a high-sensitivity alternative by leveraging their ability to operate in immediate proximity to the sample. In this work, we propose a quantum control protocol designed to overcome the inherent challenges of solid-state environments, specifically by mitigating anisotropy and strong dipole-dipole interactions to enable the detection of isotropic chemical shifts at the nanoscale. To achieve this, our scheme synchronizes a slowly rotating magnetic field with tailored RF decoupling and MW control of the NV sensors. We provide an analytical mapping that explicitly links the measured spectrum to the control sequence features and the underlying system parameters, enabling a straightforward characterization of the sample.

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Enhanced microscale NMR spectroscopy of low-gyromagnetic ratio nuclei via hydrogen transfer

Chemical shifts and J-couplings are fundamental parameters in NMR spectroscopy as they provide structural information about molecules. Extracting these quantities from isotopes such as carbon or nitrogen results in reduced sensitivity due to their low gyromagnetic ratios. In this work, we present a method for detecting chemical shifts and J-couplings at the microscale in low-gyromagnetic-ratio nuclei using NV centers. By leveraging hydrogen nuclei, we achieve strong coupling with NVs and fast signal emission that aligns with NV coherence times. In addition, the technique is well-suited for implementations under high magnetic fields. We demonstrate that our protocol achieves a sensitivity enhancement of more than one order of magnitude for scenarios involving $^{13}$C, with even greater improvements for nuclei with lower gyromagnetic ratios.

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J-coupling NMR Spectroscopy with Nitrogen Vacancy Centers at High Fields

A diamond-based sensor utilizing nitrogen-vacancy (NV) center ensembles permits the analysis of micron-sized samples through NMR techniques at room temperature. Current efforts are directed towards extending the operating range of NV centers into high magnetic fields, driven by the potential for larger nuclear spin polarization of the target sample and the presence of enhanced chemical shifts. Especially interesting is the access to J-couplings as they carry information of chemical connectivity inside molecules. In this work, we present a protocol to access J-couplings in both homonuclear and heteronuclear cases with NV centers at high magnetic fields. Our protocol leads to a clear spectrum exclusively containing J-coupling features with high resolution. This resolution is limited primarily by the decoherence of the target sample, which is mitigated by the noise filtering capacities of our method.

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Automatic Detection of Nuclear Spins at Arbitrary Magnetic Fields via Signal-to-Image AI Model

Quantum sensors leverage matter's quantum properties to enable measurements with unprecedented spatial and spectral resolution. Among these sensors, those utilizing nitrogen-vacancy (NV) centers in diamond offer the distinct advantage of operating at room temperature. Nevertheless, signals received from NV centers are often complex, making interpretation challenging. This is especially relevant in low magnetic field scenarios, where standard approximations for modeling the system fail. Additionally, NV signals feature a prominent noise component. In this Letter, we present a signal-to-image deep learning model capable of automatically inferring the number of nuclear spins surrounding a NV sensor and the hyperfine couplings between the sensor and the nuclear spins. Our model is trained to operate effectively across various magnetic field scenarios, requires no prior knowledge of the involved nuclei, and is designed to handle noisy signals, leading to fast characterization of nuclear environments in real experimental conditions. With detailed numerical simulations, we test the performance of our model in scenarios involving varying numbers of nuclei, achieving an average error of less than $2\ \rm{kHz}$ in the estimated hyperfine constants.

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Enhancing polarization transfer from nitrogen-vacancy centers in diamond to external nuclear spins via dangling bond mediators

The use of nitrogen-vacancy centers in diamond as a non-invasive platform for hyperpolarizing nuclear spins in molecular samples is a promising area of research with the potential to enhance the sensitivity of nuclear magnetic resonance experiments. Transferring NV polarization out of the diamond structure has been achieved on nanoscale targets using dynamical nuclear polarization methods, but extending this to relevant NMR volumes poses significant challenges. One major technical hurdle is the presence of paramagnetic defects in the diamond surface which can interfere with polarization outflow. However, these defects can also be harnessed as intermediaries for the interaction between NVs and nuclear spins. We present a method that benefits from existing microwave sequences, namely the PulsePol, to transfer polarization efficiently and robustly using dangling bonds or other localized electronic spins, with the potential to increase polarization rates under realistic conditions.

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Amplified Nanoscale Detection of Labelled Molecules via Surface Electrons on Diamond

The detection of individual molecules and their dynamics has been a long-standing challenge in the field of nanotechnology. In this work, we present a method that utilizes a nitrogen vacancy (NV) center and a dangling-bond on the diamond surface to measure the coupling between two electronic targets tagged on a macromolecule. To achieve this, we design a multi-tone dynamical decoupling sequence that leverages the strong interaction between the nitrogen vacancy center and the dangling bond. In addition, this sequence minimizes the impact of decoherence finally resulting in an increased signal-to-noise ratio. This proposal has the potential to open up new avenues for fundamental research and technological innovation in distinct areas such as biophysics and biochemistry.

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Quantum neural networks with multi-qubit potentials

We propose quantum neural networks that include multi-qubit interactions in the neural potential leading to a reduction of the network depth without losing approximative power. We show that the presence of multi-qubit potentials in the quantum perceptrons enables more efficient information processing tasks such as XOR gate implementation and prime numbers search, while it also provides a depth reduction to construct distinct entangling quantum gates like CNOT, Toffoli, and Fredkin. This simplification in the network architecture paves the way to address the connectivity challenge to scale up a quantum neural network while facilitates its training.

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Robust Oscillator-Mediated Phase Gates Driven by Low-Intensity Pulses

Robust qubit-qubit interactions mediated by bosonic modes are central to many quantum technologies. Existing proposals combining fast oscillator-mediated gates with dynamical decoupling require strong pulses or fast control over the qubit-boson coupling. Here, we present a method based on dynamical decoupling techniques that leads to faster-than-dispersive entanglement gates with low-intensity pulses. Our method is general, i.e., it is applicable to any quantum platform that has qubits interacting with bosonic mediators via longitudinal coupling. Moreover, the protocol provides robustness to fluctuations in qubit frequencies and control fields, while also being resistant to common errors such as frequency shifts and heating in the mediator as well as crosstalk effects. We illustrate our method with an implementation for trapped ions coupled via magnetic field gradients. With detailed numerical simulations, we show that entanglement gates with infidelities of $10^{-3}$ or $10^{-4}$ are possible with current or near-future experimental setups, respectively.

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High-Resolution NMR Spectroscopy at Large Fields with Nitrogen Vacancy Centers

Ensembles of nitrogen-vacancy (NV) centers are used as sensors to detect NMR signals from micron-sized samples at room temperature. In this scenario, the regime of large magnetic fields is especially interesting as it leads to a large nuclear thermal polarisation -- thus, to a strong sensor response even in low concentration samples -- while chemical shifts and J-couplings become more accessible. Nevertheless, this regime remains largely unexplored owing to the difficulties to couple NV-based sensors with high-frequency nuclear signals. In this work, we circumvent this problem with a method that maps the relevant energy shifts in the amplitude of an induced nuclear spin signal that is subsequently transferred to the sensor. This stage is interspersed with free-precession periods of the sample nuclear spins where the sensor does not participate. Thus, our method leads to high spectral resolutions ultimately limited by the coherence of the nuclear spin signal.

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Detection of Molecular Transitions with Nitrogen-Vacancy Centers and Electron-Spin Labels

We present a protocol that detects molecular conformational changes with two nitroxide electron-spin labels and a nitrogen-vacancy (NV) center in diamond. More specifically, we demonstrate that the NV can detect energy shifts induced by the coupling between electron-spin labels. The protocol relies on the judicious application of microwave and radiofrequency pulses in a range of parameters that ensures stable nitroxide resonances. Furthermore, we demonstrate that our scheme is optimized by using nitroxides with distinct nitrogen isotopes. We use detailed numerical simulations and Bayesian inference techniques to demonstrate that our method enables the detection of conformational changes under realistic conditions including strong NV dephasing rates as a consequence of the diamond surface proximity and nitroxide thermalization mechanisms. Finally, we show that random molecular tumbling can be exploited to extract the inter-label distance.

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Double Quantum Magnetometry at Large Static Magnetic Fields

We present a protocol to achieve double quantum magnetometry at large static magnetic fields. This is a regime where sensitive sample parameters, such as the chemical shift, get enhanced facilitating their characterization. In particular, our method delivers two-tone stroboscopic radiation patterns with modulated Rabi frequencies to achieve larger spectral signals. Furthermore, it does not introduce inhomogeneous broadening in the sample spectrum preventing signal misinterpretation. Moreover, our protocol is designed to work under realistic conditions such as the presence of moderate microwave power and errors on the radiation fields. Albeit we particularise to nitrogen vacancy centers, our protocol is general, thus applicable to distinct quantum sensors.

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Versatile Atomic Magnetometry Assisted by Bayesian Inference

Quantum sensors typically translate external fields into a periodic response whose frequency is then determined by analyses performed in Fourier space. This allows for a linear inference of the parameters that characterize external signals. In practice, however, quantum sensors are able to detect fields only in a narrow range of amplitudes and frequencies. A departure from this range, as well as the presence of significant noise sources and short detection times, lead to a loss of the linear relationship between the response of the sensor and the target field, thus limiting the working regime of the sensor. Here we address these challenges by means of a Bayesian inference approach that is tolerant to strong deviations from desired periodic responses of the sensor and is able to provide reliable estimates even with a very limited number of measurements. We demonstrate our method for an $^{171}$Yb$^{+}$ trapped-ion quantum sensor but stress the general applicability of this approach to different systems.

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Speed-up Quantum Perceptron via Shortcuts to Adiabaticity

The quantum perceptron is a fundamental building block for quantum machine learning. This is a multidisciplinary field that incorporates abilities of quantum computing, such as state superposition and entanglement, to classical machine learning schemes. Motivated by the techniques of shortcuts to adiabaticity, we propose a speed-up quantum perceptron where a control field on the perceptron is inversely engineered leading to a rapid nonlinear response with a sigmoid activation function. This results in faster overall perceptron performance compared to quasi-adiabatic protocols, as well as in enhanced robustness against imperfections in the controls.

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Tailored Ion Beam for Precise Color Center Creation

We present a unitary quantum control scheme that produces a highly monochromatic ion beam from a Paul trap. Our protocol is implementable by supplying the segmented electrodes with voltages of the order of Volts, which mitigates the impact of fluctuating voltages in previous designs and leads to a low-dispersion beam of ions. Moreover, our proposal does not rely on sympathetically cooling the ions, which bypasses the need of loading different species in the trap -- namely, the propelled ion and, e.g., a $^{40}$Ca$^+$ atom able to exert sympathetic cooling -- incrementing the repetition rate of the launching procedure. Our scheme is based on an invariant operator linear in position and momentum, which enables us to control the average extraction energy and the outgoing momentum spread. In addition, we propose a sequential operation to tailor the transversal properties of the beam before the ejection to minimize the impact spot and to increase the lateral resolution of the implantation.

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Dynamical decoupling methods in nanoscale NMR

Nuclear magnetic resonance (NMR) schemes can be applied to micron-, and nanometer-sized samples by the aid of quantum sensors such as nitrogen-vacancy (NV) color centers in diamond. These minute devices allow for magnetometry of nuclear spin ensembles with high spatial and frequency resolution at ambient conditions, thus having a clear impact in different areas such as chemistry, biology, medicine, and material sciences. In practice, NV quantum sensors are driven by microwave (MW) control fields with a twofold objective: On the one hand, MW fields bridge the energy gap between NV and nearby nuclei which enables a coherent and selective coupling among them while, on the other hand, MW fields remove environmental noise on the NV leading to enhanced interrogation time. In this work we review distinct MW radiation patterns, or dynamical decoupling techniques, for nanoscale NMR applications.

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Measurement-based adaptation protocol with quantum reinforcement learning in a Rigetti quantum computer

We present an experimental realization of a measurement-based adaptation protocol with quantum reinforcement learning in a Rigetti cloud quantum computer. The experiment in this few-qubit superconducting chip faithfully reproduces the theoretical proposal, setting the first steps towards a semiautonomous quantum agent. This experiment paves the way towards quantum reinforcement learning with superconducting circuits.

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Selective Interactions in the Quantum Rabi Model

We demonstrate the emergence of selective $k$-photon interactions in the strong and ultrastrong coupling regimes of the quantum Rabi model with a Stark coupling term. In particular, we show that the interplay between the rotating and counter-rotating terms produces multi-photon interactions whose resonance frequencies depend, due to the Stark term, on the state of the bosonic mode. We develop an analytical framework to explain these $k$-photon interactions by using time-dependent perturbation theory. Finally, we propose a method to achieve the quantum simulation of the quantum Rabi model with a Stark term by using the internal and vibrational degrees of freedom of a trapped ion, and demonstrate its performance with numerical simulations considering realistic physical parameters.

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