arXiv subjects

J. D. Denlinger

Publications and source records attributed to J. D. Denlinger.

At least 37 records · Page 2Linked to original sources

arXiv2016

Disentangling the surface and bulk electronic structures of LaOFeAs

We performed a comprehensive angle-resolved photoemission spectroscopy study of the electronic band structure of LaOFeAs single crystals. We found that samples cleaved at low temperature show an unstable and highly complicated band structure, whereas samples cleaved at high temperature exhibit a stable and clearer electronic structure. Using \emph{in-situ} surface doping with K and supported by first-principles calculations, we identify both surface and bulk bands. Our assignments are confirmed by the difference in the temperature dependence of the bulk and surface states.

cond-mat.supr-con↗

arXiv2016

Electronic structure of YbB$_{6}$: Is it a Topological Insulator or not?

To resolve the controversial issue of the topological nature of the electronic structure of YbB$_{6}$, we have made a combined study using density functional theory (DFT) and angle resolved photoemission spectroscopy (ARPES). Accurate determination of the low energy band topology in DFT requires the use of modified Becke-Johnson exchange potential incorporating the spin-orbit coupling and the on-site Coulomb interaction $U$ of Yb $4f$ electrons as large as 7 eV. We have double-checked the DFT result with the more precise GW band calculation. ARPES is done with the non-polar (110) surface termination to avoid band bending and quantum well confinement that have confused ARPES spectra taken on the polar (001) surface termination. Thereby we show definitively that YbB$_{6}$ has a topologically trivial B 2$p$-Yb 5$d$ semiconductor band gap, and hence is a non-Kondo non-topological insulator (TI). In agreement with theory, ARPES shows pure divalency for Yb and a $p$-$d$ band gap of 0.3 eV, which clearly rules out both of the previous scenarios of $f$-$d$ band inversion Kondo TI and $p$-$d$ band inversion non-Kondo TI. We have also examined the pressure-dependent electronic structure of YbB$_{6}$, and found that the high pressure phase is not a Kondo TI but a \emph{p}-\emph{d} overlap semimetal.

cond-mat.str-el↗

arXiv2016

Consistency of Photoemission and Quantum Oscillations for Surface States of SmB6

The mixed valent compound SmB6 is of high current interest as the first candidate example of topologically protected surface states in a strongly correlated insulator and also as a possible host for an exotic bulk many-body state that would manifest properties of both an insulator and a metal. Two different de Haas van Alphen (dHvA) experiments have each supported one of these possibilities, while angle resolved photoemission spectroscopy (ARPES) for the (001) surface has supported the first, but without quantitative agreement to the dHvA results. We present new ARPES data for the (110) surface and a new analysis of all published dHvA data and thereby bring ARPES and dHvA into substantial consistency around the basic narrative of two dimensional surface states.

cond-mat.str-el↗

arXiv2015

20 K superconductivity in heavily electron doped surface layer of FeSe bulk crystal

A superconducting transition temperature Tc as high as 100 K was recently discovered in 1 monolayer (1ML) FeSe grown on SrTiO3 (STO). The discovery immediately ignited efforts to identify the mechanism for the dramatically enhanced Tc from its bulk value of 7 K. Currently, there are two main views on the origin of the enhanced Tc; in the first view, the enhancement comes from an interfacial effect while in the other it is from excess electrons with strong correlation strength. The issue is controversial and there are evidences that support each view. Finding the origin of the Tc enhancement could be the key to achieving even higher Tc and to identifying the microscopic mechanism for the superconductivity in iron-based materials. Here, we report the observation of 20 K superconductivity in the electron doped surface layer of FeSe. The electronic state of the surface layer possesses all the key spectroscopic aspects of the 1ML FeSe on STO. Without any interface effect, the surface layer state is found to have a moderate Tc of 20 K with a smaller gap opening of 4 meV. Our results clearly show that excess electrons with strong correlation strength alone cannot induce the maximum Tc, which in turn strongly suggests need for an interfacial effect to reach the enhanced Tc found in 1ML FeSe/STO.

cond-mat.supr-con↗

arXiv2015

Observation of a $d$-wave gap in electron-doped Sr$_2$IrO$_4$

High temperature superconductivity in cuprates emerges out of a highly enigmatic `pseudogap' metal phase. The mechanism of high temperature superconductivity is likely encrypted in the elusive relationship between the two phases, which spectroscopically is manifested as Fermi arcs---disconnected segments of zero-energy states---collapsing into $d$-wave point nodes upon entering the superconducting phase. Here, we reproduce this distinct cuprate phenomenology in the 5$d$ transition-metal oxide Sr$_2$IrO$_4$. Using angle-resolved photoemission, we show that clean, low-temperature phase of 6-8$\%$ electron-doped Sr$_2$IrO$_4$ has gapless excitations only at four isolated points in the Brillouin zone with a predominant $d$-wave symmetry of the gap. Our work thus establishes a connection between the low-temperature $d$-wave instability and the previously reported high-temperature Fermi arcs in electron-doped Sr$_2$IrO$_4$. Although the physical origin of the $d$-wave gap remains to be understood, Sr$_2$IrO$_4$ is a first non-cuprate material to spectroscopically reproduce the complete phenomenology of the cuprates, thus offering a new material platform to investigate the relationship between the pseudogap and the $d$-wave gap.

cond-mat.str-el↗

arXiv2015

Spectroscopic evidence for negative electronic compressibility in a quasi-three-dimensional spin-orbit correlated metal

Negative compressibility is a sign of thermodynamic instability of open or non-equilibrium systems. In quantum materials consisting of multiple mutually coupled subsystems, the compressibility of one subsystem can be negative if it is countered by positive compressibility of the others. Manifestations of this effect have so far been limited to low-dimensional dilute electron systems. Here we present evidence from angle-resolved photoemission spectroscopy (ARPES) for negative electronic compressibility (NEC) in the quasi-three-dimensional (3D) spin-orbit correlated metal (Sr1-xLax)3Ir2O7. Increased electron filling accompanies an anomalous decrease of the chemical potential, as indicated by the overall movement of the deep valence bands. Such anomaly, suggestive of NEC, is shown to be primarily driven by the lowering in energy of the conduction band as the correlated bandgap reduces. Our finding points to a distinct pathway towards an uncharted territory of NEC featuring bulk correlated metals with unique potential for applications in low-power nanoelectronics and novel metamaterials.

cond-mat.str-el↗

arXiv2015

Soft X-ray Angle Resolved Photoemission with Micro Positioning Techniques for Metallic V$_2$O$_3$

We have performed soft-X-ray angle resolved photoemission for metallic V$_2$O$_3$. Combining a micro focus beam (40 x 65 $μ$m$^2$) and micro positioning techniques with a long working distance microscope, we have succeeded in observing band dispersions from tiny cleavage surfaces with typical size of the several tens of $μ$m. The photoemission spectra show a clear position dependence reflecting the morphology of the cleaved sample surface. By selecting high quality flat regions on the sample surface, we have succeeded in band mapping using both photon-energy and polar-angle dependences, opening the door to three-dimensional ARPES for typical three dimensional correlated materials where large cleavage planes are rarely obtained.

cond-mat.str-el↗

arXiv2014

Observation of an electron band above the Fermi level in FeTe$_{0.55}$Se$_{0.45}$ from \emph{in-situ} surface doping

We used \emph{in-situ} potassium (K) evaporation to dope the surface of the iron-based superconductor FeTe$_{0.55}$Se$_{0.45}$. The systematic study of the bands near the Fermi level confirms that electrons are doped into the system, allowing us to tune the Fermi level of this material and to access otherwise unoccupied electronic states. In particular, we observe an electron band located above the Fermi level before doping that shares similarities with a small three-dimensional pocket observed in the cousin, heavily-electron-doped KFe$_{2-x}$Se$_2$ compound.

cond-mat.supr-con↗

arXiv2014

Fermi Arcs in a Doped Pseudospin-1/2 Heisenberg Antiferromagnet

High temperature superconductivity in cuprates arises from an electronic state that remains poorly understood. We report the observation of a related electronic state in a non-cuprate material Sr2IrO4 in which the unique cuprate Fermiology is largely reproduced. Upon surface electron doping through in situ deposition of alkali-metal atoms, angle-resolved photoemission spectra of Sr2IrO4 display disconnected segments of zero-energy states, known as Fermi arcs, and a gap as large as 80 meV. Its evolution toward a normal metal phase with a closed Fermi surface as a function of doping and temperature parallels that in the cuprates. Our result suggests that Sr2IrO4 is a useful model system for comparison to the cuprates.

cond-mat.str-el↗

arXiv2014

Termination-dependent Surface In-gap States in a Mixed-valent Topological Insulator: SmB$_6$

We have investigated the surface states of a potential mixed-valent topological insulator SmB$_6$ based on the first principles density functional theory slab band structure analysis. We have found that metallic surface states are formed in the bulk band gap region, providing evidence for the topological insulating nature of SmB$_6$. The obtained surface in-gap states are quite different from those in existing reports in that they are formed differently depending on the Sm or B$_6$ surface termination, and are composed of mainly Sm $4f$ state indicating the essentiality of including $f$ electrons in describing the surface states. We have obtained the spin chiral structures of the Fermi surfaces, which are also in accordance with the topological insulating nature of SmB$_6$.

cond-mat.str-el↗

arXiv2014

Temperature Dependence of Linked Gap and Surface State Evolution in the Mixed Valent Topological Insulator SmB6

Taken together and viewed holistically, recent theory, low temperature (T) transport, photoelectron spectroscopy and quantum oscillation experiments have built a very strong case that the paradigmatic mixed valence insulator SmB6 is currently unique as a three-dimensional strongly correlated topological insulator (TI). As such, its many-body T-dependent bulk gap brings an extra richness to the physics beyond that of the weakly correlated TI materials. How will the robust, symmetry-protected TI surface states evolve as the gap closes with increasing T? For SmB6 exploiting this opportunity first requires resolution of other important gap-related issues, its origin, its magnitude, its T-dependence and its role in bulk transport. In this paper we report detailed T-dependent angle resolved photoemission spectroscopy (ARPES) measurements that answer all these questions in a unified way.

cond-mat.str-el↗

arXiv2013

Band symmetries of mixed-valence topological insulator: SmB6

We have investigated the band structure and the band symmetry of mixed-valence insulator SmB$_{6}$ systematically within the density functional theory (DFT). We have analyzed the symmetries and characters of Sm $4f$ and $5d$ bands near the Fermi level ($E_F$) in terms of the non-relativistic real cubic bases as well as the relativistic complex bases incorporating the spin-orbit coupling and the cubic crystal field. Further, we have found that the semi-core band located at $\sim 15$ eV below $E_F$ has the mixed parity and thereby affects the parity eigenvalues of the special ${\bf k}$-points considerably. We have discussed the possible surface states and topological class of SmB$_{6}$, based on the bulk parity tables.

cond-mat.str-el↗

arXiv2013

Experimental Electronic Structure of the Metallic Pyrochlore Iridate Bi2Ir2O7

Angle-resolved photoemission measurements have been performed on Bi2Ir2O7 single crystals, a prototypical example of the pyrochlore iridates. The density of states, the Fermi surface, and the near Fermi level band dispersion in the plane perpendicular to the (111) direction were all measured and found to be in overall agreement with our LDA + SOC density functional calculations. Our observations indicate the general validity of the LDA + SOC-based approach for the electronic structure of pyrochlore iridates, raising the possibility that some of the novel predicted phases such as quantum spin ice or Weyl Fermion states may exist in this family of compounds.

cond-mat.str-el↗

arXiv2013

Angle-resolved photoemission spectroscopy observation of anomalous electronic states in EuFe$_2$As$_{2-x}$P$_x$

We used angle-resolved photoemission spectroscopy to investigate the electronic structure of EuFe$_2$As$_2$, EuFe$_2$As$_{1.4}$P$_{0.6}$ and EuFe$_2$P$_2$. We observed doubled core level peaks associated to the pnictide atoms, which are related to a surface state. Nevertheless, strong electronic dispersion along the $c$ axis, especially pronounced in EuFe$_2$P$_2$, is observed for at less one band, thus indicated that the Fe states, albeit probably affected at the surface, do not form pure two-dimensional surface states. However, this latter material shows reduced spectral weight near the Fermi level as compared to EuFe$_2$As$_2$ and EuFe$_2$As$_{1.4}$P$_{0.6}$. An anomalous jump is also found in the electronic states associated with the Eu$^{2+}$ $f$ states in EuFe$_2$P$_2$.

cond-mat.supr-con↗

arXiv2013

Yb Valence Change in (Ce,Yb)CoIn5 from spectroscopy and bulk properties

The electronic structure of (Ce,Yb)CoIn5 has been studied by a combination of photoemission, x-ray absorption and bulk property measurements. Previous findings of a Ce valence near 3+ for all x and of an Yb valence near 2.3+ for x>0.3 were confirmed. One new result of this study is that the Yb valence for x<0.2 increases rapidly with decreasing x from 2.3+ toward 3+, which correlates well with de Haas van Alphen results showing a change of Fermi surface around x=0.2. Another new result is the direct observation by angle resolved photoemission Fermi surface maps of about 50% cross sectional area reductions of the α- and β-sheets for x=1 compared to x=0, and a smaller, essentially proportionate, size change of the α-sheet for x=0.2. These changes are found to be in good general agreement with expectations from simple electron counting. The implications of these results for the unusual robustness of superconductivity and Kondo coherence with increasing x in this alloy system are discussed.

cond-mat.str-el↗

arXiv2013

Electronic superlattice revealed by resonant scattering from random impurities in Sr3Ru2O7

Resonant elastic x-ray scattering (REXS) is an exquisite element-sensitive tool for the study of subtle charge, orbital, and spin superlattice orders driven by the valence electrons, which therefore escape detection in conventional x-ray diffraction (XRD). Although the power of REXS has been demonstrated by numerous studies of complex oxides performed in the soft x-ray regime, the cross section and photon wavelength of the material-specific elemental absorption edges ultimately set the limit to the smallest superlattice amplitude and periodicity one can probe. Here we show -- with simulations and REXS on Mn-substituted Sr$_3$Ru$_2$O$_7$ -- that these limitations can be overcome by performing resonant scattering experiments at the absorption edge of a suitably-chosen, dilute impurity. This establishes that -- in analogy with impurity-based methods used in electron-spin-resonance, nuclear-magnetic resonance, and Mössbauer spectroscopy -- randomly distributed impurities can serve as a non-invasive, but now momentum-dependent probe, greatly extending the applicability of resonant x-ray scattering techniques.

cond-mat.str-el↗

arXiv2013

Photoemission Spectroscopy and the Unusually Robust One Dimensional Physics of Lithium Purple Bronze

Temperature dependent photoemission spectroscopy in Li0.9Mo6O17 contributes to evidence for one dimensional physics that is unusually robust. Three generic characteristics of the Luttinger liquid are observed, power law behavior of the k-integrated spectral function down to temperatures just above the superconducting transition, k-resolved lineshapes that show holon and spinon features, and quantum critical (QC) scaling in the lineshapes. Departures of the lineshapes and the scaling from expectations in the Tomonaga Luttinger model can be partially described by a phenomenological momentum broadening that is presented and discussed. The possibility that some form of 1d physics obtains even down to the superconducting transition temperature is assessed.

cond-mat.str-el↗

arXiv2012

A topological crystalline insulator (TCI) phase via topological phase transition and crystalline mirror symmetry

A Z2 topological insulator protected by time-reversal symmetry is realized via spin-orbit interaction driven band inversion. For example, the topological phase in the Bi-Sb system is due to an odd number of band inversions. A related spin-orbit system, the (Pb/Sn)Te class, has been known to contain an even number of inversions based on band theory. Here we experimentally investigate the possibility of a mirror symmetry protected topological crystalline insulator phase in the (Pb/Sn)Te class of materials which has been theoretically predicted to exist in its non-alloyed version. Our experimental results show that at a finite-Pb composition above the topological inversion phase transition, the surface exhibits even number of spin-polarized Dirac cone states (as opposed to odd as observed in Bi-Sb alloy or Bi2Se3) revealing mirror protected topological order distinct from that observed in Bi-Sb or Bi2Se3. Our observation of the spin-polarized Dirac surface states in the inverted (Pb/Sn)Te and their absence in the non-inverted compounds related via a topological phase transition (spin-orbit induced band inversion type) provide the experimental groundwork for opening the research on novel topological order in future quantum devices.

cond-mat.mes-hall↗