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J. D. Denlinger

Publications and source records attributed to J. D. Denlinger.

At least 19 recordsLinked to original sources

UV$_6$Sn$_6$: a new kagome material with unusual $5f$ magnetism

Materials in the family $R$V$_{6}$Sn$_{6}$ ($R=$ rare earth) provide a unique platform to investigate the interplay between local moments from $R$ layers and nonmagnetic vanadium kagome layers. Yet, the investigation of actinide members remains scarce. Here we report the synthesis of UV$_{6}$Sn$_{6}$ single crystals through the self-flux technique. Magnetic susceptibility, specific heat, electrical resistivity, and thermal expansion measurements reveal two uranium-driven antiferromagnetic transitions at $T_{N1}=29$~K and $T_{N2}=24$~K, a complex field-temperature phase diagram, and unusual negative domain wall magnetoresistance. Specific heat measurements unveil a modest Sommerfeld coefficient of $\gamma = 40$~mJ/mol.K$^{2}$, consistent with angle-resolved photoemission spectroscopy measurements that show a moderate $f$-electron enhancement at the Fermi level ($E_{F}$). Our experiments support a modest contribution from \textit{5f} flat bands to the density of states at $E_{F}$, whereas our band structure calculations place the vanadium flat bands 0.25~eV above $E_{F}$. Our findings point to a materials opportunity to expand the uranium 166 family with the goal of enhancing correlations by tuning $5f$ and $3d$ flat bands to $E_{F}$.

cond-mat.str-el

Anomalous 4$f$ fine structure in TmSe$_{1-x}$Te$_x$ across the metal-insulator transition

Hybridization between localized 4$f$ and itinerant 5$d$6$s$ states in heavy fermion compounds is a well-studied phenomenon and commonly captured by the paradigmatic Anderson model. However, the investigation of additional electronic interactions, beyond the standard Anderson model, has been limited, despite their predicted important role in the exotic quasiparticle formation in mixed-valence systems. We investigate the 4$f$ states in TmSe$_{1-x}$Te$_x$ throughout a semimetal-insulator phase transition, which drastically varies the interactions related to the 4$f$ states. Using synchrotron-based hard x-ray and extreme ultraviolet photoemission spectroscopy, we resolve subtle peak splitting in the 4$f$ peaks near the Fermi level in the mixed-valent semimetal phase. The separation is enhanced by several tens of meV by increasing the lattice parameter by a few percent. Our results elucidate the evolving nature of the 4$f$ state across the phase transition, and provide direct experimental evidence for electronic interactions beyond the standard Anderson model in mixed-valence systems.

cond-mat.str-el

Kondo quasiparticle dynamics observed by resonant inelastic x-ray scattering

Effective models focused on pertinent low-energy degrees of freedom have substantially contributed to our qualitative understanding of quantum materials. An iconic example, the Kondo model, was key to demonstrating that the rich phase diagrams of correlated metals originate from the interplay of localized and itinerant electrons. Modern electronic structure calculations suggest that to achieve quantitative material-specific models, accurate consideration of the crystal field and spin-orbit interactions is imperative. This poses the question of how local high-energy degrees of freedom become incorporated into a collective electronic state. Here, we use resonant inelastic x-ray scattering (RIXS) on CePd$_3$ to clarify the fate of all relevant energy scales. We find that even spin-orbit excited states acquire pronounced momentum-dependence at low temperature - the telltale sign of hybridization with the underlying metallic state. Our results demonstrate how localized electronic degrees of freedom endow correlated metals with new properties, which is critical for a microscopic understanding of superconducting, electronic nematic, and topological states.

cond-mat.str-el

Global perspectives of the bulk electronic structure of URu$_2$Si$_2$ from angle-resolved photoemission

Previous high-resolution angle-resolved photoemission (ARPES) studies of URu$_2$Si$_2$ have characterized the temperature-dependent behavior of narrow-band states close to the Fermi level ($E_\mathrm{F}$) at low photon energies near the zone center, with an emphasis on electronic reconstruction due to Brillouin zone folding. A substantial challenge to a proper description is that these states interact with other hole-band states that are generally absent from bulk-sensitive soft x-ray ARPES measurements. Here we provide a more global $k$-space context for the presence of such states and their relation to the bulk Fermi surface topology using synchrotron-based wide-angle and photon energy-dependent ARPES mapping of the electronic structure using photon energies intermediate between the low-energy regime and the high-energy soft x-ray regime. Small-spot spatial dependence, $f$-resonant photoemission, Si 2$p$ core-levels, x-ray polarization, surface-dosing modification, and theoretical surface slab calculations are employed to assist identification of bulk versus surface state character of the $E_\mathrm{F}$-crossing bands and their relation to specific U- or Si-terminations of the cleaved surface. The bulk Fermi surface topology is critically compared to density functional theory and to dynamical mean field theory calculations. In addition to clarifying some aspects of the previously measured high symmetry $Γ$, Z and X points, incommensurate 0.6a* nested Fermi-edge states located along Z-N-Z are found to be distinctly different from the density functional theory Fermi surface prediction. The temperature evolution of these states above $T_{HO}$, combined with a more detailed theoretical investigation of this region, suggests a key role of the N-point in the hidden order transition.

cond-mat.str-el

Colossal band renormalization and stoner ferromagnetism induced by electron-antiferromagnetic-magnon coupling

The interactions between electrons and antiferromagnetic magnons (AFMMs) are important for a large class of correlated materials. For example, they are the most plausible pairing glues in high-temperature superconductors, such as cuprates and iron pnictides. However, unlike electron-phonon interactions (EPIs), clear-cut observations regarding how electron-AFMM interactions (EAIs) affect the band structure are still lacking. Consequently, critical information on the EAIs, such as its strength and doping dependence, remains elusive. Here we directly observe that EAIs induces a kink structure in the band dispersion in Ba$_{1-x}$K$_x$Mn$_2$As$_2$, and subsequently unveil several key characteristics of EAIs. We found that the coupling constant of EAIs can be as large as 6, and it shows huge doping dependence and temperature dependence, all in stark contrast to the behaviors of EPI and beyond our current understanding of EAIs. Such a colossal renormalization of electronic bands by EAIs drives the system to the Stoner criteria, giving the intriguing ferromagnetic state in Ba$_{1-x}$K$_x$Mn$_2$As$_2$. Our results expand the current knowledge of EAIs, which may facilitate the further understanding of many correlated materials where EAIs play a critical role, such as high-temperature superconductors.

cond-mat.str-el

Proximity-induced hidden order transition in a correlated heterostructure Sr$_2$VO$_3$FeAs

Symmetry is one of the most significant concepts in physics, and its importance has been largely manifested in phase transitions by its spontaneous breaking. In strongly correlated systems, however, mysterious and enigmatic phase transitions, inapplicable of the symmetry description, have been discovered and often dubbed hidden order transitions, as found in, $\it{e.g.}$, high-$T_C$ cuprates, heavy fermion superconductors, and quantum spin liquid candidates. Here, we report a new type of hidden order transition in a correlated heterostructure Sr$_2$VO$_3$FeAs, whose origin is attributed to an unusually enhanced Kondo-type proximity coupling between localized spins of V and itinerant electrons of FeAs. Most notably, a fully isotropic gap opening, identified by angle-resolved photoemission spectroscopy, occurs selectively in one of the Fermi surfaces below $T_{\rm HO}$ $\sim$ 150 K, associated with a singular behavior of the specific heat and a strong enhancement on the anisotropic magnetoresistance. These observations are incompatible with the prevalent broken-symmetry-driven scenarios of electronic gap opening and highlight a critical role of proximity coupling. Our findings demonstrate that correlated heterostructures offer a novel platform for design and engineering of exotic hidden order phases.

cond-mat.str-el

Momentum dependent $d_{xz/yz}$ band splitting in LaFeAsO

We performed angle-resolved photoemission spectroscopy (ARPES) studies of the electronic structure of the nematic phase in LaFeAsO. Degeneracy breaking between the dxz and dyz hole bands near the Γ and M point is observed in the nematic phase. Different temperature dependent band splitting behaviors are observed at the Γ and M points. The energy of the band splitting near the M point decreases as the temperature decreases while it has little temperature dependence near the Γ point. The nematic nature of the band shift near the M point is confirmed through a detwin experiment using a piezo device. Since a momentum dependent splitting behavior has been observed in other iron based superconductors, our observation confirms that the behavior is a universal one among iron based superconductors.

cond-mat.supr-con

Surface states and Rashba-type spin polarization in antiferromagnetic MnBi$_2$Te$_4$

The layered van der Waals antiferromagnet MnBi$_2$Te$_4$ has been predicted to combine the band ordering of archetypical topological insulators such as Bi$_2$Te$_3$ with the magnetism of Mn, making this material a viable candidate for the realization of various magnetic topological states. We have systematically investigated the surface electronic structure of MnBi$_2$Te$_4$(0001) single crystals by use of spin- and angle-resolved photoelectron spectroscopy experiments. In line with theoretical predictions, the results reveal a surface state in the bulk band gap and they provide evidence for the influence of exchange interaction and spin-orbit coupling on the surface electronic structure.

cond-mat.str-el

Multiple topological Dirac cones in a mixed-valent Kondo semimetal: g-SmS

We demonstrate theoretically that the golden phase of SmS ($g$-SmS), a correlated mixed-valent system, exhibits nontrivial surface states with diverse topology. It turns out that this material is an ideal playground to investigate different band topologies in different surface terminations. We have explored surface states on three different (001), (111), and (110) surface terminations. Topological signature in the (001) surface is not apparent due to a hidden Dirac cone inside the bulk-projected bands. In contrast, the (111) surface shows a clear gapless Dirac cone in the gap region, demonstrating the unambiguous topological Kondo nature of $g$-SmS. Most interestingly, the (110) surface exhibits both topological-insulator-type and topological-crystalline-insulator (TCI)-type surface states simultaneously. Two different types of double Dirac cones, Rashba-type and TCI-type, realized on the (001) and (110) surfaces, respectively, are analyzed with the mirror eigenvalues and mirror Chern numbers obtained from the model-independent \emph{ab initio} band calculations.

cond-mat.str-el

Lifted electron pocket and reversed orbital occupancy imbalance in FeSe

The FeSe nematic phase has been the focus of recent research on iron based superconductors (IBSs) due to its unique properties. A number of electronic structure studies were performed to find the origin of the phase. However, such attempts came out with conflicting results and caused additional controversies. Here, we report results from angle resolved photoemission and X-ray absorption spectroscopy studies on FeSe with detwinning by a piezo stack. We have fully resolved band dispersions with orbital characters near the Brillouin zone corner which reveals absence of a Fermi pocket at the Y point in the 1Fe Brillouin zone. In addition, the occupation imbalance between dxz and dyz orbitals is found to be opposite to that of iron pnictides, which is consistent with the identified band characters. These results settle down controversial issues in the FeSe nematic phase and shed light on the origin of nematic phases in IBSs.

cond-mat.supr-con

Wannier-Orbital theory and ARPES for the quasi-1D conductor LiMo$_{6}$O$_{17}$

In this set of three papers, we present the results of a combined study by density-functional (LDA) band theory (NMTO) and angle-resolved photoemission spectroscopy (ARPES) of lithium purple bronze, 2(Li$_{1x}$Mo$_{6}$O$_{17}$). This material is particularly notable for its unusually robust quasi-one-dimensional (quasi-1D) behavior. The band structure, in a large energy window around the Fermi energy, is basically 2D and formed by three Mo $t_{2g}$-like extended Wannier orbitals (WOs) per cell, each one giving rise to a 1D band running at a 120$^{\circ }$ angle to the two others. A structural "dimerization" from $\mathbf{c}/2$ to $\mathbf{c}$ gaps the $xz$ and $yz$ bands while leaving the $xy$ bands metallic in the gap but resonantly coupled to the gap edges and, hence, to the two other directions. The resulting complex shape of the quasi-1D Fermi surface (FS), verified by our ARPES, thus depends strongly on the Fermi energy position in the gap, implying a great sensitivity to Li stoichiometry of properties dependent on the FS, such as FS nesting or superconductivity. The band structure, expressed as a six-band, analytical tight-binding (TB) Hamiltonian, is verified in detail by the recognition and application of an ARPES selection rule that enables, for the first time, the separation in ARPES spectra of the two barely split $xy$ bands and the observation of their complex split FS. The strong resonances prevent either a two-band TB model or a related real-space ladder picture from giving a valid description of the low-energy electronic structure. Down to a temperature of 6$\,$K we find no evidence for a theoretically expected downward renormalization of perpendicular single particle hopping due to LL fluctuations in the quasi-1D chains.

cond-mat.str-el

Direct visualization of coexisting channels of interaction in CeSb

Our understanding of correlated electron systems is vexed by the complexity of their interactions. Heavy fermion compounds are archetypal examples of this physics, leading to exotic properties that weave together magnetism, superconductivity and strange metal behavior. The Kondo semimetal CeSb is an unusual example where different channels of interaction not only coexist, but their physical signatures are coincident, leading to decades of debate about the microscopic picture describing the interactions between the $f$ moments and the itinerant electron sea. Using angle-resolved photoemission spectroscopy, we resonantly enhance the response of the Ce$f$-electrons across the magnetic transitions of CeSb and find there are two distinct modes of interaction that are simultaneously active, but on different kinds of carriers. This study is a direct visualization of how correlated systems can reconcile the coexistence of different modes on interaction - by separating their action in momentum space, they allow their coexistence in real space.

cond-mat.str-el

Stable Weyl points, trivial surface states and particle-hole compensation in WP2

A possible connection between extremely large magneto-resistance and the presence of Weyl points has garnered much attention in the study of topological semimetals. Exploration of these concepts in transition metal phosphide WP2 has been complicated by conflicting experimental reports. Here we combine angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations to disentangle surface and bulk contributions to the ARPES intensity, the superposition of which has plagued the determination of the electronic structure in WP2. Our results show that while the hole- and electron-like Fermi surface sheets originating from surface states have different areas, the bulk-band structure of WP2 is electron-hole-compensated in agreement with DFT. Furthermore, the detailed band structure is compatible with the presence of at least 4 temperature-independent Weyl points, confirming the topological nature of WP2 and its stability against lattice distortions.

cond-mat.mtrl-sci

Experimental observation of hidden Berry curvature in inversion-symmetric bulk 2H-WSe2

We investigate the hidden Berry curvature in bulk 2H-WSe2 by utilizing the surface sensitivity of angle resolved photoemission (ARPES). The symmetry in the electronic structure of transition metal dichalcogenides is used to uniquely determine the local orbital angular momentum (OAM) contribution to the circular dichroism (CD) in ARPES. The extracted CD signals for the K and K' valleys are almost identical but their signs, which should be determined by the valley index, are opposite. In addition, the sign is found to be the same for the two spin-split bands, indicating that it is independent of spin state. These observed CD behaviors are what are expected from Berry curvature of a monolayer of WSe2. In order to see if CD-ARPES is indeed representative of hidden Berry curvature within a layer, we use tight binding analysis as well as density functional calculation to calculate the Berry curvature and local OAM of a monolayer WSe2. We find that measured CD-ARPES is approximately proportional to the calculated Berry curvature as well as local OAM, further supporting our interpretation.

cond-mat.mtrl-sci

Observation of two-dimensional Fermi surface and Dirac dispersion in YbMnSb$_2$

We present the crystal structure, electronic structure, and transport properties of the material YbMnSb$_2$, a candidate system for the investigation of Dirac physics in the presence of magnetic order. Our measurements reveal that this system is a low-carrier-density semimetal with a 2D Fermi surface arising from a Dirac dispersion, consistent with the predictions of density functional theory calculations of the antiferromagnetic system. The low temperature resistivity is very large, suggesting scattering in this system is highly efficient at dissipating momentum despite its Dirac-like nature.

cond-mat.mtrl-sci

Nearly-free-electron system of monolayer Na on the surface of single-crystal HfSe$_2$

The electronic structure of a single Na monolayer on the surface of single-crystal HfSe$_2$ is investigated using angle-resolved photoemission spectroscopy. We find that this system exhibits an almost perfect "nearly-free-electron" behavior with an extracted effective mass of $\sim\!1m_e$, in contrast to heavier masses found previously for alkali metal monolayers on other substrates. Our density-functional-theory calculations indicate that this is due to the large lattice constant, causing both exchange and correlation interactions to be suppressed, and to the weak hybridization between the overlayer and the substrate. This is therefore an ideal model system for understanding the properties of two-dimensional materials.

cond-mat.mtrl-sci

Evolution of the Kondo lattice electronic structure above the transport coherence temperature

The temperature-dependent evolution of the Kondo lattice is a long-standing topic of theoretical and experimental investigation and yet it lacks a truly microscopic description of the relation of the basic $f$-$d$ hybridization processes to the fundamental temperature scales of Kondo screening and Fermi-liquid lattice coherence. Here, the temperature-dependence of $f$-$d$ hybridized band dispersions and Fermi-energy $f$ spectral weight in the Kondo lattice system CeCoIn$_5$ is investigated using $f$-resonant angle-resolved photoemission (ARPES) with sufficient detail to allow direct comparison to first principles dynamical mean field theory (DMFT) calculations containing full realism of crystalline electric field states. The ARPES results, for two orthogonal (001) and (100) cleaved surfaces and three different $f$-$d$ hybridization scenarios, with additional microscopic insight provided by DMFT, reveal $f$ participation in the Fermi surface at temperatures much higher than the lattice coherence temperature, $T^*\approx$ 45 K, commonly believed to be the onset for such behavior. The identification of a $T$-dependent crystalline electric field degeneracy crossover in the DMFT theory $below$ $T^*$ is specifically highlighted.

cond-mat.str-el

Fermi Surface of Metallic V$_2$O$_3$ from Angle-Resolved Photoemission: Mid-level Filling of $e_g^π$ Bands

Using angle resolved photoemission spectroscopy (ARPES) we report the first band dispersions and distinct features of the bulk Fermi surface (FS) in the paramagnetic metallic phase of the prototypical metal-insulator transition material V$_2$O$_3$. Along the $c$-axis we observe both an electron pocket and a triangular hole-like FS topology, showing that both V 3$d$ $a_{1g}$ and $e_g^π$ states contribute to the FS. These results challenge the existing correlation-enhanced crystal field splitting theoretical explanation for the transition mechanism and pave the way for the solution of this mystery.

cond-mat.str-el